CN109437210A - A kind of combustion gas counter-current produces the device and method of silica flour using quartz tail sand - Google Patents
A kind of combustion gas counter-current produces the device and method of silica flour using quartz tail sand Download PDFInfo
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- CN109437210A CN109437210A CN201811639648.8A CN201811639648A CN109437210A CN 109437210 A CN109437210 A CN 109437210A CN 201811639648 A CN201811639648 A CN 201811639648A CN 109437210 A CN109437210 A CN 109437210A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
Abstract
The present invention provides a kind of devices of gas heating countercurrent spray method production spherical quartz emery dust, including tailings storehouse, gas-fired heater, high temperature spheroidizing furnace, finished bin and screening system.The high temperature spheroidizing furnace bottom connects gas-fired heater；Gas-fired heater lower end is connected to coarse granule collecting bin by collecting pipe；Air-intake device side is linked into collecting pipe, and air-intake device includes blower and conduit；Gas-fired heater side is connect with tailings storehouse；High temperature spheroidizing furnace bottom also passes through cooling tube and is communicated to finished bin.High temperature spheroidizing furnace top connects screening system.Beneficial effects of the present invention: using the combination of high temperature spheroidizing furnace and screening system, the nodularization and screening of quartz tail sand are realized；By the way of the charging of bottom, classification is sieved using adverse current, realizes the screening of micro mist；By the real-time adjusting for controlling the air quantity of air-introduced machine, the gas flow and feeding quantity realization grain diameter of compressed air.
Description
Technical field
The invention belongs to non-metal ore advanced processing technical areas, and in particular to a kind of gas heating countercurrent spray method is with quartz
Tailings is the device and method that raw material produces spherical quartz powder.
Background technique
In recent years, with the fast development of microelectric technique, people are higher and higher to the quality requirement of microelectronic element, make
It is also higher and higher to obtain silicon powder quality requirement.The 97% of global integrated circuit (IC) encapsulating material uses epoxy-plastic packaging material (EMC),
And in the composition of EMC, in addition to major ingredient novolac epoxy resin, silicon powder is the most filler of dosage.Silicon powder filler accounts for epoxy
Moulding compound weight ratio reaches 70%-90%.So in order to high quality plastic packaging material in addition to requiring ultra-fine silicon powder, high-purity, low putting
Outside penetrating property element, its spheroidizing of particles is also specially required.This is because: the surface mobility of (1) ball is good, form a film with resin agitating
Uniformly, so that the additive amount of resin is small, the loading of silicon powder reaches highest, therefore spheroidization means silicon powder filling rate
Increase, and the filling rate of silicon powder is higher, for the coefficient of expansion with regard to smaller, thermal coefficient is also lower, also just closer to monocrystalline silicon
The service performance of thermal expansion coefficient, resulting electronic component is also better；(2) with plastic packaging material phase made of angular silicon powder
Than, spherical plastic packaging material profit concentrates minimum, intensity highest, when it is 1 that the plastic packaging material stress of angular powder, which is concentrated, the stress of spherical powder
Only 0.6, thus manufactured microelectronic component high yield rate, is readily transported, installs, and be not likely to produce machine in use
Tool damage；(3) compared to angular silicon powder, spherical powder coefficient of friction is small, small to the abrasion of mold, so that the service life of mold
It can be improved one times.(Ruan Jianjun " progress of ball-shaped silicon micro powder " He Lijun, Jiang Shuxing " ball-shaped silicon micro powder ")
Currently, high quality ball-shaped silicon micro powder part required for China also relies on import, high-purity, ultra-fine ball how is prepared
Shape silicon powder is still domestic powder research hotspot.The preparation method of ball-shaped silicon micro powder mainly includes physical method and chemistry at this stage
Method.
1, physical method
1.1, flame spherical container shaping method: flame spherical container shaping method such as is crushed to quartz first, sieves, purifies at the pre-treatments, then will
Quartz micropowder is sent into the high-temperature field that gas-oxygen generates, and is carried out high-temperature fusion, cooling balling-up, is ultimately formed high-purity spherical shape
Silicon powder.
Clean pollution-free fire of the industrial fuels such as acetylene gas, hydrogen, natural gas gas as melting powder specifically can be used
Flame is heat source, and such method is related to the theory of thermodynamics, hydrodynamics, granule fluid mechanics etc..With plasma high-temperature
Flame is compared, and is not involved in the problems, such as that electromagnetic theory and ion are flowed and moved in electromagnetic field, produces easy to control, Yi Shixian work
Industryization large-scale production, is a kind of production technology with development prospect.
The disadvantages of this method is: industrial combustion gas -- acetylene gas and natural gas can also give product quality during burning
Bring certain pollution.Danger coefficient is big in use for hydrogen.It is industrially extensive, mature to yet there are no this method
Application report.
1.2, high-temperature fusion gunite: high-temperature fusion gunite is to melt high-purity quartz at 2100-2500 DEG C to be
Liquid obtains ball-shaped silicon micro powder by spraying, cooling.Product surface is smooth, and spherical rate and amorphous form quotient can reach
100%.According to investigation, the ball-shaped silicon micro powder in the U.S. mainly uses this method to produce, due to being related to high-performance computer technology, he
Externally bottle up.High-temperature fusion gunite easily guarantees Oxygen potential and amorphous rate, but is not easy to solve purity and atomizing particle size
The problems such as adjustment.The country is there is not yet this respect is studied and the report of production at present.
1.3, self- propagating low-temperature combustion method: the process flow of self- propagating low-temperature combustion method includes the preparation of sodium metasilicate, silicic acid
The preparation of colloidal sol, the preparation for being mixed and burned liquid, combustion reaction, annealing are except carbon, carrying out washing treatment.
The technical method has the advantage that as follows:
(1) it can also be extended to using melting silicon powder as raw material using natural powdery quartz as raw material；(2) simple process,
Easy to operate without especial equipment requirements, easily controllable, production cost is low；(3) material used in production process only includes easily
It is dissolved in the sodium ion and nitrate ion of water, other impurities ion will not be introduced, is conducive to the preparation of high purity silica powder.
Disadvantage is: this method is merely resting on laboratory stage at present, can't be mass produced well.
1.4, plasma method: the basic principle of plasma method is to utilize the high-temperature region of plasma square by silica
(SiO2) powder fusing, since the effect of surface tension of liquid forms spherical droplets, spheroidization is formed during rapid cooling
Particle.This method energy is high, heat transfer is fast, cooling block, prepared product morphology controllable, purity is high, soilless sticking.
The disadvantages of this method: this method is merely resting on laboratory stage at present, can't be mass produced well.
1.5, high-temperature calcination spheroidization: high-temperature calcination spheroidization is generally used for preparing high-purity ultra-fine sphere silicon micro-powder, mainly
It is that the processing that miberal powder is passed through the techniques such as calcining, ball milling, magnetic separation and selection by winnowing prepares high-purity ultra-fine sphere SILICA FUME.
The advantages of this method: not only Oxygen potential is high, whiteness is good, silicon content is high, iron content aluminium is few for high-purity ultra-fine sphere silicon micro-powder,
PH value is in neutrality slant acidity, flowing good dispersion, and expansion and thermal coefficient are small, and conductivity is low, and corrosion-resistant, production cost is low.
The disadvantages of this method: the technology is at present also in the experimental stage.
2, chemical method
2.1, vapor phase method: vapor phase method SiO2(being commonly called as fume colloidal silica) is to be hydrolyzed to be made at high temperature by the halide of silicon
Fine, the special amorphous powder body material of one kind.In the water that oxyhydrogen combustion flame generates high-temperature water occurs for silane halide
Solution reaction, temperature are generally up to 1200-1600 DEG C, are then quenched, using aggregation, cyclonic separation, air injection depickling, boiling
The post-processings such as bed screening, vacuum compression packaging obtain the SiO that finished product vapor phase method generates2Product purity is high, and Average primary partial size is
7-40nm, specific surface area 50-380m2/ g, SiO2Mass fraction is not less than 99.8%.The disadvantages of this method is in organic matter
It is difficult to disperse and pollutes environment.
2.2, hydrothermal synthesis method: hydrothermal synthesis method is a kind of common method that liquid phase prepares nanoparticle, generally in 100-
At 350 DEG C of temperature and hyperbaric environment, make inorganic and organic compound and hydrate, by acceleration dialysis reaction and physical process
Control, obtain improved inorganic matter, using filter, washing, drying, obtain high-purity, ultra-fine particulate.The advantages of hydro-thermal method
It is that can directly generate oxide, the step for general liquid phase synthesizing method need to be converted to oxide by calcination is avoided, to drop
The low formation probability of hard aggregation.
The shortcomings that method, is also apparent from: being limited to the size of reaction kettle, hydro-thermal method prepares SiO at present2Also it is in laboratory
Stage.
2.3, sol-gel method: sol-gel method be metal organic or inorganic compound by solution, colloidal sol, gel and
Solidification, then the method for thermally treated and formation oxide or other compound solids.The advantages of this method be chemical uniformity it is good,
Particle is thin, with high purity, equipment is simple, and powder active is high.Disadvantage is: raw material are more expensive, and particle asks that agglutinating property is poor, receive when dry
Contracting is big, agglomeration traits easily occurs.
2.4, the precipitation method: surfactant, control reaction temperature is added using waterglass and acidulant as raw material in the precipitation method in due course
Degree adds stabilizer when precipitation solution pH value is 8, and gained precipitating is washed, dry, forms silicon powder after calcining.The precipitation method are raw
At SiO2Uniform particle sizes and at low cost, technique is easy to control, is conducive to industrialized production, but there are certain agglomerations.
2.5, microemulsion method: microemulsion method is formed under the action of surfactant using two kinds of immiscible solvents
Uniform lotion is confined to the processes such as nucleation, production, coalescence, reunion in one small spherical droplets, is precipitated from lotion
Solid phase forms spheric granules, avoids and further reunites between particle.SiO is prepared using microemulsion method2Mostly with ethyl orthosilicate
It for silicon source, is spread by ethyl orthosilicate molecule, is permeated through reverse micelle interfacial film into water core, it is anti-that hydrolytic condensation then occurs
It answers, SiO is made2.The preparation of this method Granularity Distribution is narrow, size tunable, good dispersion.The shortcomings that method: this method at present
It is merely resting on laboratory stage, can't be mass produced well.
3, spray-on process: spray-on process is that solution is carried out a kind of chemistry that atomization obtains ultramicron by various physical means
The method combined with physics.Its basic process is the preparation, spraying, dry, collection and heat treatment of solution.The method feature
It is that distribution of particles is relatively uniform, but particle size is sub-micron to 10 μm, is a kind of synthesis size tunable nanoparticle oxide
New method.The shortcomings that method: energy consumption is high, and the micro mist after drying is reunited seriously, and use is very inconvenient.
By the way that the above-mentioned comparison for preparing the various methods of silicon powder, we can substantially be obtained: the spherical shape of physical method preparation
Raw material needed for silicon powder are relatively inexpensive, but more demanding to raw material quartz quality and production equipment etc..Its Flame at
Ball is currently a kind of achievable large-scale production and promising technology, but its there are purity and atomizing particle size
The problem of adjustment.
Chemical method can prepare high-purity and uniform particle sizes spherical SiOs2, but since a large amount of surfactant need to be used, because
This is not easy cleared, easy reunion there are high production cost, organic impurities and is difficult to the disadvantages of industrializing.In line with economic principle,
If the problems of chemical method can be solved by the method for chemical modification, the production of China's ball-shaped silicon micro powder will be industrialized
And the fast development of Electronic Packaging industry has profound significance.
Chinese patent literature is inquired, is not found using quartz tail sand as atomizing raw materials to 2000-2300 DEG C of gas heating
The industrial application of spherical quartz emery dust and the report of industrialized unit service condition are prepared in high temperature ultrahigh-temperature molten furnace.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of gas heating countercurrent spray methods using quartz tail sand as raw material
Produce the device and method of spherical quartz emery dust.Device provided by the invention will be atomized and nodularization combines, and passes through parameter
Control and optimization, so that prepared spherical quartz emery dust has the advantages that with high purity, particle diameter distribution is narrow, size tunable.Simultaneously
The device is versatile, is applicable to the production of the spherical quartz emery dust of various purity and granularity.
Preparation method provided by the present invention, which uses, to be first atomized quartz tail sand, melt or gasifies, gathers the think of of cold nodularization again
The quartz tail sand in certain particle size section is atomized by road with compressed gas first, in the 2000- generated by fuel gas buring after atomization
Lower fusing rapidly or gasification in 2300 DEG C of high-temperature melting furnace, then under the draft of air-introduced machine and the push of air blower effect,
The gas of particle or gasification after fusing, anti-gravity direction is from balling furnace bottom to ionized motion, natural shrinking during the motion
At spherical particle, wherein the biggish particle of partial size is fallen after rise under the effect of gravity through cooling tube to finished bin, the lesser particle of partial size
It sieves and collects through multicyclone dust collector, sieve and collect using being realized under the collective effect of gravity and external force.Use this hair
The device of bright offer carries out micro mist production and is convenient to carry out the regulation of grain size of micropowder according to demand, that is, passes through the grain for the powder that feeds intake
The regulation of partial size is realized in the adjusting of the technical parameter of the equipment such as diameter, cyclone dust collectors, bag filter and air-introduced machine.
Quartz tail sand typically refers to 120 meshes particle between 300 mesh, due to wet process water sieve point in actual production process
When grade, there is breakage in when sieve；When hydraulic classiciation, the sometimes excessively high situation of hydraulic pressure occurs, and thus has 120 purposes
On sieve sand particles be mixed into wherein, according to experience have shown that: 60 mesh sand accounting 5-8%, 120 mesh accounting 10-15% in general quartz tail sand.
Bulky grain emery dust in tailings is certain in air quantity and wind speed due to the larger pole of partial size in passing through compressed air transmission process
In the case where, it cannot smoothly enter in high-temperature melting furnace, cause air duct to block in the air -return duct that is easy to backflow instead.Based on above-mentioned
Coarse granule collecting bin is arranged in reason below gas-fired heater, and air-intake device is by the way of the air inlet of side, so that bulky grain
Flowback of fines enters in coarse granule collecting bin, not will cause air duct blocking.
Scheme provided by the invention is as follows:
A kind of gas heating countercurrent spray method produces the device of spherical quartz emery dust, including tailings using quartz tail sand as raw material
Storehouse, gas-fired heater, high temperature spheroidizing furnace, finished bin and screening system.
High temperature spheroidizing furnace (3) bottom connects gas-fired heater (2)；Gas-fired heater (2) lower end passes through collecting pipe
(131) coarse granule collecting bin (13) are connected to；Air-intake device (11) side is linked into collecting pipe (131), air-intake device (11) packet
Include blower (111) and conduit (112)；Gas-fired heater (2) side is connect with tailings storehouse (1).
High temperature spheroidizing furnace bottom also passes through cooling tube and is communicated to finished bin.
High temperature spheroidizing furnace top connects screening system.
Above-mentioned gas-fired heater includes air inlet pipe, burner noz(zle) and high temperature pipe；The air inlet pipe is connected to high temperature pipe lower end
Inside is simultaneously connected to burner noz(zle)；High temperature pipe outsourcing insulating layer.
Above-mentioned screening system includes condenser pipe, cyclone dust collectors and air-introduced machine；Condenser pipe, cyclone dust collectors and air-introduced machine according to
Secondary connection；High temperature spheroidizing furnace top connects condenser pipe.
Above-mentioned gas-fired heater is provided with thermometer.
Above-mentioned cyclone dust collectors include one cyclonic deduster, second cyclone dust extractor and bag filter, and three is successively
It is connected.
Above-mentioned high temperature spheroidizing furnace is cylindrical type, and upper outlet is arc with horizontal connection to screening system, outlet at bottom
For arc.
Above-mentioned high temperature spheroidizing furnace side wall is provided with observation window.
Above-mentioned finished bin upper end is provided with exhaust-valve.
Another object of the present invention is to provide the methods using above-mentioned apparatus production ball-shaped silicon micro powder, including following step
It is rapid:
(1) igniting preheating gas-fired heater, opens air-introduced machine and condenser, stablizes the temperature in gas-fired heater
2000-2300℃；
(2) quartz tail sand material is added in tailings storehouse, opens air-intake device so that silicon powder is introduced into gas heating
In furnace；
(3) compressed air brings quartz tail sand powder in high temperature spheroidizing furnace into；
(4) micro mist is melted and is settled rapidly；The biggish particle of partial size is fallen into finished bin through cooling tube to be collected, and partial size is smaller
The screened system of particle collect.
The partial size of above-mentioned particle can be adjusted in real time by the air quantity of control air-introduced machine, the gas flow of compressed air and feeding quantity
Section.
Beneficial effects of the present invention:
(1) combination for using high temperature spheroidizing furnace and screening system, realizes the nodularization and screening of quartz tail sand；
(2) by the way of the charging of bottom, classification is sieved using adverse current, and coarse granule can carry out ball after melting at high temperature
Change, and tiny particle then melt or gasifies after by air-introduced machine bring into cyclone separator cool down and nodularization, to reach thick
The purpose of the quick separating and fast spheroidizing annealing of granule and fine particle；
(3) Quartz Tails are used to produce ball spherical quartz powder as raw material, changing rejected material to useful resource reduces the cost；
(4) nodularization process introduces external force by air-introduced machine, in conjunction with the gravity of particle itself, is conducive to improve nodularization speed,
And the size of the air volume control partial size of control air-introduced machine can be passed through；
(5) the side-entry design of setting and use of coarse granule collecting bin is so that the coarse granule of quartz tail sand effectively returns
It receives, not will cause air duct blocking；
(6) three-level screening system is conducive to the subdivision of partial size；
(7) design of observation window facilitates the atomization situation of observation particle, to be controlled in real time by adjustment parameter as needed
The size of partial size；
(8) by the air quantity of control air-introduced machine, the gas flow and feeding quantity, grain diameter size of compressed air, in real time
The wind speed that adjusting enters first order cyclone dust collectors is 8-12m/s.
Detailed description of the invention
Fig. 1 provides the structural schematic diagram of device for the present invention；
Fig. 2 is burner noz(zle) structural schematic diagram；
Appended drawing reference: 1- tailings storehouse, 2- gas-fired heater, 21- air inlet pipe, 22- burner noz(zle), 23- high temperature pipe, 3- high temperature
Balling furnace, 31- peep hole, 4- condenser, 5- one cyclonic deduster, 6- second cyclone dust extractor, 7- bag filter, 8- draw
Blower, 9- cooling tube, 10- finished bin, 101- exhaust-valve, 11- air-intake device, 111- blower, 112- conduit, 12- thermometer,
13- coarse granule collecting bin, 131- collecting pipe.
Specific embodiment
The present invention is further described combined with specific embodiments below, and the contents of the present invention are completely without being limited thereto.
Embodiment 1
Fig. 1 shows the present invention and provides the structure of device.
A kind of combustion gas counter-current produces the device of silica flour, including tailings storehouse 1, gas-fired heater 2, height using quartz tail sand
Warm balling furnace 3, finished bin 10 and screening system.
3 bottom of high temperature spheroidizing furnace connects gas-fired heater 2, and 2 lower end of gas-fired heater is connected to thick by collecting pipe 131
Grain collecting bin 13.11 side of air-intake device is linked into collecting pipe 131, and air-intake device 11 includes blower 111 and conduit 112, combustion gas
2 side of heating furnace is connect with tailings storehouse 1.
3 bottom of high temperature spheroidizing furnace also passes through cooling tube 9 and is communicated to finished bin 10.
Gas-fired heater 2 includes air inlet pipe 21, burner noz(zle) 22 and high temperature pipe 23.Air inlet pipe 21 is connected under high temperature pipe 23
End, inside are simultaneously connected to burner noz(zle) 22；23 outsourcing insulating layer of high temperature pipe.Gas-fired heater 2 is additionally provided with thermometer 12.Air inlet
Pipe 21 divides for oxygen and gas inlet pipe, and the two is transported in high temperature pipe after being mixed by threeway, recycles 22 points of burner noz(zle)
Fire burning.The outlet in tailings storehouse 1 is higher than burner noz(zle) 22.
3 bottom of high temperature spheroidizing furnace also passes through cooling tube 9 and is communicated to finished bin 10.10 upper end of finished bin is provided with exhaust-valve
101.Exhaust-valve 101 is used for exhaust decompression.
It is that hat is spherical, and middle part is cylindrical type at the top and bottom of high temperature spheroidizing furnace 3.Top exit horizontal connection to screening be
System, outlet at bottom are connected to finished bin by cooling tube.Insulating layer is provided in high temperature spheroidizing furnace 3.3 side wall of high temperature spheroidizing furnace is set
Observation window 31 is equipped with for observing the size of micro powder granule with conveniently regulating and controlling particle size.
Screening system includes condenser 4, cyclone dust collectors and air-introduced machine 8, and three is sequentially connected.Preferably, cyclone dust removal
Device includes one cyclonic deduster 5, second cyclone dust extractor 6 and bag filter 7, and three is sequentially connected.Condenser 4 may be selected
Air-cooled or water cooling preferably uses water cooling.Cyclone dust collectors select II type of XPX-, CLK type or ceramic multi-tube type etc.；Bag-type dusting
Device selects DMCC type or the flat pouch-type of GP type high temperature etc.；Cooler selects air-cooled or indirect water-cooling type indirectly；Air-introduced machine uses G, Y4-
73 types or 9-19,9-26 type.4 top of balling furnace connects condenser 5.
Application Example 1
By taking the sharp quartz tail sand for rising quartzy Science and Technology Ltd. in Hubei as an example
Preparation step is as follows:
1, that quartz tail sand material is put into hopper is spare.
2, it is passed through combustion gas and oxygen, igniting heating gas-fired heater observes flame conditions by observation window and adjusts two kinds of gas
The ratio of body makes the flame of fuel gas buring in face, and heating furnace is heated to 2300 DEG C at leisure.While igniting, open
Blower and air-introduced machine, the carbon dioxide gas discharge for generating burning, regulating air volume, so that the temperature in high temperature pipe is stablized
At 2300 DEG C.
3, tailings is sent into high temperature pipe with the pressure of compressed air between 0.2-0.5MPa by the condensed water for connecting condenser
It is interior, under the collective effect of blower and air-introduced machine quartz tail sand powder be brought into gas-fired heater by flame envelope heating and it is rapid
Fusing, control gas flow are 60-70NM3/h.Quartz tail sand powder after fusing is then brought into high temperature spheroidizing furnace by air,
Since the diameter and volume of balling furnace are N times (N >=3) of high temperature pipe, wind-force and wind speed in wind-force and wind speed and high temperature pipe
Compared to thering is significant reduction, the biggish micro mist of particle to fall on balling furnace bottom through cooling tube under settling in high temperature spheroidizing furnace
Cooling meat is at spherical shape, then falls into finished bin up to spherical quartz powder.The lesser powder of partial size is made by the suction of air-introduced machine
With enter condenser in, by after one, two cyclone dust removals sieve after collect, most thin powder will be collected by bag-type dust after again
It is emptied by air-introduced machine.Spray pattern of the material in furnace, then appropriate adjusting air inducing are observed by the external observation window of balling furnace
To control the partial size of quartz micropowder, one cyclonic removes the feeding quantity size of the air quantity of machine, the gas flow of compressed air and material
The wind speed of dirt device is 8-10m/s.
4, the product for collecting finished bin, firsts and seconds micro mist collector, obtains thinner and different-grain diameter spherical stone
English powder product.
It is cooled down in addition, the air-cooled mode of blower can be used in the condenser between primary dust removing device and balling furnace, it is cooling
Cold air be heated after be recycled to high temperature bottom of the tube as the air entered needed for high temperature pipe.Heat can be both saved in this way
Amount, and can reduce by an air blower.
Application Example 2
Spherical quartz powder is prepared by taking the produced quartz tail sand of Zhanjiang company as an example
Preparation step is as follows:
1, that quartz tail sand material is put into hopper is spare.
2, it is passed through combustion gas and oxygen, igniting heating gas-fired heater observes flame conditions by observation window and adjusts two kinds of gas
The ratio of body keeps the flame of fuel gas buring blue, and heating furnace is heated to 2300 DEG C at leisure.While igniting, open
Blower and air-introduced machine are opened, the carbon dioxide gas discharge for generating burning, regulating air volume, so that the temperature in high temperature pipe is steady
It is scheduled on 2300 DEG C.
3, tailings is sent into high temperature pipe with the pressure of compressed air between 0.2-0.5MPa by the condensed water for connecting condenser
It is interior, under the collective effect of air blower and air-introduced machine quartz tail sand be brought into gas-fired heater by flame envelope heating and it is rapid
Fusing, the flow for controlling combustion gas is 50-60NM3/h.Quartz tail sand powder after fusing is then brought into high temperature spheroidizing furnace by air
In, since the diameter and volume of balling furnace are N times (N >=3) of high temperature pipe, wind-force and wind in wind-force and wind speed and high temperature pipe
Speed is compared under having significant reduction, the biggish micro mist of particle that can settle in high temperature spheroidizing furnace and falls on balling furnace bottom through cooling
Pipe cooling meat is at spherical shape, then falls into finished bin up to spherical quartz powder.Suction of the lesser powder of partial size by air-introduced machine
Effect enters in condenser, by collecting after sieving after one, two cyclone dust removals, after most thin powder will be collected by bag-type dust
It is emptied again by air-introduced machine.Spray pattern of the material in furnace is observed by the external observation window of balling furnace, then appropriate adjust is drawn
To control the partial size of silica flour, one cyclonic removes the feeding quantity size of the air quantity of blower, the gas flow of compressed air and material
The wind speed of dirt device is 10-12m/s.
4, the product for collecting finished bin, firsts and seconds micro mist collector, obtains thinner and different-grain diameter spherical stone
English powder product.
The foregoing is only a preferred embodiment of the present invention, but the scope of protection of the invention be not limited thereto,
Any modification that anyone skilled in the art is made in the technical scope disclosed by the present invention, equivalent replacement and
Improve etc., it should be included within the protection scope of invention.
Claims (10)
1. a kind of device of gas heating countercurrent spray method production spherical quartz emery dust, it is characterised in that:
Including tailings storehouse (1), gas-fired heater (2), high temperature spheroidizing furnace (3), finished bin (10) and screening system；
High temperature spheroidizing furnace (3) bottom connects gas-fired heater (2)；Gas-fired heater (2) lower end is connected by collecting pipe (131)
It is connected to coarse granule collecting bin (13)；Air-intake device (11) side is linked into collecting pipe (131), and air-intake device (11) includes blower
(111) and conduit (112)；Gas-fired heater (2) side is connect with tailings storehouse (1)；
High temperature spheroidizing furnace (3) bottom also passes through cooling tube (9) and is communicated to finished bin (10)；
High temperature spheroidizing furnace (3) top connects screening system.
2. the apparatus according to claim 1, it is characterised in that: the gas-fired heater (2) includes air inlet pipe (21), burning
Nozzle (22) and high temperature pipe (23)；The air inlet pipe (21) is connected to inside high temperature pipe (23) lower end and is connected to burner noz(zle)
(22)；High temperature pipe (23) outsourcing insulating layer.
3. the apparatus according to claim 1, it is characterised in that: screening system includes condenser pipe (4), cyclone dust collectors and draws
Blower (8)；Condenser pipe (4), cyclone dust collectors and air-introduced machine (8) are sequentially connected；High temperature spheroidizing furnace (3) top connects condenser pipe
(4)。
4. device according to claim 1 or 2, it is characterised in that: the gas-fired heater (2) is provided with thermometer
(12)。
5. the apparatus of claim 2, it is characterised in that: the cyclone dust collectors include one cyclonic deduster (5),
Second cyclone dust extractor (6) and bag filter (7), three is sequentially connected.
6. the apparatus according to claim 1, it is characterised in that: the high temperature spheroidizing furnace (3) is cylindrical type, and upper outlet is
For arc with horizontal connection to screening system, outlet at bottom is also arc.
7. device according to claim 1 or 4, it is characterised in that: described high temperature spheroidizing furnace (3) side wall is provided with observation
Window (31).
8. the apparatus according to claim 1, it is characterised in that: finished bin (10) upper end is provided with exhaust-valve (101).
9. a kind of method using claim 1 described device production ball-shaped silicon micro powder, which comprises the following steps:
(1) igniting preheating gas-fired heater (2) opens air-introduced machine (8) and condenser (4), makes the temperature in gas-fired heater (2)
Degree is stablized at 2000-2300 DEG C；
(2) quartz tail sand material is added in tailings storehouse (1), opens air-intake device (11) and is added so that silicon powder is introduced into combustion gas
In hot stove；
(3) compressed air brings quartz tail sand powder in high temperature spheroidizing furnace (3) into；
(4) micro mist is melted and is settled rapidly；The biggish particle of partial size falls into finished bin (10) through cooling tube (9) and collects, partial size
The lesser screened system of particle is collected.
10. according to the method described in claim 9, it is characterized by: the partial size of the particle can pass through the wind of control air-introduced machine
Amount, the gas flow of compressed air, raw material particle size and feeding quantity are adjusted in real time.
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