CN109473190A - A kind of secondary neutron source rod reducing tritium discharge - Google Patents

A kind of secondary neutron source rod reducing tritium discharge Download PDF

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Publication number
CN109473190A
CN109473190A CN201811444024.0A CN201811444024A CN109473190A CN 109473190 A CN109473190 A CN 109473190A CN 201811444024 A CN201811444024 A CN 201811444024A CN 109473190 A CN109473190 A CN 109473190A
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CN
China
Prior art keywords
neutron source
tritium
secondary neutron
source rod
end plug
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811444024.0A
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Chinese (zh)
Inventor
党宇
卢俊强
付亚茹
郑轶雄
毛兰方
崔严光
徐时吟
孙靖雅
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Shanghai Nuclear Engineering Research and Design Institute Co Ltd
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Shanghai Nuclear Engineering Research and Design Institute Co Ltd
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Publication date
Application filed by Shanghai Nuclear Engineering Research and Design Institute Co Ltd filed Critical Shanghai Nuclear Engineering Research and Design Institute Co Ltd
Priority to CN201811444024.0A priority Critical patent/CN109473190A/en
Publication of CN109473190A publication Critical patent/CN109473190A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21CNUCLEAR REACTORS
    • G21C19/00Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/02Details of handling arrangements
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21CNUCLEAR REACTORS
    • G21C19/00Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/20Arrangements for introducing objects into the pressure vessel; Arrangements for handling objects within the pressure vessel; Arrangements for removing objects from the pressure vessel
    • G21C19/22Arrangements for obtaining access to the interior of a pressure vessel whilst the reactor is operating
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21GCONVERSION OF CHEMICAL ELEMENTS; RADIOACTIVE SOURCES
    • G21G4/00Radioactive sources
    • G21G4/02Neutron sources
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Abstract

The present invention provides a kind of secondary neutron source rod of reduction tritium discharge, it is characterized in that, the coating resistance tritium coating on the cladding tubes of the secondary neutron source rod, or placing nickel plating to inhale tritium material or the interior cladding materials in the cladding tubes is zircaloy, above-mentioned three kinds of modes also can be used in combination.The tritium that itself is generated can be deposited in stick by secondary neutron source rod provided by the invention, and tritium discharge amount is effectively reduced, and reduce the tritium level in coolant, mitigate environmental pollution.

Description

A kind of secondary neutron source rod reducing tritium discharge
Technical field
The present invention relates to a kind of secondary neutron source rods of reduction tritium discharge.
Background technique
The main function of secondary neutron source rod is that the secondary neutron source by being loaded in stick is filled in the fuel of following cycle Carry, shutdown and the reactor cores neutron flux such as critical it is lesser during, provide a primary neutron level for ex-core instrumentation. In the starting of first reactor core, primary neutron level is provided by primary neutron source.Secondary neutron source rod can be inserted separately into fuel assembly It uses, can also be fitted into secondary neutron source component and use.Secondary neutron source component is usually by compacting part underhung secondary Component stick and resistance stopper or other associated component sticks composition.When reactor operation, secondary neutron source rod is inserted in fuel assembly Fixed, usually secondary source rod is inserted in fuel assembly guide pipe.
Nuclear reactor secondary neutron source rod structure is substantially similar in the world, including single layer involucrum secondary neutron source rod and bilayer Two kinds of involucrum secondary neutron source rod is made of single or double layer cladding tubes cladding secondary neutron source respectively, and both ends are close by end plug Envelope.Now widely used secondary neutron source is Sb-Be material, reacts given-ioff neutron by Be (γ, n).Stable isotope Sb Sb-122 and Sb-124 is generated by neutron irradiation under reactor core normal operation, the decay of Sb-122 and Sb-124 generate gamma-ray Ray provides gamma-rays for Be (γ, n) reaction.Secondary neutron source rod would generally use multiple circulations in nuclear reactor, by heap The material of the influence of core use environment and service life, cladding tubes and end plug is usually stainless steel.Secondary neutron source component knot As shown in figure 1 and 2, secondary neutron source rod is as shown in figures 3 and 4 for structure.
Sb-Be material can generate tritium after reacting in-pile irradiation, and tritium permeates in Stainless Steel Cladding used at present It measures very high, it is easy to enter coolant across cladding tubes.Radioactivity tritium is entered by cladding tubes will cause coolant in coolant Pollution, tritium once enter coolant, because it is almost the same with ordinary hydrogen in physics and chemically, are difficult to remove, can be with anti- Waste water or steam waste discharge in heap is answered to cause environmental pollution to outside.
Therefore, how to provide it is a kind of the tritium that itself is generated can be deposited in stick, be effectively reduced tritium discharge amount, reduce cooling Tritium level in agent, the secondary neutron source rod for mitigating environmental pollution become urgent problem to be solved.
Summary of the invention
In view of the deficiencies of the prior art, the present invention proposes a kind of secondary neutron source rods of reduction tritium discharge, which is characterized in that Coating hinders tritium coating or places nickel plating in the cladding tubes and inhales tritium material or make on the cladding tubes of the secondary neutron source rod With zircaloy inner envelope pipe.The preferred secondary neutron source rod for reducing tritium discharge, which is characterized in that in the secondary Component stick is single layer involucrum secondary neutron source rod, is made of cladding tubes cladding secondary neutron source material, the cladding tubes Both ends are sealed by the first end plug and the second end plug, and the resistance tritium coating is coated on the cladding tubes.
The preferred secondary neutron source rod for reducing tritium discharge, which is characterized in that the secondary neutron source rod is double Layer involucrum secondary neutron source rod, the cladding tubes include interior involucrum and outer envelope, coat secondary neutron source material by the interior involucrum Material, both ends are sealed by third end plug and the 4th end plug, and outside coats one layer of outer envelope again, and the outer envelope both ends pass through First end plug and the sealing of the second end plug, coat the resistance tritium coating on the interior involucrum.
The secondary neutron source rod for reducing tritium discharge, which is characterized in that the resistance tritium coating material is Cr2O3、Al2O3、ZrO2, SiC or other materials with Tritium Resistivity.
The preferred secondary neutron source rod for reducing tritium discharge, which is characterized in that the secondary neutron source rod is double Layer involucrum secondary neutron source rod, the cladding tubes include interior involucrum and outer envelope, coat secondary neutron source material by the interior involucrum Material, both ends are sealed by third end plug and the 4th end plug, and outside coats one layer of outer envelope again, and the outer envelope both ends pass through First end plug and the sealing of the second end plug, the interior cladding materials are zircaloy, and the outsourcing shell material is stainless steel.
The preferred secondary neutron source rod for reducing tritium discharge, which is characterized in that the secondary neutron source rod is single Layer involucrum secondary neutron source rod is made of cladding tubes cladding secondary neutron source material, and the both ends of the cladding tubes pass through the One end plug and the sealing of the second end plug place the nickel plating in the cladding tubes and inhale tritium material, and tritium material is inhaled in the nickel plating to be put It sets above or below the secondary neutron source material.
The preferred secondary neutron source rod for reducing tritium discharge, which is characterized in that the secondary neutron source rod is double Layer involucrum secondary neutron source rod, the cladding tubes include interior involucrum and outer envelope, coat secondary neutron source material by the interior involucrum Material, both ends are sealed by third end plug and the 4th end plug, and outside coats one layer of outer envelope again, and the outer envelope both ends pass through First end plug and the sealing of the second end plug, the nickel plating is placed in the outer envelope or interior cladding tubes and inhales tritium material.
The preferred secondary neutron source rod for reducing tritium discharge, which is characterized in that tritium material is inhaled in the nickel plating to be set It is placed between the outer envelope and the interior involucrum, is located above or below the interior involucrum.
The preferred secondary neutron source rod for reducing tritium discharge, which is characterized in that tritium material is inhaled in the nickel plating to be set It is placed in the interior involucrum, is located above or below the secondary neutron source material.
Compared with prior art, the invention has the following advantages: secondary neutron source rod provided by the invention can incite somebody to action oneself The tritium that body generates is deposited in stick, and tritium discharge amount is effectively reduced, and reduces the tritium level in coolant, mitigates environmental pollution.
Detailed description of the invention
Fig. 1 is one of the schematic diagram of secondary neutron source component structure in the prior art.
Fig. 2 is the two of the schematic diagram of secondary neutron source component structure in the prior art.
Fig. 3 is a kind of cross-sectional view of single layer secondary neutron source rod for reducing tritium discharge provided by the invention.
Fig. 4 is a kind of cross-sectional view of secondary neutron source rod of bilayer for reducing tritium discharge provided by the invention.
1- compacting part;2- resistance stopper;3- secondary neutron source rod;4- connection handle;The first end plug of 5-;6- cladding tubes;61- Outer envelope;7- secondary neutron source material;The second end plug of 8-;9- third end plug;Involucrum in 10-;The 4th end plug of 11-;12- nickel plating is inhaled Tritium material.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, with reference to the accompanying drawing and specific real Applying mode, the present invention is described in further detail.
Secondary neutron source rod can be used individually in reactor, can also be loaded in secondary neutron source component and be used, such as Fig. 1 Shown in 2, secondary neutron source component by compacting part 1 or 4 underhung secondary neutron source rod 3 of connection handle and resistance stopper 2 or Other associated component sticks composition.
The object of the present invention is to provide the secondary neutron source rods that one kind can reduce tritium discharge, by promoting secondary neutron source The resistance tritium-permeation performance of stick cladding tubes or in cladding tubes place inhale tritium material the tritium generated in stick is stayed in stick, to subtract Few tritium discharge, specifically includes three kinds of schemes: the coating resistance tritium coating on secondary neutron source rod cladding tubes;Using involucrum in zircaloy Pipe;Nickel plating is placed in cladding tubes inhales tritium material.
Specifically, the secondary neutron source rod that one kind provided by the invention can reduce tritium discharge includes following embodiment.
1) the coating resistance tritium coating on secondary neutron source rod cladding tubes
Single layer involucrum secondary neutron source rod forms as shown in figure 3, coating secondary neutron source material 7 by cladding tubes 6, cladding tubes 6 both ends are sealed by the first end plug 5 and the second end plug 8.
The double-deck involucrum secondary neutron source rod is as shown in figure 4, coat secondary neutron source material 7 by interior involucrum 10, both ends pass through Third end plug and the sealing of the 4th end plug 9 and 11, outside coat one layer of outer envelope 61 again, and 61 both ends of outer envelope pass through the first end plug 5 It is sealed with the second end plug 8.The material of outer envelope 61 and 10 and end plug 5,8,9,11 is stainless steel.
One layer of tritium permeation barrier is coated in the present invention on the outer envelope 61 of secondary neutron source rod 3 or interior involucrum 10, with Reduce the permeability of tritium.Resistance tritium coating material is Cr2O3、Al2O3、ZrO2, SiC or other materials with Tritium Resistivity.Hinder tritium Coating can be coated on inner surface or the outer surface of cladding tubes 61 or interior involucrum 10.
2) using cladding tubes in zircaloy
For secondary neutron source rod of the present invention as shown in figure 4, coating secondary neutron source material 7 by interior involucrum 10, both ends pass through the Three end plugs 9 and the sealing of the 4th end plug 11, interior 10 material of involucrum are zircaloy, and the material of end plug 9 and 11 is also zircaloy.It wraps again outside Cover one layer of outer envelope 61,61 both ends of outer envelope are sealed by the first end plug 5 and the second end plug 8, outer envelope 61 and end plug 5 and 8 Material is stainless steel.The outer diameter of involucrum 10 is 5~9mm in zircaloy, and wall thickness is 0.1~2mm.
3) nickel plating is placed in cladding tubes inhale tritium material
Single layer involucrum secondary neutron source rod of the present invention forms as shown in figure 3, coating secondary neutron source material 7 by cladding tubes 6, 6 both ends of cladding tubes are sealed by the first end plug 5 and the second end plug 8, in cladding tubes 6, are placed nickel plating and are inhaled tritium material 12.Nickel plating is inhaled Tritium material 12 can be placed in above or below secondary neutron source material 7.The matrix that tritium material 12 is inhaled in nickel plating is zircaloy, surface Nickel plating, nickel plating layer thick are 5~20 μm.It is tubular or other shapes that tritium material 12 is inhaled in nickel plating.
The double-deck involucrum secondary neutron source rod is as shown in figure 4, coat secondary neutron source material 7 by interior involucrum 10, both ends pass through End plug 9 and 11 seals, and outside coats one layer of outer envelope 61 again, and 61 both ends of outer envelope are close by the first end plug 5 and the second end plug 8 Envelope.Tritium material 12 is inhaled in nickel plating may be disposed between outer envelope 6 and interior involucrum 10, be located above or below interior involucrum.Tritium is inhaled in nickel plating Material 12 may also set up in interior involucrum 10, be located above or below secondary neutron source material 7.
Compared with prior art, the invention has the following advantages: in the secondary provided by the invention for reducing tritium discharge The tritium that itself is generated can be deposited in stick by component stick, and tritium discharge amount is effectively reduced, and reduce the tritium level in coolant, mitigate ring Border pollution.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with other The difference of embodiment, the same or similar parts in each embodiment may refer to each other.For system disclosed in embodiment For, due to corresponding to the methods disclosed in the examples, so being described relatively simple, related place is referring to method part illustration ?.
Those skilled in the art can use different methods to achieve the described function each specific application, but It is that such implementation should not be considered as beyond the scope of the present invention.
Obviously, those skilled in the art can carry out various modification and variations without departing from spirit of the invention to invention And range.If in this way, these modifications and changes of the present invention belong to the claims in the present invention and its equivalent technologies range it Interior, then the invention is also intended to include including these modification and variations.

Claims (10)

1. a kind of secondary neutron source rod for reducing tritium discharge, which is characterized in that applied on the cladding tubes of the secondary neutron source rod It covers resistance tritium coating or places nickel plating in the cladding tubes of the secondary neutron source rod and inhale tritium material or in the secondary neutron source rod It is interior to be applied in combination using zircaloy inner envelope pipe or above scheme.
2. reducing the secondary neutron source rod of tritium discharge as described in claim 1, which is characterized in that the secondary neutron source rod is Single layer involucrum secondary neutron source rod is made of cladding tubes cladding secondary neutron source material, and the both ends of the cladding tubes pass through First end plug and the sealing of the second end plug, coat the resistance tritium coating on the cladding tubes.
3. reducing the secondary neutron source rod of tritium discharge as described in claim 1, which is characterized in that the secondary neutron source rod is The double-deck involucrum secondary neutron source rod, the cladding tubes include interior involucrum and outer envelope, coat secondary neutron source by the interior involucrum Material, both ends are sealed by third end plug and the 4th end plug, and outside coats one layer of outer envelope again, and the outer envelope both ends are logical The first end plug and the sealing of the second end plug are crossed, the resistance tritium coating is coated on the interior involucrum.
4. the secondary neutron source rod for reducing tritium discharge as claimed in claims 3 and 4, which is characterized in that the resistance tritium coating material Material is Cr2O3、Al2O3、ZrO2, SiC or other materials with Tritium Resistivity.
5. reducing the secondary neutron source rod of tritium discharge as described in claim 1, which is characterized in that the secondary neutron source rod is The double-deck involucrum secondary neutron source rod, the cladding tubes include interior involucrum and outer envelope, coat secondary neutron source by the interior involucrum Material, both ends are sealed by third end plug and the 4th end plug, and outside coats one layer of outer envelope again, and the outer envelope both ends are logical The first end plug and the sealing of the second end plug are crossed, the interior cladding materials is zircaloy, and the outsourcing shell material is stainless steel.
6. reducing the secondary neutron source rod of tritium discharge as described in claim 1, which is characterized in that the secondary neutron source rod is Single layer involucrum secondary neutron source rod is made of cladding tubes cladding secondary neutron source material, and the both ends of the cladding tubes pass through First end plug and the sealing of the second end plug place the nickel plating in the cladding tubes and inhale tritium material, and tritium material is inhaled in the nickel plating can It is placed on above or below the secondary neutron source material.
7. reducing the secondary neutron source rod of tritium discharge as described in claim 1, which is characterized in that the secondary neutron source rod is The double-deck involucrum secondary neutron source rod, the cladding tubes include interior involucrum and outer envelope, coat secondary neutron source by the interior involucrum Material, both ends are sealed by third end plug and the 4th end plug, and outside coats one layer of outer envelope again, and the outer envelope both ends are logical The first end plug and the sealing of the second end plug are crossed, the nickel plating is placed in the outer envelope or interior cladding tubes and inhales tritium material.
8. reducing the secondary neutron source rod of tritium discharge as claimed in claim 7, which is characterized in that tritium material is inhaled in the nickel plating can It is set between the outer envelope and the interior involucrum, is located above or below the interior involucrum.
9. reducing the secondary neutron source rod of tritium discharge as claimed in claim 7, which is characterized in that tritium material is inhaled in the nickel plating can It is set in the interior involucrum, is located above or below the secondary neutron source material.
10. reducing the secondary neutron source rod of tritium discharge as claimed in claim 7, which is characterized in that tritium material is inhaled in the nickel plating Matrix be zircaloy, plating nickel on surface, nickel plating layer thick be 5~20 μm.
CN201811444024.0A 2018-11-29 2018-11-29 A kind of secondary neutron source rod reducing tritium discharge Pending CN109473190A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111667939A (en) * 2020-05-19 2020-09-15 上海核工程研究设计院有限公司 Reactor core assembly and system for producing carbon-14 isotopes

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JP2002168983A (en) * 2000-11-30 2002-06-14 Mitsubishi Heavy Ind Ltd Method of manufacturing control rod for pressurized water reactor
CN106782714A (en) * 2017-01-10 2017-05-31 上海核工程研究设计院 A kind of interpolation type neutron-absorbing component for irradiated fuel assembly
CN209374067U (en) * 2018-11-29 2019-09-10 上海核工程研究设计院有限公司 A kind of secondary neutron source rod reducing tritium discharge

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