CN109486303A - A kind of flushable self-luminous marking paint composition and preparation method thereof - Google Patents
A kind of flushable self-luminous marking paint composition and preparation method thereof Download PDFInfo
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- CN109486303A CN109486303A CN201811331432.5A CN201811331432A CN109486303A CN 109486303 A CN109486303 A CN 109486303A CN 201811331432 A CN201811331432 A CN 201811331432A CN 109486303 A CN109486303 A CN 109486303A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
- C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Road Signs Or Road Markings (AREA)
- Road Repair (AREA)
Abstract
The present invention discloses a kind of flushable self-luminous marking paint composition and preparation method thereof, the coating is using PVA resin as matrix resin, by components such as addition aluminium oxide, hydrophobing agent, rare earth luminescent material, defoaming agent, levelling agent, ultraviolet absorbing agent, antibacterial agents, it is prepared using heating stirring.The present invention is with following the utility model has the advantages that compared to traditional marking paint, the present invention is using water-solubility PVA resin as matrix resin, distilled water is as solvent, rare earth luminescent material is added simultaneously, self-luminous marking paint can not only be prepared, and under the conditions of certain temperature, removing directly can be rinsed to marking paint with water, solve the problems such as traditional marking paint is difficult to clean off and changes.Raw material sources are extensively and environmentally friendly, and operating procedure is simple, and production process is generated without poisonous and harmful pollution, while material can realize recycling and reusing.
Description
Technical field
The present invention relates to a kind of flushable self-luminous marking paint compositions and preparation method thereof, belong to novel environment friendly road sign
Technical field of coatings.
Background technique
In recent years, with the increasingly raising of Living consumption, the consumer goods that automobile is increasingly becoming people enter people
Life, for pavement strip as a part in road security facility, main function is that visual guide mechanism is provided for driver, is made
Busy wagon flow can take their own roads, it is ensured that vehicle fast and safely travels, and is the important component of traffic safety.
Traditional pavement marking paint mainly based on heat molten type pavement marking paint, reaches luminous by adding reflecting beads
Purpose, Chinese patent literature CN106634310A disclose a kind of environment-friendly type aqueous marking paint and preparation method thereof, the coating
It is grouped as by two groups of A, B, wherein component A, by weight percentage, epoxy-modified acrylic emulsion 10~35%；Fluorine silicon cream
Liquid 5~25%；Wetting agent 0.1~0.5%；Dispersing agent 0.1~0.5%；Defoaming agent 0.1~0.5%；Pigment 5~15%；Filler
35~55%；Cosolvent 5~10%；Coalescing agent: 0~5%；Antifreezing agent 0~5%；Auxiliary rheological agents 0.05~0.5%；Surplus
Water；B component is aqueous epoxy curing agent, and marking paint has outstanding wearability, weatherability, stain resistance and outstanding attached
Put forth effort, it is outstanding with cement pavement binding ability, and paint film corrosion spalling will not be caused due to the anti-alkali of cement pavement.Chinese patent
Document CN104250489A discloses a kind of weather-proof reflector marker coating, and Chinese patent literature CN104250489A discloses one kind
Weather-proof reflector marker coating, but be difficult to after traditional marking paint coating, it needs to carry out using the removing coating apparatus of profession
It removes, it is time-consuming and laborious, it is that influence is huge especially for needing road reformation or traffic route to change.
Summary of the invention
It is an object of the invention to overcome traditional marking paint self-luminous and subsequent removing, providing one kind can be rushed
Self-luminous marking paint composition and preparation method thereof is washed, provides a kind of environmentally friendly, quick, reliable solution party for above-mentioned problem
Case.
The present invention is achieved by the following technical solutions:
The present invention provides a kind of flushable self-luminous marking paint compositions comprising according to parts by weight such as the following group
Point:
Preferably, the degree of polymerization of the PVA resin is 1600~1800, and alcoholysis degree is 98~100%.
This is because material is easy hydrolysis or swelling under lower temperature conditions when PVA resin polymerization degree is less than 1600,
The adhesion strength for influencing coating and road surface, when PVA resin polymerization degree is greater than 1800, material Aqueous Solution Viscosity is excessively high, is unfavorable for
Actual production.
Preferably, the shape of the aluminium oxide is sheet, and partial size is 0.5~1.5 μm, radius-thickness ratio 3~8.
This is because using partial size for 0.5~1.5 μm, the tabular alumina of radius-thickness ratio 3~8 is utilized as reinforcing material
" sliding " characteristic between tabular alumina laminated structure plays humidification, and uses class ball-type aluminium oxide or cube
Then reinforcing effect is not so good as tabular alumina to structure aluminium oxide.
Preferably, the hydrophobing agent is modified paraffin type of latex type hydrophobing agent.
Preferably, the rare earth luminescent material is at least one of cerium oxide, europium oxide, dysprosia.
Preferably, the defoaming agent is at least one of water-soluble organic silicon class and organic fluoride class.
Preferably, the levelling agent is alkyl-modified organosiloxane class levelling agent and/or polyether-modified organic
Type siloxane levelling agent.
Preferably, the ultraviolet absorbing agent is 2-hydroxy-4-n-octoxybenzophenone and 2- (2'- hydroxyl-
One or both of the tertiary phenyl of 3', 5'- bis-) -5- chlorination benzotriazole.
Preferably, the antibacterial agent is one of silver ion class antibacterial agent and quaternary ammonium salt antibacterial agent or two
Kind.
A kind of preparation method of flushable self-luminous marking paint composition as the aforementioned comprising following steps:
Distilled water is added in reaction kettle, 90~100 DEG C is heated to, PVA resin is added after starting blender stirring, to
PVA resin sequentially adds aluminium oxide, hydrophobing agent, rare earth luminescent material, defoaming agent, levelling agent, ultraviolet radiation absorption after being completely dissolved
It is stood after agent, 1~2h of antibacterial agent uniform stirring, discharges, obtain flushable self-luminous marking paint composition.
Compared with prior art, the present invention have it is following the utility model has the advantages that
1, compared to traditional marking paint, the present invention is using water-solubility PVA resin as matrix resin, and distilled water is as molten
Agent, while rare earth luminescent material is added, self-luminous marking paint can be not only prepared, but also under the conditions of certain temperature, it can be straight
It connects and removing is rinsed to marking paint with water, solve the problems such as traditional marking paint is difficult to clean off and changes.
2, it is connect for a long time with moisture as matrix resin with certain hydrophily due to coating using water-solubility PVA resin
Touching easily causes swelling to be detached from road surface, using modified paraffin type of latex type hydrophobing agent as coating hydrophobing agent, in coating table
Face forms hydrophobic layer, and barrier coating for a long time and contact with moisture, improves coating service life, can pass through again under the conditions of hot water injection
The resolution of itself melted by heating realizes that marking paint is flushable；
3, rare earth luminescent material and tabular alumina are added, not only improves the marking paint self-luminous time, but also greatly mention
The wear-resisting property of high marking paint.
4, raw material sources are extensively and environmentally friendly, and operating procedure is simple, and production process is generated without poisonous and harmful pollution, while material
Expect that recycling and reusing can be achieved.
Detailed description of the invention
Upon reading the detailed description of non-limiting embodiments with reference to the following drawings, other feature of the invention,
Objects and advantages will become more apparent upon:
Fig. 1 be using flushable self-luminous marking paint prepared by 90~100 DEG C of hot water injection's embodiment of the present invention 1 with
The not flushable self-luminous marking paint of comparative example 1 coats the appearance effects figure on road surface.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection scope.
PVA resin model used in the embodiment of the present invention are as follows: PVA17-99 (L) is selected from Wanwei High-new Technology Co., Anhui Province material strand
Part Co., Ltd；
Aluminium oxide used in the embodiment of the present invention is tabular alumina, and 0.5~1.5 μm of partial size, radius-thickness ratio 3~8 is selected from upper
Hai Jingrui Chemical Co., Ltd., model: JR-0845P；
Modified paraffin type of latex type hydrophobing agent used in the embodiment of the present invention is selected from Germany keim-additec, model: E-
360；
Rare earth cerium oxide (CeO used in the embodiment of the present invention2), rare-earth oxidation europium (Eu2O3), rare-earth oxidation dysprosium (Dy2O3)
Rare earth luminescent material is commercial product；
Defoaming agent water-soluble organic silicon class used in the embodiment of the present invention and organic fluoride class defoaming agent be Germany BYK-028 and
Guangdong Nan Hui new material Co., Ltd CI-1094；
Alkyl-modified organosiloxane class levelling agent used in the embodiment of the present invention is that Nore Chemical Co., Ltd. is thought in Changzhou
TR-9323, organic silicon modified by polyether oxygen alkanes levelling agent are that Foshan City thousand helps Chemical Co., Ltd. AKN-1131.
2-hydroxy-4-n-octoxybenzophenone used in the embodiment of the present invention and 2- (the tertiary benzene of 2'- hydroxyl -3', 5'- bis-
Base) -5- chlorination benzotriazole UV absorbers are respectively UV-531 and UVP-327, and it is commercially available.
The ws-L05 of silver ion class antibacterial agent ten thousand new material Co., Ltds in Guangzhou used in the embodiment of the present invention,
Quaternary ammonium salt antibacterial agent is selected from the DR-2141 of Dongguan City a century grand plan Chemical Industry Science Co., Ltd.
Embodiment 1
The present embodiment is related to a kind of flushable self-luminous marking paint, matches according to the following raw material and carries out ingredient:
Embodiment 2
The present embodiment is related to a kind of flushable self-luminous marking paint, matches according to the following raw material and carries out ingredient:
Embodiment 3
The present embodiment is related to a kind of flushable self-luminous marking paint, matches according to the following raw material and carries out ingredient:
Embodiment 4
The present embodiment is related to a kind of flushable self-luminous marking paint, matches according to the following raw material and carries out ingredient:
Embodiment 5
The present embodiment is related to the preparation method of flushable self-luminous marking paint, the specific steps are as follows:
Distilled water is added in reaction kettle, 90~100 DEG C is heated to, is separately added into PVA resin after starting blender stirring,
Sequentially added after PVA resin is completely dissolved aluminium oxide, hydrophobing agent, rare earth luminescent material, defoaming agent,
It stands, discharges after levelling agent, ultraviolet absorbing agent, 1~2h of antibacterial agent uniform stirring, obtain a kind of flushable spontaneous
Light marking paint.
Comparative example 1
This comparative example is related to a kind of not flushable self-luminous marking paint, matches according to the following raw material and carries out ingredient:
Comparative example 2
This comparative example is related to a kind of not flushable self-luminous marking paint, matches according to the following raw material and carries out ingredient:
Comparative example 3
This comparative example is related to a kind of flushable self-luminous marking paint, formula and preparation method and embodiment 1 basic one
It causes, the difference is that only that this comparative example is not added with tabular alumina.
Comparative example 4
This comparative example is related to a kind of flushable self-luminous marking paint, formula and preparation method and embodiment 1 basic one
It causes, the difference is that only that this comparative example uses luminescent powder for strontium carbonate class luminescent powder.
Comparative example 5
This comparative example is related to a kind of flushable self-luminous marking paint, formula and preparation method and embodiment 1 basic one
It causes, the difference is that only the aluminium oxide that this comparative example uses for ball-aluminium oxide.
Comparative example 6
This comparative example is related to a kind of flushable self-luminous marking paint, formula and preparation method and embodiment 1 basic one
It causes, the difference is that only the aluminium oxide that this comparative example uses for cube aluminium oxide.
Performance test
Examples 1 to 4 and comparative example 1~6 are tested for the property respectively, the result is shown in tables 1.
1 performance measurement result of table
From 1 result of table:
(1) Examples 1 to 4 and comparative example 1~6, the persistence of Examples 1 to 4 are substantially better than comparative example 1~6, simultaneously
Flushing can be realized with the flushable self-luminous marking paint of 90~100 DEG C of hot water injections, Examples 1 to 4 preparation,
(2) embodiment 1 and comparative example 5~6, for embodiment 1 using tabular alumina as reinforcing material, wear-resistant strength is obvious
Better than comparative example 5~6 using class ball-type aluminium oxide and cube aluminium oxide as reinforcing material.
(3) Fig. 1 is to be applied using flushable self-luminous road sign prepared by 90~100 DEG C of hot water injection's embodiment of the present invention 1
The appearance effects figure that road surface is coated with the not flushable self-luminous marking paint of comparative example 1 is expected, it is evident that embodiment 1 is using water-soluble
For property PVA resin as matrix resin, distilled water adds rare earth luminescent material as solvent, can not only prepare self-luminous
Marking paint, and under the conditions of certain temperature, removing directly can be rinsed to marking paint with water, and comparative example 1 uses
Traditional non-water soluble material prepares marking paint, exists and is difficult to the problems such as cleaning, and therefore, the present invention is applied for solving traditional road sign
The problems such as material is difficult to clean off and changes is with important directive significance.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring substantive content of the invention.
Claims (10)
1. a kind of flushable self-luminous marking paint composition, which is characterized in that including following component according to parts by weight:
2. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the PVA resin gathers
Right is 1600~1800, and alcoholysis degree is 98~100%.
3. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the shape of the aluminium oxide
For sheet, partial size is 0.5~1.5 μm, radius-thickness ratio 3~8.
4. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the hydrophobing agent is to be modified
Paraffin wax emulsions class hydrophobing agent.
5. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the rare earth luminescent material
For at least one of cerium oxide, europium oxide, dysprosia.
6. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the defoaming agent is water-soluble
Property at least one of organic silicon and organic fluoride class.
7. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the levelling agent is alkyl
Azo polyether polyeste class levelling agent and/or organic silicon modified by polyether oxygen alkanes levelling agent.
8. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the ultraviolet absorbing agent
For one in 2-hydroxy-4-n-octoxybenzophenone and 2- (the tertiary phenyl of 2'- hydroxyl -3', 5'- bis-) -5- chlorination benzotriazole
Kind or two kinds.
9. flushable self-luminous marking paint composition as described in claim 1, which is characterized in that the antibacterial agent be silver from
One or both of subclass antibacterial agent and quaternary ammonium salt antibacterial agent.
10. a kind of preparation side of the flushable self-luminous marking paint composition as described in any one of claim 1~9
Method, which comprises the steps of:
Distilled water is added in reaction kettle, 90~100 DEG C is heated to, PVA resin is added after starting blender stirring, to PVA tree
Rouge sequentially adds aluminium oxide, hydrophobing agent, rare earth luminescent material, defoaming agent, levelling agent, ultraviolet absorbing agent, resists after being completely dissolved
It is stood after 1~2h of microbial inoculum uniform stirring, discharges, obtain flushable self-luminous marking paint composition.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811331432.5A CN109486303B (en) | 2018-11-09 | 2018-11-09 | Washable self-luminous road sign coating composition and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811331432.5A CN109486303B (en) | 2018-11-09 | 2018-11-09 | Washable self-luminous road sign coating composition and preparation method thereof |
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| CN109486303A true CN109486303A (en) | 2019-03-19 |
| CN109486303B CN109486303B (en) | 2020-12-15 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115058150A (en) * | 2022-07-02 | 2022-09-16 | 苏州中亚油墨有限公司 | High-glossiness composite ink for film printing and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115058150A (en) * | 2022-07-02 | 2022-09-16 | 苏州中亚油墨有限公司 | High-glossiness composite ink for film printing and preparation method thereof |
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| CN109486303B (en) | 2020-12-15 |
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