CN109467968A - A kind of bolt MULTILAYER COMPOSITE anticorrosion new material - Google Patents
A kind of bolt MULTILAYER COMPOSITE anticorrosion new material Download PDFInfo
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- CN109467968A CN109467968A CN201811370923.0A CN201811370923A CN109467968A CN 109467968 A CN109467968 A CN 109467968A CN 201811370923 A CN201811370923 A CN 201811370923A CN 109467968 A CN109467968 A CN 109467968A
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- Prior art keywords
- parts
- bolt
- multilayer composite
- new material
- composite anticorrosion
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/46—Anti-skinning agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses bolt MULTILAYER COMPOSITE anticorrosion new materials, it is related to bolt anti-corrosion technical field, the material is a kind of bolt Multi-layer composite anticorrosion masking liquid, it includes following components in terms of mass fraction that it, which is formulated: 100-150 parts of organic siliconresin, 1-2 parts of anti-settling agent, 12-30 parts of trbasic zinc phosphate, acrylic emulsion 50-100 parts, 16-23 parts of micaceous iron oxide, 3-5 parts of adhesion promoter, 5-6 parts of anti skinning agent.The bolt MULTILAYER COMPOSITE anticorrosion new material; by organic siliconresin, trbasic zinc phosphate, acrylic emulsion, micaceous iron oxide, dimethylaminoethyl methacrylate, hydroxyethyl methacrylate, butyl acrylate, phenolic resin and between acrylic emulsion more materials with the use of the anticorrosive coating being prepared into; layer protecting film is integrally formed in coating; effectively spiralization is protected; bolt is avoided to corrode; cause operating equipment to be paralysed, brings serious economic loss for enterprise.
Description
Technical field
The present invention relates to bolt anti-corrosion technical field, specially a kind of bolt MULTILAYER COMPOSITE anticorrosion new material.
Background technique
The phenomenon that bolt is metal product, not can avoid its corrosion, and the environment used is different, corrosion also has apparent poor
Different, automobile is substantially grown up in recent years, the exhaust gas largely discharged, make in air full of corrosivity sulfide and nitride gas and
Particle, these are all the main reason for causing metal erosion.
The use scope of bolt is very extensive, and quantity demand is also very big, and bolt is contacted with ambient enviroment to be subject to corrode,
The corrosion of bolt will cause operating equipment paralysis, bring serious economic loss for enterprise, we have proposed a kind of bolts thus
MULTILAYER COMPOSITE anticorrosion new material, to solve the problems, such as this.
Summary of the invention
It is new the object of the invention is in order to make up for the deficiencies of the prior art, provide a kind of bolt MULTILAYER COMPOSITE anticorrosion
Material, it have the advantages that it is corrosion resistant, solve the problems, such as bolt be subject in use corrosion.
The present invention is in order to solve the above technical problems, provide the following technical solutions: a kind of bolt MULTILAYER COMPOSITE anticorrosion green wood
Material, the material are a kind of bolt Multi-layer composite anticorrosion masking liquid, and formula includes following components: organosilicon in terms of mass fraction
It is 100-150 parts of resin, 1-2 parts of anti-settling agent, 12-30 parts of trbasic zinc phosphate, acrylic emulsion 50-100 parts, 16-23 parts of micaceous iron oxide, attached
3-5 parts of adhesion promoter, 5-6 parts of anti skinning agent, 5-10 parts of antioxidant, 10-20 parts of dimethylaminoethyl methacrylate,
6-10 parts of hydroxyethyl methacrylate, 30-40 parts of butyl acrylate, 1-3 parts of defoaming agent, 10-15 parts of phenolic resin, water 30-50
Part.
Further, the preparation method of the anticorrosion masking liquid includes the following steps:
The inside that organic siliconresin is put into emulsion pot is constantly mixed, and injects anti-settling agent wherein simultaneously by S1, after dispersing
Obtain viscous liquid;
S2, the viscous liquid obtained in step sl are added acrylic emulsion and water, disperse 10- under the conditions of 300-500rpm
30min obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by trbasic zinc phosphate, dimethylaminoethyl methacrylate, hydroxyethyl methacrylate second
Ester, butyl acrylate and micaceous iron oxide powder it is evenly dispersed with emulsion in, 1-2h is stirred with the speed of 300-500rpm,
Obtain mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and adhesion promoter, anti-skinning are added dropwise thereto
Agent and antioxidant, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, and defoaming agent is added and phenolic resin continues to disperse
20-40min, MULTILAYER COMPOSITE anticorrosion new material.
Further, the defoaming agent is lower alcohol, the model SD-202 of the defoaming agent.
Further, the organic siliconresin is first class organic siliconresin, and the anti-settling agent is organobentonite.
Further, described anticorrosive paint using when need to uniformly be applied to the outer surface of spiral, used after being allowed to dry.
Further, the anti skinning agent is dipentene, and described non-volatile part of adhesion promoter accounts for 78%-82%.
Compared with prior art, the bolt MULTILAYER COMPOSITE anticorrosion new material have it is following the utility model has the advantages that
1, the present invention is by the setting of defoaming agent, can effectively inhibit the generation of coating foam in production, and reduction is seemingly
The tension of coating surface.
2, the present invention is by the setting of anti-settling agent, it makes coating have thixotropy, and viscosity greatly improves.
3, setting of the present invention by anti skinning agent, crust forming agent vapour pressure highly volatile with higher, the steam of generation
The space in tank is filled, surface of the paint film and air exclusion are made, plays the role of oxygen barrier, avoids coating skinning.
4, the present invention passes through organic siliconresin, trbasic zinc phosphate, acrylic emulsion, micaceous iron oxide, dimethylaminoethyl acrylate methyl base ammonia
Base ethyl ester, hydroxyethyl methacrylate, butyl acrylate, phenolic resin and between acrylic emulsion more materials with the use of system
It is standby at anticorrosive coating, coating is integrally formed layer protecting film, effectively protects to spiralization, avoids bolt from occurring rotten
Erosion, causes operating equipment to be paralysed, and brings serious economic loss for enterprise.
Specific embodiment
Based on the embodiments of the present invention, those of ordinary skill in the art are obtained without making creative work
The every other embodiment obtained, shall fall within the protection scope of the present invention.
Embodiment one
A kind of bolt MULTILAYER COMPOSITE anticorrosion new material, the material are a kind of bolt Multi-layer composite anticorrosion masking liquid, formula
Include following components in terms of mass fraction: 100 parts of organic siliconresin, 1 part of anti-settling agent, 12 parts of trbasic zinc phosphate, 50 parts of acrylic emulsion, cloud
16 parts of female iron oxide, 3 parts of adhesion promoter, 5 parts of anti skinning agent, 5 parts of antioxidant, dimethylaminoethyl methacrylate
10 parts, 6 parts of hydroxyethyl methacrylate, 30 parts of butyl acrylate, 1 part of defoaming agent, 10 parts of phenolic resin, 30 parts of water.
The preparation method of anticorrosion masking liquid includes the following steps:
S1 constantly mixes the inside that 100 parts of organic siliconresin are put into emulsion pot, and injects 1 part of anti-settling agent wherein simultaneously, to
Viscous liquid is obtained after dispersion;
S2,50 parts and 30 parts of water of acrylic emulsion are added in the viscous liquid obtained in step sl, under the conditions of 300-500rpm
Disperse 10-30min, obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by 12 parts of trbasic zinc phosphate, dimethylaminoethyl methacrylate, 10 parts, methyl-prop
6 parts of olefin(e) acid hydroxyl ethyl ester, 30 parts of butyl acrylate and 16 parts of powder of micaceous iron oxide it is evenly dispersed with emulsion in, with 300-
The speed of 500rpm stirs 1-2h, obtains mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and 3 parts of adhesion promoter is added dropwise thereto, prevents
5 parts and 5 parts of antioxidant of crust forming agent, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, be added 10 parts of 1 part of defoaming agent and phenolic resin after
Continuous dispersion 20-40min, MULTILAYER COMPOSITE anticorrosion new material.
Embodiment two
A kind of bolt MULTILAYER COMPOSITE anticorrosion new material, the material are a kind of bolt Multi-layer composite anticorrosion masking liquid, formula
Include following components in terms of mass fraction: 150 parts of organic siliconresin, 2 parts of anti-settling agent, 30 parts of trbasic zinc phosphate, 100 parts of acrylic emulsion,
23 parts of micaceous iron oxide, 5 parts of adhesion promoter, 6 parts of anti-skinning, 10 parts of antioxidant, dimethylamine second
20 parts of ester, 10 parts of hydroxyethyl methacrylate, 40 parts of butyl acrylate, 3 parts of defoaming agent, 15 parts of phenolic resin, 50 parts of water.
The preparation method of anticorrosion masking liquid includes the following steps:
S1 constantly mixes the inside that 150 parts of organic siliconresin are put into emulsion pot, and injects 2 parts of anti-settling agent wherein simultaneously, to
Viscous liquid is obtained after dispersion;
S2,100 parts and 50 parts of water of acrylic emulsion are added in the viscous liquid obtained in step sl, under the conditions of 300-500rpm
Disperse 10-30min, obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by 30 parts of trbasic zinc phosphate, 20 parts of dimethylaminoethyl methacrylate, methyl-prop
10 parts of olefin(e) acid hydroxyl ethyl ester, 40 parts of butyl acrylate and 23 parts of powder of micaceous iron oxide it is evenly dispersed with emulsion in, with 300-
The speed of 500rpm stirs 1-2h, obtains mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and 5 parts of adhesion promoter is added dropwise thereto, prevents
6 parts and 10 parts of antioxidant of crust forming agent, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, be added 15 parts of 3 parts of defoaming agent and phenolic resin after
Continuous dispersion 20-40min, MULTILAYER COMPOSITE anticorrosion new material.
Embodiment three
Existing anticorrosive coating currently on the market, formula include following components: organic siliconresin 150 in terms of mass fraction
Part, 100 parts of acrylic emulsion, 23 parts of micaceous iron oxide, 5 parts of adhesion promoter, 10 parts of hydroxyethyl methacrylate, acrylic acid fourth
40 parts of ester, 50 parts of water.
The preparation method of anticorrosion masking liquid includes the following steps:
S1, by 120 parts of organic siliconresin, 20 parts of addition emulsion pots inside uniform stirrings of 90 parts of acrylic emulsion and micaceous iron oxide obtain
To mixed liquor A;
S2, by 90 parts of 4 parts of adhesion promoter, 7 parts of hydroxyethyl methacrylate, 38 parts of butyl acrylate and water addition step S1
Obtained in mixed liquor A, to react 50min under the conditions of 100-200rpm, obtain anticorrosive coating.
MULTILAYER COMPOSITE anticorrosion new material and existing anticorrosive coating is taken to be detected at random, efficacy detection result is such as
Following table:
Classification | Embodiment one | Embodiment two | Embodiment three |
Adhesive force | Level-one | Level-one | Three-level |
Rate of corrosion | 0.03mm/a | 0.035mm/a | 2mm/a |
In the description of the present invention, the terms "include", "comprise" or its any other variant are intended to the packet of nonexcludability
Contain, so that the process, method, article or equipment for including a series of elements not only includes those elements, but also including
Other elements that are not explicitly listed, or further include for elements inherent to such a process, method, article, or device.
In the absence of more restrictions, the element limited by sentence " including a reference structure ", it is not excluded that including described
There is also other identical elements in the process, method, article or equipment of element.It should be noted that, in this document, such as
The relational terms of " first ", " second " or the like are used merely to distinguish an entity or operation with another entity or operation
It comes, without necessarily requiring or implying between these entities or operation, there are any actual relationship or orders.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
1. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material, it is characterised in that: the material is a kind of bolt Multi-layer composite anti-corrosion
Masking liquid is lost, formula includes following components in terms of mass fraction: 100-150 parts of organic siliconresin, 1-2 parts of anti-settling agent, trbasic zinc phosphate
12-30 parts, acrylic emulsion 50-100 parts, 16-23 parts of micaceous iron oxide, 3-5 parts of adhesion promoter, 5-6 parts of anti skinning agent, resist
5-10 parts of oxidant, 10-20 parts of dimethylaminoethyl methacrylate, 6-10 parts of hydroxyethyl methacrylate, acrylic acid fourth
30-40 parts of ester, 1-3 parts of defoaming agent, 10-15 parts of phenolic resin, 30-50 parts of water.
2. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the anticorrosion applies
The preparation method of liquid includes the following steps:
The inside that organic siliconresin is put into emulsion pot is constantly mixed, and injects anti-settling agent wherein simultaneously by S1, after dispersing
Obtain viscous liquid;
S2, the viscous liquid obtained in step sl are added acrylic emulsion and water, disperse 10- under the conditions of 300-500rpm
30min obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by trbasic zinc phosphate, dimethylaminoethyl methacrylate, hydroxyethyl methacrylate second
Ester, butyl acrylate and micaceous iron oxide powder it is evenly dispersed with emulsion in, 1-2h is stirred with the speed of 300-500rpm,
Obtain mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and adhesion promoter, anti-skinning are added dropwise thereto
Agent and antioxidant, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, and defoaming agent is added and phenolic resin continues to disperse
20-40min, MULTILAYER COMPOSITE anticorrosion new material.
3. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the defoaming agent is
Lower alcohol, the model SD-202 of the defoaming agent.
4. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the organosilicon tree
Rouge is first class organic siliconresin, and the anti-settling agent is organobentonite.
5. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: described anti-corrosion applies
Material need to uniformly be applied to the outer surface of spiral when using, use after being allowed to dry.
6. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the anti skinning agent
For dipentene, described non-volatile part of adhesion promoter accounts for 78%-82%.
Priority Applications (1)
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CN201811370923.0A CN109467968A (en) | 2018-11-18 | 2018-11-18 | A kind of bolt MULTILAYER COMPOSITE anticorrosion new material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811370923.0A CN109467968A (en) | 2018-11-18 | 2018-11-18 | A kind of bolt MULTILAYER COMPOSITE anticorrosion new material |
Publications (1)
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CN109467968A true CN109467968A (en) | 2019-03-15 |
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Family Applications (1)
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CN201811370923.0A Pending CN109467968A (en) | 2018-11-18 | 2018-11-18 | A kind of bolt MULTILAYER COMPOSITE anticorrosion new material |
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CN (1) | CN109467968A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110003545A (en) * | 2019-04-28 | 2019-07-12 | 常州春南环保设备有限公司 | A kind of preparation method of the anticorrosive new material of environmental protection |
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KR20050094658A (en) * | 2004-03-24 | 2005-09-28 | 주식회사 나노코 | A composition for steel coating materials and a manufacturing method therefor |
JP2012082376A (en) * | 2010-10-06 | 2012-04-26 | Shinrin Kenkyusho:Kk | Iron rust preventive coating |
CN104231827A (en) * | 2014-09-19 | 2014-12-24 | 苏州云舒新材料科技有限公司 | Anticorrosive coating for household appliances and preparation method thereof |
CN106280987A (en) * | 2016-10-09 | 2017-01-04 | 湖南博弈飞装备新材料研究所 | Transparent anticorrosive coating of rustless steel and preparation method thereof |
CN106978040A (en) * | 2017-03-16 | 2017-07-25 | 孟鋆辉 | A kind of special interior strong antiwear powder paint of anti-corrosion of oil extraction in oil field well casing |
CN108410288A (en) * | 2018-02-01 | 2018-08-17 | 东莞市佳乾新材料科技有限公司 | A kind of watery anti-corrosion vinyl acetate emulsion coating |
-
2018
- 2018-11-18 CN CN201811370923.0A patent/CN109467968A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20050094658A (en) * | 2004-03-24 | 2005-09-28 | 주식회사 나노코 | A composition for steel coating materials and a manufacturing method therefor |
JP2012082376A (en) * | 2010-10-06 | 2012-04-26 | Shinrin Kenkyusho:Kk | Iron rust preventive coating |
CN104231827A (en) * | 2014-09-19 | 2014-12-24 | 苏州云舒新材料科技有限公司 | Anticorrosive coating for household appliances and preparation method thereof |
CN106280987A (en) * | 2016-10-09 | 2017-01-04 | 湖南博弈飞装备新材料研究所 | Transparent anticorrosive coating of rustless steel and preparation method thereof |
CN106978040A (en) * | 2017-03-16 | 2017-07-25 | 孟鋆辉 | A kind of special interior strong antiwear powder paint of anti-corrosion of oil extraction in oil field well casing |
CN108410288A (en) * | 2018-02-01 | 2018-08-17 | 东莞市佳乾新材料科技有限公司 | A kind of watery anti-corrosion vinyl acetate emulsion coating |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110003545A (en) * | 2019-04-28 | 2019-07-12 | 常州春南环保设备有限公司 | A kind of preparation method of the anticorrosive new material of environmental protection |
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