Summary of the invention
Based on this, it is necessary to aiming at the problem that, streamline wire drawing big existing wax hand product brittleness, provide a kind of toughness it is high, at
The smooth fingerprint wax of type.
In addition, also providing a kind of preparation method and application of fingerprint wax.
A kind of fingerprint wax, according to mass percentage meter, the stone for preparing raw material and including: 60%~85% of the fingerprint wax
Oily wax, 1%~15% flow ability modifying agent, 1%~10% toughener and 8%~20% Stiffening agent.
In above-mentioned fingerprint wax, toughener, Stiffening agent and flow ability modifying agent joined, and be equipped with certain proportion, it is therein
The toughness and rigidity of toughener and the adjustable fingerprint wax of Stiffening agent, so that the fingerprint wax rigidity-toughness balanced prepared, to slip out of the hand
Fingerprint wax will not be destroyed when pattern wax shell;Flow ability modifying agent can be such that fingerprint wax has again while with certain caking property centainly
Mobility does not occur the phenomenon that streamline wire drawing to keep fingerprint was moulding smooth.
The pertroleum wax is selected from fully refined paraffin wax of the fusing point lower than 55 DEG C in one of the embodiments, fusing point is lower than 55
DEG C semi-refined paraffin wax and fusing point be lower than 80 DEG C of at least one of microwax.
Fully refined paraffin wax of the fusing point lower than 55 DEG C is selected from 52# fully refined paraffin wax and 54# in one of the embodiments,
At least one of fully refined paraffin wax;And/or
The fusing point lower than 55 DEG C of semi-refined paraffin wax in 52# semi-refined paraffin wax and 54# semi-refined paraffin wax at least
It is a kind of;And/or
The fusing point is lower than at least one of 80 DEG C of microwax in 70# microwax, 75# microwax and W445 microwax
Kind.
The flow ability modifying agent is selected from C5 hydrogenated petroleum resin, terpene resin, monostearate in one of the embodiments,
In glyceride, diisononyl phthalate, diisooctyl phthalate, tributyl citrate and epoxidized soybean oil at least
It is a kind of;And/or
The toughener be selected from oligomer, amorphous state alpha olefin copolymer, ethylene-vinyl acetate copolymer, polyisobutene,
Styrene-ethylene-butylene-styrene block copolymer, styrene-isoprene-styrene block copolymer and styrene-fourth
At least one of styrene block copolymer;And/or
The Stiffening agent is selected from stearic acid, Fischer-Tropsch wax, river wax, polyethylene wax, polypropylene wax and low-molecular-weight polystyrene
At least one of, the relative molecular weight of the low-molecular-weight polystyrene is 2000~4000.
In one of the embodiments, the fingerprint wax prepare raw material further include mass percentage be 0.1%~
0.5% stabilizer, it is different that the stabilizer is selected from butylated hydroxy anisole, dibutyl hydroxy toluene, tert-butyl hydroquinone, N-
Propyl-N '-at least one of diphenyl-para-phenylene diamine and DBPC 2,6 ditertiary butyl p cresol;And/or the preparation of the fingerprint wax is former
Material further includes that mass percentage is 0.2% toner below, and the toner is color masterbatch, color or toner.
A kind of preparation method of fingerprint wax, includes the following steps:
Based on mass percentage, weigh the raw material for preparing of fingerprint wax, the fingerprint wax prepare raw material include: 60%~
85% pertroleum wax, 1%~15% flow ability modifying agent, 1%~10% toughener and 8%~20% Stiffening agent;
By the pertroleum wax uniform melt, basic wax liquor A is obtained;
The toughener and the Stiffening agent are added in the basic wax liquor A, is uniformly mixed, obtains wax liquor B;
The flow ability modifying agent is added in the wax liquor B, is uniformly mixed, obtains fingerprint wax.
Described by the pertroleum wax uniform melt in one of the embodiments, the step of obtaining basic wax liquor A, includes:
By the pertroleum wax at 100 DEG C~110 DEG C uniform melt, obtain basic wax liquor A;
It is described that the toughener and the Stiffening agent are added in the basic wax liquor A, it is uniformly mixed, obtains wax liquor B
The step of include: that the toughener and the Stiffening agent are added in the basic wax liquor A, controlled at 100 DEG C~110
DEG C, 0.5h~1h is stirred with the mixing speed of 450r/min~800r/min, obtains wax liquor B;
It is described that the flow ability modifying agent is added in the wax liquor B, it is uniformly mixed, the step of obtaining fingerprint wax includes:
The flow ability modifying agent is added in the wax liquor B, to adjust kinematic viscosity of the wax liquor B at 80 DEG C as 5mm2/ s~
15mm2/ s continues to stir 0.5h~1h at 100 DEG C~110 DEG C, is cooled to room temperature, obtains fingerprint wax.
In one of the embodiments, the fingerprint wax prepare raw material further include mass percentage be 0.1%~
0.5% stabilizer, the step that the toughener and the Stiffening agent are added in the basic wax liquor A include: by
The toughener, the Stiffening agent and the stabilizer are added in the basic wax liquor A.
In one of the embodiments, the fingerprint wax prepare raw material further include mass percentage be 0.2% or less
Toner, the step packet toughener, the Stiffening agent and the stabilizer being added in the basic wax liquor A
It includes: the toughener, the Stiffening agent, the stabilizer and the toner is added in the basic wax liquor A.
The fingerprint wax that the preparation method of above-mentioned fingerprint wax or above-mentioned fingerprint wax is prepared answering in production wax hand product
With.
Specific embodiment
To facilitate the understanding of the present invention, a more comprehensive description of the invention is given in the following sections with reference to the relevant attached drawings.In attached drawing
Give preferred embodiment of the invention.But the invention can be realized in many different forms, however it is not limited to herein
Described embodiment.On the contrary, purpose of providing these embodiments is keeps the understanding to the disclosure more saturating
It is thorough comprehensive.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
The fingerprint wax of one embodiment, according to mass percentage meter, the fingerprint wax prepare raw material include: 60%~
85% pertroleum wax, 1%~15% flow ability modifying agent, 1%~10% toughener and 8%~20% Stiffening agent.
Wherein, pertroleum wax is selected from fully refined paraffin wax of the fusing point lower than 55 DEG C, semi-refined paraffin wax of the fusing point lower than 55 DEG C and melts
Point is lower than 80 DEG C of at least one of microwax.Specifically, fully refined paraffin wax of the fusing point lower than 55 DEG C is selected from 52# full refining stone
At least one of wax and 54# fully refined paraffin wax, semi-refined paraffin wax of the fusing point lower than 55 DEG C are selected from 52# semi-refined paraffin wax and 54#
At least one of semi-refined paraffin wax, microwax of the fusing point lower than 80 DEG C are selected from 70# microwax, 75# microwax and W445 crystallite
At least one of wax.That is, pertroleum wax can be selected from 52# fully refined paraffin wax, 52# semi-refined paraffin wax, 54# fully refined paraffin wax, 54#
At least one of semi-refined paraffin wax, 70# microwax, 75# microwax and W445 microwax.
Flow ability modifying agent can be improved or control the rheological behaviors such as viscosity, improve the wax hand product for using the waxed work of fingerprint
Surface flatness.Specifically, flow ability modifying agent is selected from C5 hydrogenated petroleum resin, terpene resin, glycerin monostearate, adjacent benzene
At least one of dioctyl phthalate dinonyl, diisooctyl phthalate, tributyl citrate and epoxidized soybean oil.
Toughener can reduce the brittleness of fingerprint wax, increase the toughness of fingerprint wax, improve bearing strength.Specifically, toughening
Agent is selected from oligomer, amorphous state alpha olefin copolymer, ethylene-vinyl acetate copolymer, polyisobutene, styrene-ethylene-fourth
Alkene-styrene block copolymer, styrene-isoprene-styrene block copolymer and s-B-S are embedding
At least one of section copolymer.Wherein, oligomer can be random shape low molecular weight polyethylene, molecular weight be 500~
5000。
Stiffening agent can effectively increase the tensile strength and hardness of fingerprint wax, improve the bending resistance of fingerprint wax.Stiffening agent
Selected from least one of stearic acid, Fischer-Tropsch wax, river wax, polyethylene wax, polypropylene wax and low-molecular-weight polystyrene, low molecule
The relative molecular weight for measuring polystyrene is 2000~4000.Wherein, river wax can be natural river wax, or synthesis river wax.
In some embodiments, the raw material for preparing of fingerprint wax further includes the stabilization that mass percentage is 0.1%~0.5%
Agent, stabilizer can increase the stability of fingerprint wax, prevent it from decomposing, aging.Specifically, stabilizer is selected from butylhydroxy fennel
Ether, dibutyl hydroxy toluene, tert-butyl hydroquinone, N- isopropyl-N '-diphenyl-para-phenylene diamine and DBPC 2,6 ditertiary butyl p cresol
At least one of.
In some embodiments, fingerprint wax prepare raw material further include mass percentage be 0.2% toner below,
The mass percentage for the toner being added is no more than 0.2%, and toner can be color masterbatch, color or toner.Toning is added
Agent can make fingerprint wax have certain color, and appearance is vivider.Specifically the tune of different colours can be selected according to actual needs
Toner, to obtain the fingerprint wax of various colors.
In above-mentioned fingerprint wax, toughener, Stiffening agent and flow ability modifying agent joined, and be equipped with certain proportion, it is therein
The toughness and rigidity of toughener and the adjustable fingerprint wax of Stiffening agent, so that the fingerprint wax rigidity-toughness balanced prepared, to slip out of the hand
Fingerprint wax will not be destroyed when pattern wax shell;Flow ability modifying agent can be such that fingerprint wax has again while with certain caking property centainly
Mobility does not occur the phenomenon that streamline wire drawing to keep fingerprint was moulding smooth.
Refering to fig. 1, the preparation method of the fingerprint wax of an embodiment includes the following steps:
S110, based on mass percentage, weigh the raw material for preparing of fingerprint wax, the raw material for preparing of fingerprint wax includes: 60%
~85% pertroleum wax, 1%~15% flow ability modifying agent, 1%~10% toughener and 8%~20% Stiffening agent.
Wherein, pertroleum wax is selected from fully refined paraffin wax of the fusing point lower than 55 DEG C, semi-refined paraffin wax of the fusing point lower than 55 DEG C and melts
Point is lower than 80 DEG C of at least one of microwax.Specifically, fully refined paraffin wax of the fusing point lower than 55 DEG C is selected from 52# full refining stone
At least one of wax and 54# fully refined paraffin wax, semi-refined paraffin wax of the fusing point lower than 55 DEG C are selected from 52# semi-refined paraffin wax and 54#
At least one of semi-refined paraffin wax, microwax of the fusing point lower than 80 DEG C are selected from 70# microwax, 75# microwax and W445 crystallite
At least one of wax.That is, pertroleum wax can be selected from 52# fully refined paraffin wax, 52# semi-refined paraffin wax, 54# fully refined paraffin wax, 54#
At least one of semi-refined paraffin wax, 70# microwax, 75# microwax and W445 microwax.
Flow ability modifying agent can be improved or control the rheological behaviors such as viscosity, improve the wax hand product for using the waxed work of fingerprint
Surface flatness.Specifically, flow ability modifying agent is selected from C5 hydrogenated petroleum resin, terpene resin, glycerin monostearate, adjacent benzene
At least one of dioctyl phthalate dinonyl, diisooctyl phthalate, tributyl citrate and epoxidized soybean oil.
Toughener can reduce the brittleness of fingerprint wax, increase the toughness of fingerprint wax, improve bearing strength.Specifically, toughening
Agent is selected from oligomer, amorphous state alpha olefin copolymer, vinyl chloride-vinyl acetate copolymer, polyisobutene, styrene-ethylene-fourth
Alkene-styrene block copolymer, styrene-isoprene-styrene block copolymer and s-B-S are embedding
At least one of section copolymer.Wherein, oligomer can be random shape low molecular weight polyethylene, molecular weight be 500~
5000。
Stiffening agent (being called hardness regulator) can effectively increase the tensile strength and hardness of fingerprint wax, improve fingerprint wax
Bending resistance.Specifically, Stiffening agent is selected from stearic acid, Fischer-Tropsch wax, river wax, polyethylene wax, polypropylene wax and low molecule polyphenyl second
At least one of alkene.Wherein, river wax can be natural river wax, or synthesis river wax.
S120, by pertroleum wax uniform melt, obtain basic wax liquor A.
Specifically, step S120 include: by pertroleum wax at 100 DEG C~110 DEG C uniform melt, obtain basic wax liquor A.More
For that specifically, pertroleum wax can be put into reaction kettle, the temperature of reaction kettle is adjusted at 100 DEG C~110 DEG C, keeps pertroleum wax uniform
Fusing, obtains basic wax liquor A.
S130, toughener and Stiffening agent are added in basic wax liquor A, are uniformly mixed, obtain wax liquor B.
Specifically, step S130 includes: that toughener and Stiffening agent are added in basic wax liquor A, controlled at 100 DEG C
~110 DEG C, 0.5h~1h is stirred with the mixing speed of 450r/min~800r/min, obtains wax liquor B.
S140, flow ability modifying agent is added in wax liquor B, is uniformly mixed, obtains fingerprint wax.
Specifically, step S140 includes: that flow ability modifying agent is added in wax liquor B, to adjust fortune of the wax liquor B at 80 DEG C
Kinetic viscosity is 5mm2/ s~15mm2/ s continues to stir 0.5h~1h at 100 DEG C~110 DEG C, is cooled to room temperature, obtains fingerprint
Wax.
In one of the embodiments, fingerprint wax prepare raw material further include mass percentage be 0.1%~0.5%
The step that toughener and Stiffening agent are added in basic wax liquor A is included: then in step s 130 by toughener, increasing by stabilizer
Rigid agent and stabilizer are added in basic wax liquor A.
Further, fingerprint wax prepare raw material further include mass percentage be 0.2% toner below, then will increase
The tough dose of step being added in basic wax liquor A with Stiffening agent includes: to be added to toughener, Stiffening agent, stabilizer and toner
In basic wax liquor A.
The fingerprint wax that the preparation method of above-mentioned fingerprint wax and above-mentioned fingerprint wax is prepared can be applied to be produced in production wax hand
In product.
The following are specific examples part, material involved in following embodiment can be obtained from commercial channel.
Example 1
(1) based on mass percentage, 85% 52# fully refined paraffin wax, 5.6% amorphous state alpha-olefin copolymer are weighed
Object, 8% stearic acid, 0.1% dibutyl hydroxy toluene, 0.1% toner and 1.2% C5 hydrogenated petroleum resin;
(2) 52# fully refined paraffin wax is added in reaction kettle, the operating temperature for adjusting reaction kettle is 100 DEG C, keeps 52# complete
Fully refined paraffin wax uniform melt obtains basic wax liquor A;
(3) amorphous state alpha olefin copolymer, stearic acid, dibutyl hydroxy toluene and toner are added in basic wax liquor A,
Controlled at 100 DEG C, 1h is stirred with the mixing speed of 450r/min, obtains wax liquor B;
(4) C5 hydrogenated petroleum resin is added in wax liquor B, adjusting kinematic viscosity of the wax liquor at 80 DEG C is 5.2mm2/
S continues to stir 1h at 100 DEG C, is cooled to room temperature, obtains fingerprint wax.
Example 2
(1) based on mass percentage, 54.7% 52# fully refined paraffin wax, 5.3% W445 microwax, 9.8% are weighed
Oligomer, 12.8% stearic acid, 2.1% low-molecular-weight polystyrene, 0.5% tert-butyl hydroquinone, 0.2%
Toner, 9.8% terpene resin and 4.8% diisononyl phthalate;
(2) 52# fully refined paraffin wax and W445 microwax are added in reaction kettle, the operating temperature for adjusting reaction kettle is
100 DEG C, make each wax uniform melt, obtains basic wax liquor A;
(3) oligomer, stearic acid, low molecular weight polycaprolactone styrene, tert-butyl hydroquinone and toner are added to basic wax liquor A
In, controlled at 110 DEG C, 1h is stirred with the mixing speed of 550r/min, obtains wax liquor B;
(4) terpene resin and diisononyl phthalate are added in wax liquor B, adjust movement of the wax liquor at 80 DEG C
Viscosity is 14.7mm2/ s (80 DEG C) continues to stir 1h at 110 DEG C, and cooling obtains fingerprint wax.
Example 3
(1) based on mass percentage, 62.3% 52# semi-refined paraffin wax, 5.7% 70# microwax, 1.6% are weighed
Ethylene-vinyl acetate copolymer, 15.1% stearic acid, 4.5% polyethylene wax, 0.2% 2,6- di-t-butyl to first
Phenol, 0.2% toner, 5.7% C5 hydrogenated petroleum resin and 4.7% tributyl citrate;
(2) 52# semi-refined paraffin wax and 70# microwax are added in reaction kettle, the operating temperature for adjusting reaction kettle is 110
DEG C, make each wax uniform melt, obtains basic wax liquor A;
(3) ethylene-vinyl acetate copolymer, stearic acid, polyethylene wax, DBPC 2,6 ditertiary butyl p cresol and toner are added
Into basic wax liquor A, controlled at 110 DEG C, 0.5h is stirred with the mixing speed of 800r/min, obtains wax liquor B;
(4) C5 hydrogenated petroleum resin and tributyl citrate are added in wax liquor B, adjust movement of the wax liquor at 80 DEG C
Viscosity is 7.8mm2/ s (80 DEG C) continues to stir 0.5h at 110 DEG C, is cooled to room temperature, obtains fingerprint wax.
Example 4
(1) based on mass percentage, 78% W445 microwax, 4.2% styrene-ethylene-butadiene-benzene second are weighed
Alkene block copolymer, 3.6% Fischer-Tropsch wax, 5.6% synthesis river wax, 0.1% N- isopropyl-N '-diphenyl-para-phenylene diamine,
0.1% toner, 6.2% C5 hydrogenated petroleum resin and 2.2% epoxidized soybean oil;
(2) W445 microwax is added in reaction kettle, the operating temperature for adjusting reaction kettle is 110 DEG C, makes W445 crystallite
Wax uniform melt obtains basic wax liquor A;
(3) by styrene-ethylene-butylene-styrene block copolymer, Fischer-Tropsch wax, synthesis river wax, N- isopropyl-N '-benzene
Base p-phenylenediamine and toner are added in basic wax liquor A, controlled at 110 DEG C, are stirred with the mixing speed of 700r/min
0.5h obtains wax liquor B;
(4) C5 hydrogenated petroleum resin and epoxidized soybean oil are added in wax liquor B, it is viscous adjusts movement of the wax liquor at 80 DEG C
Degree is 10.9mm2/ s continues to stir 0.5h at 100 DEG C, is cooled to room temperature, obtains fingerprint wax.
With commercially available a existing domestic fingerprint wax as a comparison case 1, commercially available a existing import fingerprint wax as pair
Ratio 2, the fingerprint obtained respectively using 1~embodiment of above-described embodiment 4 is waxed to make wax hand product, respectively using comparative example 1~
The fingerprint of comparative example 2 is waxed to make wax hand product, then tests the performance of fingerprint wax and the performance of prepared wax hand product, tool
Body test result is as shown in table 1.
The performance of test includes: the kinematic viscosity at the fusing point and 80 DEG C of fingerprint wax;And needle of the wax hand product at 25 DEG C
In-degree, smoothness, toughness and whether be easy demoulding.Examination criteria when test performance is as follows:
Fusing point: the measurement cooling curve method of GB/T 2539-2008 pertroleum wax fusing point;
Kinematic viscosity: GB/T 265-1998 oil product kinematic viscosity measuring method and dynamic viscosity calculating method;
Needle penetration: GB/T 4985-2010 pertroleum wax penetration test method.
Wax hand product the production method is as follows:
(1) in being put into of the amount of taking fully fingerprint wax wax machine, it is liquid that raising temperature is fused into fingerprint wax sufficiently, then normal
Liquid fingerprint wax is allowed slowly to cool to 62 DEG C or less and constant temperature under temperature stirring;
(2) it is being evenly coated with one layer of mould oil on hand;
(3) handle is immersed in 5 DEG C~10 DEG C ice water and is taken out rapidly, wipes droplet on hand;
(4) handle immerses in the wax liquor of watery fusion, and hand is made uniformly to coat coating of wax film;
(5) (3), (4) step 2 time~3 time are repeated, are already coated with 3 layers~4 layers uniform and smooth fingerprint on hand in this way
Wax;
(6) carefully deviate from wax shell, impregnate hardening after removing in 5 DEG C~10 DEG C of ice water again, observe the light of wax hand product
Slippery, needle penetration, flexibility, if be easy demoulding and whether have crack etc..Wherein, the smaller expression hardness of needle penetration is higher.
Table 1.
By upper table 1 it is found that compared with the fingerprint wax that comparative example 1 and comparative example 2 obtain, 1~embodiment of embodiment 4 is prepared into
The fingerprint wax fusing point and kinematic viscosity arrived is low, wax hand product light made by the fingerprint wax hand obtained with 1~embodiment of embodiment 4
It slides, has higher toughness, is easy demoulding, show that the fingerprint wax that 1~embodiment of embodiment 4 obtains has outstanding performance.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.