CN109467753A - Clothing expansion glue mixture - Google Patents
Clothing expansion glue mixture Download PDFInfo
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- CN109467753A CN109467753A CN201710800041.2A CN201710800041A CN109467753A CN 109467753 A CN109467753 A CN 109467753A CN 201710800041 A CN201710800041 A CN 201710800041A CN 109467753 A CN109467753 A CN 109467753A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The present invention provides a kind of expanding glue for spray coating clothing, it is that vulcanizing agent, oxygen agent, reinforcing agent, promotor, softening agent, filler and defoaming agent is added in mixing in rubber major ingredient, is made using after mixer or mill mixing material through vulcanizing press high temperature and pressure.The preparation method is as follows: firstly, rubber major ingredient is put into open mill carry out low temperature it is thin it is logical plasticate, each ingredient is sequentially added and is sufficiently kneaded, it is thin it is logical repeatedly, park；Then, back mixing processing is carried out, vulcanizing agent is added, thin logical multiple, film is made in slice；Finally, planting piece is put into vulcanizer press cure, expansion glue can be produced.
Description
Technical field
The present invention relates to a kind of expansion glue and its production technology, espespecially a kind of clothing expansion glue mixture.
Background technique
Mostly using natural emulsion as rubber major ingredient, powder is ground for the preparation of traditional expansion glue, ammonia solvent is added, then
It is blended into glue to be stirred, parks a period of time, the sizing material after mixing is put into after being impregnated one hour in mold, by the expansion
Glue semi-finished product are dried or are dried, then demoulding, after drying or drying again, can obtain expansion glue product.This kind of expansion glue one
As be used to be sprayed at clothing when clothing, obtain beautiful pattern.
Due to containing a large amount of ammonium hydroxide in powder solvent and glue in the expansion glue of this kind of technique preparation, powder is stirred with latex
A large amount of ammonia tastes are issued when mixing, and waste material cannot recycle again, not only cause seriously to pollute and waste, work in process of production
Make personnel's Long Term Contact and very major injury is also resulted in body；Secondly, traditional expansion glue preparation process is fairly time consuming, high-volume is raw
Produce low efficiency；Again, since the corrosion resistance of latex is poor, the expansion glue produced using latex as rubber major ingredient is easy to aging,
Rupture.
Therefore it provides the system that a kind of corrosion resistance is strong, preparation process is simple, pollution-free, waste recycling utilization rate is high
Clothing expanding glue for spray coating and its production technology are actually necessary.
Summary of the invention
In order to overcome the deficiencies of the prior art, that it is an object of that present invention to provide a kind of corrosion resistancies is strong, preparation process is simple, nothing
Pollution, waste recycling utilization rate high expanding glue for spray coating clothing and its production technology.
The present invention is implemented by the following technical programs.Activating agent, softening is added in sequentially mixing in rubber major ingredient
The ingredients such as agent, promotor, filler, reinforcing agent, anti-aging agent, defoaming agent, vulcanizing agent, wherein natural rubber can be selected in rubber major ingredient
The proportion of glue, chlorinated butyl, EPDM or chlorosulfonated polyethylene, blend glue stuff is listed below:
Using natural rubber as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of natural rubber
4 parts of sulphur
5 parts of nano zine oxide
2 parts of altax
0.2 part of promotor TT
2 parts of antioxidant H S-P11
30 parts of barium sulfate
20 parts of carbon black
1 part of stearic acid
10 parts of machine oil
5 parts of defoaming agent
Using chlorinated butyl as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of chlorinated butyl
1.5 parts of sulphur
7 parts of nano zine oxide
1.5 parts of captax
1.5 parts of promotor ZDC
0.5 part of promotor TT
1 part of antioxidant H S-P11
30 parts of barium sulfate
20 parts of carbon black
1 part of stearic acid
10 parts of paraffin oil
5 parts of defoaming agent
Using chlorinated butyl and natural rubber as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
50 parts of chlorinated butyl
50 parts of natural rubber
2 parts of sulphur
5 parts of nano zine oxide
1 part of captax
1 part of promotor ZDC
0.5 part of promotor TT
1 part of anti-aging agent
30 parts of barium sulfate
20 parts of carbon black
0.5 part of stearic acid
10 parts of paraffin oil
3 parts of defoaming agent
5 parts of calcium oxide
Using EPDM as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of EPDM
1.5 parts of sulphur
10 parts of zinc oxide
3 parts of promotor EG-3
1 part of antioxidant 4010NA
50 parts of barium sulfate
20 parts of carbon black
0.8 part of stearic acid
25 parts of naphthenic oil
3 parts of defoaming agent RG
Using chlorosulfonated polyethylene as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of chlorosulfonated polyethylene
5 parts of magnesia
1.5 parts of promotor TRA
1 part of anti-aging agent RD
50 parts of barium sulfate
10 parts of carbon black
1 part of stearic acid
15 parts of dibutyl ester
A kind of expanding glue for spray coating clothing of the present invention is prepared using vulcanizer, and production method is as follows:
Firstly, rubber major ingredient is put into mixer or open mill carry out low temperature it is thin it is logical plasticate, it is sufficiently mixed that each ingredient is sequentially added
Refining, it is thin logical multiple, it parks；
Then, back mixing processing is carried out, vulcanizing agent is added, thin logical multiple, film is made in slice；
Finally, planting piece is put into vulcanizer press cure, expansion glue can be produced.
Compared with prior art, expanding glue for spray coating clothing of the present invention using natural rubber, chlorinated butyl, EPDM,
Chlorosulfonated polyethylene is rubber major ingredient, and it is strong to produce product corrosion resistance through cooperation, non-aging, rupture；It is prepared using vulcanizer
This kind of expansion glue, speed is fast, can recycle reconstruction after desulfurization for leftover bits, correlative regeneration glue can also be added, reduce cost,
It is pollution-free, high financial profit.
Specific embodiment
Description is further analysed to the present invention below with reference to embodiment.
The formula of expanding glue for spray coating clothing using rubber as major ingredient, and be mixed with vulcanizing agent, activating agent, softening agent, promotor,
Filler, anti-aging agent, reinforcing agent, defoaming agent, using after mixer or mill mixing material through vulcanizing press high temperature and pressure
It is made.
Can be used for hardness adjusting in the formula mainly has reinforcing agent, softening agent, filler, by increasing in formula
The hardness of expanding glue for spray coating clothing can be improved in the proportion of reinforcing agent, softening agent and filler, conversely, spray coating clothing can be reduced
With the hardness of expansion glue, it is allowed to more soft.The appropriate proportion softening agent of addition also ensures that expanding glue for spray coating clothing has foot
Enough plasticity.Promotor is used to accelerate the reaction speed of sizing material.
In the present invention, natural rubber, chlorinated butyl, EPDM, chlorosulfonated polyethylene can be selected as major ingredient in rubber
Deng.
Vulcanizing agent be used for rubber vulcanization and crosslinking, can be selected No. 1 vulcanizing agent, No. 2 vulcanizing agents, No. 3 vulcanizing agents, DCP and
Sulphur etc..
Zinc oxide, nano zine oxide, magnesia, lead monoxide, stearic acid, glycerol, diethylene glycol (DEG) etc. can be selected in activating agent.
Dibutyl ester, dioctyl ester, chlorinated paraffin, machine oil, naphthenic oil etc. can be selected in softening agent.
Altax, captax, promotor EG-3, promotor ZDC, promotor TRA, promotor can be selected in promotor
CBS, accelerant N A-22, promotor TT, diphenylguanidine etc..
Calcium carbonate, barium carbonate, talcum powder, barium sulfate, calcirm-fluoride, alumina silicate etc. can be selected in filler.
Carbon black, high abrasion carbon black, White Carbon black, magnesium carbonate etc. can be selected in reinforcing agent.
Antioxidant H S-P11, antioxidant 4010NA, antioxidant D, anti-aging agent RD, antioxidant 264 etc. can be selected in anti-aging agent.
Defoaming agent can be calcium oxide, defoaming agent RG etc..
The following are the available formulas of expanding glue for spray coating clothing of the present invention:
Component match ratio (parts by weight)
100 parts of rubber
1-5 parts of vulcanizing agent
2-10 parts of activating agent
5-40 parts of softening agent
1-8 parts of promotor
5-80 parts of filler
5-100 parts of reinforcing agent
0.5-5 parts of anti-aging agent
1-10 parts of defoaming agent
According to different using major ingredient, list three kinds of formulas for being used to prepare expanding glue for spray coating clothing, wherein with chlorinated butyl and
Expansion glue effect made of sizing compound formula of the chlorosulfonated polyethylene as major ingredient is ideal.
For embodiment 1-using natural rubber as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of natural rubber
4 parts of sulphur
5 parts of nano zine oxide
2 parts of altax
0.2 part of promotor TT
2 parts of antioxidant H S-P11
30 parts of barium sulfate
20 parts of carbon black
1 part of stearic acid
10 parts of machine oil
5 parts of defoaming agent
For embodiment 2-using chlorinated butyl as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of chlorinated butyl
1.5 parts of sulphur
7 parts of nano zine oxide
1.5 parts of captax
1.5 parts of promotor ZDC
0.5 part of promotor TT
1 part of antioxidant H S-P11
30 parts of barium sulfate
20 parts of carbon black
1 part of stearic acid
10 parts of paraffin oil
5 parts of defoaming agent
For embodiment 3-using chlorinated butyl and natural rubber as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
50 parts of chlorinated butyl
50 parts of natural rubber
2 parts of sulphur
5 parts of nano zine oxide
1 part of captax
1 part of promotor ZDC
0.5 part of promotor TT
1 part of anti-aging agent
30 parts of barium sulfate
20 parts of carbon black
0.5 part of stearic acid
10 parts of paraffin oil
3 parts of defoaming agent
5 parts of calcium oxide
For embodiment 4-using EPDM as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of EPDM
1.5 parts of sulphur
10 parts of zinc oxide
3 parts of promotor EG-3
1 part of antioxidant 4010NA
50 parts of barium sulfate
20 parts of carbon black
0.8 part of stearic acid
25 parts of naphthenic oil
3 parts of defoaming agent RG
For embodiment 5-using chlorosulfonated polyethylene as major ingredient, blend glue stuff component and proportion are as follows:
Component match ratio (parts by weight)
100 parts of chlorosulfonated polyethylene
5 parts of magnesia
1.5 parts of promotor TRA
1 part of anti-aging agent RD
50 parts of barium sulfate
10 parts of carbon black
1 part of stearic acid
15 parts of dibutyl ester
A kind of expanding glue for spray coating clothing production method of the present invention is as follows:
Firstly, by above-mentioned sizing material component materials pretreatment after weigh, by rubber major ingredient be put into mixer or open mill into
Row low temperature it is thin it is logical plasticate about 5 minutes, roller temperature is thin logical multiple no more than 50 DEG C；Then, it is sequentially added in the rubber after plasticating
Ingredient is kneaded, and is parked after mixing one day；Then, back mixing processing is carried out, it is thin to the rubber progress after mixing that vulcanizing agent is added
After leading to for several times, it is kneaded, and adjust its thickness degree, film is made in slice；Finally, planting piece is put into vulcanizer press cure, can make
Expansion glue out.
Vulcanization time in production technology of the invention is fast, general only to need 5 minutes or so, and the corner sizing material after deburring can
It recycles again, carries out desulfurization through desulfurizing agent, repeat above-mentioned technique production, using reclaimed rubber, achieve the purpose that materials recycling, drop
Low cost, the rate of recovery is high, pollutes small.
Above disclosed is only the preferred embodiment of expanding glue for spray coating clothing of the present invention and its production technology, when
So the scope of the invention cannot be limited thereby, therefore according to equivalent variations made by scope of the present invention patent, still belongs to
The range that the present invention is covered.
Claims (6)
1. a kind of expanding glue for spray coating clothing, vulcanizing agent, oxygen agent, reinforcing agent, promotor, soft is added in mixing in rubber major ingredient
Agent, filler and defoaming agent are made using after mixer or mill mixing material through vulcanizing press high temperature and pressure, special
Sign is: the component and proportion of the blend glue stuff are as follows:
Component match ratio (parts by weight)
100 parts of rubber
1-5 parts of vulcanizing agent
2-10 parts of activating agent
5-40 parts of softening agent
1-8 parts of promotor
5-80 parts of filler
5-100 parts of reinforcing agent
0.5-5 parts of anti-aging agent
1-10 parts of defoaming agent.
2. a kind of expanding glue for spray coating clothing as described in claim 1, it is characterised in that: natural rubber can be selected in the rubber
Any one of glue, chlorinated butyl, EPDM, chlorosulfonated polyethylene.
3. a kind of expanding glue for spray coating clothing as claimed in claim 2, it is characterised in that: the rubber major ingredient is natural rubber
Formula it is as follows:
Component match ratio (parts by weight)
100 parts of natural rubber
4 parts of sulphur
5 parts of nano zine oxide
2 parts of altax
0.2 part of promotor TT
2 parts of antioxidant H S-P11
30 parts of barium sulfate
20 parts of carbon black
1 part of stearic acid
10 parts of machine oil
5 parts of defoaming agent.
4. a kind of expanding glue for spray coating clothing as claimed in claim 2, it is characterised in that: the rubber major ingredient is chlorinated butyl
Formula it is as follows:
Component match ratio (parts by weight)
100 parts of chlorinated butyl
1.5 parts of sulphur
7 parts of nano zine oxide
1.5 parts of captax
1.5 parts of promotor ZDC
0.5 part of promotor TT
1 part of antioxidant H S-P11
30 parts of barium sulfate
20 parts of carbon black
1 part of stearic acid
10 parts of paraffin oil
5 parts of defoaming agent.
5. a kind of expanding glue for spray coating clothing as claimed in claim 2, it is characterised in that: the rubber major ingredient is chlorinated butyl
It is as follows with the formula of natural rubber:
Component match ratio (parts by weight)
50 parts of chlorinated butyl
50 parts of natural rubber
2 parts of sulphur
5 parts of nano zine oxide
1 part of captax
1 part of promotor ZDC
0.5 part of promotor TT
1 part of anti-aging agent
30 parts of barium sulfate
20 parts of carbon black
0.5 part of stearic acid
10 parts of paraffin oil
3 parts of defoaming agent
5 parts of calcium oxide.
6. a kind of expanding glue for spray coating clothing as claimed in claim 2, it is characterised in that: the rubber major ingredient is EPDM
Formula it is as follows:
Component match ratio (parts by weight)
100 parts of EPDM
1.5 parts of sulphur
10 parts of zinc oxide
3 parts of promotor EG-3
1 part of antioxidant 4010NA
50 parts of barium sulfate
20 parts of carbon black
0.8 part of stearic acid
25 parts of naphthenic oil
3 parts of defoaming agent RG.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710800041.2A CN109467753A (en) | 2017-09-07 | 2017-09-07 | Clothing expansion glue mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710800041.2A CN109467753A (en) | 2017-09-07 | 2017-09-07 | Clothing expansion glue mixture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109467753A true CN109467753A (en) | 2019-03-15 |
Family
ID=65658348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710800041.2A Pending CN109467753A (en) | 2017-09-07 | 2017-09-07 | Clothing expansion glue mixture |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109467753A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110330701A (en) * | 2019-07-18 | 2019-10-15 | 成都五一六隔震科技有限公司 | A kind of refining glue formula and processing technology using vulcanizing agent |
-
2017
- 2017-09-07 CN CN201710800041.2A patent/CN109467753A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110330701A (en) * | 2019-07-18 | 2019-10-15 | 成都五一六隔震科技有限公司 | A kind of refining glue formula and processing technology using vulcanizing agent |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190315 |
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| WD01 | Invention patent application deemed withdrawn after publication |