CN109440478A - A kind of hygroscopic technique of improvement polyester fiber - Google Patents

A kind of hygroscopic technique of improvement polyester fiber Download PDF

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Publication number
CN109440478A
CN109440478A CN201811097665.3A CN201811097665A CN109440478A CN 109440478 A CN109440478 A CN 109440478A CN 201811097665 A CN201811097665 A CN 201811097665A CN 109440478 A CN109440478 A CN 109440478A
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CN
China
Prior art keywords
modified
polyester fiber
cabinet
hygroscopic
stoste
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811097665.3A
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Chinese (zh)
Inventor
张建武
严淳
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Wuhan Lovegod Knitting Industry Co Ltd
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Wuhan Lovegod Knitting Industry Co Ltd
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Priority to CN201811097665.3A priority Critical patent/CN109440478A/en
Publication of CN109440478A publication Critical patent/CN109440478A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a kind of hygroscopic techniques of improvement polyester fiber, comprising: 1) preparation of fluid nutrient medium;2) it is inoculated with, is inoculated with cellulase strain liquid toward fluid nutrient medium, inoculation volume is the 6% of fluid nutrient medium, is placed in 36 DEG C, stands for 24 hours, obtains processing stoste;3) handle, by above-mentioned steps 1) and 2) preparation target volume processing stoste;Processing polyester fiber to be modified is placed in modified device, impregnates 36h to get modified polyester fiber.Present invention process improves the activity of cellulase strain liquid first with myrothecium roidium seed liquor, and complement each other therebetween, collective effect is modified polyester fibre surface, and then it is effectively improved the hydrophily of polyester fibre surface, to improve its moisture pick-up properties.

Description

A kind of hygroscopic technique of improvement polyester fiber
Technical field
The present invention relates to the modified fields of polyester fiber.It is more particularly related to a kind of improvement polyester fiber moisture absorption The technique of property.
Background technique
Polyester fiber (polyester fibre), is commonly called as " terylene ", is the first big kind of current synthetic fibers.As A kind of important high molecular material, PET are also widely used for multiple necks such as engineering plastics, biomaterial, container and product packaging Domain.Although having many excellent performances, since its surface has very high hydrophobicity, it is limited as informational function The application of material, biomedical material and filtering material.
Summary of the invention
The present invention provides a kind of improvement polyester fiber hygroscopic technique, can be effectively improved the hydrophilic of polyester fibre surface Property, to improve its moisture pick-up properties.
In order to achieve the goal above, the present invention provides a kind of improvement polyester fiber hygroscopic technique, comprising:
1) preparation of fluid nutrient medium
Take 100 parts by weight micro-electrolytic waters, 3 parts by weight brown sugar, 1 parts by weight magnesium chloride, 1 parts by weight calcium chloride, in 2 parts by weight Gluten flour, 1 parts by weight of phosphoric acid potassium and 1 parts sulfuric acid zinc, mixing, the sterilization processing at pressure 0.05MPa, 80 DEG C of temperature 15min obtains liquid medium;
Rice vinegar is added into liquid medium, adjusts pH of mixed to the slightly sour environment of 5.6-6.5, obtains acid medium liquid;It is quiet It sets for 24 hours;
Oxytropism liquid medium accesses cultured myrothecium roidium seed liquor in advance again, wherein myrothecium roidium seed liquor Access amount be acid medium liquid product 5%, stand 48h, obtain fluid nutrient medium;
2) it is inoculated with
It is inoculated with cellulase strain liquid toward fluid nutrient medium, inoculation volume is the 6% of fluid nutrient medium, 36 DEG C are placed in, It stands for 24 hours, obtains processing stoste;
3) it handles
By above-mentioned steps 1) and 2) prepare target volume processing stoste;
Processing polyester fiber to be modified is placed in modified device, environment temperature is kept for 36 DEG C, impregnates 36h to get changing Polyester fiber after property.
Preferably, the hygroscopic technique of improvement polyester fiber, the reforming apparatus include:
More preferably, the hygroscopic technique of improvement polyester fiber, the modified device include:
Cabinet, top is open, interior for accommodating modified stoste;Sliding rail is arranged along its height in the cabinet;
A pair of of baffle is articulated with the cabinet wall two sides by the first spring respectively;It is stretched often when the first spring is in When state, a pair of of baffle inclination interlocks, and the two staggered place forms gap, is escaped with supplied gas;
Dispersion plate is laterally detachably built in the cabinet, and is located at modified stoste liquid level or more;On the dispersion plate It is full of the venthole for allowing gas to pass through;
Two accommodates plates, interval is detachably built in the cabinet up and down, is formed place place to be modified therebetween Manage the accommodation space of polyester fiber;Two accommodates plates move up and down each along the sliding rail;The accommodates plate include fixed frame with And it is adhered to reticular structure made of rubber in fixed frame;Several second springs are connected between the fixed frame of two accommodates plates; The reticular structure of underlying accommodates plate is separately connected sphere by several rubber covered wires, in the case where the movement of accommodates plate drives, rubber Deformation occurs for tree lace, so that sphere be driven to beat, and then is stirred to modified stoste;
Wherein, cabinet side opens up air inlet, is located at modified stoste liquid level or more and is close to modified stoste liquid level, and And it is located at dispersion plate or less.
More preferably, the hygroscopic technique of improvement polyester fiber, the cabinet wall coat erosion shield.
More preferably, the hygroscopic technique of improvement polyester fiber, the cabinet are flat column structure.
More preferably, the hygroscopic technique of improvement polyester fiber, further includes:
Motor is fixed on the dispersion plate;
The body of rod, one end connect motor output shaft, and the other end is fixed on the accommodates plate of top, driven by the motor, band The accommodates plate movement of dynamic top.
More preferably, the hygroscopic technique of improvement polyester fiber, further includes:
Several spray heads are enclosed around cabinet one, and towards box house;Spray head is located at cabinet along box height direction Middle part.
More preferably, the hygroscopic technique of improvement polyester fiber, further includes:
Controller, the every 30min work 10min of control motor.
The present invention is include at least the following beneficial effects: present invention process improves fiber first with myrothecium roidium seed liquor The activity of plain enzyme bacterial strain liquid, and complement each other therebetween, collective effect is modified polyester fibre surface, in its table Face forms rough microvoid structure, is effectively improved the hydrophily of polyester fibre surface, to improve its moisture pick-up properties.
Further advantage, target and feature of the invention will be partially reflected by the following instructions, and part will also be by this The research and practice of invention and be understood by the person skilled in the art.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of reforming apparatus in the present invention.
Specific embodiment
Present invention will be described in further detail below with reference to the accompanying drawings, to enable those skilled in the art referring to specification text Word can be implemented accordingly.
Embodiment 1
A kind of hygroscopic technique of improvement polyester fiber, comprising:
1) preparation of fluid nutrient medium
Take 100 parts by weight micro-electrolytic waters, 3 parts by weight brown sugar, 1 parts by weight magnesium chloride, 1 parts by weight calcium chloride, in 2 parts by weight Gluten flour, 1 parts by weight of phosphoric acid potassium and 1 parts sulfuric acid zinc, mixing, the sterilization processing at pressure 0.05MPa, 80 DEG C of temperature 15min obtains liquid medium;
Rice vinegar is added into liquid medium, adjusts pH of mixed to the slightly sour environment of 5.6-6.5, obtains acid medium liquid;It is quiet It sets for 24 hours;
Oxytropism liquid medium accesses cultured myrothecium roidium seed liquor in advance again, wherein myrothecium roidium seed liquor Access amount be acid medium liquid product 5%, stand 48h, obtain fluid nutrient medium;
2) it is inoculated with
It is inoculated with cellulase strain liquid toward fluid nutrient medium, inoculation volume is the 6% of fluid nutrient medium, 36 DEG C are placed in, It stands for 24 hours, obtains processing stoste;
3) it handles
By above-mentioned steps 1) and 2) prepare target volume processing stoste;
Processing polyester fiber to be modified is placed in modified device, impregnates 36h to get modified polyester fiber.
Embodiment 2
A kind of hygroscopic technique of improvement polyester fiber, comprising:
1) preparation of fluid nutrient medium
Take 100 parts by weight micro-electrolytic waters, 3 parts by weight brown sugar, 1 parts by weight magnesium chloride, 1 parts by weight calcium chloride, in 2 parts by weight Gluten flour, 1 parts by weight of phosphoric acid potassium and 1 parts sulfuric acid zinc, mixing, the sterilization processing at pressure 0.05MPa, 80 DEG C of temperature 15min obtains liquid medium;
Rice vinegar is added into liquid medium, adjusts pH of mixed to the slightly sour environment of 5.6-6.5, obtains acid medium liquid;It is quiet It sets for 24 hours;
Oxytropism liquid medium accesses cultured myrothecium roidium seed liquor in advance again, wherein myrothecium roidium seed liquor Access amount be acid medium liquid product 5%, stand 48h, obtain fluid nutrient medium;
2) it is inoculated with
It is inoculated with cellulase strain liquid toward fluid nutrient medium, inoculation volume is the 6% of fluid nutrient medium, 36 DEG C are placed in, It stands for 24 hours, obtains processing stoste;
3) it handles
By above-mentioned steps 1) and 2) prepare target volume processing stoste;
Processing polyester fiber to be modified is placed in modified device, impregnates 36h to get modified polyester fiber.
The reforming apparatus includes: a kind of modified device for polyester fiber modifying process, comprising:
Cabinet 1, the cabinet are flat column structure;Top is open, interior to accommodate modified stoste;The cabinet 1 is along its height Degree setting sliding rail 2;A pair of of baffle 3 is articulated with the 1 inner wall two sides of cabinet by the first spring 4 respectively;At the first spring 4 In stretching under normal conditions, a pair of of inclination of baffle 3 interlocks, and the two staggered place forms gap, is escaped with supplied gas;
Dispersion plate 5 is laterally detachably built in the cabinet 1, and is located at modified stoste liquid level or more;The dispersion plate The venthole for allowing gas to pass through is full of on 5;
Two accommodates plates 6, interval is detachably built in the cabinet 1 up and down, and it is to be modified to form placement therebetween Handle the accommodation space of polyester fiber;Two accommodates plates 6 move up and down each along the sliding rail 2;The accommodates plate 6 includes fixing Reticular structure made of frame and the rubber being adhered in fixed frame;Several second are connected between the fixed frame of two accommodates plates 6 Spring 7;The reticular structure of underlying accommodates plate 6 is separately connected sphere 9 by several rubber covered wires 8, in the movement of accommodates plate 6 Under drive, deformation occurs for rubber covered wire 8, so that sphere 9 be driven to beat, and then is stirred to modified stoste;Motor 11, is fixed In on the dispersion plate 5;The body of rod 12, one end connect motor output shaft, and the other end is fixed on the accommodates plate 6 of top, in motor Drive under, drive top accommodates plate 6 move.Wherein, 1 side of cabinet opens up air inlet 10, is located at modified stoste liquid level Above and it is close to modified stoste liquid level, and is located at 5 or less dispersion plate;Aseptic gas from the air inlet entrance after, via Dispersion plate up escapes.
When polyester fiber needs improve in reforming apparatus, polyester fiber to be modified is put into two accommodates plates 6 Between, then using motor drive top fixed frame up and down motion, and due between two accommodates plates 6 by the first spring bullet Property connection, so that two accommodates plates 6 will move simultaneously, and then drive the slowly agitation of entire modified stoste, keep modified stoste Uniformity so that polyester fiber treatment effect is more preferable, more uniformly.And whole process, led in cabinet 1 by air inlet 10 Enter aseptic gas, since gas escapes from lower to upper, is gnotobasis to keep entire modified environment, guarantees the suitable of modifying process Benefit carries out.
The water imbibition for the polyester fiber being modified through present invention process is greatly improved, and can be improved 65%.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details and legend shown and described herein.

Claims (7)

1. a kind of hygroscopic technique of improvement polyester fiber characterized by comprising
1) preparation of fluid nutrient medium
Take 100 parts by weight micro-electrolytic waters, 3 parts by weight brown sugar, 1 parts by weight magnesium chloride, 1 parts by weight calcium chloride, muscle face in 2 parts by weight Powder, 1 parts by weight of phosphoric acid potassium and 1 parts sulfuric acid zinc, mixing, the sterilization processing 15min at pressure 0.05MPa, 80 DEG C of temperature, Obtain liquid medium;
Rice vinegar is added into liquid medium, adjusts pH of mixed to the slightly sour environment of 5.6-6.5, obtains acid medium liquid;It stands 24h;
Oxytropism liquid medium accesses cultured myrothecium roidium seed liquor in advance again, and wherein myrothecium roidium seed liquor connects Enter 5% that amount is acid medium liquid product, stands 48h, obtain fluid nutrient medium;
2) it is inoculated with
It is inoculated with cellulase strain liquid toward fluid nutrient medium, inoculation volume is the 6% of fluid nutrient medium, is placed in 36 DEG C, stands For 24 hours, processing stoste is obtained;
3) it handles
By above-mentioned steps 1) and 2) prepare target volume processing stoste;
Processing polyester fiber to be modified is placed in modified device, environment temperature is kept for 36 DEG C, impregnates 36h to get modified Polyester fiber.
2. improving the hygroscopic technique of polyester fiber as described in claim 1, which is characterized in that the modified device includes:
Cabinet, top is open, interior for accommodating modified stoste;Sliding rail is arranged along its height in the cabinet;
A pair of of baffle is articulated with the cabinet wall two sides by the first spring respectively;It is stretched under normal conditions when the first spring is in, A pair of of baffle inclination interlocks, and the two staggered place forms gap, is escaped with supplied gas;
Dispersion plate is laterally detachably built in the cabinet, and is located at modified stoste liquid level or more;It is full of on the dispersion plate Allow the venthole that gas passes through;
Two accommodates plates, interval is detachably built in the cabinet up and down, and it is poly- to form placement processing to be modified therebetween The accommodation space of ester fiber;Two accommodates plates move up and down each along the sliding rail;The accommodates plate includes fixed frame and glues It is attached to reticular structure made of the rubber in fixed frame;Several second springs are connected between the fixed frame of two accommodates plates;It is located at The reticular structure of the accommodates plate of lower section is separately connected sphere by several rubber covered wires, in the case where the movement of accommodates plate drives, rubber covered wire Deformation occurs, so that sphere be driven to beat, and then is stirred to modified stoste;
Wherein, cabinet side opens up air inlet, is located at modified stoste liquid level or more and is close to modified stoste liquid level, and position Below dispersion plate.
3. improving the hygroscopic technique of polyester fiber as claimed in claim 2, which is characterized in that the cabinet wall coating is anti- Corrosion resistant coating.
4. improving the hygroscopic technique of polyester fiber as claimed in claim 2, which is characterized in that the cabinet is flat column knot Structure.
5. the hygroscopic technique of improvement polyester fiber as described in right wants 2, which is characterized in that further include:
Motor is fixed on the dispersion plate;
The body of rod, one end connect motor output shaft, and the other end is fixed on the accommodates plate of top, driven by the motor, in drive The accommodates plate movement of side.
6. improving the hygroscopic technique of polyester fiber as claimed in claim 2, which is characterized in that further include:
Several spray heads are enclosed around cabinet one, and towards box house;Spray head is located in cabinet along box height direction Portion.
7. improving the hygroscopic technique of polyester fiber as claimed in claim 5, which is characterized in that further include:
Controller, the every 30min work 10min of control motor.
CN201811097665.3A 2018-09-20 2018-09-20 A kind of hygroscopic technique of improvement polyester fiber Pending CN109440478A (en)

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CN201811097665.3A CN109440478A (en) 2018-09-20 2018-09-20 A kind of hygroscopic technique of improvement polyester fiber

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112429999A (en) * 2020-12-01 2021-03-02 李平 Preparation method of crack-resistant and impervious cement concrete

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1278195A (en) * 1969-02-03 1972-06-14 Kyowa Hakko Kogyo Kk Cellulase
JPH08158265A (en) * 1994-12-02 1996-06-18 Ekorogu Recycling Japan:Kk Method for recovering textile product
US6066494A (en) * 1996-03-06 2000-05-23 The Regents Of The University Of California Enzyme treatment to enhance wettability and absorbency of textiles
JP2004141027A (en) * 2002-10-23 2004-05-20 Aichi Prefecture New laccase and method for producing the same
CN107641844A (en) * 2017-10-12 2018-01-30 邳州市银潮纺织有限公司 A kind of manufacture method of water imbibition polyester fiber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1278195A (en) * 1969-02-03 1972-06-14 Kyowa Hakko Kogyo Kk Cellulase
JPH08158265A (en) * 1994-12-02 1996-06-18 Ekorogu Recycling Japan:Kk Method for recovering textile product
US6066494A (en) * 1996-03-06 2000-05-23 The Regents Of The University Of California Enzyme treatment to enhance wettability and absorbency of textiles
JP2004141027A (en) * 2002-10-23 2004-05-20 Aichi Prefecture New laccase and method for producing the same
CN107641844A (en) * 2017-10-12 2018-01-30 邳州市银潮纺织有限公司 A kind of manufacture method of water imbibition polyester fiber

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
于跃、张剑: "纤维素酶降解纤维素机理的研究进展", 《化学通报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112429999A (en) * 2020-12-01 2021-03-02 李平 Preparation method of crack-resistant and impervious cement concrete

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Application publication date: 20190308