CN109482990A - The method that sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining - Google Patents
The method that sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining Download PDFInfo
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- CN109482990A CN109482990A CN201811416749.9A CN201811416749A CN109482990A CN 109482990 A CN109482990 A CN 109482990A CN 201811416749 A CN201811416749 A CN 201811416749A CN 109482990 A CN109482990 A CN 109482990A
- Authority
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- China
- Prior art keywords
- sodium nitrate
- ethylene glycol
- aluminium
- electrolyte
- processing
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 44
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000003792 electrolyte Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 37
- -1 sodium nitrate ethylene glycol Chemical compound 0.000 title claims abstract description 26
- 239000004411 aluminium Substances 0.000 title abstract description 38
- 238000005459 micromachining Methods 0.000 title abstract description 19
- 238000012545 processing Methods 0.000 claims abstract description 33
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical group [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 32
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 16
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 3
- 238000003754 machining Methods 0.000 claims description 21
- 239000000463 material Substances 0.000 abstract description 5
- 238000003672 processing method Methods 0.000 abstract description 4
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000000243 solution Substances 0.000 description 10
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009760 electrical discharge machining Methods 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23H—WORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
- B23H3/00—Electrochemical machining, i.e. removing metal by passing current between an electrode and a workpiece in the presence of an electrolyte
- B23H3/08—Working media
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
Abstract
A kind of method that sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining, belongs to technical field of electrolysis processing.The present invention is characterized in that proposing a kind of sodium nitrate ethylene glycol electrolyte and its processing method for aluminium electrochemical micromachining, it is characterised in that: solute is sodium nitrate in above-mentioned sodium nitrate ethylene glycol solution, and solvent is ethylene glycol；Concentration of the above-mentioned sodium nitrate ethylene glycol solution at 20 DEG C is 0.2 ~ 1mol/L；Above-mentioned sodium nitrate ethylene glycol solution is suitable for the electrochemical micromachining of aluminium, and the cost of material is low, and preparation method is easy, and processing quality is good.
Description
Technical field
A kind of sodium nitrate ethylene glycol electrolyte and its processing method for aluminium electrochemical micromachining, belong to Electrolyzed Processing skill
Art field.
Background technique
Aluminium is a kind of silvery white light metal, and density is small, only 2.7 g/cm3, has good conductive and heating conduction, height
Reflexive and oxidative resistance and be widely used in micro parts.In the field MEMS, aluminium is processed to core model of various shapes,
For making cavity shape complexity, the high micro parts of required precision such as have the Feed Horn of corrugated inner surface structure, also
Waveguide class device etc. for THz wave transmission.
The processing method of aluminum current mainly includes plastic processing, machining, electrical discharge machining, high energy beam machining etc..
Plastic processing is mainly used to process heavy parts, is not suitable for carrying out microfabrication.When micro-cutting processes aluminium, there is workpiece tables
The disadvantages of face easily scratches, and is easily deformed after processing, generates burr.India scholar R.K.Arya etc., which is proposed, utilizes Powder-mixed EDM
The method of processing processes aluminum matrix composite, and after being mixed into graphite particle in emulsion, material removing rate is reduced, workpiece table
Face quality is improved, but inevitably generates re cast layer in workpiece surface.Louisiana Polytechnics, the U.S.
Adams etc. processes microflute in revolving body aluminum alloy surface using ion beam, and the width of mini longitudinal channels processed is 13.2M, groove depth 4M, but there are apparent burr phenomenas for workpiece surface.
Electrochemical micromachining technology is as a kind of electrical-chemistry method technology, the basic principle is that being dissolved using Anodic
To remove material.Cathode tool is not contacted with anode workpiece in electrochemical micromachining, does not generate cutting heat, without processing hardening
And heat affected area, and cathode tool is substantially lossless.Therefore, electrochemical micromachining technology is usually used in processing various difficult cutting materials
Material and thin-walled, easily-deformable workpiece.
Electrolyte is most important component part in electrochemical micromachining system, it to the electrochemical reaction of anode material,
Rate of dissolution and machining accuracy play decisive role.Meanwhile electrolyte can also take away the bubble of machining area generation, metal
Cation, insoluble product and Joule heat etc..Since the chemical property of aluminium is more active, the Electrolyzed Processing of aluminium often selects passivation type
Electrolyte such as sodium nitrate aqueous solution.But aluminium, due to the effect of oxygen/water molecule, is easy to produce passivating film in water based electrolyte.
In process, the fault location of passivating film can generate spot corrosion first, with the continuous destruction and formation of passivating film, so that processing
Difficulty, processing quality are deteriorated.In addition, processing product of the aluminium in water based electrolyte is flocculent undissolved substance, minute yardstick is easily blocked
Gap is processed, processing stability is influenced.
A kind of sodium nitrate ethylene glycol electrolyte proposed by the present invention and its processing method for aluminium electrochemical micromachining, solution
Having determined, processing efficiency is low in traditional water based electrolyte for aluminium, and surface quality is poor, the unstable problem of process.It is of the present invention
Sodium nitrate ethylene glycol electrolyte prepare easy, at low cost, machining accuracy is high, and surface quality is good.
Summary of the invention
Present invention aims at propose a kind of method that sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining, solution
Certainly aluminium machined surface quality in traditional water based electrolyte is poor, the low problem of machining accuracy.
A kind of method that sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining, it is characterised in that: above-mentioned sodium nitrate
Solute is sodium nitrate in ethylene glycol electrolyte, and solvent is ethylene glycol；Concentration of the above-mentioned sodium nitrate ethylene glycol electrolyte at 20 DEG C
For 0.2 ~ 1mol/L；Machining voltage is 6V ~ 12V.
Electrochemical micromachining technology does not generate cutting heat without cutting force, and it is variable to efficiently solve aluminium in tradition machinery processing
Shape has residual stress, the poor problem of machined surface quality.Aluminium is easy to produce passivating film in water based electrolyte, so that processing
Difficulty, processing quality are deteriorated.In addition, processing product of the aluminium in water based electrolyte is flocculent undissolved substance, minute yardstick is easily blocked
Gap is processed, processing stability is influenced.And sodium nitrate ethylene glycol electrolyte of the present invention, since hydrone content is extremely low,
The generation of oxygen in process is avoided, the passivating film of aluminium surface is difficult to regenerate again after being destroyed, ensure that processed
The stability of journey.Meanwhile processing product of the aluminium in sodium nitrate ethylene glycol electrolyte be it is soluble, processing district will not be blocked
Domain ensure that the stability of processing.In general, concentration of electrolyte is higher, voltage is higher, then the efficiency of Electrolyzed Processing is higher,
But excessively high concentration of electrolyte and machining voltage will affect machining accuracy, and generate dispersion corrosion.In general, using higher
Frequency, lower duty ratio is conducive to the exclusion of machining area product, the update of electrolyte, so that processing effect is more preferable.
The method that the sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining, it is characterised in that: electrolyte is dense
Spend 1mol/L, machining voltage 8V.
The method that the sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining, it is characterised in that: frequency 100 ~
300KHz, duty ratio 15 ~ 30%, 0.1 ~ 0.2 μm/s of process velocity.In general, using higher frequency (being greater than 100KHz),
Lower duty ratio (less than 30%) is conducive to the exclusion of machining area product, the update of electrolyte, so that processing effect is more preferable.
The method that the sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining, it is characterised in that: frequency
200KHz, duty ratio 20%, 0.2 μm/s of process velocity.
Detailed description of the invention
Fig. 1 is the schematic diagram of aluminium electrochemical micromachining；
Fig. 2 is the scanning electron microscope (SEM) photograph of embodiment 1；
Fig. 3 is the scanning electron microscope (SEM) photograph of embodiment 2；
Fig. 4 is the scanning electron microscope (SEM) photograph of embodiment 3；
Fig. 5 is the scanning electron microscope (SEM) photograph of embodiment 4；
Fig. 6 is the scanning electron microscope (SEM) photograph of embodiment 5；
Its label is entitled: 1, electrolyte；2, screw electrode；3, the pulse power；4, aluminium workpiece；5, ethylene glycol；6, sodium nitrate；7,
Deionized water.
Specific embodiment
Electrolyte 1 is poured into electrolytic bath first, submerges screw electrode 2 and aluminium workpiece 4.
The pulse power 3 is connect into positive aluminium workpiece 4, cathode connects screw electrode 2, and make pulse power supply 3 utilizes Anodic
Solution principle processes aluminium workpiece 4 by the numerical control campaign of screw electrode 2, can process slit structure.The pulse power
3 output voltage range is 5 ~ 20V, duty ratio 10 ~ 80%, frequency 1KHz ~ 500KHz.Optional 0.1 μm/s ~ 2 of process velocity range
μm/s。
Technical solution of the present invention and its advantages are described further below with reference to embodiment.Nitre is used by comparison
Acid sodium aqueous solution and sodium nitrate ethylene glycol solution carry out the effect of aluminium electrochemical micromachining, illustrate sodium nitrate ethylene glycol of the invention
Electrolyte can solve aluminium, and processing efficiency is low in traditional water based electrolyte, and surface quality is poor, the unstable problem of process.
Embodiment 1
15g sodium nitrate is added in deionized water under room temperature, is configured to 1L solution, the sodium nitrate 6 is to analyze pure, deionized water
7 be industry standard reagent.Pulse power anode is connect into aluminium workpiece, cathode connects screw electrode, using 8V voltage, 10% duty ratio,
10KHz frequency, 0.2 μm/s of process velocity.The slit that processes is deposited bright around machining area as shown in Fig. 2, slit pattern is poor
Aobvious dispersion corrosion.
Embodiment 2
1mol sodium nitrate is added in ethylene glycol under room temperature, is configured to 1L solution, the sodium nitrate 6 is to analyze pure, deionized water 5
It is pure to analyze.Pulse power anode is connect into aluminium workpiece, cathode connects screw electrode, using 6V voltage, 20% duty ratio, 200KHz frequency
Rate, 0.1 μm/s of process velocity.The slit that processes as shown in figure 3, without dispersion corrosion around machining area, but due to voltage compared with
Small, permitted feed speed also very little, processing efficiency is lower, and will appear short circuit phenomenon once in a while in processing.
Embodiment 3
1mol sodium nitrate is added in ethylene glycol under room temperature, is configured to 1L solution, the sodium nitrate 6 is to analyze pure, deionized water 5
It is pure to analyze.Pulse power anode is connect into aluminium workpiece, cathode connects screw electrode, using 8V voltage, 20% duty ratio, 200KHz frequency
Rate, 0.2 μm/s of process velocity.The slit that processes is as shown in figure 4, the slit pattern processed is good, base around machining area
, without dispersion corrosion, surface quality is good for this, and process is stablized, and slit width consistency is good.
Embodiment 4
1mol sodium nitrate is added in ethylene glycol under room temperature, is configured to 1L solution, the sodium nitrate 6 is to analyze pure, deionized water 5
It is pure to analyze.Pulse power anode is connect into aluminium workpiece, cathode connects screw electrode, using 12V voltage, 20% duty ratio, 200KHz frequency
Rate, 0.2 μm/s of process velocity.The slit that processes is as shown in figure 5, the slit width consistency processed is poor, and with electricity
Pressure increases, and will appear point corrosion around machining area, and surface quality reduces.
Embodiment 5
0.2mol sodium nitrate is added in ethylene glycol under room temperature, is configured to 1L solution, the sodium nitrate 6 is to analyze pure, deionization
Water 5 is that analysis is pure.Pulse power anode is connect into aluminium workpiece, cathode connects screw electrode, using 8V voltage, 20% duty ratio, 200KHz
Frequency, 0.2 μm/s of process velocity.The slit processed is as shown in fig. 6, substantially without dispersion corrosion, surface matter around machining area
It measures, and process is basicly stable, slit width consistency is preferable.
Claims (4)
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| CN201811416749.9A CN109482990A (en) | 2018-11-26 | 2018-11-26 | The method that sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining |
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|---|---|---|---|
| CN201811416749.9A CN109482990A (en) | 2018-11-26 | 2018-11-26 | The method that sodium nitrate ethylene glycol electrolyte is used for aluminium electrochemical micromachining |
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Cited By (4)
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| CN110560806A (en) * | 2019-08-20 | 2019-12-13 | 南京航空航天大学 | Method for finely electrolyzing and processing titanium and aluminum by sodium chloride and ethylene glycol electrolyte |
| CN111014854A (en) * | 2019-11-15 | 2020-04-17 | 鞍钢集团矿业有限公司 | Electrolyte for titanium alloy micro-electrochemical machining and preparation method thereof |
| CN111545850A (en) * | 2020-05-11 | 2020-08-18 | 南京航空航天大学 | Electrolytic EDM Composite Wire Cutting Processing Method of Ethylene Glycol-Based Solution |
| CN112008166A (en) * | 2019-05-29 | 2020-12-01 | 天津大学 | Electrolyte for nickel-titanium memory alloy micro-electrochemical machining |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112008166A (en) * | 2019-05-29 | 2020-12-01 | 天津大学 | Electrolyte for nickel-titanium memory alloy micro-electrochemical machining |
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Application publication date: 20190319 |