CN109485108A - A kind of printing and dyeing wastewater treatment agent - Google Patents
A kind of printing and dyeing wastewater treatment agent Download PDFInfo
- Publication number
- CN109485108A CN109485108A CN201811583913.5A CN201811583913A CN109485108A CN 109485108 A CN109485108 A CN 109485108A CN 201811583913 A CN201811583913 A CN 201811583913A CN 109485108 A CN109485108 A CN 109485108A
- Authority
- CN
- China
- Prior art keywords
- parts
- printing
- treatment agent
- wastewater treatment
- dyeing wastewater
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 25
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 239000010802 sludge Substances 0.000 claims abstract description 10
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 241000196324 Embryophyta Species 0.000 claims abstract description 7
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 7
- 229940037003 alum Drugs 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- 239000004411 aluminium Substances 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 7
- 239000000440 bentonite Substances 0.000 claims abstract description 7
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 7
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 7
- 239000010452 phosphate Substances 0.000 claims abstract description 7
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 7
- 235000009566 rice Nutrition 0.000 claims abstract description 7
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 7
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 7
- 239000000661 sodium alginate Substances 0.000 claims abstract description 7
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 6
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 6
- 239000010902 straw Substances 0.000 claims abstract description 6
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 22
- 239000010439 graphite Substances 0.000 claims description 15
- 229910002804 graphite Inorganic materials 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 7
- 241000209094 Oryza Species 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- -1 alum Chemical compound 0.000 claims description 3
- 229940010048 aluminum sulfate Drugs 0.000 claims description 3
- 229940092782 bentonite Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 229960001781 ferrous sulfate Drugs 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 239000005955 Ferric phosphate Substances 0.000 claims 1
- 229940032958 ferric phosphate Drugs 0.000 claims 1
- 229910000399 iron(III) phosphate Inorganic materials 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 239000010865 sewage Substances 0.000 abstract description 6
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 238000000034 method Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000002306 biochemical method Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/30—Nature of the water, waste water, sewage or sludge to be treated from the textile industry
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The application belongs to sewage treatment field, specially a kind of printing and dyeing wastewater treatment agent, the raw material including following portions by weight, 15 parts of river sludge, 21 parts of rice straw, 27 parts of ferric trichloride, 9 parts of ferrous sulfate, 11 parts of sodium alginate, 15 parts of aluminum sulfate, 7 parts of alum, 5 parts of bentonite, 12 parts of plant ash, 3 parts of graphite powder, 17 parts of polymer phosphate aluminium, 19 parts of polymer phosphate iron, it is poly- 20 parts, 22 parts of polyacrylamide ferrous.
Description
Technical field
The application belongs to sewage treatment field, specially a kind of printing and dyeing wastewater treatment agent.
Background technique
Printing and dyeing are also referred to as dyeing and finishing, are a kind of processing method and pre-treatment, dyeing, stamp, final finishing, wash water etc.
The waste component of general name, the waste water of generation of printing and dyeing and other industry difference, and dyeing and printing sewage processing difficulty is bigger.With
In the processing method that the main method for the treatment of of dyeing wastewater has physico-chemical process, biochemical method, chemical method and several techniques to combine.But
Dyeing waste water is since waste water is complex in composition, chemical stability is good, it is difficult to life degradation, be difficult processed industrial wastewater it
One.
Summary of the invention
In order to solve the above-mentioned technical problem, this application provides a kind of printing and dyeing wastewater treatment agent, the application is by following
What scheme was realized:
A kind of printing and dyeing wastewater treatment agent, the raw material including following portions by weight, 15 parts of river sludge, 21 parts of rice straw, trichlorine
27 parts of iron of change, 9 parts of ferrous sulfate, 11 parts of sodium alginate, 15 parts of aluminum sulfate, 7 parts of alum, 5 parts of bentonite, 12 parts of plant ash, stone
3 parts of ink powder, 17 parts of polymer phosphate aluminium, 19 parts of polymer phosphate iron, gather 20 parts, 22 parts of polyacrylamide ferrous.
Preferably, preparation method includes the following steps: that (1) river sludge is uniformly mixed with water, makes the aqueous of river sludge
Rate is 86%, and rear be added is uniformly mixed by the rice straw crushed, and 29h is stood at 50 DEG C and obtains mixing one；(2) ferric trichloride,
Ferrous sulfate, sodium alginate, aluminum sulfate, alum, bentonite, plant ash and graphite powder are placed in spheroidal graphite tank pulverize after in 80
Mixing two is dried to obtain at DEG C；(3) polymer phosphate aluminium, polymer phosphate iron, poly- ferrous and polyacrylamide are placed in another spheroidal graphite tank
In pulverize after mixing three；(4) mixing one, mixing two, mixing three are prepared into particle with pelletizer after mixing；
(5) particle is heat-treated.
Preferably, abrasive media is the alcohol water blend that mass fraction is 23% in spheroidal graphite tank in the step (2), grinding
It is 100-150um to fineness.
Preferably, abrasive media is steel ball in step (3) the spheroidal graphite tank, and the spheroidal graphite time is 1h, revolving speed 800r/min.
Preferably, the heat treatment of the step (5) includes four-stage: first stage, particle are at the uniform velocity warming up to by room temperature
30min is kept the temperature after 300 DEG C；Second stage is at the uniform velocity warming up to 500 DEG C by 300 DEG C, keeps the temperature 30min；It is phase III, even by 500 DEG C
Speed is warming up to 700 DEG C, keeps the temperature 3h；Fourth stage is cooled to room temperature by 700 DEG C.
Preferably, the heating rate of the first stage is 6 DEG C/min.
Preferably, the heating rate of the second stage is 7 DEG C/min.
Preferably, the heating rate of the phase III is 5 DEG C/min.
Preferably, the cooling rate of the fourth stage is 5 DEG C/min.
The utility model has the advantages that the application step of preparation process is simple, strong operability, the application compounds each raw material, Tong Geyuan
The synergistic effect of material by dyeing and printing sewage handle for colourless, tasteless, COD value it is low can direct emission water.
Specific embodiment
Embodiment 1
A kind of printing and dyeing wastewater treatment agent, the raw material including following portions by weight, 15 parts of river sludge, 21 parts of rice straw, trichlorine
27 parts of iron of change, 9 parts of ferrous sulfate, 11 parts of sodium alginate, 15 parts of aluminum sulfate, 7 parts of alum, 5 parts of bentonite, 12 parts of plant ash, stone
3 parts of ink powder, 17 parts of polymer phosphate aluminium, 19 parts of polymer phosphate iron, gather 20 parts, 22 parts of polyacrylamide ferrous；
Preferably, preparation method includes the following steps: that (1) river sludge is uniformly mixed with water, makes the moisture content of river sludge
86%, rear be added is uniformly mixed by the rice straw crushed, and 29h is stood at 50 DEG C and obtains mixing one；(2) ferric trichloride, sulfuric acid
Ferrous iron, sodium alginate, aluminum sulfate, alum, bentonite, plant ash and graphite powder are placed in spheroidal graphite tank pulverize after at 80 DEG C
Dry to obtain mixing two；(3) polymer phosphate aluminium, polymer phosphate iron, poly- ferrous and polyacrylamide are placed in another spheroidal graphite tank and are ground
Mixing three is obtained after grinds；(4) mixing one, mixing two, mixing three are prepared into particle with pelletizer after mixing；(5) will
Particle is heat-treated；
Preferably, abrasive media is the alcohol water blend that mass fraction is 23% in spheroidal graphite tank in the step (2), is ground to thin
Degree is 100-150um；
Preferably, abrasive media is steel ball in step (3) the spheroidal graphite tank, and the spheroidal graphite time is 1h, revolving speed 800r/min；
Preferably, the heat treatment of the step (5) includes four-stage: first stage, particle are at the uniform velocity warming up to 300 DEG C by room temperature
After keep the temperature 30min；Second stage is at the uniform velocity warming up to 500 DEG C by 300 DEG C, keeps the temperature 30min；Phase III is at the uniform velocity risen by 500 DEG C
Temperature keeps the temperature 3h to 700 DEG C；Fourth stage is cooled to room temperature by 700 DEG C；
Preferably, the heating rate of the first stage is 6 DEG C/min；
Preferably, the heating rate of the second stage is 7 DEG C/min；
Preferably, the heating rate of the phase III is 5 DEG C/min；
Preferably, the cooling rate of the fourth stage is 5 DEG C/min.
Inorganic agent prepared by embodiment is added into the dyeing and printing sewage handled by simple filtration, the additional amount of inorganic agent is
0.9-1.5g/L stands to obtain supernatant after stirring 1h, by the sewage of this method single treatment 1t, 5t, 10t, measures supernatant and obtain
The following table of indices:
Discharge standard is reached by top clear water prepared by the application it can be seen from above table.
Claims (9)
1. a kind of printing and dyeing wastewater treatment agent, which is characterized in that the raw material including following portions by weight, 15 parts of river sludge, rice
21 parts of stalk, 27 parts of ferric trichloride, 9 parts of ferrous sulfate, 11 parts of sodium alginate, 15 parts of aluminum sulfate, 7 parts of alum, 5 parts of bentonite,
12 parts of plant ash, 3 parts of graphite powder, 17 parts of polymer phosphate aluminium, 19 parts of polymer phosphate iron, gather 20 parts, 22 parts of polyacrylamide ferrous.
2. a kind of printing and dyeing wastewater treatment agent as described in claim 1, which is characterized in that preparation method includes the following steps: (1)
River sludge is uniformly mixed with water, makes the moisture content 86% of river sludge, and the rear rice straw mixing being added by crushing is equal
It is even, 29h, which is stood, at 50 DEG C obtains mixing one；(2) ferric trichloride, ferrous sulfate, sodium alginate, aluminum sulfate, alum, bentonite,
Plant ash and graphite powder are placed in spheroidal graphite tank pulverize after mixing two is dried to obtain at 80 DEG C；(3) by polymer phosphate aluminium, polymerization
Ferric phosphate, poly- ferrous and polyacrylamide are placed in another spheroidal graphite tank after pulverizing and obtain mixing three；(4) by mixing one, mixing
Two, mixing three is prepared into particle with pelletizer after mixing；(5) particle is heat-treated.
3. a kind of printing and dyeing wastewater treatment agent as claimed in claim 2, which is characterized in that ground in spheroidal graphite tank in the step (2)
Grinding media is the alcohol water blend that mass fraction is 23%, and being ground to fineness is 100-150um.
4. a kind of printing and dyeing wastewater treatment agent as claimed in claim 2, which is characterized in that ground in step (3) the spheroidal graphite tank
Medium is steel ball, and the spheroidal graphite time is 1h, revolving speed 800r/min.
5. a kind of printing and dyeing wastewater treatment agent as claimed in claim 2, which is characterized in that the heat treatment of the step (5) includes
Four-stage: first stage, particle keep the temperature 30min after being at the uniform velocity warming up to 300 DEG C by room temperature；Second stage is at the uniform velocity risen by 300 DEG C
Temperature keeps the temperature 30min to 500 DEG C；Phase III is at the uniform velocity warming up to 700 DEG C by 500 DEG C, keeps the temperature 3h；Fourth stage, it is cold by 700 DEG C
But to room temperature.
6. a kind of printing and dyeing wastewater treatment agent as claimed in claim 5, which is characterized in that the heating rate of the first stage is
6℃/min。
7. a kind of printing and dyeing wastewater treatment agent as claimed in claim 5, which is characterized in that the heating rate of the second stage is
7℃/min。
8. a kind of printing and dyeing wastewater treatment agent as claimed in claim 5, which is characterized in that the heating rate of the phase III is
5℃/min。
9. a kind of printing and dyeing wastewater treatment agent as claimed in claim 5, which is characterized in that the cooling rate of the fourth stage is
5℃/min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811583913.5A CN109485108A (en) | 2018-12-24 | 2018-12-24 | A kind of printing and dyeing wastewater treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811583913.5A CN109485108A (en) | 2018-12-24 | 2018-12-24 | A kind of printing and dyeing wastewater treatment agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109485108A true CN109485108A (en) | 2019-03-19 |
Family
ID=65711588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811583913.5A Pending CN109485108A (en) | 2018-12-24 | 2018-12-24 | A kind of printing and dyeing wastewater treatment agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109485108A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103084143A (en) * | 2013-01-28 | 2013-05-08 | 安徽工程大学 | Two-pore zeolite microsphere and preparation method thereof |
| US8981250B2 (en) * | 2001-07-16 | 2015-03-17 | Foret Plasma Labs, Llc | Apparatus for treating a substance with wave energy from plasma and an electrical Arc |
| CN105692846A (en) * | 2016-04-20 | 2016-06-22 | 张能力 | Multi-effect sewage treatment flocculating agent and preparation method thereof |
| CN106006780A (en) * | 2016-06-23 | 2016-10-12 | 江苏保瑞工业水处理有限公司 | Sewage treatment chemical |
| CN107572635A (en) * | 2017-11-06 | 2018-01-12 | 广东石油化工学院 | A kind of preparation method of waste water light electrolysis iron carbon filler |
| CN108751294A (en) * | 2018-09-07 | 2018-11-06 | 滨州学院 | Sewage-treating agent |
-
2018
- 2018-12-24 CN CN201811583913.5A patent/CN109485108A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8981250B2 (en) * | 2001-07-16 | 2015-03-17 | Foret Plasma Labs, Llc | Apparatus for treating a substance with wave energy from plasma and an electrical Arc |
| CN103084143A (en) * | 2013-01-28 | 2013-05-08 | 安徽工程大学 | Two-pore zeolite microsphere and preparation method thereof |
| CN105692846A (en) * | 2016-04-20 | 2016-06-22 | 张能力 | Multi-effect sewage treatment flocculating agent and preparation method thereof |
| CN106006780A (en) * | 2016-06-23 | 2016-10-12 | 江苏保瑞工业水处理有限公司 | Sewage treatment chemical |
| CN107572635A (en) * | 2017-11-06 | 2018-01-12 | 广东石油化工学院 | A kind of preparation method of waste water light electrolysis iron carbon filler |
| CN108751294A (en) * | 2018-09-07 | 2018-11-06 | 滨州学院 | Sewage-treating agent |
Non-Patent Citations (1)
| Title |
|---|
| 张启龙等: "《中国战略新兴产业.新材料.功能陶瓷材料与器件》", 31 December 2017, 中国铁道出版社 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20190319 |