CN109470750A - A kind of online flow cell of water solubility atmosphere multi-parameter - Google Patents

A kind of online flow cell of water solubility atmosphere multi-parameter Download PDF

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Publication number
CN109470750A
CN109470750A CN201811282655.7A CN201811282655A CN109470750A CN 109470750 A CN109470750 A CN 109470750A CN 201811282655 A CN201811282655 A CN 201811282655A CN 109470750 A CN109470750 A CN 109470750A
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CN
China
Prior art keywords
electrode
flow cell
socket
water solubility
sockets
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CN201811282655.7A
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Chinese (zh)
Inventor
覃潇潇
杨海涛
柳向咏
杨池
章炎麟
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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Priority to CN201811282655.7A priority Critical patent/CN109470750A/en
Publication of CN109470750A publication Critical patent/CN109470750A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/27Association of two or more measuring systems or cells, each measuring a different parameter, where the measurement results may be either used independently, the systems or cells being physically associated, or combined to produce a value for a further parameter

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

The present invention relates to a kind of online flow cells of water-soluble atmosphere multi-parameter, including flow cell ontology, electrode sockets and inlet are equipped on flow cell, the electrode sockets are electrode thread socket, including first electrode socket and second electrode socket stream, it is respectively for insertion into pH electrode and ORP electrode;Conductivity electrode is inserted into using thread socket in flow cell cavity one end, the conductivity electrode of insertion is connected with on-line checking Conjoint Analysis system, can reach the real-time detection to Atmospheric Liquid Phase constituent analysis;There is a tiny inlet opening in flow cell center upper portion, the aerosol for receiving to flow out from MARGA system, the flow cell cavity other side is tap hole.Flow cell of the invention is inserted into electrode by the way that more sockets are arranged, it realizes and different detection projects is detected simultaneously, to the loss of laboratory sample when avoiding detecting one by one, and the flow cell passes through the real-time monitoring and analysis record tested and can be realized after electrode is connect with on-line analysis system to laboratory sample.

Description

A kind of online flow cell of water solubility atmosphere multi-parameter
Technical field
The present invention relates to air monitoring fields, and in particular to a kind of online flow cell of water solubility atmosphere multi-parameter.
Background technique
The pollutant of air can be divided into polluted gas and particulate pollutant, and MARGA provides a kind of completely new for atmospheric research , online air monitoring and research means, particulate pollutant and sour gas are directly inhaled using unique sampler It receives in water phase, reuses ion chromatography and monitor its ingredient, whole process is performed fully automatic.Its collected liquefied sample can be with Other analyzers are directly combined.
When detecting Atmospheric Liquid Phase, generally requires while measuring compared with entry (such as pH value, ORP, conductivity, and detection The reaction that sample occurs under ultraviolet irradiation condition), but since the sample that can be collected is less, each single item content is carried out respectively When measurement, the loss of sample is caused, and is unable to reach the reaction that sample is occurred and carries out real-time monitoring.
Summary of the invention
The object of the present invention is to provide a kind of water-soluble online flow cell of atmosphere multi-parameter, in order to improve the efficiency of detection The utilization rate of sample no longer detects one by one by a variety of test electrode sets on a flow cell;And the flow cell and online Atmospheric Liquid Phase analysis system can accomplish the real-time detection to different detection projects after combining.
To achieve the above object, present invention provide the technical scheme that
A kind of online flow cell of water solubility atmosphere multi-parameter, including flow cell ontology, are equipped with electrode sockets on flow cell And inlet, the electrode sockets are electrode thread socket, including first electrode socket and second electrode socket, are respectively used to insert Enter pH electrode and ORP electrode;Conductivity electrode, the conductivity electrode of insertion are inserted into using thread socket in flow cell cavity one end It is connected with on-line checking Conjoint Analysis system, the real-time detection to Atmospheric Liquid Phase constituent analysis can be reached;On flow cell There is a tiny inlet opening in portion center, the aerosol for receiving to flow out from MARGA system, and the flow cell cavity other side is outflow Hole;The flow cell is detected simultaneously for multiple electrodes.
Further, tap hole is externally connected to a timing valve, can carry out timesharing piecewise analysis inspection to the liquid of collection It surveys.
Further, when valve is closed, collected liquid is saturated with cavity, and electrode is enable to come into full contact with liquid, Reach testing goal.
Further, when the conductivity electrode of the thread socket of described flow cell cavity one end is taken out, the thread socket It can be used as second outflow hole.
Compared with prior art, the beneficial effects of the present invention are:
Flow cell of the invention is inserted into electrode by the way that more sockets are arranged, and realizes while examining to different detection projects It surveys, loss when avoiding detection one by one to laboratory sample, and the flow cell is connect by testing electrode with on-line analysis system It can be realized the real-time monitoring and analysis record to laboratory sample afterwards.
Detailed description of the invention
Fig. 1: the structural schematic diagram of the water-soluble online flow cell of atmosphere multi-parameter of the invention.
In figure: 1- first electrode socket, 2- inlet, 3- second electrode socket, 4- thread socket, 5- tap hole.
Specific embodiment
The present invention is further explained in the light of specific embodiments.
A kind of online flow cell of water solubility atmosphere multi-parameter, including flow cell ontology, are equipped with electrode sockets on flow cell With inlet 2, the electrode sockets are electrode thread socket 4, including first electrode socket 1 and second electrode socket 3, are used respectively In insertion pH electrode and ORP electrode.
Conductivity electrode, the conductivity electrode of insertion and online inspection are inserted into using thread socket 4 in flow cell cavity one end It surveys Conjoint Analysis system to be connected, the real-time detection to Atmospheric Liquid Phase constituent analysis can be reached.
There is a tiny inlet opening in flow cell center upper portion, the aerosol for receiving to flow out from MARGA system, circulation The cell cavity body other side is tap hole 5.
Tap hole 5 is externally connected to a timing valve, can carry out analysis detection at times to the liquid of collection.
When valve closure, collected liquid is saturated with cavity, and electrode is enable to come into full contact with liquid, reaches detection mesh 's.
When the conductivity electrode of the thread socket 4 of described flow cell cavity one end is taken out, which can be used as the Two tap holes.
Flow cell of the invention is inserted into electrode by the way that more sockets are arranged, and realizes while examining to different detection projects It surveys, loss when avoiding detection one by one to laboratory sample, and the flow cell is connect by testing electrode with on-line analysis system It can be realized the real-time monitoring and analysis record to laboratory sample afterwards.
Tap water, In Nanjing Changjiang water quality, In Nanjing precipitation are detected by experiment, is as a result distinguished as follows:
1. detecting tap water: conductivity: 350 μ s/cm, pH are as follows: 7.8
2. detecting In Nanjing Changjiang water quality: conductivity: 236 μ s/cm, pH are as follows: 7.9.
3. detecting In Nanjing precipitation: conductivity: 98 μ s/cm, pH are as follows: 5.5
The water-soluble online flow cell of atmosphere multi-parameter of the invention by a variety of test electrode sets on a flow cell, no It detects one by one again;And the flow cell can accomplish the reality to different detection projects after in conjunction with line Atmospheric Liquid Phase analysis system When detect.
The above is only presently preferred embodiments of the present invention, is not intended to limit the present invention in any form, any ripe Professional and technical personnel is known, without departing from the scope of the present invention, according to the technical essence of the invention, to the above reality Any simple modifications, equivalent substitutions and improvements etc. made by example are applied, it is fallen within the scope of protection of the technical scheme of the present invention It is interior.

Claims (4)

1. a kind of online flow cell of water solubility atmosphere multi-parameter, it is characterised in that: including flow cell ontology, be equipped on flow cell Electrode sockets and inlet, the electrode sockets are electrode thread socket, including first electrode socket and second electrode socket, are divided PH electrode and ORP electrode Yong Yu be inserted into;Conductivity electrode, the electricity of insertion are inserted into using thread socket in flow cell cavity one end Conductance electrode is connected with on-line checking Conjoint Analysis system, can reach the real-time detection to Atmospheric Liquid Phase constituent analysis;? Flow cell center upper portion has a tiny inlet opening, the aerosol for receiving to flow out from MARGA system, and flow cell cavity is another Side is tap hole;The flow cell is detected simultaneously for multiple electrodes.
2. the online flow cell of water solubility atmosphere multi-parameter according to claim 1, it is characterised in that: tap hole external connection There is a timing valve, analysis detection at times can be carried out to the liquid of collection.
3. the online flow cell of water solubility atmosphere multi-parameter according to claim 2, it is characterised in that: when valve closure, Collected liquid is saturated with cavity, and electrode is enable to come into full contact with liquid.
4. the online flow cell of water solubility atmosphere multi-parameter according to claim 1, it is characterised in that: the circulation cell cavity When the conductivity electrode of the thread socket of body one end is taken out, which can be used as second outflow hole.
CN201811282655.7A 2018-10-31 2018-10-31 A kind of online flow cell of water solubility atmosphere multi-parameter Pending CN109470750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811282655.7A CN109470750A (en) 2018-10-31 2018-10-31 A kind of online flow cell of water solubility atmosphere multi-parameter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811282655.7A CN109470750A (en) 2018-10-31 2018-10-31 A kind of online flow cell of water solubility atmosphere multi-parameter

Publications (1)

Publication Number Publication Date
CN109470750A true CN109470750A (en) 2019-03-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022264389A1 (en) * 2021-06-17 2022-12-22 株式会社バイオケミカルイノベーション Air management device, air management method, and program

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN200968942Y (en) * 2006-11-07 2007-10-31 王保齐 Gas automatic acquiring, monitoring device
CN101221145A (en) * 2008-01-25 2008-07-16 大连理工大学 Subaqueous chemical oxygen demand measuring apparatus and method and method based on flow injection sampling
CN101598719A (en) * 2009-06-30 2009-12-09 烟台大学 Wastewater flow, ammonia nitrogen concentration and ammonia nitrogen total content water quality on-line combined tester
CN204925005U (en) * 2015-08-20 2015-12-30 北京矿冶研究总院 Flow cell

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN200968942Y (en) * 2006-11-07 2007-10-31 王保齐 Gas automatic acquiring, monitoring device
CN101221145A (en) * 2008-01-25 2008-07-16 大连理工大学 Subaqueous chemical oxygen demand measuring apparatus and method and method based on flow injection sampling
CN101598719A (en) * 2009-06-30 2009-12-09 烟台大学 Wastewater flow, ammonia nitrogen concentration and ammonia nitrogen total content water quality on-line combined tester
CN204925005U (en) * 2015-08-20 2015-12-30 北京矿冶研究总院 Flow cell

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《空气和废气监测分析方法指南》编委会: "《空气和废气监测分析方法指南.下》", 31 July 2014, 北京:中国环境出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022264389A1 (en) * 2021-06-17 2022-12-22 株式会社バイオケミカルイノベーション Air management device, air management method, and program
JPWO2022264389A1 (en) * 2021-06-17 2022-12-22

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