CN109442609A - A kind of air cleaning unit of formaldehyde - Google Patents
A kind of air cleaning unit of formaldehyde Download PDFInfo
- Publication number
- CN109442609A CN109442609A CN201811064091.XA CN201811064091A CN109442609A CN 109442609 A CN109442609 A CN 109442609A CN 201811064091 A CN201811064091 A CN 201811064091A CN 109442609 A CN109442609 A CN 109442609A
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- CN
- China
- Prior art keywords
- formaldehyde
- cleaning unit
- air cleaning
- air
- catalytic plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
- F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
- F24F3/16—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by purification, e.g. by filtering; by sterilisation; by ozonisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- B60H3/00—Other air-treating devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F11/00—Control or safety arrangements
- F24F11/89—Arrangement or mounting of control or safety devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/24—Means for preventing or suppressing noise
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/15—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means
- F24F8/167—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means using catalytic reactions
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/40—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by ozonisation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/24—Means for preventing or suppressing noise
- F24F2013/247—Active noise-suppression
Abstract
A kind of air cleaning unit of formaldehyde of the present invention, purification device inside both ends are equipped with air inlet and air outlet, are successively arranged ozone generator, catalytic plate and blower between air inlet and air outlet from left to right；Wherein, catalytic plate the preparation method is as follows: Step 1: four water manganese acetates, six water nickel nitrates, cerium nitrate hexahydrate reagent is selected to prepare 60 DEG C of saturated solutions of manganese acetate；Step 2: selecting 300-400 mesh, the catalytic plate that water absorption rate is 18-24% is impregnated in manganese acetate saturated solution；Step 3: residual agent in the duct of catalytic plate is blown out after being sufficiently impregnated, directly into Muffle furnace program gradient increased temperature, natural cooling.The air cleaning unit of formaldehyde of the present invention, significantly solve existing purification device be hazardous to the human body as ozone occurring source using high-voltage electrostatic field, higher cost, the problem that noise is larger, size is larger and formaldehyde removal rate is low.
Description
Technical field
The present invention relates to a kind of air cleaning unit more particularly to a kind of air cleaning units of formaldehyde.
Background technique
Air purifier is to refer to adsorb, decompose or convert the pollutant in various air, effectively improves room air
The product of cleannes.There is application in house, medical treatment, industrial circle.Most important function is the particulate matter removed in air, packet
Include anaphylactogen, indoor PM2.5 etc., at the same can also solve the interior as caused by finishing or other reasons, the underground space,
Interior volatile organic matter air pollution problems inherent, and formaldehyde is as being a kind of common pollution gas, all to environment and human body
Biggish harm can be brought, for having occurred more processing technique and product on the market in terms of purifying formaldehyde.
Shanghai Communications University's master thesis " load type double-metal composite oxides ozone auxiliary catalysis degradation low concentration
The performance study of formaldehyde " it refers to using cobalt nitrate in chapter 3 " Co-MnOx/ZSM-5 Catalytic Ozonation low concentration formaldehyde "
With manganese nitrate molar ratio 1:1 match, be added mass ratio 5%ZSM-5 it is molecular sieve carried be fired into 500 DEG C on ceramic honey comb urge
Change plate, match and the ozone yield of two hours 3m3 closed cabin ozone cumulative amount 2290ppb of about 10mg/h, 60m3/h air quantity, two is small
When 3m3 closed in space in the formaldehyde of initial concentration 1.07ppm is down to 0.44ppm, ozone concentration is in 60ppb or so；It hands in Shanghai
Logical University Ph.D. Dissertation " research of plasmon coupling catalytic elimination volatile organic matter " chapter 5 " meets metal oxidation
321ppb ozone cooperation cobalt nitrate and manganese nitrate Co/ are referred in the experimental study of object coupled high voltage electrostatic field removal indoor VOCs "
Mn molar ratio 1:1, mass ratio 5%ZSM-5 molecular sieve, the catalytic plates of 500 DEG C of firings, under 60m3/h air quantity, 3m3 is closed within six hours
By formaldehyde removal 95%, the Co/Mn molar ratio 1:4 formaldehyde removal 80% of initial concentration 0.9ppm in cabin, ozone concentration is kept
In 30ppb hereinafter, more than two correlative theses be all with processing formaldehyde it is related, substantially all with ozone occurring source cooperate catalyst with
Concentration of formaldehyde is reduced, but oxygen occurring source employed in above two papers is high-voltage electrostatic field.The normal work in high-voltage electrostatic field
As when the ozone amount that generates it is smaller, be not able to satisfy the ability of coupling and catalyzing plate obvious degradation formaldehyde；Only when its size is sufficiently large,
Perhaps voltage is increased to a certain amount of or discharging gap and is reduced to certain distance, and oxygen in discharge breakdown gap generates obvious draw
When arc phenomenon, a large amount of ozone can be just released, but can also ionize nitrogen at this time, generates a large amount of nitrogen oxides.According to existing text
It offers, this type catalyst acts on nitrogen oxides without obvious removal, and nitrogen oxides is diffused into air and can have obviously to human body
Harm, electric field arcing can also generate corresponding electromagnetic interference to other electric appliances, therefore high-pressure electrostatic is uncomfortable as ozone occurring source
It closes；ZSM-5 molecular sieve is used in two papers simultaneously, this molecular sieve price is higher at present, average 70 yuan of 100g price
RMB or so, large scale investment higher operating costs；Its formaldehyde removal rate is also relatively low, and the initial concentration two of 0.55mg/m3 is small
When also only eliminate 61.8%；It can be calculated to obtain its equipment size according to described in paper to be 0.5*0.15*0.15m3, but contracted
Small size will affect the removal efficiency of its formaldehyde；Last gas passes through from narrow air duct inherently generates biggish noise, such as
Fruit is to reduce noise not necessarily to can guarantee enough formaldehyde removal effects to reduce air quantity also.
Therefore, for the ozone occurring source of existing formaldehyde purifier be high-voltage electrostatic field be harmful to the human body, ZSM-5 molecule
The problems such as price is higher, formaldehyde removal rate is low, size is larger and noise is biggish is sieved, becomes those skilled in the art and urgently solves
Certainly the technical issues of.
Summary of the invention
The present invention be solve existing formaldehyde purifier ozone occurring source be high-voltage electrostatic field be harmful to the human body, ZSM-5
The problems such as molecular sieve price is higher, formaldehyde removal rate is low, size is larger and noise is biggish, provides the air cleaning of formaldehyde
Device.
To achieve the above object, the invention adopts the following technical scheme:
A kind of air cleaning unit of formaldehyde is provided, both ends are equipped with air inlet 1 and air outlet inside the purification device
5, ozone generator 2, catalytic plate 3 and blower 4 are successively arranged between the air inlet 1 and air outlet 5 from left to right；
Wherein, the catalytic plate 3 the preparation method is as follows:
Step 1: 60 DEG C of saturations for selecting four water manganese acetates, six water nickel nitrates, cerium nitrate hexahydrate reagent to prepare manganese acetate are molten
Liquid；
Step 2: select 300-400 mesh, water absorption rate be 18-24% catalytic plate in the manganese acetate saturated solution into
Row dipping；
Step 3: residual agent in the duct of the catalytic plate is blown out after being sufficiently impregnated, directly into Muffle furnace program gradient
Heating, natural cooling.
Further, the ozone generator 2 be the Japanese Ao Naite production that ozone yield is 5mg/h low temperature etc. from
Daughter module.
Further, the shape of the catalytic plate 3 is cylinder.
Further, the diameter of the catalytic plate 3 is 65-73mm, and thickness 25-30mm, its aperture are 0.6-1mm.
Further, four water manganese acetates described in step 1, six water nickel nitrates, cerium nitrate hexahydrate reagent molar ratio be 1:
0.6-1:1-2。
Further, the size of the blower 4 is Φ 72-75mm*30-35mm, revolving speed 3600-3800r/min.
Further, the 5 flare shape of air outlet.
Further, formaldehyde concentration detection device 6 is equipped at the air inlet 1.
Further, the formaldehyde concentration detection device 6 is wirelessly connected with terminal device.
Further, the terminal device is mobile phone or tablet computer or computer.
Further, the step of Muffle furnace program gradient increased temperature are as follows: 6-10 DEG C/min rises to 60-70 DEG C from room temperature,
Heat preservation 1-1.2 hour, then 6-10 DEG C/min rise to 120-130 DEG C from room temperature, heat preservation 1-1.2 hours, and 6-10 DEG C/min is from room temperature
180-200 DEG C is risen to, keeps the temperature 1-1.2 hours, 2-5 DEG C/min rises to 350-400 DEG C from room temperature, keeps the temperature 2.5-3 hours.
The present invention by adopting the above technical scheme, compared with prior art, has the following technical effect that
The air cleaning unit of formaldehyde provided by the invention is dense by air inlet, ozone generator, catalytic plate, blower, formaldehyde
It spends detector and air outlet composition is sent out after air enters the air inlet of apparatus of the present invention after blower drives by ozone
Formaldehyde in raw device and catalytic plate removal air, formaldehyde concentration detection device can monitor purified air formaldehyde concentration, lead to
It crosses wireless technology and transfers data to terminal device to observe its operating condition, air outlet does flaring design to reduce making an uproar for equipment sending
Sound.
Invention significantly solves existing purification devices to be hazardous to the human body using high-voltage electrostatic field as ozone occurring source,
The problem that higher cost, noise are larger, size is larger and formaldehyde removal rate is low.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the air cleaning unit of formaldehyde of the present invention；
Wherein, each appended drawing reference are as follows:
1- air inlet, 2- ozone generator, 3- catalytic plate, 4- blower, 5- air outlet, 6- formaldehyde concentration detection device.
Specific embodiment
The present invention is described in more detail below by specific embodiment, for a better understanding of the present invention,
But following embodiments are not intended to limit the scope of the invention.
As shown in Figure 1, both ends are set inside purification device the embodiment of the invention provides a kind of air cleaning unit of formaldehyde
Have air inlet 1 and air outlet 5, be successively arranged from left to right between air inlet 1 and air outlet 5 ozone generator 2, catalytic plate 3 with
And blower 4；
Wherein, catalytic plate 3 the preparation method is as follows:
Step 1: 60 DEG C of saturations for selecting four water manganese acetates, six water nickel nitrates, cerium nitrate hexahydrate reagent to prepare manganese acetate are molten
Liquid；
Step 2: selecting 300-400 mesh, the catalytic plate that water absorption rate is 18-24% is soaked in manganese acetate saturated solution
Stain；
Step 3: residual agent in the duct of catalytic plate is blown out after being sufficiently impregnated, directly into Muffle furnace program gradient liter
Temperature, natural cooling.
The one aspect of the present embodiment, as shown in Figure 1, ozone generator 2 be Japan that ozone yield is 5mg/h it is difficult to understand how
The low-temperature plasma module of spy's production, this module win multinomial patent of invention in Japan, China, U.S. etc., generate degree of purity
99% or more ozone does not generate nitrogen oxides, harmless.
The one aspect of the present embodiment, as shown in Figure 1, the shape of catalytic plate 3 is cylinder.
The one aspect of the present embodiment, as shown in Figure 1, the diameter of catalytic plate 3 be 65-73mm, thickness 25-30mm, its
Aperture is 0.6-1mm.
The one aspect of the present embodiment, as shown in Figure 1, four water manganese acetates, six water nickel nitrates, cerium nitrate hexahydrate in step 1
The molar ratio of reagent is 1:0.6-1:1-2, and catalytic plate 3 is impregnated in the solution of the proportion.
The one aspect of the present embodiment, as shown in Figure 1, the size of blower 4 is Φ 72-75mm*30-35mm, revolving speed is
3600-3800r/min, air by blower 4 drive after enter apparatus of the present invention air inlet 1 after, by ozone generator 2 with
And catalytic plate 3 removes the formaldehyde in air.
The one aspect of the present embodiment reduces noise as shown in Figure 1, air outlet 5 carries out flare shape.
The one aspect of the present embodiment, as shown in Figure 1, being equipped with formaldehyde concentration detection device 6 at air inlet 1, concentration of formaldehyde is visited
The air formaldehyde concentration before purification can be monitored by surveying device 6.
The one aspect of the present embodiment passes through nothing as shown in Figure 1, formaldehyde concentration detection device 6 and terminal device are wirelessly connected
Line technology transfers data to terminal device to observe its operating condition.
The one aspect of the present embodiment is set as shown in Figure 1, terminal device is mobile phone or tablet computer or computer in terminal
Standby upper observable is by the concentration of formaldehyde in the purified air of apparatus of the present invention.
The one aspect of the present embodiment, as shown in Figure 1, the step of Muffle furnace program gradient increased temperature are as follows: 6-10 DEG C/min from
Room temperature rises to 60-70 DEG C, keeps the temperature 1-1.2 hours, then 6-10 DEG C/min rises to 120-130 DEG C from room temperature, keeps the temperature 1-1.2 hours,
6-10 DEG C/min rises to 180-200 DEG C from room temperature, keeps the temperature 1-1.2 hours, and 2-5 DEG C/min rises to 350-400 DEG C from room temperature, heat preservation
2.5-3 hour.
Also provide a different formulations formaldehyde removal rate table 1, in which: arrange using identical structure, different formulations formaldehyde
One hour removal data comparison, test reference " national standard 18801-2015 air purifier ", the formaldehyde removal in one hour of three cubes of storehouses
As a result；The formula that embodiment in the application uses is adopted for water manganese acetate, six water nickel nitrates and cerium nitrate hexahydrate, comparative example 1
The cobalt nitrate and manganese nitrate that formula is molar ratio 1:1, the formula that comparative example 2 uses is the cobalt nitrate of molar ratio 1:4 and nitre
Sour manganese, the formula that comparative example 3 uses is four water manganese acetate and cobalt nitrate hexahydrate molar ratio 3:1.
Table 1
The air cleaning unit of formaldehyde of the present invention is high-voltage electrostatic field for the ozone occurring source of existing formaldehyde purifier
It is harmful to the human body, the problems such as ZSM-5 molecular sieve price is higher, formaldehyde removal rate is low, size is larger and noise is biggish, this hair
The air cleaning unit of bright formaldehyde significantly solves existing purification device and uses high-voltage electrostatic field as ozone occurring source to human body
The problem that harmful, higher cost, noise are larger, size is larger and formaldehyde removal rate is low.
The specific embodiment of the air cleaning unit of this practical formaldehyde is described in detail above, but it is intended only as
Example, the present invention are not restricted to particular embodiments described above.To those skilled in the art, any couple of present invention
The equivalent modifications and substitution of progress are also all among scope of the invention.Therefore, without departing from the spirit and scope of the invention
Made equal transformation and modification, all should be contained within the scope of the invention.
Claims (11)
1. a kind of air cleaning unit of formaldehyde, which is characterized in that both ends are equipped with air inlet (1) and go out inside the purification device
Air port (5), be successively arranged from left to right between the air inlet (1) and air outlet (5) ozone generator (2), catalytic plate (3) with
And blower (4)；
Wherein, the catalytic plate (3) the preparation method is as follows:
Step 1: four water manganese acetates of selection, six water nickel nitrates, cerium nitrate hexahydrate reagent prepare 60 DEG C of saturated solutions of manganese acetate；
Step 2: selecting 300-400 mesh, the catalytic plate that water absorption rate is 18-24% is soaked in the manganese acetate saturated solution
Stain；
Step 3: residual agent in the duct of the catalytic plate is blown out after being sufficiently impregnated, directly into Muffle furnace program gradient liter
Temperature, natural cooling.
2. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that the ozone generator (2) is smelly
The low-temperature plasma module that the Japanese Ao Naite that oxygen yield is 5mg/h is produced.
3. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that the shape of the catalytic plate (3) is
It is cylindrical.
4. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that the diameter of the catalytic plate (3) is
65-73mm, thickness 25-30mm, its aperture are 0.6-1mm.
5. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that four water acetic acid described in step 1
Manganese, six water nickel nitrates, cerium nitrate hexahydrate reagent molar ratio be 1:0.6-1:1-2.
6. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that the size of the blower (4) is Φ
72-75mm*30-35mm, revolving speed 3600-3800r/min.
7. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that air outlet (5) flare
Shape.
8. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that be equipped with first at the air inlet (1)
Aldehyde concentration detector (6).
9. the air cleaning unit of formaldehyde according to claim 8, which is characterized in that the formaldehyde concentration detection device (6)
It is wirelessly connected with terminal device.
10. the air cleaning unit of formaldehyde according to claim 9, which is characterized in that the terminal device be mobile phone or
Tablet computer or computer.
11. the air cleaning unit of formaldehyde according to claim 1, which is characterized in that the Muffle furnace program gradient liter
The step of temperature are as follows: 6-10 DEG C/min rises to 60-70 DEG C from room temperature, keeps the temperature 1-1.2 hours, then 6-10 DEG C/min rises to from room temperature
120-130 DEG C, 1-1.2 hours are kept the temperature, 6-10 DEG C/min rises to 180-200 DEG C from room temperature, keeps the temperature 1-1.2 hours, 2-5 DEG C/min
350-400 DEG C is risen to from room temperature, keeps the temperature 2.5-3 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811064091.XA CN109442609A (en) | 2018-09-12 | 2018-09-12 | A kind of air cleaning unit of formaldehyde |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811064091.XA CN109442609A (en) | 2018-09-12 | 2018-09-12 | A kind of air cleaning unit of formaldehyde |
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| Publication Number | Publication Date |
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| CN109442609A true CN109442609A (en) | 2019-03-08 |
Family
ID=65530384
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|---|---|---|---|
| CN201811064091.XA Pending CN109442609A (en) | 2018-09-12 | 2018-09-12 | A kind of air cleaning unit of formaldehyde |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111494693A (en) * | 2020-04-24 | 2020-08-07 | 安徽网阅教育科技有限公司 | Suspended classroom disinfection instrument |
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| WO2005030370A1 (en) * | 2003-09-25 | 2005-04-07 | Carrier Corporation | Photocatalytic oxidation air purification system |
| CN104084192A (en) * | 2014-07-29 | 2014-10-08 | 山东沁宇环保科技有限公司 | Catalyst for degrading ozone and removing VOCs synergistically as well as preparation method and application of catalyst |
| CN106731577A (en) * | 2016-12-29 | 2017-05-31 | 上海新耦合空气净化技术有限公司 | A kind of air cleaning unit of volatile organic contaminant |
-
2018
- 2018-09-12 CN CN201811064091.XA patent/CN109442609A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005030370A1 (en) * | 2003-09-25 | 2005-04-07 | Carrier Corporation | Photocatalytic oxidation air purification system |
| CN104084192A (en) * | 2014-07-29 | 2014-10-08 | 山东沁宇环保科技有限公司 | Catalyst for degrading ozone and removing VOCs synergistically as well as preparation method and application of catalyst |
| CN106731577A (en) * | 2016-12-29 | 2017-05-31 | 上海新耦合空气净化技术有限公司 | A kind of air cleaning unit of volatile organic contaminant |
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| Title |
|---|
| 唐谟堂: "《精细冶金》", 30 September 2017, 中南大学出版社 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111494693A (en) * | 2020-04-24 | 2020-08-07 | 安徽网阅教育科技有限公司 | Suspended classroom disinfection instrument |
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Application publication date: 20190308 |