CN109467968A - A kind of bolt MULTILAYER COMPOSITE anticorrosion new material - Google Patents

A kind of bolt MULTILAYER COMPOSITE anticorrosion new material Download PDF

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Publication number
CN109467968A
CN109467968A CN201811370923.0A CN201811370923A CN109467968A CN 109467968 A CN109467968 A CN 109467968A CN 201811370923 A CN201811370923 A CN 201811370923A CN 109467968 A CN109467968 A CN 109467968A
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CN
China
Prior art keywords
parts
bolt
multilayer composite
new material
composite anticorrosion
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Pending
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CN201811370923.0A
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Chinese (zh)
Inventor
张雅慧
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Individual
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Individual
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Priority to CN201811370923.0A priority Critical patent/CN109467968A/en
Publication of CN109467968A publication Critical patent/CN109467968A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/45Anti-settling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/46Anti-skinning agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses bolt MULTILAYER COMPOSITE anticorrosion new materials, it is related to bolt anti-corrosion technical field, the material is a kind of bolt Multi-layer composite anticorrosion masking liquid, it includes following components in terms of mass fraction that it, which is formulated: 100-150 parts of organic siliconresin, 1-2 parts of anti-settling agent, 12-30 parts of trbasic zinc phosphate, acrylic emulsion 50-100 parts, 16-23 parts of micaceous iron oxide, 3-5 parts of adhesion promoter, 5-6 parts of anti skinning agent.The bolt MULTILAYER COMPOSITE anticorrosion new material; by organic siliconresin, trbasic zinc phosphate, acrylic emulsion, micaceous iron oxide, dimethylaminoethyl methacrylate, hydroxyethyl methacrylate, butyl acrylate, phenolic resin and between acrylic emulsion more materials with the use of the anticorrosive coating being prepared into; layer protecting film is integrally formed in coating; effectively spiralization is protected; bolt is avoided to corrode; cause operating equipment to be paralysed, brings serious economic loss for enterprise.

Description

A kind of bolt MULTILAYER COMPOSITE anticorrosion new material
Technical field
The present invention relates to bolt anti-corrosion technical field, specially a kind of bolt MULTILAYER COMPOSITE anticorrosion new material.
Background technique
The phenomenon that bolt is metal product, not can avoid its corrosion, and the environment used is different, corrosion also has apparent poor Different, automobile is substantially grown up in recent years, the exhaust gas largely discharged, make in air full of corrosivity sulfide and nitride gas and Particle, these are all the main reason for causing metal erosion.
The use scope of bolt is very extensive, and quantity demand is also very big, and bolt is contacted with ambient enviroment to be subject to corrode, The corrosion of bolt will cause operating equipment paralysis, bring serious economic loss for enterprise, we have proposed a kind of bolts thus MULTILAYER COMPOSITE anticorrosion new material, to solve the problems, such as this.
Summary of the invention
It is new the object of the invention is in order to make up for the deficiencies of the prior art, provide a kind of bolt MULTILAYER COMPOSITE anticorrosion Material, it have the advantages that it is corrosion resistant, solve the problems, such as bolt be subject in use corrosion.
The present invention is in order to solve the above technical problems, provide the following technical solutions: a kind of bolt MULTILAYER COMPOSITE anticorrosion green wood Material, the material are a kind of bolt Multi-layer composite anticorrosion masking liquid, and formula includes following components: organosilicon in terms of mass fraction It is 100-150 parts of resin, 1-2 parts of anti-settling agent, 12-30 parts of trbasic zinc phosphate, acrylic emulsion 50-100 parts, 16-23 parts of micaceous iron oxide, attached 3-5 parts of adhesion promoter, 5-6 parts of anti skinning agent, 5-10 parts of antioxidant, 10-20 parts of dimethylaminoethyl methacrylate, 6-10 parts of hydroxyethyl methacrylate, 30-40 parts of butyl acrylate, 1-3 parts of defoaming agent, 10-15 parts of phenolic resin, water 30-50 Part.
Further, the preparation method of the anticorrosion masking liquid includes the following steps:
The inside that organic siliconresin is put into emulsion pot is constantly mixed, and injects anti-settling agent wherein simultaneously by S1, after dispersing Obtain viscous liquid;
S2, the viscous liquid obtained in step sl are added acrylic emulsion and water, disperse 10- under the conditions of 300-500rpm 30min obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by trbasic zinc phosphate, dimethylaminoethyl methacrylate, hydroxyethyl methacrylate second Ester, butyl acrylate and micaceous iron oxide powder it is evenly dispersed with emulsion in, 1-2h is stirred with the speed of 300-500rpm, Obtain mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and adhesion promoter, anti-skinning are added dropwise thereto Agent and antioxidant, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, and defoaming agent is added and phenolic resin continues to disperse 20-40min, MULTILAYER COMPOSITE anticorrosion new material.
Further, the defoaming agent is lower alcohol, the model SD-202 of the defoaming agent.
Further, the organic siliconresin is first class organic siliconresin, and the anti-settling agent is organobentonite.
Further, described anticorrosive paint using when need to uniformly be applied to the outer surface of spiral, used after being allowed to dry.
Further, the anti skinning agent is dipentene, and described non-volatile part of adhesion promoter accounts for 78%-82%.
Compared with prior art, the bolt MULTILAYER COMPOSITE anticorrosion new material have it is following the utility model has the advantages that
1, the present invention is by the setting of defoaming agent, can effectively inhibit the generation of coating foam in production, and reduction is seemingly The tension of coating surface.
2, the present invention is by the setting of anti-settling agent, it makes coating have thixotropy, and viscosity greatly improves.
3, setting of the present invention by anti skinning agent, crust forming agent vapour pressure highly volatile with higher, the steam of generation The space in tank is filled, surface of the paint film and air exclusion are made, plays the role of oxygen barrier, avoids coating skinning.
4, the present invention passes through organic siliconresin, trbasic zinc phosphate, acrylic emulsion, micaceous iron oxide, dimethylaminoethyl acrylate methyl base ammonia Base ethyl ester, hydroxyethyl methacrylate, butyl acrylate, phenolic resin and between acrylic emulsion more materials with the use of system It is standby at anticorrosive coating, coating is integrally formed layer protecting film, effectively protects to spiralization, avoids bolt from occurring rotten Erosion, causes operating equipment to be paralysed, and brings serious economic loss for enterprise.
Specific embodiment
Based on the embodiments of the present invention, those of ordinary skill in the art are obtained without making creative work The every other embodiment obtained, shall fall within the protection scope of the present invention.
Embodiment one
A kind of bolt MULTILAYER COMPOSITE anticorrosion new material, the material are a kind of bolt Multi-layer composite anticorrosion masking liquid, formula Include following components in terms of mass fraction: 100 parts of organic siliconresin, 1 part of anti-settling agent, 12 parts of trbasic zinc phosphate, 50 parts of acrylic emulsion, cloud 16 parts of female iron oxide, 3 parts of adhesion promoter, 5 parts of anti skinning agent, 5 parts of antioxidant, dimethylaminoethyl methacrylate 10 parts, 6 parts of hydroxyethyl methacrylate, 30 parts of butyl acrylate, 1 part of defoaming agent, 10 parts of phenolic resin, 30 parts of water.
The preparation method of anticorrosion masking liquid includes the following steps:
S1 constantly mixes the inside that 100 parts of organic siliconresin are put into emulsion pot, and injects 1 part of anti-settling agent wherein simultaneously, to Viscous liquid is obtained after dispersion;
S2,50 parts and 30 parts of water of acrylic emulsion are added in the viscous liquid obtained in step sl, under the conditions of 300-500rpm Disperse 10-30min, obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by 12 parts of trbasic zinc phosphate, dimethylaminoethyl methacrylate, 10 parts, methyl-prop 6 parts of olefin(e) acid hydroxyl ethyl ester, 30 parts of butyl acrylate and 16 parts of powder of micaceous iron oxide it is evenly dispersed with emulsion in, with 300- The speed of 500rpm stirs 1-2h, obtains mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and 3 parts of adhesion promoter is added dropwise thereto, prevents 5 parts and 5 parts of antioxidant of crust forming agent, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, be added 10 parts of 1 part of defoaming agent and phenolic resin after Continuous dispersion 20-40min, MULTILAYER COMPOSITE anticorrosion new material.
Embodiment two
A kind of bolt MULTILAYER COMPOSITE anticorrosion new material, the material are a kind of bolt Multi-layer composite anticorrosion masking liquid, formula Include following components in terms of mass fraction: 150 parts of organic siliconresin, 2 parts of anti-settling agent, 30 parts of trbasic zinc phosphate, 100 parts of acrylic emulsion, 23 parts of micaceous iron oxide, 5 parts of adhesion promoter, 6 parts of anti-skinning, 10 parts of antioxidant, dimethylamine second 20 parts of ester, 10 parts of hydroxyethyl methacrylate, 40 parts of butyl acrylate, 3 parts of defoaming agent, 15 parts of phenolic resin, 50 parts of water.
The preparation method of anticorrosion masking liquid includes the following steps:
S1 constantly mixes the inside that 150 parts of organic siliconresin are put into emulsion pot, and injects 2 parts of anti-settling agent wherein simultaneously, to Viscous liquid is obtained after dispersion;
S2,100 parts and 50 parts of water of acrylic emulsion are added in the viscous liquid obtained in step sl, under the conditions of 300-500rpm Disperse 10-30min, obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by 30 parts of trbasic zinc phosphate, 20 parts of dimethylaminoethyl methacrylate, methyl-prop 10 parts of olefin(e) acid hydroxyl ethyl ester, 40 parts of butyl acrylate and 23 parts of powder of micaceous iron oxide it is evenly dispersed with emulsion in, with 300- The speed of 500rpm stirs 1-2h, obtains mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and 5 parts of adhesion promoter is added dropwise thereto, prevents 6 parts and 10 parts of antioxidant of crust forming agent, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, be added 15 parts of 3 parts of defoaming agent and phenolic resin after Continuous dispersion 20-40min, MULTILAYER COMPOSITE anticorrosion new material.
Embodiment three
Existing anticorrosive coating currently on the market, formula include following components: organic siliconresin 150 in terms of mass fraction Part, 100 parts of acrylic emulsion, 23 parts of micaceous iron oxide, 5 parts of adhesion promoter, 10 parts of hydroxyethyl methacrylate, acrylic acid fourth 40 parts of ester, 50 parts of water.
The preparation method of anticorrosion masking liquid includes the following steps:
S1, by 120 parts of organic siliconresin, 20 parts of addition emulsion pots inside uniform stirrings of 90 parts of acrylic emulsion and micaceous iron oxide obtain To mixed liquor A;
S2, by 90 parts of 4 parts of adhesion promoter, 7 parts of hydroxyethyl methacrylate, 38 parts of butyl acrylate and water addition step S1 Obtained in mixed liquor A, to react 50min under the conditions of 100-200rpm, obtain anticorrosive coating.
MULTILAYER COMPOSITE anticorrosion new material and existing anticorrosive coating is taken to be detected at random, efficacy detection result is such as Following table:
Classification Embodiment one Embodiment two Embodiment three
Adhesive force Level-one Level-one Three-level
Rate of corrosion 0.03mm/a 0.035mm/a 2mm/a
In the description of the present invention, the terms "include", "comprise" or its any other variant are intended to the packet of nonexcludability Contain, so that the process, method, article or equipment for including a series of elements not only includes those elements, but also including Other elements that are not explicitly listed, or further include for elements inherent to such a process, method, article, or device. In the absence of more restrictions, the element limited by sentence " including a reference structure ", it is not excluded that including described There is also other identical elements in the process, method, article or equipment of element.It should be noted that, in this document, such as The relational terms of " first ", " second " or the like are used merely to distinguish an entity or operation with another entity or operation It comes, without necessarily requiring or implying between these entities or operation, there are any actual relationship or orders.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material, it is characterised in that: the material is a kind of bolt Multi-layer composite anti-corrosion Masking liquid is lost, formula includes following components in terms of mass fraction: 100-150 parts of organic siliconresin, 1-2 parts of anti-settling agent, trbasic zinc phosphate 12-30 parts, acrylic emulsion 50-100 parts, 16-23 parts of micaceous iron oxide, 3-5 parts of adhesion promoter, 5-6 parts of anti skinning agent, resist 5-10 parts of oxidant, 10-20 parts of dimethylaminoethyl methacrylate, 6-10 parts of hydroxyethyl methacrylate, acrylic acid fourth 30-40 parts of ester, 1-3 parts of defoaming agent, 10-15 parts of phenolic resin, 30-50 parts of water.
2. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the anticorrosion applies The preparation method of liquid includes the following steps:
The inside that organic siliconresin is put into emulsion pot is constantly mixed, and injects anti-settling agent wherein simultaneously by S1, after dispersing Obtain viscous liquid;
S2, the viscous liquid obtained in step sl are added acrylic emulsion and water, disperse 10- under the conditions of 300-500rpm 30min obtains emulsion;
Emulsion is warming up to 50 DEG C by S3, and by trbasic zinc phosphate, dimethylaminoethyl methacrylate, hydroxyethyl methacrylate second Ester, butyl acrylate and micaceous iron oxide powder it is evenly dispersed with emulsion in, 1-2h is stirred with the speed of 300-500rpm, Obtain mixing liquid A;
Mixing liquid A obtained in step S3 is warming up to 80-90 DEG C by S4, and adhesion promoter, anti-skinning are added dropwise thereto Agent and antioxidant, and mixing liquid B is obtained to react 30min under the conditions of 100-200rpm;
Mixing liquid B temperature obtained in step S4 is reduced to 30 degree by S5, and defoaming agent is added and phenolic resin continues to disperse 20-40min, MULTILAYER COMPOSITE anticorrosion new material.
3. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the defoaming agent is Lower alcohol, the model SD-202 of the defoaming agent.
4. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the organosilicon tree Rouge is first class organic siliconresin, and the anti-settling agent is organobentonite.
5. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: described anti-corrosion applies Material need to uniformly be applied to the outer surface of spiral when using, use after being allowed to dry.
6. a kind of bolt MULTILAYER COMPOSITE anticorrosion new material according to claim 1, it is characterised in that: the anti skinning agent For dipentene, described non-volatile part of adhesion promoter accounts for 78%-82%.
CN201811370923.0A 2018-11-18 2018-11-18 A kind of bolt MULTILAYER COMPOSITE anticorrosion new material Pending CN109467968A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811370923.0A CN109467968A (en) 2018-11-18 2018-11-18 A kind of bolt MULTILAYER COMPOSITE anticorrosion new material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811370923.0A CN109467968A (en) 2018-11-18 2018-11-18 A kind of bolt MULTILAYER COMPOSITE anticorrosion new material

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CN109467968A true CN109467968A (en) 2019-03-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003545A (en) * 2019-04-28 2019-07-12 常州春南环保设备有限公司 A kind of preparation method of the anticorrosive new material of environmental protection

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050094658A (en) * 2004-03-24 2005-09-28 주식회사 나노코 A composition for steel coating materials and a manufacturing method therefor
JP2012082376A (en) * 2010-10-06 2012-04-26 Shinrin Kenkyusho:Kk Iron rust preventive coating
CN104231827A (en) * 2014-09-19 2014-12-24 苏州云舒新材料科技有限公司 Anticorrosive coating for household appliances and preparation method thereof
CN106280987A (en) * 2016-10-09 2017-01-04 湖南博弈飞装备新材料研究所 Transparent anticorrosive coating of rustless steel and preparation method thereof
CN106978040A (en) * 2017-03-16 2017-07-25 孟鋆辉 A kind of special interior strong antiwear powder paint of anti-corrosion of oil extraction in oil field well casing
CN108410288A (en) * 2018-02-01 2018-08-17 东莞市佳乾新材料科技有限公司 A kind of watery anti-corrosion vinyl acetate emulsion coating

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050094658A (en) * 2004-03-24 2005-09-28 주식회사 나노코 A composition for steel coating materials and a manufacturing method therefor
JP2012082376A (en) * 2010-10-06 2012-04-26 Shinrin Kenkyusho:Kk Iron rust preventive coating
CN104231827A (en) * 2014-09-19 2014-12-24 苏州云舒新材料科技有限公司 Anticorrosive coating for household appliances and preparation method thereof
CN106280987A (en) * 2016-10-09 2017-01-04 湖南博弈飞装备新材料研究所 Transparent anticorrosive coating of rustless steel and preparation method thereof
CN106978040A (en) * 2017-03-16 2017-07-25 孟鋆辉 A kind of special interior strong antiwear powder paint of anti-corrosion of oil extraction in oil field well casing
CN108410288A (en) * 2018-02-01 2018-08-17 东莞市佳乾新材料科技有限公司 A kind of watery anti-corrosion vinyl acetate emulsion coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003545A (en) * 2019-04-28 2019-07-12 常州春南环保设备有限公司 A kind of preparation method of the anticorrosive new material of environmental protection

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