CN109434989A - A kind of aluminium clad wood doors and windows fireproof wood and preparation method thereof - Google Patents
A kind of aluminium clad wood doors and windows fireproof wood and preparation method thereof Download PDFInfo
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- CN109434989A CN109434989A CN201811442862.4A CN201811442862A CN109434989A CN 109434989 A CN109434989 A CN 109434989A CN 201811442862 A CN201811442862 A CN 201811442862A CN 109434989 A CN109434989 A CN 109434989A
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- wood
- timber
- windows
- aluminium clad
- fireproof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/0207—Pretreatment of wood before impregnation
- B27K3/0214—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/005—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process employing compositions comprising microparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/025—Controlling the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/003—Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
- B27K5/0055—Radio-waves, e.g. microwaves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/04—Combined bleaching or impregnating and drying of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/70—Hydrophobation treatment
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a kind of aluminium clad wood doors and windows fireproof woods and preparation method thereof, fireproof wood is made of the functional liquid filled in timber and timber hole, functional liquid includes sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite, obtains aluminium clad wood doors and windows fireproof wood using vacuum impregnation technique and microwave drying process.Aluminium clad wood doors and windows of the invention fireproof wood has the excellent properties such as fire protection flame retarding, insulation, sound insulation, dimensionally stable, anti-corrosion, service life length, coats film without surface, retains the original texture of timber, both artistic and practical, market prospects are huge.
Description
Technical field
The present invention relates to a kind of aluminium clad wood doors and windows fireproof woods and preparation method thereof, belong to composite material technology of preparing neck
Domain.
Background technique
Timber has the characteristics that low heat conductivity, high sound-proofing, easy processing as a kind of reproducible natural resources;Simultaneously
It is inflammable due to the natural quality of timber, and then mechanical property is lost, if dealing with improperly, it may appear that phenomena such as being bent, distorting, from
And influence the normal use of door and window.When wood section moisture content is higher than 20%, fungi is easy to be bred in vivo at it, so as to cause
There is phenomena such as mildew, rot in timber;The effectively any absorption and loss of control Water In Wood, is to ensure that aluminium clad wood doors and windows are used
The key factor of wood section quality.
Timber pickling is common Wooden modifying technique, can assign timber more excellent properties;However, current timber
That there are pickling efficiencies is low for impregnation technology, into timber pore dipping liquid measure it is few, maceration extract is not fire-retardant the problems such as, influence timber
Safe handling.Based on this, the present invention is proposed.
Summary of the invention
The first purpose of this invention is to be to provide aluminium clad wood doors and windows fireproof wood, has fire protection flame retarding, thermal insulation separation
The excellent properties such as heat, sound insulation, dimensionally stable, anti-corrosion, service life length, coat film without surface, retain the original texture of timber, beautiful
Practical, market prospects are huge.
Second object of the present invention is to be to provide the preparation method of aluminium clad wood doors and windows fireproof wood, and the present invention utilizes
Sodium methyl silicate is as hydrophobic crosslinking agent, and using hydrophobic tobermorite as heat-insulating flame-retardant filler, phosphoric acid is gel catalyst, methyl
Cellulose is thickener and surfactant, prepares Wooden modifying functional liquid, and pass through vacuum impregnation technique and microwave drying work
Skill compounds timber with modified function liquid.It is coagulated the study found that colloidal sol-occurs under the catalytic action of phosphoric acid for (1) sodium methyl silicate
Glue reaction, can form Si-O-Si key and tridimensional network, hydrophobic performance and fire protecting performance are excellent;(2) hydrophobic Tuo Beimo comes
Stone has um porous structure, still keeps um porous structure to be not filled in sodium methyl silicate water-based system, has heat-insulated
And fire retardation;(3) methylcellulose not only has hydrophilic radical, but also has hydrophobic grouping, is conducive to hydrophobic tobermorite and exists
It is evenly dispersed in sodium methyl silicate water-based system, and the hydrophobic main chain of methylcellulose and surrounding water molecules are formed by hydrogen bond
It closes, improves the fluid volume of polymer itself, reduce the movable space of Particle free makes to improve system viscosity
When being separated with functional liquid after timber adsorption function liquid, greatly reduce wood internal functional liquid and be lost before gel.
Third object of the present invention is to provide the applications of the fireproof wood, are used for aluminium clad wood doors and windows, show
Excellent comprehensive performance.
In order to achieve the above technical purposes, the present invention provides a kind of aluminium clad wood doors and windows fireproof wood, by timber and timber
The functional liquid filled in hole is constituted;The functional liquid includes sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic Tuo Beimo
Carry out stone.
Further, the timber is one of pine, birch, oak.
Further, the hydrophobic tobermorite can be substituted by hydrophobic fumed silica.
It in this way, tobermorite and fumed silica all have um porous structure, and is inorganic incombustible material, into
And there is heat-insulating flame-retardant performance;Hydrophobic property is not filled it in water-based system Hole, guarantees excellent heat-proof quality.
A kind of preparation method of aluminium clad wood doors and windows fireproof wood of the invention, comprising the following steps:
(1) prepared by functional liquid, and sodium methyl silicate, water, phosphoric acid are mixed, 3h is stirred, and methylcellulose is added, hydrophobic Tuo Beimo comes
Stone continues to stir 0.5h, for use, the wherein mass ratio of sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite
For 20:12 ~ 15:0.001 ~ 0.005:0.1 ~ 0.15:5 ~ 8;
(2) timber is dried in microwave device 0.5 ~ 1h, is cooled to room temperature, is placed in vacuum equipment by timber pre-treatment
It vacuumizes, to vacustat, vacuum degree is 10 ~ 100Pa;
(3) vacuum impregnation mixes the functional liquid of step (1) with the timber of step (2) in vacuum equipment, will be more after 0.2h
Remaining functional liquid and wood seperation, standby function lyogel restore normal pressure;
(4) sodium is removed, the timber of step (3) is impregnated in water, solvent displacement, each 12h is replaced 3 times;
(5) timber of step (4) is placed in microwave device dry 1 ~ 2h by microwave drying, obtains aluminium clad wood doors and windows fire prevention wood
Material.
Further, in the step (4), weak-acid cation-exchange resin is added.
In this way, weak-acid cation-exchange resin can significantly improve the removal rate of Na+, reduce solvent displacement number with
Time reduces the generation of industrial wastewater.
Fireproof wood produced by the present invention can be used for aluminium clad wood doors and windows, excellent combination property.
Beneficial effects of the present invention: (1) using the sodium methyl silicate of included hydrophobic grouping as crosslinking agent, have hydrophobic
Property, rigidity, anti-flammability, wood cell wall inflated by sodium methyl silicate system, and cell is filled by it, effectively control Water In Wood
It is any absorption and loss, improve the dimensional stability, service life anti-flammability and mechanical property of timber;(2) tobermorite is by work
Industry waste material flyash is made by hydro-thermal reaction, and waste utilization and emission reduction is environmentally protective;(3) on the one hand methylcellulose is used as surface living
Property agent improve the compatibility of hydrophobic tobermorite and water-based system, be on the other hand used as thickener, avoid functional liquid in gel
It is preceding to be flowed out from timber;(4) before impregnating, microwave drying treatment is carried out to timber, most of water in timber is excluded in advance, improves function
It can the loading of liquid in wood;(5) vacuum impregnation technique can to form negative pressure in timber hole, improve functional liquid filling
The amount of timber pore;(6) microwave drying process makes wood internal and external heat drying simultaneously, with traditional heating mode phase
Than significantly improving drying efficiency, making the high efficiency of thick matter timber is filling-modified to be achieved;(7) equipment that the present invention uses is equal
For working standard equipment, it is easy to accomplish industrialized production.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, below to specific reality of the invention
The mode of applying is described in detail.In the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention.But
The invention can be embodied in many other ways as described herein, and those skilled in the art can be without prejudice to this hair
Similar improvement is done in the case where bright intension, therefore the present invention is not limited to the specific embodiments disclosed below.
A kind of embodiment of aluminium clad wood doors and windows fireproof wood of the invention, by the function of being filled in timber and timber hole
Liquid is constituted;The functional liquid includes sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite.
In the present embodiment, the timber is one of pine, birch, oak.
In the present embodiment, the hydrophobic tobermorite can be substituted by hydrophobic fumed silica.
A kind of a kind of embodiment of the preparation method of aluminium clad wood doors and windows fireproof wood of the invention, comprising the following steps:
(1) prepared by functional liquid, and sodium methyl silicate, water, phosphoric acid are mixed, 3h is stirred, and methylcellulose is added, hydrophobic Tuo Beimo comes
Stone continues to stir 0.5h, for use, the wherein mass ratio of sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite
For 20:12 ~ 15:0.001 ~ 0.005:0.1 ~ 0.15:5 ~ 8;
(2) timber is dried in microwave device 0.5 ~ 1h, is cooled to room temperature, is placed in vacuum equipment by timber pre-treatment
It vacuumizes, to vacustat, vacuum degree is 10 ~ 100Pa;
(3) vacuum impregnation mixes the functional liquid of step (1) with the timber of step (2) in vacuum equipment, will be more after 0.2h
Remaining functional liquid and wood seperation, standby function lyogel restore normal pressure;
(4) sodium is removed, the timber of step (3) is impregnated in water, solvent displacement, each 12h is replaced 3 times;
(5) timber of step (4) is placed in microwave device dry 1 ~ 2h by microwave drying, obtains aluminium clad wood doors and windows fire prevention wood
Material.
In the present embodiment, in the step (4), weak-acid cation-exchange resin is added.
Fireproof wood produced by the present invention can be used for aluminium clad wood doors and windows, excellent combination property.
It is below specific embodiment part.
Embodiment 1
Aluminium clad wood doors and windows fireproof wood is prepared using following steps:
(1) prepared by functional liquid, and sodium methyl silicate, water, phosphoric acid are mixed, 3h is stirred, and methylcellulose is added, hydrophobic Tuo Beimo comes
Stone continues to stir 0.5h, for use, the wherein mass ratio of sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite
For 20:12:0.001:0.1:5;
(2) pine is dried in microwave device 0.5h, is cooled to room temperature, is placed in vacuum equipment and vacuumizes by timber pre-treatment,
To vacustat, vacuum degree 10Pa;
(3) vacuum impregnation mixes the functional liquid of step (1) with the pine of step (2) in vacuum equipment, will be more after 0.2h
Remaining functional liquid is separated with pine, standby function lyogel, restores normal pressure;
(4) sodium is removed, the pine of step (3) is impregnated in water, solvent displacement, each 12h is replaced 3 times;
(5) timber of step (4) is placed in microwave device dry 1h, obtains aluminium clad wood doors and windows fireproof wood by microwave drying.
Fire-protection rating is A2 grades, and thermal coefficient is 0.09W/m K, and the contact angle with water is 151 °.
Embodiment 2
Aluminium clad wood doors and windows fireproof wood is prepared using following steps:
(1) prepared by functional liquid, and sodium methyl silicate, water, phosphoric acid are mixed, 3h is stirred, and methylcellulose is added, hydrophobic Tuo Beimo comes
Stone continues to stir 0.5h, for use, the wherein mass ratio of sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite
For 20:15:0.005:0.15:8;
(2) oak is dried in microwave device 1h, is cooled to room temperature, is placed in vacuum equipment and vacuumizes by timber pre-treatment, to
Vacustat, vacuum degree 100Pa;
(3) vacuum impregnation mixes the functional liquid of step (1) with the oak of step (2) in vacuum equipment, will be more after 0.2h
Remaining functional liquid is separated with oak, standby function lyogel, restores normal pressure;
(4) sodium is removed, the oak of step (3) is impregnated in water, solvent displacement, each 12h is replaced 3 times;
(5) oak of step (4) is placed in microwave device dry 2h, obtains aluminium clad wood doors and windows fireproof wood by microwave drying.
Fire-protection rating is A2 grades, and thermal coefficient is 0.08W/m K, and the contact angle with water is 149 °.
Embodiment 3
Aluminium clad wood doors and windows fireproof wood is prepared using following steps:
(1) prepared by functional liquid, and sodium methyl silicate, water, phosphoric acid are mixed, 3h is stirred, methylcellulose, hydrophobic gas phase dioxy is added
SiClx continues to stir 0.5h, for use, the wherein matter of sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic fumed silica
Amount is than being 20:13:0.004:0.14:6;
(2) birch is dried in microwave device 0.8h, is cooled to room temperature, is placed in vacuum equipment and vacuumizes by timber pre-treatment,
To vacustat, vacuum degree 50Pa;
(3) vacuum impregnation mixes the functional liquid of step (1) with the birch of step (2) in vacuum equipment, will be more after 0.2h
Remaining functional liquid is separated with birch, standby function lyogel, restores normal pressure;
(4) sodium is removed, the birch of step (3) is impregnated in water, solvent displacement, each 12h is replaced 3 times;
(5) birch of step (4) is placed in microwave device dry 1.5h by microwave drying, obtains aluminium clad wood doors and windows fire prevention wood
Material.Fire-protection rating is A2 grades, and thermal coefficient is 0.09W/m K, and the contact angle with water is 145 °.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (6)
1. a kind of aluminium clad wood doors and windows fireproof wood, which is characterized in that be made of the functional liquid filled in timber and timber hole;
The functional liquid includes sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite.
2. a kind of aluminium clad wood doors and windows fireproof wood according to claim 1, which is characterized in that the timber is pine, birch
One of wood, oak.
3. a kind of aluminium clad wood doors and windows fireproof wood according to claim 1, which is characterized in that the hydrophobic tobermorite
It is substituted by hydrophobic fumed silica.
4. a kind of preparation method of aluminium clad wood doors and windows fireproof wood, which comprises the following steps:
(1) prepared by functional liquid, and sodium methyl silicate, water, phosphoric acid are mixed, 3h is stirred, and methylcellulose is added, hydrophobic Tuo Beimo comes
Stone continues to stir 0.5h, for use, the wherein mass ratio of sodium methyl silicate, water, phosphoric acid, methylcellulose, hydrophobic tobermorite
For 20:12 ~ 15:0.001 ~ 0.005:0.1 ~ 0.15:5 ~ 8;
(2) timber is dried in microwave device 0.5 ~ 1h, is cooled to room temperature, is placed in vacuum equipment by timber pre-treatment
It vacuumizes, to vacustat, vacuum degree is 10 ~ 100Pa;
(3) vacuum impregnation mixes the functional liquid of step (1) with the timber of step (2) in vacuum equipment, will be more after 0.2h
Remaining functional liquid and wood seperation, standby function lyogel restore normal pressure;
(4) sodium is removed, the timber of step (3) is impregnated in water, solvent displacement, each 12h is replaced 3 times;
(5) timber of step (4) is placed in microwave device dry 1 ~ 2h by microwave drying, obtains aluminium clad wood doors and windows fire prevention wood
Material.
5. a kind of preparation method of aluminium clad wood doors and windows fireproof wood according to claim 4, which is characterized in that the step
(4) in, weak-acid cation-exchange resin is added.
6. a kind of aluminium clad wood doors and windows fireproof wood of claim 1 ~ 5, which is characterized in that as aluminium clad wood doors and windows material.
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CN201811442862.4A CN109434989B (en) | 2018-11-29 | 2018-11-29 | Fireproof wood for aluminum-clad wood doors and windows and preparation method thereof |
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CN201811442862.4A CN109434989B (en) | 2018-11-29 | 2018-11-29 | Fireproof wood for aluminum-clad wood doors and windows and preparation method thereof |
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CN109434989B CN109434989B (en) | 2020-12-11 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5021390A (en) * | 1986-09-12 | 1991-06-04 | Hatton John H | Liquid hydrocarbon absorbent composition and method |
CN101851471A (en) * | 2009-04-03 | 2010-10-06 | 毛仁军 | Fireproof bonding glue and production process thereof |
CN104647500A (en) * | 2013-11-19 | 2015-05-27 | 黄培伟 | Impregnation liquid used for processing of rubber-wood heated floor |
CN106671237A (en) * | 2016-12-09 | 2017-05-17 | 广西北海浩邦新能源科技有限公司 | Wood carbonizing treatment technology |
CN107630646A (en) * | 2017-09-30 | 2018-01-26 | 浙江盼家门业有限公司 | One kind fire prevention solid wood composite door |
-
2018
- 2018-11-29 CN CN201811442862.4A patent/CN109434989B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5021390A (en) * | 1986-09-12 | 1991-06-04 | Hatton John H | Liquid hydrocarbon absorbent composition and method |
CN101851471A (en) * | 2009-04-03 | 2010-10-06 | 毛仁军 | Fireproof bonding glue and production process thereof |
CN104647500A (en) * | 2013-11-19 | 2015-05-27 | 黄培伟 | Impregnation liquid used for processing of rubber-wood heated floor |
CN106671237A (en) * | 2016-12-09 | 2017-05-17 | 广西北海浩邦新能源科技有限公司 | Wood carbonizing treatment technology |
CN107630646A (en) * | 2017-09-30 | 2018-01-26 | 浙江盼家门业有限公司 | One kind fire prevention solid wood composite door |
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