CN109479896A - Bactericidal composition and its preparing the application in antibacterial fabric - Google Patents
Bactericidal composition and its preparing the application in antibacterial fabric Download PDFInfo
- Publication number
- CN109479896A CN109479896A CN201811391357.1A CN201811391357A CN109479896A CN 109479896 A CN109479896 A CN 109479896A CN 201811391357 A CN201811391357 A CN 201811391357A CN 109479896 A CN109479896 A CN 109479896A
- Authority
- CN
- China
- Prior art keywords
- parts
- bactericidal composition
- ammonium chloride
- octadecyldimethyl
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Biochemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of bactericidal composition and its preparing the application in antibacterial fabric.The bactericidal composition includes octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride and methanol.In parts by weight, the bactericidal composition includes 0.0008 part~0.5 part octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.0008 part~0.5 part of methanol.The present invention selects the combination of octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, methanol as antibiotic effective ingredient, forms specific bactericidal composition.When being used to prepare antibacterial fabric as effective component preparation antimicrobial fluid using the bactericidal composition, when being especially used to prepare antibacterial nonwoven cloth, it can be achieved with good antibacterial effect in the case where required effective component concentration is very low, and antibacterial time is obviously prolonged, and especially antibacterial fabric is to no skin irritation.
Description
Technical field
The present invention relates to technical field of textile auxiliary agent, more particularly to a kind of bactericidal composition and its in preparation antibacterial weaving
Application in product.
Background technique
Current textile, especially bonded fabric product are rich in color, bright-coloured bright and beautiful, Eco-Fashion, widely used, beautiful
See generous, pattern and style are all various, and light, environmentally friendly, recyclable, are the environmental protection for ecology of preserving our planet by internationally recognized
Product.Suitable for agricultural film, shoemaking, process hides, mattress, child-mother-covering, decoration, chemical industry, printing, automobile, building materials, the row such as furniture
Industry and dress lining cloth, cap, sheet, the disposable tablecloth in hotel, beauty, the gift bag of Saunas or even current fashion, fine work bag, purchase
Object bag, advertising bag etc., particularly useful for making health care disposable surgical clothing, mask, sanitary napkin, diaper etc..
In the application of textile, the realization of antibacterial functions is very crucial.The preparation of traditional antibacterial fabric
Such as: the textile sterilization processing agent used is in parts by weight, comprising: vinyl acetate 6~8, methanol 10~20, O-phthalic
Dibutyl phthalate 4~6, triethylene tetramine 1~3, polyoxypropylene triol 3~8, ethyl methacrylate 30~50；Also have using such as
Lower antibacterial finishing agent: by 2~3 mass parts polyoxyethylene oleic acid esters, 1~2 mass parts trifluoromethyl acardite, 15~17 mass parts
3- (trimethoxysilyl) propyl-dimethyl octadecyl ammonium chloride and the mixing of 4~5 mass parts sorbic acids, then delay simultaneously
It is slow that 1~2 mass parts polypropylene glycol, 6~8 mass parts alkyl vinyl ureas, 20~25 mass parts zinc oxide and 7~8 mass parts are added
Aluminum zirconium coupling agent feeds intake in 30~35 minutes and finishes, and continuess to mix 1.5~2.5 hours；There are also use following antibiotic finish
Agent: use octadecyldimethyl (3- trimethoxysilylpropyl) ammonium chloride 65~75%, organosiloxane D420~30%,
TMPTMA2~5% adds water to be configured to 10~50g/L.Although can make to weave to a certain extent using these antibacterial fabrics
Product play antibacterial effect, but the antibacterial time limit is shorter, and used chemical concentration is higher, irritation is strong, is not suitable for
Prepare health care disposable surgical clothing, mask, sanitary napkin, diaper etc..
It would therefore be highly desirable to provide it is a kind of with long acting antibiotic effect and low concentration, without the antimicrobial fluid of skin irritation.
Summary of the invention
Based on this, the main object of the present invention is to provide a kind of bactericidal composition.Using the bactericidal composition as effective component
When preparation antimicrobial fluid is used to prepare antibacterial fabric (especially non-woven fabrics), in the required lower situation of effective component concentration just
It is able to achieve good antibacterial effect, and antibacterial time is obviously prolonged, especially antibacterial fabric is to no skin irritation.
The purpose of the present invention is what is be achieved through the following technical solutions.
A kind of bactericidal composition, in parts by weight, the bactericidal composition include 0.0008 part~0.5 part of octadecane
Base dimethyl (3- methoxy silane base propyl) ammonium chloride, 0.0008 part~0.5 part of methanol.
In wherein some embodiments, in parts by weight, the bactericidal composition includes the 18 of 0.1 part~0.4 part
Alkyl dimethyl (3- methoxy silane base propyl) ammonium chloride, 0.1 part~0.32 part of methanol.
In wherein some embodiments, in parts by weight, the bactericidal composition includes the ten of 0.16 part~0.35 part
Eight alkyl dimethyls (3- methoxy silane base propyl) ammonium chloride, 0.16 part~0.25 part of methanol.
It is a further object of the present invention to provide a kind of above-mentioned bactericidal compositions to prepare answering in antimicrobial fluid used for textiles
With.
A further object of the invention is to provide a kind of antimicrobial fluid used for textiles, in parts by weight, weaving described in every 100 parts
Product octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride that antimicrobial fluid includes 0.0008 part~0.5 part,
0.0008 part~0.5 part of methanol, 0 part~1 part of hydrophilic agent and 98 parts~99.998 parts of water.
In wherein some embodiments, in parts by weight, antimicrobial fluid used for textiles described in every 100 parts includes 0.1 part~
0.4 part octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.1 part~0.32 part of methanol, 0 part~1 part
Hydrophilic agent and 98.28 parts~99.8 parts of water.
In wherein some embodiments, in parts by weight, the antimicrobial fluid used for textiles includes 0.16 part~0.35 part
Octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.16 part~0.25 part of methanol, 0 part~1 part of parent
Aqua and 98.4 parts~99.68 parts of water.
It can be realized antibacterial and hydrophilic double effects after addition hydrophilic agent in antimicrobial fluid used for textiles of the invention.
In wherein some embodiments, the hydrophilic agent is SILASTOL PHP-01.
Another object of the present invention is to provide a kind of preparation method of antibacterial fabric, and the preparation method includes as follows
Step:
Take textile and above-mentioned antimicrobial fluid used for textiles；The textile is soaked with the antimicrobial fluid used for textiles
It is wet uniformly after it is dry to get.
In wherein some embodiments, the textile is non-woven fabrics.
It is yet another object of the invention to provide a kind of antibacterial fabrics, are obtained by above-mentioned preparation method.
Compared with prior art, the present invention have it is following the utility model has the advantages that
The present invention selects the combination of octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, methanol as antibacterial
Effective component forms specific bactericidal composition.Antimicrobial fluid, which is prepared, as effective component using the bactericidal composition is used to prepare antibacterial
When textile (especially non-woven fabrics), good antibacterial effect can be achieved in the case where required effective component concentration is very low,
And antibacterial time is obviously prolonged, and for especially antibacterial fabric to no skin irritation, such characteristic makes the antibacterial weave
Product are highly suitable for preparing disposable sanitary articles, such as diaper, sanitary napkin etc..
Specific embodiment
It to facilitate the understanding of the present invention, below will be to invention is more fully described.But the present invention can be to be permitted
Mostly different form is realized, however it is not limited to embodiment described herein.On the contrary, purpose of providing these embodiments is makes
It is more thorough and comprehensive to the understanding of the disclosure.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein "and/or" includes one or more phases
Any and all combinations of the listed item of pass.
The hydrophilic agent that the present embodiment uses is commercially available for SILASTOL PHP-01.
Examples 1 to 6
Embodiment 1 to 6 is provided a kind of bactericidal composition respectively and is prepared using the bactericidal composition as effective component anti-
Bacterium solution.Formula refers to table 1.
Table 1, antibacterial formula of liquid (parts by weight)
Comparative example 1
This comparative example is the comparative example of embodiment 1, in place of the essential difference of embodiment 1: this comparative example is using poly-
Propylene glycol replaces methanol to combine with octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride.
Comparative example 2
This comparative example is the comparative example of embodiment 1, in place of the essential difference of embodiment 1: this comparative example uses ten
Eight alkyl trimethyl ammonium chlorides replace octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride to combine with methanol.
Comparative example 3
This comparative example is the comparative example of embodiment 1, in place of the essential difference of embodiment 1: the antibacterial of this comparative example
Liquid contains 1 part octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 1 part of methanol.
Performance test
Non-woven fabrics, drying are impregnated with the antimicrobial fluid that above-mentioned each example provides, antibacterial nonwoven cloth is prepared, following three kinds of sides can be used
One of case:
When by the way that non-woven fabrics being passed through spray system space under the rotation of conveying roller, can quantitatively be adjusted by bull nozzle will resist
Bacterium solution sprays respectively from non-woven fabrics is two-sided.Antimicrobial fluid is uniformly imposed on non-woven fabrics by the method, and antibacterial effect is stablized.
Alternatively, nano ceramics roller local infiltration is in antimicrobial fluid inside groove, under the rotation of conveying roller non-woven fabrics by with receive
When rice ceramic roller contact, the antimicrobial fluid transfer for being attached to nano ceramics roller is coated on non-woven fabrics.Upper liquid measure passes through nano ceramics
The nano-pore unit of roller chooses and nano ceramics roller rotational speed regulation.
Alternatively, antimicrobial fluid is delivered in liquid bath via agitator, compositional liquor transfer is coated on nonwoven by nano ceramics roller
On cloth, extraction raffinate is shut out by roll.
When preparing antibacterial nonwoven cloth, wet rate of body weight gain can be controlled 10%~30%.
The antibacterial nonwoven cloth being prepared is performed the following performance tests:
(1) gained antibacterial nonwoven cloth is sent to microbiological analysis inspection center, Guangdong Province, Guangdong Province's microbiological analysis test
Center is tested according to GB/T20944.2-2007 absorption process.When test, with the nonwoven not handled by any antimicrobial fluid
For cloth as control sample, above each example gained non-woven fabrics is sample.Respectively toward be inoculated on control sample, sample Escherichia coli 6.0 ×
104Cfu/ piece, staphylococcus aureus 3.0 × 104Cfu/ piece.The total plate count measured after control sample inoculated and cultured 18h is large intestine
Bacillus 4.9 × 106Cfu/ piece, staphylococcus aureus 4.3 × 107Cfu/ piece.The bacterium colony measured after sample inoculated and cultured 18h is total
Number is shown in Table 2.
Table 2 (unit: cfu/ piece)
Referring to the above operation, take respectively shelf life January, March, June, August, 1 year, 1.5 years, 2 years samples carry out antibacterial
Test, as a result as follows:
Table 3 (unit: cfu/ piece)
The gained antibacterial nonwoven cloth sample of more than present invention each example is sent to SGS and according to GB/T20944.2-2007 simultaneously
Absorption process is tested, and the result trend presented is identical as table 2, table 3.
(2) antibacterial nonwoven cloth obtained by above each example is sent to Inspection and Quarantine Technic Center, Guangdong Entry-Exit Inspection and Qu,
Inspection and Quarantine Technic Center, Guangdong Entry-Exit Inspection and Qu is according to GB15979-2002 " Disposable Sanitary Accessory standard "
Detect skin irritatin sample.
Environment: regular grade animal house is tested, experimental animal is numbered using licensing: SYXK (Guangdong) 2018-0081；Room temperature 21
DEG C~23 DEG C, relative humidity 55%~65%.
Experimental animal: regular grade New Zealand White rabbit, (experiment is dynamic for Guangdong Medical Lab Animal Center's (three water basely)
Object licensing number: SCXK (Guangdong) 2014-0035) it provides.Experimental animal weight 2.3~2.4kg, experimental animal quality certification number:
NO.44411600004681。
Sample treatment: each sample is cut into about 2.5cm × 2.5cm/ block, as receipts examination object after physiological saline wetting.
Point of observation: remove tested material after 1h, for 24 hours, 48h observe the dermoreaction for giving tested material position respectively.
Operating procedure: 1) healthy New Zealand White rabbit is taken before test for 24 hours to cut experimental animal back backbone diamond wool
Fall, prepares 2 pieces of unhairing regions (each unhairing range respectively about 3cm × 3cm).) take tested material a piece of, it is attached on the left of experimental animal and goes
On hair area skin, patch covering is fixed with nonirritant adhesive plaster and bandage.Take patch a piece of, with which physiological saline
It is attached to after wetting on the right side of experimental animal on unhairing area skin as control.It sticks and removes residual tested material with warm water after 4h.In
Remove tested material after 1h, for 24 hours, 48h observe the dermoreaction for giving tested material position respectively, record the skin of each point of observation
Skin reaction.
Standards of grading:
0- without erythema,
1- very slight erythema,
2- erythema is high-visible to be easy to determining,
3- moderate to severe erythema,
4- Severe erythema (aubergine) is formed to eschar.
0- without oedema,
1- very slight oedema,
2- Mild edema (cutaneous protuberance is clearly outlined),
3- intermediate edema (cutaneous protuberance about 1mm),
4- Severe edema (protuberance exceeds chemical contaminated zone more than 1mm, range).
The result is as follows:
Table 4
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of bactericidal composition, which is characterized in that in parts by weight, the bactericidal composition includes 0.0008 part~0.5
Octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.0008 part~0.5 part of methanol of part.
2. bactericidal composition according to claim 1, which is characterized in that in parts by weight, the bactericidal composition packet
Include 0.1 part~0.4 part octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.1 part~0.32 part of methanol.
3. bactericidal composition according to claim 2, which is characterized in that in parts by weight, the bactericidal composition packet
Include 0.16 part~0.35 part octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.16 part~0.25 part of first
Alcohol.
4. the described in any item bactericidal compositions of claims 1 to 3 are preparing the application in antimicrobial fluid used for textiles.
5. a kind of antimicrobial fluid used for textiles, which is characterized in that in parts by weight, antimicrobial fluid packet used for textiles described in every 100 parts
Containing 0.0008 part~0.5 part of octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.0008 part~0.5 part
Methanol, 0 part~1 part of hydrophilic agent and 98 parts~99.998 parts of water.
6. antimicrobial fluid used for textiles according to claim 5, which is characterized in that in parts by weight, spinning described in every 100 parts
Fabric antimicrobial fluid includes 0.1 part~0.4 part octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.1 part
~0.32 part of methanol, 0 part~1 part of hydrophilic agent and 98.28 parts~99.8 parts of water.
7. antimicrobial fluid used for textiles according to claim 6, which is characterized in that in parts by weight, spinning described in every 100 parts
Fabric antimicrobial fluid includes 0.16 part~0.35 part octadecyldimethyl (3- methoxy silane base propyl) ammonium chloride, 0.16
Part~0.25 part of methanol, 0 part~1 part of hydrophilic agent and 98.4 parts~99.68 parts of water.
8. a kind of preparation method of antibacterial fabric, which is characterized in that the preparation method includes the following steps:
Take textile and the described in any item antimicrobial fluids used for textiles of claim 5 to 7；With the antimicrobial fluid used for textiles
After the textile is soaked uniformly it is dry to get.
9. the preparation method of antibacterial fabric according to claim 8, which is characterized in that the textile is nonwoven
Cloth.
10. a kind of antibacterial fabric, which is characterized in that the preparation method as described in claim 8 or 9 obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811391357.1A CN109479896A (en) | 2018-11-21 | 2018-11-21 | Bactericidal composition and its preparing the application in antibacterial fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811391357.1A CN109479896A (en) | 2018-11-21 | 2018-11-21 | Bactericidal composition and its preparing the application in antibacterial fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109479896A true CN109479896A (en) | 2019-03-19 |
Family
ID=65697214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811391357.1A Pending CN109479896A (en) | 2018-11-21 | 2018-11-21 | Bactericidal composition and its preparing the application in antibacterial fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109479896A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143275A (en) * | 2020-08-25 | 2020-12-29 | 任轶 | Formula and using method of sterilization bacteriostat |
| CN113914098A (en) * | 2020-07-07 | 2022-01-11 | 中科鼎晟科技有限公司 | Antibacterial material and preparation method and application thereof |
| CN115852585A (en) * | 2022-11-29 | 2023-03-28 | 上海水星家用纺织品股份有限公司 | Low-sensitization textile padding for infants and preparation method thereof |
| CN115852515A (en) * | 2022-11-29 | 2023-03-28 | 上海水星家用纺织品股份有限公司 | Low-sensitization antibacterial polyester fiber and preparation method thereof |
-
2018
- 2018-11-21 CN CN201811391357.1A patent/CN109479896A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113914098A (en) * | 2020-07-07 | 2022-01-11 | 中科鼎晟科技有限公司 | Antibacterial material and preparation method and application thereof |
| WO2022007430A1 (en) * | 2020-07-07 | 2022-01-13 | 中科鼎晟科技有限公司 | Antibacterial material, preparation method therefor, and application thereof |
| CN112143275A (en) * | 2020-08-25 | 2020-12-29 | 任轶 | Formula and using method of sterilization bacteriostat |
| CN115852585A (en) * | 2022-11-29 | 2023-03-28 | 上海水星家用纺织品股份有限公司 | Low-sensitization textile padding for infants and preparation method thereof |
| CN115852515A (en) * | 2022-11-29 | 2023-03-28 | 上海水星家用纺织品股份有限公司 | Low-sensitization antibacterial polyester fiber and preparation method thereof |
| CN115852515B (en) * | 2022-11-29 | 2024-06-11 | 上海水星家用纺织品股份有限公司 | Hypoallergenic antibacterial polyester fiber and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109479896A (en) | Bactericidal composition and its preparing the application in antibacterial fabric | |
| CN105019236B (en) | A kind of textile composite antibacterial finishing agent | |
| CN100521943C (en) | Inorganic/organic nano composite antibacterial agent and its fabric product application | |
| KR102009127B1 (en) | Composition and method to form a self decontaminating surface | |
| US9089138B2 (en) | Organosilane-nonionic water stable quaternary ammonium compositions and methods | |
| AU2010274654B2 (en) | Silver oxide formulations having improved whiteness characteristics | |
| WO2010144503A4 (en) | Antimicrobial textiles comprising peroxide | |
| CN103184694A (en) | Nano microcapsule type dry garment piece, and preparation method and application thereof | |
| TWI279226B (en) | Dressings which can be applied several times to textile fibres and textile fabrics | |
| CN106222883A (en) | A kind of have the inner lining of automobile material that sterilization eliminates the unusual smell | |
| JPH04255767A (en) | Coating composition and textile material | |
| CN108265374A (en) | A kind of wormwood antibacterial towel and its production method | |
| JP3829640B2 (en) | Antibacterial and antifungal agents and antibacterial or antifungal methods | |
| CN102535007A (en) | Moxa non-woven fabric and production method thereof | |
| JP2000328448A (en) | Production of functional textile product | |
| KR20100002509A (en) | Nano siver antibiosis and maunfacturing method thereof | |
| Chandrasekaran et al. | Analysis of eco-friendly medicinal herb extracts and essential oil applications on textile products for healthcare applications | |
| CN107385680A (en) | One kind melt-blown antibacterial composite fibers non-woven fabric and preparation method thereof | |
| KR100514976B1 (en) | Fiber article comprising natural pozzolan | |
| CN112626715A (en) | Spunlace nonwoven fabric and preparation method thereof | |
| EP1830000A1 (en) | Antimicrobial material consisting of polyacrylonitrile with metallic and non-metallic cations bound thereto | |
| CN113017993B (en) | Antibacterial and breathable diaper | |
| CN104213413A (en) | Antibacterial silk wadding quilt and preparation method thereof | |
| KR102459988B1 (en) | Hygiene product with antibiosis and manufacturing method thereof | |
| Іщенко et al. | Antimicrobial approaches for textiles. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190319 |