CN109459280A - A kind of transformer methane gas site sampling device and method - Google Patents

A kind of transformer methane gas site sampling device and method Download PDF

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Publication number
CN109459280A
CN109459280A CN201811063165.8A CN201811063165A CN109459280A CN 109459280 A CN109459280 A CN 109459280A CN 201811063165 A CN201811063165 A CN 201811063165A CN 109459280 A CN109459280 A CN 109459280A
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China
Prior art keywords
transformer
connecting tube
gas
jointing
air
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CN109459280B (en
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周刚
钱国良
周迅
张捷
何升华
李传才
吕超
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State Grid Corp of China SGCC
Jiaxing Power Supply Co of State Grid Zhejiang Electric Power Co Ltd
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State Grid Corp of China SGCC
Jiaxing Power Supply Co of State Grid Zhejiang Electric Power Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/24Suction devices

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention discloses a kind of transformer methane gas site sampling device and method, including air extractor, the first connecting tube and communicating pipe, air extractor is equipped with the first air exhaust head, and communicating pipe includes the first interconnected port, the second port and third connectivity mouth;First connecting tube one end is connected to the first port, and the first connecting tube other end is equipped with the jointing for connecting with Buchholz relay, and the second port is connected to the first air exhaust head, and third connectivity mouth is equipped with elastic packing plug.The present invention provides kind of transformer methane gas site sampling device and a methods, have leakproofness good, and the leakage of gas or outside air can effectively be avoided to enter to pollute sample gas;The advantages such as structure is simple, and manufacturing cost is low.

Description

A kind of transformer methane gas site sampling device and method
Technical field
The present invention relates to power equipment test instrument technical fields, take more particularly, to a kind of transformer methane gas scene Sampling device and method.
Background technique
In the power system, high-power transformer is the core equipment of entire power supply system, its failure by power supply can Normal operation by property and system produces serious influence.Protection is a kind of protective device of oil-immersed transformer, is to become Main guard block inside depressor, in the turn-to-turn and layer short circuit, iron core failure, inside pipe casing failure, winding to transformer The failures such as portion's broken string and insulation degradation and pasta decline can sensitive action.Buchholz relay is mounted on transformer box cover and oil storage In the connecting tube of tank, when breaking down inside oil-immersed transformer, since electric arc decomposes insulating materials and generates a large amount of gas Body or when oil stream being caused to impact, acts the contact of Buchholz relay.Alarm signal is issued in time or cuts off transformer automatically, is protected Protect the safe operation of equipment.
Once Buchholz relay alarm occurs, service personnel will arrive the gas in transformer field acquisition Buchholz relay Body by judging the analysis of gas componant whether inside transformer has occurred the type of failure and failure, therefore acquires The gas of Buchholz relay is particularly important.Gas is sent in collector box by transformer Buchholz relay by pipeline, tradition Sampling method be that syringe and collector box are connected by moccasin pipe, the gas in collector box is extracted into syringe.This side Method haves the shortcomings that following: (1) junction of hose and collector box, syringe does not have good sealing performance, is easy to happen gas Leakage or outside air enter to polluting sample gas.(2) gas that Buchholz relay cannot be quantified, for judging transformer event For barrier, lack the information of gas gross.
Chinese patent application publication number CN204594751U, publication date are on 08 25th, 2015, entitled " transformer watt This gas collector " discloses a kind of transformer methane gas collector, including vacuumizes collection airbag, structural feature It vacuumizes collection airbag side upper end to be provided with vertical rubber seal and take stomata, vacuumizes collection airbag other side upper end and be provided with F shape Rubber hose is provided with non-return valve on the upper end transverse tube of F shape rubber hose, is provided on the middle part transverse tube of F shape rubber hose Lower non-return valve;The upper end transverse tube outer end of F shape rubber hose is provided with attaching nut, the middle part transverse tube outer end of F shape rubber hose It is provided with lower attaching nut;It is described vacuumize collection airbag on the shape rubber hose side F middle and lower part vertical array have scale strip.But it should Device can not active inspiration, gettering efficiency is low;Vacuum bag can not reuse, the vacuum bag for taking gas to require more to renew every time, The air-tightness that vacuum bag is connect with hose is not can guarantee;And the device can not accurately measure the total amount of methane gas.
Summary of the invention
The present invention in order to overcome the shortcomings in the prior art, provides a kind of transformer methane gas site sampling device and side Method has leakproofness good, and the leakage of gas or outside air can effectively be avoided to enter to pollute sample gas;Structure is simple, system Cause this low advantage.
To achieve the goals above, the invention adopts the following technical scheme:
A kind of transformer methane gas site sampling device, including air extractor, the first connecting tube and communicating pipe, on air extractor Equipped with the first air exhaust head, communicating pipe includes the first interconnected port, the second port and third connectivity mouth;First connecting tube One end is connected to the first port, and the first connecting tube other end is equipped with the jointing for connecting with Buchholz relay, and second is logical Mouth is connected to the first air exhaust head, and third connectivity mouth is equipped with elastic packing plug.It, can be to transformer by implementing above-mentioned technical proposal Methane gas carries out field sampling.The jointing can use quick coupling in the prior art, can both guarantee to seal The quick connection of device may be implemented in property again.The air extractor can produce negative pressure, and gas is sucked air extractor.The bullet Property sealing-plug stopper in third connectivity mouth, can be replaced, can both guarantee sample needle tubing syringe needle insertion, can both guarantee The syringe needle insertion of needle tubing is sampled, and can guarantee the air-tightness of device when the syringe needle for sampling needle tubing is extracted.It is carried out using the present apparatus When gas sample, by the collector box sample connection of jointing and transformer connect, pull air extractor, when in air extractor into When entering liquid, illustrate that gas has emptied in collector box, close the switch on collector box sample connection, waits in the first connecting tube After liquid enters air extractor, by the syringe needle insertion elastic packing plug for sampling needle tubing, suitable under test gas is taken out;It will sampling Under test gas in needle tubing is injected into detecting instrument and is detected.
Preferably, the air extractor includes exhaust tube and piston rod, what first air exhaust head was connected to exhaust tube, Piston rod one end is equipped with piston head, and the exhaust tube and piston head are slidably connected, and exhaust tube is equipped with graduation mark.The exhaust tube All-transparent is partially transparent, it can be observed that exhaust tube piston head position, can read internal gas volume.Pull piston rod can So as to generate negative pressure in exhaust tube, realizes air extracting function, the gas volume in exhaust tube can be read by graduation mark.
Preferably, the exhaust tube is equipped with the second air exhaust head being connected to exhaust tube, the jointing is equipped with Three-way connection, first connecting tube are connected to by three-way connection with jointing, and three-way connection includes interconnected first Interface, second interface and third interface, first interface are connected to the first connecting tube, and second interface is connected to jointing, third Interface is connected to by the second connecting tube with the second air exhaust head, and the third interface is equipped with switch valve.By implementing above-mentioned technology Scheme, it is ensured that for the liquid in the first connecting tube completely into exhaust tube, the gas that can fix really measurement Buchholz relay is total Amount.First connecting tube caliber is smaller, and transformer oil viscosity is larger, and when the switch on collector box sample connection is closed, first connects One end that adapter tube is equipped with jointing is closed, due to draught head principle, connect the liquid in the first connecting tube be difficult completely into In exhaust tube, cause gas volume measurement inaccurate.When there is liquid in the drained connecting tube of gas in collector box, collector box is closed Switch on sample connection, then turns on the switch valve, is connected to second connecting tube with the first connecting tube, can be in collector box Switch on sample connection is formed into a loop when closing, and the height and second of the liquid in the first connecting tube and gas interface connects at this time Liquid in adapter tube is different from the height of gas interface, forms difference in height, to keep the pressure at two interfaces different, liquid can be with Reflux is formed, fully flows into liquid in exhaust tube.After liquid is completely into exhaust tube, gas volume V in exhaust tube is read2, By V2With the gas volume V in the device connecting tube and other gaps demarcated in advance1It is added, obtains surveying gas volume VAlways.Then will It samples in the syringe needle insertion elastic packing plug of needle tubing, takes out suitable under test gas;The injection of the under test gas in needle tubing will be sampled It is detected to detecting instrument.
Preferably, the jointing is equipped with air valve.The air valve can close after the gas in collector box is drained It closes, can be removed jointing after closing air valve, device is transferred to other places and carries out other steps.
Preferably, the piston head is equipped with card slot, sealing ring, the sealing ring inside and piston head are equipped in card slot Contact, sealing ring outside are contacted with pumping inside pipe wall.The structure can guarantee the leakproofness of sampler.
Preferably, first connecting tube is transparent pipe.It can be observed that the case where the first connecting tube, guarantee collector box Interior gas is fully drawn out, while when guaranteeing reading, the liquid in the first connecting tube is emptied completely.
Preferably, the piston rod, which is equipped with, pulls part, one end opposite with piston head is arranged in the part that pulls.Institute The movement for piston rod of structure being stated when can be convenient pumping.
Preferably, the elastic packing plug material is rubber.The elastic packing plug uses rubber material, can both protect The syringe needle insertion of card sampling needle tubing, and can guarantee the air-tightness of device when the syringe needle for sampling needle tubing is extracted.
A kind of transformer methane gas field sampling method, using a kind of transformer methane gas site sampling device, packet Include following steps:
A. solid measure:
A1. jointing is put into measurement liquid, opens air valve and switch valve, pulled piston rod, fill device various pieces Completely measure liquid;
A2. shift piston rod onto bottom, guarantee that exhaust tube does not measure liquid, guarantee connecting tube and and other gaps of device in Full of measurement liquid;
A3. air valve is closed, jointing is taken out from measurement liquid;
A4. air valve is opened, piston rod is pulled, all measurement liquid is made to enter exhaust tube;
A5. exhaust tube liquid volume is read, gap gas volume V is denoted as1
B. it connects: the collector box sample connection of jointing and transformer being connected, valve is turned off the switch, opens the gas of jointing Valve opens the switch on collector box sample connection;
C. air-breathing: pulling piston rod, under test gas made to enter exhaust tube, stops inhaling when occurring continuous liquid in connecting tube Gas closes the air valve on jointing;
D. it stands: turning on the switch valve, device is stood into a period of time, liquid in pipe to be connected fully enters exhaust tube;
E. it reads: after in connecting tube without liquid, reading the gas volume V of exhaust tube2
F. it calculates: calculating under test gas volume VAlways, VAlways=V1+V2
G. it samples: by the syringe needle insertion elastic packing plug for sampling needle tubing, taking out suitable under test gas;
H. it detects: the under test gas sampled in needle tubing being injected into detecting instrument and is detected.
By implementing above-mentioned technical proposal, the sealing of field sampling can be guaranteed to transformer methane gas field sampling Effect, while can accurately measure the gas gross in collector box.
Preferably, it is further comprising the steps of, between step c and step d:
I. it is detached from: jointing is removed from collector box, carry out step d after being transferred to suitable position.
By implementing above-mentioned technical proposal, after sampler being fully entered with the gas in collector box, collector box is closed Device, is removed the environment for taking to and being more suitable for doing experiment and tested, avoid being chronically near relay by switch, to reduction people The hidden danger of body safety.
The beneficial effects of the present invention are: (1) has leakproofness good, leakage or the outside air of gas can be effectively avoided Into to pollute sample gas;(2) gas gross of really measurement Buchholz relay can be fixed;(3) structure is simple, and manufacturing cost is low etc. Advantage;(4) device can be removed to the environment for taking to and being more suitable for doing experiment to test, avoid being chronically at relay nearby into Row operation, to the hidden danger for reducing personal safety.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention.
In figure: air extractor 1, exhaust tube 1.1, piston rod 1.2, the first air exhaust head 1.3, piston head 1.4, graduation mark 1.5, Second air exhaust head 1.6, communicating pipe 3, the first port 3.1, the second port 3.2, third connectivity mouth 3.3, connects first connecting tube 2 First 4, elastic packing plug 5, three-way connection 6, first interface 6.1, second interface 6.2, third interface 6.3, air valve 7, card slot 8, close Seal 9, pulls part 11, switch valve 12 at second connecting tube 10.
Specific embodiment
The present invention will be further described in the following with reference to the drawings and specific embodiments.
Embodiment 1:
As shown in Figure 1, a kind of transformer methane gas site sampling device, including air extractor 1, the first connecting tube 2 be connected to Pipe 3, air extractor 1 are equipped with the first air exhaust head 1.3, and communicating pipe 3 includes the first interconnected port 3.1, the second port 3.2 With third connectivity mouth 3.3;Described first connecting tube, 2 one end is connected to the first port 3.1, and 2 other end of the first connecting tube is equipped with and is used for The jointing 4 connecting with collector box, the second port 3.2 are connected to the first air exhaust head 1.3, and third connectivity mouth 3.3 is equipped with elasticity Sealing-plug 5.By implementing above-mentioned technical proposal, field sampling can be carried out to transformer methane gas.The jointing 4 can To use quick coupling in the prior art, it can not only guarantee leakproofness but also the quick connection of device may be implemented.The elasticity Sealing-plug 5 stoppers in third connectivity mouth 3.3, can be replaced, and can not only guarantee the syringe needle insertion for sampling needle tubing, but also can protect The air-tightness of device when the syringe needle of card sampling needle tubing is extracted.When carrying out gas sample using the present apparatus, by jointing 4 and transformation The collector box sample connection of device connects, and pulls air extractor 1, illustrates gas in collector box when entering liquid in air extractor 1 It has been emptied that, close the switch on collector box sample connection, after waiting the liquid in the first connecting tube 2 to enter air extractor 1, will take In the syringe needle insertion elastic packing plug 5 of sample needle tubing, suitable under test gas is taken out;The under test gas sampled in needle tubing is injected into Detecting instrument is detected.
The air extractor 1 includes exhaust tube 1.1 and piston rod 1.2, and first air exhaust head 1.3 connects with exhaust tube 1.1 Logical, 1.2 one end of piston rod is equipped with piston head 1.4, and the exhaust tube 1.1 and piston head 1.4 are slidably connected, on exhaust tube 1.1 Equipped with graduation mark 1.5.Exhaust tube 1.1 all-transparent or partially transparent, it can be observed that 1.1 piston head position of exhaust tube, it can To read internal gas volume.It pulls piston rod 1.2 that can make to generate negative pressure in exhaust tube, realizes air extracting function, pass through quarter Degree line 1.5 can read the gas volume in exhaust tube 1.1.
The exhaust tube 1.1 is equipped with the second air exhaust head 1.6 being connected to exhaust tube 1.1, and the jointing 4 is equipped with Three-way connection 6, first connecting tube 2 are connected to by three-way connection 6 with jointing 4, and three-way connection 6 includes being interconnected First interface 6.1, second interface 6.2 and third interface 6.3, first interface 6.1 are connected to the first connecting tube 2, second interface 6.2 are connected to jointing 4, and third interface 6.3 is connected to by the second connecting tube 10 with the second air exhaust head 1.6, and the third connects Mouth 6.3 is equipped with switch valve 12.Pass through and implement above-mentioned technical proposal, it is ensured that liquid in the first connecting tube 2 completely into Exhaust tube 1.1 can fix the gas gross of really measurement Buchholz relay.First connecting tube, 2 caliber is smaller, and transformer oil viscosity Larger, when the switch on collector box sample connection is closed, one end that the first connecting tube 2 is equipped with jointing 4 is closed, due to air pressure Poor principle connects the liquid in the first connecting tube 2 and is difficult completely into exhaust tube 1.1, causing gas volume measurement inaccurate.When Gas is drained in collector box, when occurring liquid in connecting tube, closes the switch on collector box sample connection, then turns on the switch valve 12, it is connected to second connecting tube 10 with the first connecting tube 2, can be formed when the switch on collector box sample connection is closed Circuit, the at this time height and liquid and gas interface in the second connecting tube 10 of the liquid in the first connecting tube 2 and gas interface Height it is different, form difference in height, to keep the pressure at two interfaces different, liquid can form reflux, flow liquid completely Enter in exhaust tube 1.1.After liquid is completely into exhaust tube 1.1, gas volume V in exhaust tube 1.1 is read2, by V2With prior calibration The first connecting tube of device 2 and other gaps in gas volume V1It is added, obtains surveying gas volume VAlways.Then needle tubing will be sampled Syringe needle insertion elastic packing plug 5 in, take out suitable under test gas;The under test gas sampled in needle tubing is injected into detector Device is detected.
The jointing 4 is equipped with air valve 7.The air valve 7 can close after the gas in collector box is drained, close Jointing 4 can be removed after air valve 7, device is transferred to other places and carries out other steps.
The piston head 1.4 is equipped with card slot 8, and sealing ring 9,9 inside of sealing ring and piston head are equipped in card slot 8 1.4 contacts, 9 outside of sealing ring are contacted with 1.1 inner wall of exhaust tube.The structure can guarantee the leakproofness of sampler.
First connecting tube 2 is transparent pipe.It can be observed that the case where the first connecting tube 2, guarantee the gas in collector box Body is fully drawn out, while when guaranteeing reading, the liquid in the first connecting tube 2 is emptied completely.
The piston rod 1.2 is equipped with and pulls part 11, and one end opposite with piston head 1.4 is arranged in the part 11 that pulls. The movement of piston rod 1.2 when the structure can be convenient pumping.
5 material of elastic packing plug is rubber.The elastic packing plug 5 uses rubber material, can both guarantee to sample The syringe needle of needle tubing is inserted into, and can guarantee the air-tightness of device when the syringe needle for sampling needle tubing is extracted.
Embodiment 2:
A kind of transformer methane gas field sampling method, using a kind of transformer methane gas site sampling device, including with Lower step:
A. solid measure:
A1. jointing 4 is put into measurement liquid, opens air valve 7 and switch valve 12, pulled piston rod 1.2, keep device each It is partially filled with measurement liquid;
A2. shift piston rod 1.2 onto bottom, guarantee that exhaust tube 1.1 does not measure liquid, guarantee connecting tube and and device other Full of measurement liquid in gap;
A3. air valve 7 is closed, jointing 4 is taken out from measurement liquid;
A4. air valve 7 is opened, piston rod 1.2 is pulled, all measurement liquid is made to enter exhaust tube 1.1;
A5. 1.1 liquid volume of exhaust tube is read, gap gas volume V is denoted as1
B. it connects: jointing 4 is connect with the collector box sample connection of transformer, turn off the switch valve 12, open jointing 4 Air valve 7, open collector box sample connection on switch;
C. air-breathing: piston rod 1.2 is pulled, so that under test gas is entered exhaust tube 1.1, stops when occurring continuous liquid in connecting tube Only air-breathing closes the air valve 7 on jointing 4;
D. it stands: turning on the switch valve 12, device is stood into a period of time, liquid in pipe to be connected fully enters exhaust tube 1.1;
E. it reads: after in connecting tube without liquid, reading the gas volume V of exhaust tube 1.12
F. it calculates: calculating under test gas volume VAlways, VAlways=V1+V2
G. it samples: by the syringe needle insertion elastic packing plug 5 for sampling needle tubing, taking out suitable under test gas;
H. it detects: the under test gas sampled in needle tubing being injected into detecting instrument and is detected.
By implementing above-mentioned technical proposal, the sealing of field sampling can be guaranteed to transformer methane gas field sampling Effect, while can accurately measure the gas gross in collector box.
It is further comprising the steps of, between step c and step d:
I. it is detached from: jointing 4 is removed from collector box, carry out step d after being transferred to suitable position.
By implementing above-mentioned technical proposal, after sampler being fully entered with the gas in collector box, collector box is closed Device, can be removed the environment for taking to and being more suitable for doing experiment and tested by switch, avoid being chronically at relay progress nearby Operation, to the hidden danger for reducing personal safety.
The beneficial effects of the present invention are: having leakproofness good, the leakage of gas or outside air can effectively be avoided to enter To pollute sample gas;The gas gross of really measurement Buchholz relay can be fixed;The advantages such as structure is simple, and manufacturing cost is low;It can be with Device is removed to the environment for taking to and being more suitable for doing experiment to test, avoids being chronically at relay and is nearby operated, to subtracting The hidden danger of few personal safety.

Claims (10)

1. a kind of transformer methane gas site sampling device, characterized in that including air extractor, the first connecting tube and be connected to Pipe, air extractor are equipped with the first air exhaust head, and communicating pipe includes the first interconnected port, the second port and third connectivity mouth; First connecting tube one end is connected to the first port, and the first connecting tube other end is equipped with the company for connecting with Buchholz relay Connector, the second port are connected to the first air exhaust head, and third connectivity mouth is equipped with elastic packing plug.
2. a kind of transformer methane gas site sampling device according to claim 1, characterized in that the air extractor Including exhaust tube and piston rod, what first air exhaust head was connected to exhaust tube, piston rod one end is equipped with piston head, the pumping Pipe and piston head are slidably connected, and exhaust tube is equipped with graduation mark.
3. a kind of transformer methane gas site sampling device according to claim 2, characterized in that on the exhaust tube Equipped with the second air exhaust head being connected to exhaust tube, the jointing is equipped with three-way connection, and first connecting tube passes through three Pass joint is connected to jointing, and three-way connection includes interconnected first interface, second interface and third interface, and first connects Mouth is connected to the first connecting tube, and second interface is connected to jointing, and third interface passes through the second connecting tube and the second air exhaust head Connection, the third interface are equipped with switch valve.
4. a kind of transformer methane gas site sampling device according to claim 1, characterized in that the jointing It is equipped with air valve.
5. a kind of transformer methane gas site sampling device according to Claims 2 or 3 or 4, characterized in that the work Chock plug is equipped with card slot, and sealing ring is equipped in card slot, is contacted on the inside of the sealing ring with piston head, sealing ring outside and exhaust tube Inner wall contact.
6. a kind of transformer methane gas site sampling device according to claim 1 or 2 or 3 or 4, characterized in that institute Stating the first connecting tube is transparent pipe.
7. a kind of transformer methane gas site sampling device according to Claims 2 or 3 or 4, characterized in that the work Stopper rod is equipped with and pulls part, and one end opposite with piston head is arranged in the part that pulls.
8. a kind of transformer methane gas site sampling device according to claim 1 or 2 or 3 or 4, characterized in that institute Stating elastic packing plug material is rubber.
9. a kind of transformer methane gas field sampling method, special using a kind of transformer methane gas site sampling device Sign is, comprising the following steps:
A. solid measure:
A1. jointing is put into measurement liquid, opens air valve and switch valve, pulled piston rod, fill device various pieces Completely measure liquid;
A2. shift piston rod onto bottom, guarantee that exhaust tube does not measure liquid, guarantee connecting tube and and other gaps of device in Full of measurement liquid;
A3. air valve is closed, jointing is taken out from measurement liquid;
A4. air valve is opened, piston rod is pulled, all measurement liquid is made to enter exhaust tube;
A5. exhaust tube liquid volume is read, gap gas volume V is denoted as1
B. it connects: the collector box sample connection of jointing and transformer being connected, valve is turned off the switch, opens the gas of jointing Valve opens the switch on collector box sample connection;
C. air-breathing: pulling piston rod, under test gas made to enter exhaust tube, stops inhaling when occurring continuous liquid in connecting tube Gas closes the air valve on jointing;
D. it stands: turning on the switch valve, device is stood into a period of time, liquid in pipe to be connected fully enters exhaust tube;
E. it reads: after in connecting tube without liquid, reading the gas volume V of exhaust tube2
F. it calculates: calculating under test gas volume VAlways, VAlways=V1+V2
G. it samples: by the syringe needle insertion elastic packing plug for sampling needle tubing, taking out suitable under test gas;
H. it detects: the gas injection sampled in needle tubing survey is detected to detecting instrument.
10. a kind of transformer methane gas field sampling method according to claim 9, characterized in that further include following Step, between step c and step d:
I. it is detached from: jointing is removed from collector box, carry out step d after being transferred to suitable position.
CN201811063165.8A 2018-09-12 2018-09-12 Transformer gas on-site sampling device and method Active CN109459280B (en)

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CN110186917A (en) * 2019-06-12 2019-08-30 山东民和生物科技股份有限公司 Biogas H is detected in a kind of laboratory automatically2The device and detection method of S content
CN110530687A (en) * 2019-09-18 2019-12-03 国网山东省电力公司莱芜供电公司 A kind of SF6 gas-detecting device
CN111795868A (en) * 2020-07-08 2020-10-20 广东电网有限责任公司 Gas collecting device and using method thereof

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