CN109468831A - A kind of super-hydrophobic wood fibre powder and preparation method thereof - Google Patents
A kind of super-hydrophobic wood fibre powder and preparation method thereof Download PDFInfo
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- CN109468831A CN109468831A CN201811282418.0A CN201811282418A CN109468831A CN 109468831 A CN109468831 A CN 109468831A CN 201811282418 A CN201811282418 A CN 201811282418A CN 109468831 A CN109468831 A CN 109468831A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
- D06M13/517—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond containing silicon-halogen bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The present invention relates to a kind of super-hydrophobic wood fibre powder and preparation method thereof, belong to functional living being material development field.Purpose is to improve the utility value of wood fiber biomass raw material, while solving the problems, such as super hydrophobic material preparation process complexity, higher cost.The super-hydrophobic wood fibre powder and preparation method thereof of one kind of the present invention, comprising the following steps: (1) lignocellulosic material is ground by powder using pulverizer;(2) by wood fibre powder grafted silica particle made from step (1);(3) silane coupling agent is added in step (2) the wood fibre powder solid obtained for being grafted silicon dioxide granule and carries out modifying super hydrophobicity, super-hydrophobic wood fibre powder is made.Super-hydrophobic wood fibre powder prepared by the present invention belongs to high value added product, has widened the resource utilization of wood fiber biomass raw material, has reduced the production cost of hydrophobic material, preparation process is simple, is easy to control.
Description
Technical field
The invention belongs to functional living being material development field, relate generally to a kind of super-hydrophobic wood fibre powder and
Preparation method.
Background technique
Wood fiber biomass is the organic matter that photosynthesis generates.Green plants utilizes chlorophyll will by photosynthesis
Solar energy is converted into chemical energy and is stored in wood fiber biomass, by certain method, that is, produce it is a kind of it is environmental-friendly,
Reproducible low-carbon energy has many advantages, such as that source is wide, rich reserves, renewable, low pollution, and wood fiber biomass is deposited extensively
It is in nature, main component is cellulose, hemicellulose and lignin.
Wood fiber biomass raw material have phosphorus content is high, ash content is low, abundance, it is renewable, from a wealth of sources, cheap easily
The features such as obtaining becomes the presoma of many materials preparations.Such as sawdust, almond, oil tea shell, peanut shell, cocoanut shell, corncob can
As the raw material for preparing active carbon;Using wood fiber biomass such as Semen sesami nigrum, black fungus, seaweed, mushrooms as precursor preparation carbon
Nanotube;In addition, researcher grows stone in nickel sheet and Cu foil using weeds, plastics, petal, bagasse, newspaper as presoma
Black alkene.Its recycling, high-valued and commercialization can effectively be realized by preparing a variety of materials as raw material using wood fiber biomass, no
Production cost can also be effectively reduced by being only capable of economizing on resources, while can also reduce the pollution to environment.
In recent years, due to the oil pollution accident frequently occurred, so that oily pollution becomes the global environment being concerned and asks
Topic, therefore be badly in need of developing a kind of method for separating/removing water pollutant.Super hydrophobic material is a kind of big with water contact angle
In the material for being equal to 150 °, since it is with super-hydrophobic super-oleophylic characteristic, so that it has fabulous answer in water-oil separation field
Use prospect.The big surface area of three-dimensional porous material and surface roughness make it have preferable absorption power in adsorption process
It learns, adsorption equilibrium can be reached faster, can be used as a kind of potential material of oil adsorbent.Three-dimensional porous structure super hydrophobic material is not
Only huge memory space can be mutually provided for oil, be that can reach the mutually quick separation of the oil of absorption by mechanical presses, be convenient for it
It recycles.Therefore, how to carry out simple, easy-operating modification and prepare super hydrophobic material and become to want in three-dimensional porous material substrate
The main problem of solution.
By super hydrophobic surface construction on netted or porous material, water-oil separating may be implemented, this is controlling or is mitigating
Caused marine pollution aspect is frequently revealed by petroleum and shows huge application potential, efficiently contributes to protect the marine environment
With the sustainable development for pushing marine industries.However, at present super hydrophobic material preparation technique and in the process there is also one
A little problems: most of super hydrophobic material is low using the progress of fluorinated chemical substance to its surface in order to improve its ultra-hydrophobicity
Surface can be modified, its cost is substantially increased;Many super hydrophobic material preparation steps are complicated, and preparation condition is harsh, manufacturing cycle
It is long;And super hydrophobic material surface its ultra-hydrophobicity under extraneous environmental activity is subject to destroy.Problems above restricts
Practical application of the super hydrophobic material in water-oil separating field, therefore cheap raw material, simple preparation process, surface be strong
Mechanical stability will be the following research hotspot for preparing super hydrophobic surface.
To sum up, wood fiber biomass raw material is as a kind of cheap and easy to get, abundance, reproducible bulk multi-hole material
Material has the possibility for preparing hydrophobic material;The preparation process of existing super hydrophobic material is complicated, and higher cost, the period is long, and its
Ultra-hydrophobicity is unstable.On this basis, we organically combine hydrophobicity and wood fiber biomass raw material, prepare excess of export
Hydrophobic wood fiber biomass material, it will the application for further widening wood fiber biomass raw material improves its economy
Value, while helping to solve the problems such as hydrophobic material is at high cost, preparation process is complicated.
Summary of the invention
Complicated for the preparation process of existing super hydrophobic material, higher cost, the period is long, and its ultra-hydrophobicity is unstable
Fixed defect it is an object of the invention to improve the utility value of wood fiber biomass raw material, while solving super hydrophobic material
High cost problem, provide a kind of super-hydrophobic wood fibre powder and preparation method thereof, the super-hydrophobic wood fibre is raw
Material takes full advantage of loose, porous, the inexpensive advantage of wood fiber biomass raw material, in conjunction with existing super-hydrophobic skill
Art prepares the super-hydrophobic wood fiber biomass material of very big application prospect.
The technical scheme adopted by the invention is that: a kind of super-hydrophobic wood fibre powder and preparation method thereof, including with
Lower step:
(1) a certain amount of lignocellulosic material is taken, powder is ground into using pulverizer;
(2) by wood fibre powder grafted silica particle made from step (1): 1:12~15 are by ammonium hydroxide by volume
It mixes and is added in conical flask with ethanol solution, separately to take a certain amount of tetraethyl orthosilicate to be dissolved in ethyl alcohol molten for 1:5~8 by volume
In liquid, keep it fully dispersed in ethanol solution, gained tetraethyl orthosilicate solution be added in conical flask described above later,
The fiber dust solid for weighing 5~15 parts again, is added together in conical flask described above, and constantly magnetic agitation makes it sufficiently
12h is reacted, gained mixture is placed in 80 DEG C of baking oven and is dried, the wood fibre powder for being grafted silica is solid
Body.
(3) wood fibre powder solid made from step (2) is subjected to modifying super hydrophobicity: silicon dioxide granule will be grafted
Fiber dust take 5~10 parts, be added in the silane coupling agent of heptane dissolution, continuous magnetic agitation is allowed to react 18h, will obtain
Solid in being evaporated in baking oven.
In super-hydrophobic wood fibre powder of one kind that patent provides according to the present invention and preparation method thereof, in step (1)
The lignocellulose raw material includes coffee grounds, peanut shell, stalk, timber, sawdust, reed, rice husk, cornstalk, bagasse
And corncob.
In super-hydrophobic wood fibre powder of one kind that patent provides according to the present invention and preparation method thereof, in step (1)
The wood fibre powder size is 20~200 mesh.
In super-hydrophobic wood fibre powder of one kind that patent provides according to the present invention and preparation method thereof, in step (2),
Magnetic agitation rotating speed is 300~500r/min.
In super-hydrophobic wood fibre powder of one kind that patent provides according to the present invention and preparation method thereof, in step (3)
The silane coupling agent is vinyl trichlorosilane, propyl-triethoxysilicane, vinyltriacetoxy silane, A151
(vinyltriethoxysilane), A171 (vinyltrimethoxysilane), A172 (vinyl three (beta-methoxy ethyoxyl) silicon
Alkane), octadecyl oxosilane, 1H, 1H, 2H, one or more of 2H- perfluorooctane mixing.
In super-hydrophobic wood fibre powder of one kind that patent provides according to the present invention and preparation method thereof, in step (3)
The volume ratio of the silane coupling agent and heptane is 1:400~1:1000.
In super-hydrophobic wood fibre powder of one kind that patent provides according to the present invention and preparation method thereof, in step (3)
The silane coupling agent is 0.1%~2% relative to the mass fraction of wood fibre powder.
In super-hydrophobic wood fibre powder of one kind that patent provides according to the present invention and preparation method thereof, in step (3)
Magnetic agitation rotating speed is 300~500r/min, and drying temperature is 40~120 DEG C.
The medicine have the advantages that
1, the super-hydrophobic wood fibre powder and preparation method thereof of one kind provided by the present invention, to wood fibre powder into
The super-hydrophobic wood fibre powder of row modifying super hydrophobicity, preparation belongs to high value added product, further widens wood fibre biology
The resource utilization of matter raw material improves the economic value of wood fiber biomass raw material.
2, the super-hydrophobic wood fibre powder and preparation method thereof of one kind of the present invention, it is raw materials used belong to it is sustainable
The biomass resource of development, safe and non-toxic and be easy to degrade, cheap, abundance, the hydrophobic material of preparation is non-toxic, no
Burn into can be generated to equipment will not cause environment pollution, and can also reduce cost of material.
3, the super-hydrophobic wood fibre powder and preparation method thereof of one kind of the present invention, device therefor is simply common,
Preparation method is simple, and technique is easy to control and production cost is low.
4, the super-hydrophobic wood fibre powder and preparation method thereof of one kind of the present invention, prepared is super-hydrophobic wooden
Fiber dust ultra-hydrophobicity is stablized.
The present invention will be further explained below with reference to the attached drawings, by taking coffee grounds as an example.
Detailed description of the invention
(a) is the electron microscope of coffee grounds raw material used in the implementation case 1 in Fig. 1
(b) is the coffee grounds electron microscope that case study on implementation 1 has been grafted silica in Fig. 1
In Fig. 1 (c) and (d) be coffee grounds be added it is silane coupler modified after electron microscope
Fig. 2 is the static contact angle figure of super-hydrophobic coffee grounds prepared by case study on implementation 1
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, technical matters step, condition and material is embodied, to this hair
Technical solution in bright embodiment is clearly and completely described, it is clear that described embodiment is only present invention a part
Embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not paying wound
Every other embodiment obtained under the premise of the property made labour, shall fall within the protection scope of the present invention.
Lignocellulose raw material of the invention includes coffee grounds, peanut shell, stalk, timber, sawdust, reed, rice husk, corn
All wood fiber biomass such as bar, bagasse and corncob.Hereinafter, by taking coffee grounds as an example, to the present invention be embodied into
Row explanation.
Embodiment 1
A kind of super-hydrophobic coffee residue material, prepares as follows:
Coffee grounds grafted silica particle: first measuring the ethanol solution of 5mL ammonium hydroxide and 65mL, and conical flask is added in mixing
In;Separately the tetraethyl orthosilicate of 5mL is taken to be dissolved in 25mL ethyl alcohol, keep it fully dispersed in ethanol solution, by gained silicic acid four
Ethyl ester solution is added in conical flask described above, and the coffee grounds of 40~200 mesh is collected with standard screen, weighs 10g coffee grounds, and one
And it is added in conical flask described above, and constantly magnetic agitation makes it sufficiently react 12h, magnetic agitation rotating speed 300r/
min;After the reaction was completed, gained mixture is placed in 80 DEG C of baking oven, until moisture is evaporated completely, has been grafted titanium dioxide
The coffee grounds solid of silicon, gained coffee grounds solid electron microscope are shown in that attached drawing 1 (b), attached drawing 1 (a) are that untreated coffee grounds is former
Expect electron microscope, discovery is compared, original coffee grounds surface is successfully grafted silica dioxide granule.
The coffee grounds for being grafted silica of preparation and silane coupling agent are subjected to modifying super hydrophobicity, obtain super-hydrophobic coffee
Coffee slag.By taking octadecyl oxosilane as an example, the octadecyl oxosilane of 500 μ L is measured, is dissolved in the heptane of 700mL, by gained
Solution is added in conical flask, and the coffee grounds solid obtained for being grafted silica is weighed 5g, the triangle burning is added
In bottle, continuous magnetic agitation reacts 18h, magnetic agitation rotating speed 300r/min, until the reaction is complete, by obtained solid in baking
It is evaporated in case, drying temperature is 60 DEG C, and super-hydrophobic coffee grounds obtained, surface topography is shown in attached drawing 1 (c), measures its contact angle
Attached drawing 2 is seen for 151.2 °.
Embodiment 2
A kind of super-hydrophobic coffee residue material, prepares as follows:
Coffee grounds grafted silica particle: first measuring the ethanol solution of 5mL ammonium hydroxide and 65mL, and conical flask is added in mixing
In;Separately the tetraethyl orthosilicate of 5mL is taken to be dissolved in 25mL ethyl alcohol, keep it fully dispersed in ethanol solution, by gained silicic acid four
Ethyl ester solution is added in conical flask described above, and the coffee grounds of 40~200 mesh is collected with standard screen, weighs 10g coffee grounds, and one
And it is added in conical flask described above, and constantly magnetic agitation makes it sufficiently react 12h, magnetic agitation rotating speed 400r/
min;After the reaction was completed, gained mixture is placed in 80 DEG C of baking oven, until moisture is evaporated completely, has been grafted titanium dioxide
The coffee grounds solid of silicon, shape characteristic are similar to Example 1.
The coffee grounds for being grafted silica of preparation and silane coupling agent are subjected to modifying super hydrophobicity, obtain super-hydrophobic coffee
Coffee slag.By taking octadecyl oxosilane as an example, the octadecyl oxosilane of 600 μ L is measured, is dissolved in the heptane of 700mL, by gained
Solution is added in conical flask, and the coffee grounds solid obtained for being grafted silica is weighed 5g, the triangle burning is added
In bottle, continuous magnetic agitation reacts 18h, magnetic agitation rotating speed 400r/min, until the reaction is complete, by obtained solid in baking
It is evaporated in case, drying temperature is 60 DEG C, and the surface topography that super-hydrophobic coffee grounds is made is shown in attached drawing 1 (d).
Embodiment 3
A kind of super-hydrophobic coffee residue material, prepares as follows:
Coffee grounds grafted silica particle: first measuring the ethanol solution of 5mL ammonium hydroxide and 65mL, and conical flask is added in mixing
In;Separately the tetraethyl orthosilicate of 5mL is taken to be dissolved in 25mL ethyl alcohol, keep it fully dispersed in ethanol solution, by gained silicic acid four
Ethyl ester solution is added in conical flask described above, and the coffee grounds of 40~200 mesh is collected with standard screen, weighs 10g coffee grounds, and one
And it is added in conical flask described above, and constantly magnetic agitation makes it sufficiently react 12h, magnetic agitation rotating speed 400r/
min;After the reaction was completed, gained mixture is placed in 80 DEG C of baking oven, until moisture is evaporated completely, has been grafted titanium dioxide
The coffee grounds solid of silicon.
The coffee grounds for being grafted silica of preparation and silane coupling agent are subjected to modifying super hydrophobicity, obtain super-hydrophobic coffee
Coffee slag.By taking octadecyl oxosilane as an example, the octadecyl oxosilane of 700 μ L is measured, is dissolved in the heptane of 700mL, by gained
Solution is added in conical flask, and the coffee grounds solid obtained for being grafted silica is weighed 5g, the triangle burning is added
In bottle, continuous magnetic agitation reacts 18h, magnetic agitation rotating speed 400r/min, until the reaction is complete, by obtained solid in baking
It is evaporated in case, drying temperature is 80 DEG C.
Embodiment 4
A kind of super-hydrophobic coffee residue material, prepares as follows:
Coffee grounds grafted silica particle: first measuring the ethanol solution of 5mL ammonium hydroxide and 65mL, and conical flask is added in mixing
In;Separately the tetraethyl orthosilicate of 5mL is taken to be dissolved in 25mL ethyl alcohol, keep it fully dispersed in ethanol solution, by gained silicic acid four
Ethyl ester solution is added in conical flask described above, and the coffee grounds of 40~200 mesh is collected with standard screen, weighs 10g coffee grounds, and one
And it is added in conical flask described above, and constantly magnetic agitation makes it sufficiently react 12h, magnetic agitation rotating speed 400r/
min;After the reaction was completed, gained mixture is placed in 80 DEG C of baking oven, until moisture is evaporated completely, has been grafted titanium dioxide
The coffee grounds solid of silicon.
The coffee grounds for being grafted silica of preparation and silane coupling agent are subjected to modifying super hydrophobicity, obtain super-hydrophobic coffee
Coffee slag.By taking octadecyl oxosilane as an example, the octadecyl oxosilane of 800 μ L is measured, is dissolved in the heptane of 700mL, by gained
Solution is added in conical flask, and the coffee grounds solid obtained for being grafted silica is weighed 5g, the triangle burning is added
In bottle, continuous magnetic agitation reacts 18h, magnetic agitation rotating speed 400r/min, until the reaction is complete, by obtained solid in baking
It is evaporated in case, drying temperature is 80 DEG C.
In the above various embodiments, by super-hydrophobic coffee grounds solid obtained uniformly, be laid on glass slide, measure its static state
Contact angle, test result are as shown in table 1.
Table 1: the test result of contact angle
By table 1, it can be concluded that, coffee residue material obtained all has ultra-hydrophobicity in embodiment.
Every technical staff's notice: of the invention although the present invention is described according to above-mentioned specific embodiment
Invention thought be not limited in the invention, any repacking with inventive concept will all be included in this patent protection of the patent right
In range.
Claims (8)
1. a kind of super-hydrophobic wood fibre powder and preparation method thereof, it is characterised in that the following steps are included:
(1) a certain amount of lignocellulosic material is taken, powder is ground into using pulverizer;
(2) by wood fibre powder grafted silica particle made from step (1): 1:12~15 are by ammonium hydroxide and second by volume
Alcoholic solution mixing is added in conical flask, and separately 1:5~8 take a certain amount of tetraethyl orthosilicate to be dissolved in ethanol solution by volume
In, keep it fully dispersed in ethanol solution, gained tetraethyl orthosilicate solution is added in conical flask described above later, then
The fiber dust solid for weighing 5~15 parts, is added together in conical flask described above, and constantly magnetic agitation keeps it sufficiently anti-
12h is answered, gained mixture is placed in 80 DEG C of baking oven and is dried, has been grafted the wood fibre powder solid of silica.
(3) wood fibre powder solid made from step (2) is subjected to modifying super hydrophobicity, the fibre of silicon dioxide granule will be grafted
Dimension powder takes 5~10 parts, is added in the silane coupling agent of heptane dissolution, continuous magnetic agitation is allowed to react 18h, consolidates what is obtained
Body in baking oven in being evaporated.
2. the super-hydrophobic wood fibre powder and preparation method thereof of one kind according to claim 1, it is characterised in that step
(1) lignocellulose raw material described in includes coffee grounds, peanut shell, stalk, timber, sawdust, reed, rice husk, cornstalk, sweet
Bagasse and corncob.
3. a kind of super-hydrophobic wood fibre powder and preparation method thereof according to claim 1, it is characterised in that institute in step (1)
The wood fibre powder size stated is 20~200 mesh.
4. the super-hydrophobic wood fibre powder and preparation method thereof of one kind according to claim 1, it is characterised in that in step
Suddenly in (2), magnetic agitation rotating speed is 300~500r/min.
5. the super-hydrophobic wood fibre powder and preparation method thereof of one kind according to claim 1, it is characterised in that step
(3) silane coupling agent described in be vinyl trichlorosilane, propyl-triethoxysilicane, vinyltriacetoxy silane,
A151 (vinyltriethoxysilane), A171 (vinyltrimethoxysilane), A172 (vinyl three (beta-methoxy ethyoxyl)
Silane), octadecyl oxosilane, 1H, 1H, 2H, one or more of 2H- perfluoro capryl triethoxysilane mixing.
6. the super-hydrophobic wood fibre powder and preparation method thereof of one kind according to claim 1, it is characterised in that step
(3) volume ratio of silane coupling agent and heptane described in is 1:400~1:1000.
7. the super-hydrophobic wood fibre powder and preparation method thereof of one kind according to claim 1, it is characterised in that step
(3) silane coupling agent described in is 0.1%~2% relative to the mass fraction of wood fibre powder.
8. the super-hydrophobic wood fibre powder and preparation method thereof of one kind according to claim 1, it is characterised in that step
(3) magnetic agitation rotating speed is 300~500r/min in, and drying temperature is 40~120 DEG C.
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CN110452307A (en) * | 2019-07-24 | 2019-11-15 | 衢州学院 | A kind of modified nanometer cellulose and preparation method thereof |
CN110523390A (en) * | 2019-08-23 | 2019-12-03 | 华南理工大学 | One kind having hydrophobic coffee slag adsorbent and preparation method thereof |
CN113577826A (en) * | 2021-07-27 | 2021-11-02 | 陕西科技大学 | Polyurethane foam loaded hydrophobic modified peanut shell composite material and preparation method thereof |
CN113832711A (en) * | 2021-09-01 | 2021-12-24 | 中国林业科学研究院林产化学工业研究所 | Nano silicon dioxide/fluorosilane grafted and modified wood fiber and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN110452307A (en) * | 2019-07-24 | 2019-11-15 | 衢州学院 | A kind of modified nanometer cellulose and preparation method thereof |
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CN110523390A (en) * | 2019-08-23 | 2019-12-03 | 华南理工大学 | One kind having hydrophobic coffee slag adsorbent and preparation method thereof |
CN113577826A (en) * | 2021-07-27 | 2021-11-02 | 陕西科技大学 | Polyurethane foam loaded hydrophobic modified peanut shell composite material and preparation method thereof |
CN113832711A (en) * | 2021-09-01 | 2021-12-24 | 中国林业科学研究院林产化学工业研究所 | Nano silicon dioxide/fluorosilane grafted and modified wood fiber and preparation method thereof |
CN114107436A (en) * | 2021-11-26 | 2022-03-01 | 华南理工大学 | Nano-cellulose/wood fiber composite paper-based saliva glucose detection chip |
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