CN109456569A - A kind of environment-friendly type foam board - Google Patents

A kind of environment-friendly type foam board Download PDF

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Publication number
CN109456569A
CN109456569A CN201811025128.8A CN201811025128A CN109456569A CN 109456569 A CN109456569 A CN 109456569A CN 201811025128 A CN201811025128 A CN 201811025128A CN 109456569 A CN109456569 A CN 109456569A
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CN
China
Prior art keywords
parts
foam board
environment
friendly type
stabilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811025128.8A
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Chinese (zh)
Inventor
王中华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Huatian Plastic Industry Co Ltd
Original Assignee
Xuzhou Huatian Plastic Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xuzhou Huatian Plastic Industry Co Ltd filed Critical Xuzhou Huatian Plastic Industry Co Ltd
Priority to CN201811025128.8A priority Critical patent/CN109456569A/en
Publication of CN109456569A publication Critical patent/CN109456569A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0023—Use of organic additives containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/26—Silicon- containing compounds

Abstract

The invention discloses a kind of environment-friendly type foam boards, the foam board is made of following components by mass fraction: 30-40 parts of thermosetting phenolic resin, 10-20 parts of stearic acid, 2-5 parts of metallocene PE A, 10-20 parts of ammonium polyphosphate, 2-5 parts of flyash, 1-3 parts of surfactant, 5-10 parts of refractory fibre mixture, 1-3 parts of fire retardant, 1-3 parts of stabilizer.The invention has the beneficial effects that: preparation process is simple, low raw-material cost, realizes the efficient utilization of flyash, reduces its pollution to environment, fire resistance is good, is suitable for popularization and application.

Description

A kind of environment-friendly type foam board
Technical field
The present invention relates to foam board manufacture fields, are specifically related to a kind of environment-friendly type foam board.
Background technique
Polystyrene foam plate-- also known as cystosepiment, EPS sheet are gathered by the expandability containing volatile fluid foaming agent Styrene beads, the white object of hot briquetting in a mold after heated pre- hair, have the design feature of fine closed pore, mainly For construction wall, roof heat insulation, composite plate heat preservation, freezer, air-conditioning, vehicle, ship insulation, floor heating, decoration The purposes such as engraving are very extensive.
Summary of the invention
The object of the present invention is to provide a kind of environment-friendly type foam board, the foam board presses mass parts by following components Array at: 30-40 parts of thermosetting phenolic resin, 10-20 parts of stearic acid, 2-5 parts of metallocene PE A, ammonium polyphosphate 10- 20 parts, 2-5 parts of flyash, 1-3 parts of surfactant, 5-10 parts of refractory fibre mixture, 1-3 parts of fire retardant, stabilizer 1-3 Part.
It is further preferred that the foam board is made of following components by mass fraction: thermosetting phenolic resin 40 Part, 20 parts of stearic acid, 5 parts of metallocene PE A, 20 parts of ammonium polyphosphate, 5 parts of flyash, 3 parts of surfactant, fire resisting is fine 10 parts of mixture, 3 parts of fire retardant, 3 parts of stabilizer of dimension.
It is further preferred that the foam board is made of following components by mass fraction: thermosetting phenolic resin 30 Part, 10 parts of stearic acid, 2 parts of metallocene PE A, 10 parts of ammonium polyphosphate, 2 parts of flyash, 1 part of surfactant, fire resisting is fine 5 parts of mixture, 1 part of fire retardant, 1 part of stabilizer of dimension.
It is further preferred that the foam board is made of following components by mass fraction: thermosetting phenolic resin 35 Part, 15 parts of stearic acid, 3 parts of metallocene PE A, 15 parts of ammonium polyphosphate, 3 parts of flyash, 2 parts of surfactant, fire resisting is fine 7 parts of mixture, 2 parts of fire retardant, 2 parts of stabilizer of dimension.
The stabilizer is dibutyl two (lauric acid/dodecanoic acid) tin, zinc stearate, epoxidized soybean oil, tin dilaurate di-n-octyl One of tin is several.
The fire retardant is one of antimony trioxide, magnesium hydroxide or two kinds.
The invention has the beneficial effects that: preparation process is simple, low raw-material cost, realizes the efficient benefit of flyash With reducing its pollution to environment, fire resistance is good, is suitable for popularization and application.
Specific embodiment
In order to deepen the understanding of the present invention and recognize, the present invention is made further With reference to embodiment Illustrate and introduces.
Embodiment 1
A kind of environment-friendly type foam board, the foam board are made of following components by mass fraction: thermosetting phenolic 40 parts of resin, 20 parts of stearic acid, 5 parts of metallocene PE A, 20 parts of ammonium polyphosphate, 5 parts of flyash, 3 parts of surfactant, 10 parts of refractory fibre mixture, 3 parts of fire retardant, 3 parts of stabilizer.
The stabilizer is dibutyl two (lauric acid/dodecanoic acid) tin, zinc stearate, epoxidized soybean oil, tin dilaurate di-n-octyl One of tin is several.
The fire retardant is one of antimony trioxide, magnesium hydroxide or two kinds.
Embodiment 2
A kind of environment-friendly type foam board, the foam board are made of following components by mass fraction: thermosetting phenolic 30 parts of resin, 10 parts of stearic acid, 2 parts of metallocene PE A, 10 parts of ammonium polyphosphate, 2 parts of flyash, 1 part of surfactant, 5 parts of refractory fibre mixture, 1 part of fire retardant, 1 part of stabilizer.
The stabilizer is dibutyl two (lauric acid/dodecanoic acid) tin, zinc stearate, epoxidized soybean oil, tin dilaurate di-n-octyl One of tin is several.
The fire retardant is one of antimony trioxide, magnesium hydroxide or two kinds.
Embodiment 3
A kind of environment-friendly type foam board, the foam board are made of following components by mass fraction: thermosetting phenolic 35 parts of resin, 15 parts of stearic acid, 3 parts of metallocene PE A, 15 parts of ammonium polyphosphate, 3 parts of flyash, 2 parts of surfactant, 7 parts of refractory fibre mixture, 2 parts of fire retardant, 2 parts of stabilizer.
The stabilizer is dibutyl two (lauric acid/dodecanoic acid) tin, zinc stearate, epoxidized soybean oil, tin dilaurate di-n-octyl One of tin is several.
The fire retardant is one of antimony trioxide, magnesium hydroxide or two kinds.

Claims (6)

1. a kind of environment-friendly type foam board, which is characterized in that the foam board is made of following components by mass fraction: heat 30-40 parts of solidity phenolic resin, 10-20 parts of stearic acid, 2-5 parts of metallocene PE A, 10-20 parts of ammonium polyphosphate, fine coal It is 2-5 parts grey, 1-3 parts of surfactant, 5-10 parts of refractory fibre mixture, 1-3 parts of fire retardant, 1-3 parts of stabilizer.
2. a kind of environment-friendly type foam board according to claim 1, which is characterized in that the foam board is by with the following group Divide and is formed by mass fraction: 40 parts of thermosetting phenolic resin, 20 parts of stearic acid, 5 parts of metallocene PE A, ammonium polyphosphate 20 Part, 5 parts of flyash, 3 parts of surfactant, 10 parts of refractory fibre mixture, 3 parts of fire retardant, 3 parts of stabilizer.
3. a kind of environment-friendly type foam board according to claim 1, which is characterized in that the foam board is by with the following group Divide and is formed by mass fraction: 30 parts of thermosetting phenolic resin, 10 parts of stearic acid, 2 parts of metallocene PE A, ammonium polyphosphate 10 Part, 2 parts of flyash, 1 part of surfactant, 5 parts of refractory fibre mixture, 1 part of fire retardant, 1 part of stabilizer.
4. a kind of environment-friendly type foam board according to claim 1, which is characterized in that the foam board is by with the following group Divide and is formed by mass fraction: 35 parts of thermosetting phenolic resin, 15 parts of stearic acid, 3 parts of metallocene PE A, ammonium polyphosphate 15 Part, 3 parts of flyash, 2 parts of surfactant, 7 parts of refractory fibre mixture, 2 parts of fire retardant, 2 parts of stabilizer.
5. a kind of environment-friendly type foam board according to claim 1, which is characterized in that the stabilizer is dibutyl two One of (lauric acid/dodecanoic acid) tin, zinc stearate, epoxidized soybean oil, Bis(lauroyloxy)dioctyltin are several.
6. a kind of environment-friendly type foam board according to claim 1, which is characterized in that the fire retardant is three oxidations One of antimony, magnesium hydroxide or two kinds.
CN201811025128.8A 2018-09-04 2018-09-04 A kind of environment-friendly type foam board Pending CN109456569A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811025128.8A CN109456569A (en) 2018-09-04 2018-09-04 A kind of environment-friendly type foam board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811025128.8A CN109456569A (en) 2018-09-04 2018-09-04 A kind of environment-friendly type foam board

Publications (1)

Publication Number Publication Date
CN109456569A true CN109456569A (en) 2019-03-12

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CN201811025128.8A Pending CN109456569A (en) 2018-09-04 2018-09-04 A kind of environment-friendly type foam board

Country Status (1)

Country Link
CN (1) CN109456569A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2733538A1 (en) * 1995-04-25 1996-10-31 Naud Jean Paul Mfr. of sound proofed fire-doors and panels
CN1718410A (en) * 2005-08-05 2006-01-11 四川大学 Method of preparing apertured micropore plastic product semifusion mould press shaping method
CN101649653A (en) * 2009-08-27 2010-02-17 夏良强 Preparation method of modified phenolic foam composite insulation board
CN103059503A (en) * 2013-01-11 2013-04-24 陕西煤业化工技术研究院有限责任公司 Phenolic foam plastics and preparation method thereof and preparation method of foam carbon
CN104513453A (en) * 2015-01-14 2015-04-15 苏州图纳新材料科技有限公司 Thermoset phenolic resin composite material and preparation method thereof
CN105367990A (en) * 2015-10-26 2016-03-02 北京东方雨虹防水技术股份有限公司 Heat-insulating fireproof material based on phenolic aldehyde hollow microspheres and preparation method thereof
CN105733173A (en) * 2014-12-11 2016-07-06 苏州美克思科技发展有限公司 Preparation method of high efficient and energy saving phenolic foam board
CN107902955A (en) * 2017-11-21 2018-04-13 陈纪彤 A kind of architectural engineering external-wall heat-insulation material of light flame-retardant

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2733538A1 (en) * 1995-04-25 1996-10-31 Naud Jean Paul Mfr. of sound proofed fire-doors and panels
CN1718410A (en) * 2005-08-05 2006-01-11 四川大学 Method of preparing apertured micropore plastic product semifusion mould press shaping method
CN101649653A (en) * 2009-08-27 2010-02-17 夏良强 Preparation method of modified phenolic foam composite insulation board
CN103059503A (en) * 2013-01-11 2013-04-24 陕西煤业化工技术研究院有限责任公司 Phenolic foam plastics and preparation method thereof and preparation method of foam carbon
CN105733173A (en) * 2014-12-11 2016-07-06 苏州美克思科技发展有限公司 Preparation method of high efficient and energy saving phenolic foam board
CN104513453A (en) * 2015-01-14 2015-04-15 苏州图纳新材料科技有限公司 Thermoset phenolic resin composite material and preparation method thereof
CN105367990A (en) * 2015-10-26 2016-03-02 北京东方雨虹防水技术股份有限公司 Heat-insulating fireproof material based on phenolic aldehyde hollow microspheres and preparation method thereof
CN107902955A (en) * 2017-11-21 2018-04-13 陈纪彤 A kind of architectural engineering external-wall heat-insulation material of light flame-retardant

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Application publication date: 20190312