CN109425428A - Wearable UV exposure sensor - Google Patents
Wearable UV exposure sensor Download PDFInfo
- Publication number
- CN109425428A CN109425428A CN201711347280.3A CN201711347280A CN109425428A CN 109425428 A CN109425428 A CN 109425428A CN 201711347280 A CN201711347280 A CN 201711347280A CN 109425428 A CN109425428 A CN 109425428A
- Authority
- CN
- China
- Prior art keywords
- adhesive
- sensor
- wearable
- radiation
- photochromic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 claims abstract description 154
- 230000001070 adhesive effect Effects 0.000 claims abstract description 151
- 230000002285 radioactive effect Effects 0.000 claims abstract description 102
- 239000000758 substrate Substances 0.000 claims abstract description 69
- 238000000034 method Methods 0.000 claims abstract description 49
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 230000005855 radiation Effects 0.000 claims description 128
- 239000010410 layer Substances 0.000 claims description 65
- -1 polyethylene Polymers 0.000 claims description 52
- 230000004044 response Effects 0.000 claims description 51
- 239000000975 dye Substances 0.000 claims description 34
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 19
- 239000004800 polyvinyl chloride Substances 0.000 claims description 19
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 16
- 229920001296 polysiloxane Polymers 0.000 claims description 16
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 16
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 16
- 239000004831 Hot glue Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229920001684 low density polyethylene Polymers 0.000 claims description 13
- 239000004702 low-density polyethylene Substances 0.000 claims description 13
- 229920001903 high density polyethylene Polymers 0.000 claims description 12
- 239000004700 high-density polyethylene Substances 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 10
- 239000004677 Nylon Substances 0.000 claims description 9
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 9
- 239000000806 elastomer Substances 0.000 claims description 9
- 229920001778 nylon Polymers 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- SEIWXKIVZRUELP-UHFFFAOYSA-N 2,3-dihydro-1h-indole;2h-oxazine Chemical class N1OC=CC=C1.C1=CC=C2NCCC2=C1 SEIWXKIVZRUELP-UHFFFAOYSA-N 0.000 claims description 8
- 235000019890 Amylum Nutrition 0.000 claims description 8
- 239000004821 Contact adhesive Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 229920002472 Starch Polymers 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 150000001988 diarylethenes Chemical class 0.000 claims description 8
- 229920006332 epoxy adhesive Polymers 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- 239000004793 Polystyrene Substances 0.000 claims description 7
- 229920002396 Polyurea Polymers 0.000 claims description 7
- 239000004830 Super Glue Substances 0.000 claims description 7
- FGBJXOREULPLGL-UHFFFAOYSA-N ethyl cyanoacrylate Chemical compound CCOC(=O)C(=C)C#N FGBJXOREULPLGL-UHFFFAOYSA-N 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 7
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 7
- 229920002223 polystyrene Polymers 0.000 claims description 7
- 239000004834 spray adhesive Substances 0.000 claims description 7
- 210000000707 wrist Anatomy 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- 239000005018 casein Substances 0.000 claims description 5
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 5
- 235000021240 caseins Nutrition 0.000 claims description 5
- 239000012790 adhesive layer Substances 0.000 claims description 4
- 239000007767 bonding agent Substances 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims 4
- 239000004815 dispersion polymer Substances 0.000 claims 3
- 229920001225 polyester resin Polymers 0.000 claims 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 239000012943 hotmelt Substances 0.000 claims 1
- 230000005670 electromagnetic radiation Effects 0.000 abstract description 11
- 210000003491 skin Anatomy 0.000 description 77
- 230000008859 change Effects 0.000 description 17
- 230000000694 effects Effects 0.000 description 10
- 230000008707 rearrangement Effects 0.000 description 8
- 241001141101 Nitrospirales Species 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 230000006378 damage Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 230000000475 sunscreen effect Effects 0.000 description 4
- 239000000516 sunscreening agent Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003605 opacifier Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 229920000307 polymer substrate Polymers 0.000 description 3
- 239000003223 protective agent Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- JKTCBAGSMQIFNL-UHFFFAOYSA-N 2,3-dihydrofuran Chemical compound C1CC=CO1 JKTCBAGSMQIFNL-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 210000002615 epidermis Anatomy 0.000 description 2
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 150000002240 furans Chemical class 0.000 description 2
- 150000002475 indoles Chemical class 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000037072 sun protection Effects 0.000 description 2
- SCMDRBZEIUMBBQ-UHFFFAOYSA-N (1e)-1-[(8-amino-3,7-dimethyl-10-phenylphenazin-10-ium-2-yl)hydrazinylidene]naphthalen-2-one;chloride Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N\N=C\3C4=CC=CC=C4C=CC/3=O)C=C2[N+]=1C1=CC=CC=C1 SCMDRBZEIUMBBQ-UHFFFAOYSA-N 0.000 description 1
- UOUUKBKHBOFSJV-UHFFFAOYSA-N 1,2-dimethylpyrene Chemical compound C1=CC=C2C=CC3=C(C)C(C)=CC4=CC=C1C2=C43 UOUUKBKHBOFSJV-UHFFFAOYSA-N 0.000 description 1
- CUJPFPXNDSIBPG-UHFFFAOYSA-N 1,3-propanediyl Chemical group [CH2]C[CH2] CUJPFPXNDSIBPG-UHFFFAOYSA-N 0.000 description 1
- UWNYADTZRSHNGM-UHFFFAOYSA-N 2,2-diphenylbenzo[h]chromene Chemical compound O1C(C2=CC=CC=C2C=C2)=C2C=CC1(C=1C=CC=CC=1)C1=CC=CC=C1 UWNYADTZRSHNGM-UHFFFAOYSA-N 0.000 description 1
- RZPFVRFSYMUDJO-UHFFFAOYSA-N 2h-naphthalen-1-one Chemical compound C1=CC=C2C(=O)CC=CC2=C1 RZPFVRFSYMUDJO-UHFFFAOYSA-N 0.000 description 1
- IWIKLVJXZWMRLZ-UHFFFAOYSA-N 4,5-diphenyl-2h-imidazole Chemical class N=1CN=C(C=2C=CC=CC=2)C=1C1=CC=CC=C1 IWIKLVJXZWMRLZ-UHFFFAOYSA-N 0.000 description 1
- TUZVQTLSJYAYJK-UHFFFAOYSA-N 5-(2-chlorophenyl)-2,4-diphenyl-1h-imidazole Chemical class ClC1=CC=CC=C1C1=C(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 TUZVQTLSJYAYJK-UHFFFAOYSA-N 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- QSAMQSXFHVHODR-UHFFFAOYSA-N Cl.C=CC#N Chemical compound Cl.C=CC#N QSAMQSXFHVHODR-UHFFFAOYSA-N 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- HDWLUGYOLUHEMN-UHFFFAOYSA-N Dinobuton Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)OC(C)C HDWLUGYOLUHEMN-UHFFFAOYSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 244000297179 Syringa vulgaris Species 0.000 description 1
- 235000004338 Syringa vulgaris Nutrition 0.000 description 1
- 241000425573 Talanes Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- QZHPTGXQGDFGEN-UHFFFAOYSA-N chromene Chemical compound C1=CC=C2C=C[CH]OC2=C1 QZHPTGXQGDFGEN-UHFFFAOYSA-N 0.000 description 1
- 230000001149 cognitive effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical group O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000000215 hyperchromic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- 231100000707 mutagenic chemical Toxicity 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 150000004893 oxazines Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000004880 oxines Chemical class 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000000411 transmission spectrum Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/48—Photometry, e.g. photographic exposure meter using chemical effects
- G01J1/50—Photometry, e.g. photographic exposure meter using chemical effects using change in colour of an indicator, e.g. actinometer
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Photometry And Measurement Of Optical Pulse Characteristics (AREA)
Abstract
According to some embodiments, this disclosure relates to the wearable UV sensor of the electromagnetic radiation for detecting doses, the wearable UV sensor includes: the polymeric substrates that (a) includes at least one polymer and at least one UV radioactive exposure indicator；(b) adhesive generates photochromic variation wherein the wearable UV sensor is exposed to the electromagnetic radiation of the dosage in the polymeric substrates.Present disclosure also relates to the methods for the size for determining the UV radioactive exposure of doses, which comprises providing includes polymeric substrates, UV radioactive exposure indicator and the optionally wearable UV sensor of adhesive phase；The wearable UV sensor is exposed to the electromagnetic radiation of at least dose to form the wearable UV sensor of postdose, wherein the exposure leads to photochromic variation by the wearable UV sensor；And determine the size of at least electromagnetic radiation of dose.
Description
Disclosed field
In some embodiments, this disclosure relates to the wearable items sensitive to ultraviolet radiation, the wearable object
The wearable UV exposure indicator that product are exposed to ultraviolet radiation including, for example, being used to indicate body surface.
Disclosed background
For being exposed to the public cognitive of the enhancing of the relevant cosmetics of ultraviolet (UV) radiation and medicine harm to application on human skin
Facilitate UV absorb or scattering compound (opacifier) (independently and as cosmetic product ingredient) become increasingly popular.So
And opacifier product prevents having for the light injury of the skin of the absorption from UV-B (280-290nm) and UV-A (320-400nm)
Effect property may be interfered by the compliance of the erosion of shading oxidant layer, vicious sun protection factor (SPF) label characteristics or wearer.
It summarizes
Therefore, it has had already appeared to the improved wearable items sensitive to ultraviolet radiation and for determining that is applied prevents
Shine the demand of the method for the validity of product.
One kind is for detecting the wearable UV sensor of UV radiation (for example, the UV of threshold dose is radiated), the wearable UV
Sensor includes: first layer, and the first layer includes polymeric substrates, and the polymeric substrates include UV radioactive exposure instruction
Agent；And the second layer, the second layer include adhesive；Wherein the UV radioactive exposure indicator is exposed to the UV radiation
(for example, the UV of the threshold dose is radiated), generates photochromic response in the UV radioactive exposure indicator, wherein described can
Wearing UV sensor is configured to be worn on the size in people experimenter, wherein UV radiation includes from about 290nm to about
The wave-length coverage of 400nm, and wherein the wearable UV sensor be configured as by with application on human skin it is comparable in a manner of receive and apply
The product added.It quite may include the UV sensing for the product coating being applied in method identical with the application on human skin with application on human skin
Device.It quite may include the UV sensor that the product applied is received in method identical with the application on human skin with application on human skin.With people
Skin quite may include the UV sensor for retaining the product applied in method identical with the application on human skin.
One kind is for detecting the wearable UV sensor of UV radiation (for example, the UV of threshold dose is radiated), the wearable UV
Sensor includes first layer, and the first layer includes polymeric substrates；And the second layer, the second layer include UV radioactive exposure
Indicator；Wherein the UV radioactive exposure indicator is exposed to the UV radiation (for example, the UV of the threshold dose is radiated),
Photochromic response is generated in the UV radioactive exposure indicator, wherein the wearable UV sensor is configured to be worn on
Size in people experimenter, and wherein the UV radiation includes the wave-length coverage from about 290nm to about 400nm.Wearable UV
Sensor can also include third layer, and the third layer include a certain amount of being enough to make at least the one of the wearable UV sensor
Part adheres to the adhesive in application on human skin.
A kind of skin sensor that the UV for detecting doses is radiated, the skin sensor includes: (a) polymer
Substrate, the polymeric substrates include at least one polymer and at least one UV radioactive exposure indicator；And it (b) bonds
Agent generates light-induced variable in the polymeric substrates wherein the skin sensor is exposed to the UV radiation of the dosage
Colour response, wherein the skin sensor is configured to be worn on the size in people experimenter, and the wherein UV radiation packet
Include the wave-length coverage from about 290nm to about 400nm.
A method of for sensing the UV radioactive exposure of doses, which comprises it includes polymer that (a), which is provided,
The wearable UV sensor of substrate and UV radioactive exposure indicator；(b) the wearable UV sensor is exposed at least one
The UV radiation of amount, to form the wearable UV sensor of postdose；And (c) measure the wearable UV biography of the postdose
Sensor senses the UV radioactive exposure of the dosage to the photochromic response of the UV radiation of at least dose,
Wherein the photochromic response is by including radiating to cause to the UV of the wavelength of about 400nm from about 290nm.Sense the dosage
The UV radiation may include comparing the photochromic response with the chart for including the photochromic response of UV reconditioning
Compared with.Wearable UV sensor may include adhesive.Method may include that the wearable UV sensor is applied to skin, companion
As described adhesive layer contacts the skin.
A method of for determining the radiation proof size of UV of the product applied, which comprises (a) provides packet
Include polymeric substrates, UV radioactive exposure indicator and the optionally wearable UV sensor of adhesive phase；(b) by the institute of the first amount
The product for stating application contacts to the surface of the wearable UV sensor sensor surface for generating contact；(c) it is connect described
The sensor surface of touching is exposed to the UV radiation of the first dosage, to form the sensor surface of postdose, wherein described be exposed to
Lead to photochromic variation on the sensor surface of the postdose；And it (d) measures relative to the described photochromic of reference
Variation, with the radiation proof size of the UV of the product of the determination application, wherein the UV of first dosage is radiated
Including from about 290nm to the wave-length coverage of about 400nm.Referring to may include (i) do not contacted with the product of the application and
(ii) it is exposed to the identical or other wearable UV sensing of the UV radiation of first dosage or the UV radiation of phase dosing
The photochromic variation on the surface of device.Referring to may include (i) contacted with the product of the application of the second amount and (ii) cruelly
It is exposed to the table of the identical or other wearable UV sensor of the UV radiation of first dosage or the UV radiation of phase dosing
The photochromic variation in face, second amount are more or less than first amount.Reference may include exposure to first dose
The UV of amount is radiated or the light-induced variable discoloration on the surface of the identical or other wearable UV sensor of the UV of phase dosing radiation
The chart of change.Wherein wearable UV sensor includes the optional adhesive phase, and method may include by the wearable UV
Sensor is applied to skin, contacts the skin along with described adhesive layer.
A kind of system that the UV for sensing at least dose is radiated, the system comprises: (a) at least one skin sensing
Device, the skin sensor include polymeric substrates, at least one UV radioactive exposure indicator and adhesive；And (b) reference
The chart of response (e.g., including UV dose of radiation), wherein at least one skin sensor is configured as described in the sensing
Photochromic response is carried out when at least the UV of dose is radiated, wherein UV radiation includes the wave from about 290nm to about 400nm
It is long, and wherein at least one skin sensor is configured to be worn on the size in people experimenter.Chart may include
Color gradient, wherein the color gradient corresponds to the photochromic response of UV reconditioning.For example, chart may include from first
Color transition marks wherein each step of the color gradient is used with respect to UV exposure level to the color gradient of the second color.
In some embodiments, the UV radioactive exposure indicator with color similar with the first color of color gradient may be almost
UV radioactive exposure is not received, wherein having sudden and violent with the corresponding UV of the similar color of the second color of color gradient radiation
Reveal indicator, relative to the UV radioactive exposure with the color similar with first color of the color gradient
Indicator may have received that high UV radioactive exposure.
Polymeric substrates include polyethylene, high density polyethylene (HDPE), low density polyethylene (LDPE), polypropylene, polyvinyl chloride, poly- (first
Base methyl acrylate), nylon, polytetrafluoroethylene (PTFE), polyureas, polystyrene, polysiloxanes, polyacrylonitrile, its copolymer or its group
It closes.UV radioactive exposure indicator includes photochromic dyes, the photochromic dyes include spirooxazine, spiral shell indoline oxazines,
Spiro-pyrans, diarylethene, azobenzene, photochromic quinone, inorganic photochromic material, photochromic complex or its group
It closes.Adhesive includes that solvent type adhesive, polymer dispersing binder, hot-melt adhesive, contact adhesive, response type are viscous
Mixture, structural adhesive, epoxy adhesive, hot-melt adhesive, elastomeric adhesive, elastomer contact type adhesive, three
It is melamine-formaldehyde adhesive, aerodux, vestopal binder, one-package adhesive, UV solidification adhesive, wet solid
Change adhesive, hot setting adhesive, plant amylum adhesive, casein based adhesive, cyanoacrylate adhesive, glue by spraying
Mixture, silicone based adhesive or combinations thereof.Polymeric substrates can be with wearable UV sensor from about 70 weight % to about 90
The concentration of weight % exists.UV radioactive exposure indicator can be with wearable UV sensor from about 10 weight % to about 30 weights
The concentration for measuring % exists.Adhesive can exist with wearable UV sensor from about 1 weight % to the concentration of about 10 weight %.
Wearable UV sensor can have ring, bracelet, wrist strap, armband, necklace, earrings, waistband, coat, cap, sunglasses or its group
The shape of conjunction.Wearable UV sensor further includes from about 0.1cm2To about 5cm2Area.At least one skin sensor can wrap
Include transcutaneous sensor, the transcutaneous sensor has ring, bracelet, wrist strap, armband, necklace, earrings, waistband, coat, cap, too
The shape of positive mirror or combinations thereof.At least one skin sensor further includes from about 0.1cm2To about 5cm2Area.The agent of UV radiation
Amount can be threshold dose.
The brief description of accompanying drawing
The file of this patent includes the attached drawing that an at least width is showed with colour.Once requesting and paying necessary expense, quotient
Mark and Patent Office will just provide the copy of this patent with one or more color drawings.
By partly quoting the disclosure and attached drawing, it is possible to understand that some embodiments of the disclosure, in which:
Fig. 1 illustrates the specific embodiment embodiment according to the disclosure, presence or absence of ultraviolet radiation
In the case where photochromic dyes intramolecular rearrangement and every kind of form absorption spectra data；
Fig. 2 illustrates the specific embodiment embodiment according to the disclosure, exists in visible spectrum or ultraviolet light
The photochromic dyes of intramolecular rearrangement are carried out in the case where light in spectrum；
Fig. 3 illustrates the specific embodiment embodiment according to the disclosure, there is and be not present ultraviolet radiation
In the case where wearable UV sensor material；
Fig. 4 illustrates the specific embodiment embodiment according to the disclosure, the case where ultraviolet radiation is not present
Under wearable UV sensor material；
Fig. 5 illustrates the specific embodiment embodiment according to the disclosure, there are ultraviolet radiation
Wearable UV sensor material；And
Fig. 6 illustrates the specific embodiment embodiment according to the disclosure, contacts the wearable UV sensor of skin
Material.
Specific embodiment
People have various selections, to protect themselves from having when selecting and be used for outdoors from the selection
Undesirable exposure in evil radiation.These selections include many applications or the skin contact with subject product, described
Product includes lotion, face cream, spraying, ointment and gel, and also includes fabric, clothes, cover from sun, cloth and shelter.Apply
Product can limit the ability that harmful radiation influences the skin of subject, can for example pass through filtering, blocking or other reductions
The amount for reaching the harmful radiation of subject is realized.One challenge is to know the suitable amount of the product of application to realize desired water
Flat protection.The other is assessment product (for example, apply product) once the effect used how.
In some embodiments, this disclosure relates to which the wearable items sensitive to ultraviolet radiation exposure are (comprising percutaneous
Sensor and skin sensor).In some embodiments, wearable UV sensor can be to including UV-A (320-400nm)
Radiosensitive or measurement in ultraviolet (UV) spectrum of radiation and UV-B (280-290nm) radiation is to including UV-A (320-
400nm) radiate the exposure with the radiation in ultraviolet (UV) spectrum of UV-B (280-290nm) radiation.It is radiosensitive to UV can
Wearing UV sensor may desirably be used as assess or compare be not present or there are the product of application (for example, sunscreen,
UVA filter or UVB filter) in the case where skin UV exposure means.For example, being contacted with the product of application wearable
UV sensor can qualitatively or quantitatively indicate that the product applied mitigates the degree of UV exposure.In addition, for measuring to UV spoke
The wearable UV sensor for the exposure penetrated can provide the UV spoke of doses via observable indicator (that is, color change)
Penetrate exposed of short duration informing.UV sensor may desirably indicate or show in real time the validity of the product applied.In some realities
It applies in scheme, UV sensor can be customized the skin desirably to reflect the individuation with various application scenarios.
Wearable UV sensor
Wearable UV sensor (for example, transcutaneous sensor, skin sensor) may include substrate (for example, polymer matrix
Bottom)；UV radioactive exposure indicator (for example, photochromic dyes)；And optionally adhesive.According to some embodiments, warp
Transcutaneous sensor may adapt to use near or around in the skin of subject.In some embodiments, wearable UV sensing
Device may adapt to contact the use (comprising adherency) with skin or subject.Wearable UV sensor be exposed to UV radiation can
To cause photochromic response in wearable UV sensor, wherein the size of the photochromic response can be with the UV spoke
It is related (for example, directly related) to penetrate exposed size or dosage.Photochromic response can be reversible, wherein from UV radiation source
Caused photochromic response can be overturned by removing wearable UV sensor.For example, having there is no UV radiation
The UV sensor of first color (including colorless state) can reversibly become the second color when being exposed to UV radiation (comprising nothing
Color state).For example, the initial colourless wearable UV of transformed color (for example, purple) is sensed after being exposed to UV radiation
Device may return to colorless state when removing wearable UV sensor from UV radioactive exposure.Color change can be monitored
(for example, passing through instrument or human eye).For example, color change can be monitored by colorimeter or spectrophotometer.In some implementations
In scheme, the product of application can contact that (for example, by any desired applying mode, the applying mode includes to sprawl, rub
Wipe, smear, coating, spraying, dipping or the such product applied of delivering in another way) wearable UV sensor.It can wear
Wear UV sensor and can contact, receive and/or in another way with the interaction of the product of application (for example, with application on human skin
Similar, essentially similar or identical mode).Wearable UV sensor may desirably with animal (for example, people) skin base
Similar mode coats, adsorbs or absorbs the product applied in sheet.Wearable UV sensor may desirably be suitable with application on human skin,
Wherein the wearable UV sensor can be coated with the product that method identical with application on human skin is applied.Wearable UV sensor
May desirably be suitable with application on human skin, apply wherein the wearable UV sensor can be received in method identical with application on human skin
Product.Wearable UV sensor can be desirably suitable with application on human skin, wherein the wearable UV sensor can with fell
The identical method of skin retains the product applied.Wearable UV sensor may desirably include the spy of tone, elasticity and quality
Sign aspect is suitable with application on human skin.
Substrate may include for expected from it or possible purposes desired or any material needed.In some realities
It applies in scheme, substrate can be the material of at least partly UV radiation transmission, and wherein UV radioactive exposure indicator can be molded
Into substrate.Substrate is also possible to opaque.Substrate can also include at least one surface coated in the substrate
UV radioactive exposure indicator.According to some embodiments, polymeric substrates may include at least one polymer.For example, polymerization
Object substrate may include polyethylene, high density polyethylene (HDPE), low density polyethylene (LDPE), polypropylene, polyvinyl chloride, poly- (methacrylic acid
Methyl esters), nylon, polytetrafluoroethylene (PTFE), polyureas, polystyrene, polysiloxanes, polyacrylonitrile, its copolymer or combinations thereof.For example,
Wearable UV sensor may include polymeric substrates, wherein the polymeric substrates are polyvinyl chloride.The combination of polymer can
To include the admixture or a series of more than one polymeric layers of more than one polymer.Polymer or polymer can be selected
It is combined to provide the wearable UV sensor with desired mechanical features, the mechanical features includes tensile strength, Young mould
Amount, resilience, ductility, breaking strength, specific heat capacity, warmth retention property, thermal capacity, conductivity, elongation, impact strength, is glued at toughness
Property, bending modulus, pliability, fracture elongation or combinations thereof.For example, polymeric substrates may desirably allow wearable UV
Sensor neatly surrounds wrist winding or adheres to surface (for example, skin) as strip.Polymeric substrates may include
The combination of polymer or polymer, the combination of the polymer or polymer are selected to provide with desired color, impermeable
Lightness, the dielectric constant of UV radiation, electromagnetic radiation dielectric constant or combinations thereof wearable UV sensor.Polymeric substrates can
Selectively to allow the reflection of specific wavelength or wide spectrum electromagnetic radiation, refraction, diffraction, transmission, absorption, scattering or combinations thereof.
For example, polymeric substrates may desirably allow wearable UV sensor test to UV-A radiation, uv b radiation or combinations thereof
Exposure.In some embodiments, polymeric substrates may desirably allow the property of wearable UV Sensor Analog Relay System application on human skin,
The property includes quality, absorption or the ability, pliability, hardness or the tone that retain the product applied.Polymeric substrates can be with
Desirably allow wearable UV sensor be it is ventilative, flexible, can feel and combinations thereof.
In some embodiments, wearable UV sensor (for example, transcutaneous sensor, skin sensor) may include gathering
Polymer substrates, wherein the polymeric substrates exist with any desired ratio, such as in each case, to press wearable UV
About the 5% of the weight of sensor, or about 10% or about 15%, or about 20%, or about 25%, or about 30%, or about 35%, or about
40%, or about 45%, or about 50%, or about 55%, or about 60%, or about 65%, or about 70%, or about 75%, or about 80%,
Or about 85%, or about 95%, or about 99% concentration.Wearable UV sensor may include so that in each case, pressing can
Dress UV sensor from about 5% to about 10%, or from about 10% to about 20%, or from about 20% to about 30%, or from about
30% to about 40%, or from about 40% to about 50%, or from about 50% to about 60%, or from about 60% to about 70%, or from about
70% to about 80%, or from about 80% to about 90%, or polymeric substrates existing for concentration from about 90% to about 99%.One
In a little embodiments, wearable UV sensor may include by the wearable UV sensor weight from about 70% to about
Polymeric substrates existing for 90% concentration.
According to some embodiments, wearable UV sensor (for example, transcutaneous sensor, skin sensor) may include gluing
Mixture.Adhesive may include solvent type adhesive, polymer dispersing binder, hot-melt adhesive, contact adhesive, anti-
Answer type adhesive, structural adhesive, epoxy adhesive, hot-melt adhesive, elastomeric adhesive, the bonding of elastomer contact type
Agent, melamino-formaldehyde adhesive, aerodux, vestopal binder, one-package adhesive, UV solidification bonding
Agent, moisture curable adhesive, hot setting adhesive, plant amylum adhesive, casein based adhesive, cyanoacrylate bonding
Agent, spray adhesive, silicone based adhesive or combinations thereof.Adhesive may desirably allow wearable UV sensor to be applied to
At least one surface.For example, adhesive may desirably allow wearable UV sensor to be applied to the skin of animal (for example, people)
Skin.Adhesive may desirably allow wearable UV sensor to be removedly applied to surface, wherein the wearable UV is passed
Sensor can be applied repeatedly.Adhesive may desirably allow wearable UV sensor be applied to surface more than once without
Destroy the surface or the wearable UV sensor.
According to some embodiments, wearable UV sensor (for example, transcutaneous sensor, skin sensor) may include UV
Radioactive exposure indicator.Wearable UV sensor may include UV radioactive exposure indicator, wherein the UV radioactive exposure indicates
Agent exists with any desired ratio, such as in each case, with by about the 0.1% of the weight of wearable UV sensor, or
About 1%, or about 2%, or about 5%, or about 10%, or about 15%, or about 20%, or about 25%, or about 30%, or about 35%,
Or about 40%, or about 45%, or about 50%, or the concentration more than about 50%.Wearable UV sensor may include with any phase
UV radioactive exposure indicator existing for the ratio of prestige, such as in each case, with by the weight of wearable UV sensor from
About 1% to about 10%, or from about 10% to about 20%, or from about 20% to about 30%, or from about 30% to about 40%, or from about
40% to about 50%, or the concentration more than about 50%.UV radioactive exposure indicator quantitatively and may desirably be indicated qualitatively
The exposure that wearable UV sensor radiates UV.In some embodiments, wearable UV sensor may include with by can wear
Wear UV radioactive exposure indicator existing for the concentration from about 10% to about 30% of the weight of UV sensor.
In some embodiments, wearable UV sensor (for example, transcutaneous sensor, skin sensor) may include outer
Layer；Middle layer；And internal layer.Wearable UV sensor may include outer layer；The middle layer adjacent with the outer layer；And with institute
State outer layer and the adjacent internal layer of the middle layer.Outer layer may include substrate (for example, polymeric substrates), UV radioactive exposure instruction
Agent or combinations thereof.Outer layer can be worn on the skin back to the skin of wearable UV sensor, the wearable UV sensor
On skin.Outer layer may desirably be allowed to absorb UV radiation back to skin.Outer layer may include UV exposure indicator, wherein described outer
Layer can change color in the UV radiation for being exposed to threshold amount.Middle layer may include substrate (for example, polymeric substrates) and
Adhesive.Middle layer can be exposed or can be not exposed.For example, middle layer can be covered or by the outer layer by outer layer
It is covered with internal layer.In some embodiments, middle layer can be exposed between outer layer and internal layer.Middle layer may desirably
Structural intergrity is provided to outer layer.Outer layer may desirably be adhered to internal layer by middle layer.Internal layer may include adhesive and base
Bottom (for example, polymeric substrates).Upper layer may desirably be adhered to surface (for example, skin) by internal layer.In some embodiments
In, wearable UV sensor may include the UV radioactive exposure indicator as outer layer；Polymeric substrates as middle layer；With
And the adhesive phase as internal layer.Wearable UV sensor may include outer layer, wherein the outer layer include polymeric substrates and
UV radioactive exposure indicator admixture；And the internal layer including adhesive.With the adhesive tape as internal layer and including UV spoke
The outer layer for penetrating exposed indicator may desirably allow to adhere to wearable UV sensor or dispose on the surface, wherein described can
The UV radioactive exposure indicator of wearing UV sensor can be exposed to UV radiation.Wearable UV sensor may include outer
Layer, wherein the outer layer includes substrate (for example, polymeric substrates) and UV radioactive exposure indicator admixture；With include substrate
The internal layer of (for example, polymeric substrates).
In some embodiments, wearable UV sensor (for example, transcutaneous sensor, skin sensor) may include to
The composition of small part homogeneous.The composition of at least partly homogeneous may include adhesive.Wearable UV sensor may include
Adhesive, wherein described adhesive exists with any desired ratio, for example, in each case, to be sensed by wearable UV
About the 1% of the weight of device, or about 5%, or about 10%, or about 15%, or about 20%, or about 25%, or about 30%, or about
35%, or about 40%, or about 45%, or about 50%, or about 55%, or about 60% concentration.Wearable UV sensor can wrap
Include with adhesive existing for any desired ratio, for example, in each case, with by the weight of wearable UV sensor from
About 1% to about 10%, or from about 10% to about 20%, or from about 20% to about 30%, or from about 30% to about 40%, or from about
40% to about 50%, or from the concentration of about 50% to about 60%.For example, wearable UV sensor may include about 85% polymerization
Object, about 5% adhesive and about 10% UV radioactive exposure indicator.
Wearable UV sensor (for example, transcutaneous sensor, skin sensor) can have any rule or irregular
Shape or size.For example, wearable UV sensor can generally form round, oval, starlike, one angular (monogon), three
Angular, square, rectangle, irregular quadrilateral, diamond shape, rhomboid, parallelogram, pentagon, hexagon, heptagon,
Octagon, nonagon, decagon or any other polygon.Wearable UV sensor can be substantially flat, Huo Zheke
With any 3D shape.In some embodiments, wearable UV sensor can be configured to be worn on people experimenter
On size.For example, wearable UV sensor can have ring, bracelet, wrist strap, armband, necklace, earrings, waistband, coat, cap
The form of son, sunglasses or combinations thereof.Wearable UV sensor can be embedded into fabric, the fabric include neoprene,
Cotton, spandex, nylon, silk, woolen knitwear, leather, fiber crops, jute, ramie or combinations thereof.Wearable UV sensor can be any
The patch of shape and size.For example, wearable UV sensor can be including the patch from about 0.01mm to the thickness of about 30mm
Or test-strips.Wearable UV sensor may include about 0.01mm, or about 0.05mm, or about 0.1mm, or about 0.25mm, or about
0.5mm, or about 0.75mm, or about 1mm, or about 2.5mm, or about 5mm, or about 7.5mm, or about 10mm, or about 20mm, or about
The thickness of 30mm.
Wearable UV sensor can be including the patch or test-strips from about 1mm to the width of about 700mm.Wearable UV
Sensor can be including the patch or test-strips from about 1mm to the length of about 700mm.Wearable UV sensor can be including
It is substantially circular and from about 0.01mm to the patch of the thickness of about 30mm.Wearable UV sensor can be including substantial rectangular
Or the patch of polygon, wherein vertex is substantially sharp or substantially circular.According to some embodiments, wearable UV
Sensor may include area, and the area includes about 0.1cm2, or about 0.5cm2, or about 1cm2, or about 2cm2, or about 3cm2,
Or about 4cm2, or about 5cm2, or about 7.5cm2, or about 10cm2, or about 12.5cm2, or about 15cm2, or about 17.5cm2, or about
20cm2.For example, wearable UV sensor may include 1cm2Area.
Wearable UV sensor may include various quality, patterning, stamp and the marking.For example, wearable UV sensing
Device can be turned to by quality as skin.Wearable UV sensor may include quality, and the quality includes rough, solid
, coarse prick people, sliding, hard, villous, springy, sticky, soft, granular, wet soft, fiber
It is shape, coarse, soft and smooth, furriness, hard, closely knit, slightly knitting, spongiform, viscous, flexible, wet soft or
A combination thereof.
UV sensor
According to some embodiments, this disclosure relates to UV sensor.UV sensor may include substrate (for example, polymer
Substrate)；UV radioactive exposure indicator (for example, photochromic dyes)；And optionally adhesive.UV sensor may adapt to
Use adjacent with people, wherein the people may desirably measure the opposite UV exposure of the people using the UV sensor.Example
Such as, UV sensor can be placed in the UV exposed region adjacent with people.UV sensor can have umbrella, cap, awning or screening
The shape of cover material, wherein the UV sensor may desirably measure opposite UV exposure.UV sensor is exposed to UV radiation can be with
Cause photochromic response in the UV sensor, wherein the size of the photochromic response can radiate cruelly with the UV
The size or dosage of dew are related (for example, directly related).The size of photochromic response may desirably allow relative to adjacent
People or object measurement UV exposure.
UV radioactive exposure indicator
According to some embodiments, this disclosure relates to include the UV sensor of UV radioactive exposure indicator (for example, percutaneous pass
Sensor, skin sensor).UV radioactive exposure indicator may desirably quantitatively and qualitatively indicate that UV sensor radiates UV
Exposure.UV radioactive exposure indicator may desirably distinguish UV-A radiation and uv b radiation.E.g., including UV radioactive exposure refers to
Show that the UV sensor of agent can qualitatively or be quantitatively determined to UV-A radiation, the exposure of uv b radiation or combinations thereof.Distinguish UV-
A and uv b radiation may be desired, because while it has been found that UV-A and uv b radiation lead to and length short-term to Skin Cell
The damage of phase, but UV-A radiation may be thought more dangerous to human skin than UV-B by healthy professional person.In this regard, an original
Because may be because UV-A radiation can penetrate skin surface, epidermis, and subsequently into corium, and uv b radiation is not worn usually
Saturating corium, but can break through skin surface and enter epidermis.
According to some embodiments, UV radioactive exposure indicator can be used as the UV spoke that signal desirably indicates UV sensor
Penetrate exposure.Signal may include color change.Color change (for example, color change) can be monitored (for example, by instrument or
Human eye).For example, color change can be monitored by colorimeter or spectrophotometer.Signal can be binary system or ternary
's.For example, UV radioactive exposure indicator can change color in the UV radiation for being exposed to first threshold, and then in exposure
Become the second color when the UV radiation of second threshold.UV radioactive exposure indicator may desirably indicate UV in a large amount of signals
The UV radioactive exposure of sensor.For example, UV radioactive exposure indicator can be indicated when being exposed to UV radiation from about 1 to about 11
UV index value.In some embodiments, color change may include from colourless to the variation of a color, from a color to another
The variation of one color, from the first color to the second color and be then return to the first color variation, from it is colourless to a color simultaneously
And it is then return to colourless variation, or combinations thereof.Color change may include violet shift, red shift, it is hyperchromic displacement, lose lustre displacement or its
Combination.E.g., including the UV sensor of UV exposure indicator can become in the UV radiation for being exposed to threshold amount from colourless
Purple.The UV sensor that the UV exposure indicator of purple is had changed into including the UV radiation by exposure to threshold amount, is removing
When UV exposure, color can be become colourless from purple.
In some embodiments, UV radioactive exposure indicator includes photochromic dyes (that is, photochromic pigment).Light
Chromotropic dye is caused to can be the combination of chemicals or chemicals of any apparent color variation when being exposed to UV radiation.?
In some embodiments, when being exposed to UV radiation, photochromic dyes can be in absorption, reflection, transmission or emission spectrum
It shows band position and becomes longer wavelength (for example, red shift) or shorter wavelength (for example, violet shift).
Photochromic dyes may include spirooxazine, spiral shell indoline oxazines, spiro-pyrans, diarylethene, azobenzene, photic
Change colour quinone, inorganic photochromic material, photochromic complex or combinations thereof.For example, photochromic dyes may include
1,3 '-dihydro -8- methoxyl groups -1 ', 3 ', 3 '-trimethyl -6- nitro spiral shells [2H-1- chromene -2,2 '-(2H)-indoles], benzyl
Benzyl viologen dichloride, 1,1 '-diheptyls -4,4 '-bipyridine salt dibromide, 1 ', 3 '-dihydros -1 ', 3 ', 3 '-front threes
Base -6- nitro spiral shell [2H-1- chromene -2,2 '-(2H)-indoles], 1,3- dihydro -1,3,3- trimethyl spiral shell [indoles -2 2H-,
3 '-[3H] naphtha [2,1-b] [1,4] oxazines], 4,4 '-bipyridyls, indoine blue dye content, hydration dichloromethyl purpurine,
2,3,3- trimethyl -1- propyl -3H- indoles iodide, azobenzene, silver halide, zinc halide, hydrogenation yttrium, talan, 1,2-
The amyl- 1- alkene of two (thiene-3-yl) rings, 2,2- diphenyl -2H- benzo [h] chromene, dimethyl pyrene, 2- (4- (8- (4- (4,5- bis-
Phenyl -2H- imidazoles -2- base) phenyl) naphthalene -1- base) phenyl) -4,5- diphenyl -1H- imidazoles or combinations thereof.Photochromic dyes
It may include 1,3- dihydro spiral shell [- 2,1 hexamethylene of 2H- anthra [2,3-d] imidazoles] -5,10- diketone；2- nitro -3- aminofluorene -2-
Amino -4- (2 '-furyl) -6H-1,3- thiazine -6- thioketones, 1,3- dihydro -4- (phenyl) spiral shell [2H- anthra -1,2- two
Imidazoles -2,1 '-hexamethylene] -6,11- diketone, 1,3- dihydro spiral shell [2-H- anthra [1,2- diimidazole -2,1 '-cycloheptane] -6,11-
Diketone, 8- methoxyl group -1 ', (2H-1- chromene -2,2 ' (1 ' H)-quinoline, (1,3- propane diyl) are double for 3 '-dimethyl spiral shells
[3 ', 3 '-dimethyl -6- nitro spiral shells [2H-1- chromene -2,2 '-indoline] or combinations thereof.Photochromic dyes can wrap
Include 1,3,3- trimethyl spiral shell-indoles -2,3 '-[3H]-naphtha [2,1-b] -1,4- oxazines], spiral shell [chromene -2 2H-1-,
9 '-xanthenes], 5 '-amino -1,3 ', 3 '-trimethyl spiral shells [2H-1- chromene -2,2 '-indoline, 3,3- dimethyl -6- nitre
Base spiral shell [2H-1- chromene -2,2 '-benzoxazoles quinoline], [(2 ', 4 '-dinitrophenyl) methyl] -1H- benzimidazole, 2,5-
Diphenyl -4- (2 '-chlorphenyl) imidazoles, 6 '-methyl mercaptos -3,3 '-dimethyl -8- methoxyl group -6- nitro spiral shell [2H-1- benzopyrene
Mutter -2,2 '-benzothiazolines], (1,2- ethane diyl) bis- [8- methoxyl group -3- methyl -6- nitro spiral shell [2H-1- chromenes -
2,2 '-benzothiazolines], 2- phenyl -3- methyl -7- methoxyl group -8 '-nitro spiral shell [4H- chromene -4,3 '-[3H]-naphtho-]
2,1-b] pyrans, 1,3- dihydro spiral shell [2H- anthra [2,3-d] imidazoles -2,1 '-hexamethylene] -6,11- diketone, ethyl-Beta-methyl -
β-(3 ', 3 '-dimethyl -6- nitro spiral shell (2H-1- chromene -2,2 '-indoline -1 '-yl)-acrylate, 3,4,4- tetrachloro
Naphthalene -1 (4H) -one, (E) -3- (1- (furans -3- base) ethylidene) -4- (propyl- 2- subunit) dihydrofuran -2,5- diketone or its group
It closes.According to some embodiments, the combination of photochromic dyes or photochromic dyes may desirably become and typical skin
Skin has the color of striking contrast.For example, dyestuff may desirably become include red, orange, yellow, dark green, blue,
Purple or violaceous color.The various combination of dyestuff may desirably be supplied to UV exposure sensor with from colourless or white
Become various colors.
According to some embodiments, photochromic dyes or pigment when being exposed to UV radiation, can by intramolecular or
Intermolecular rearrangement, reaction or combinations thereof generate color change.As shown in Figure 1,2,2- diphenyl -2H- benzo [h] chromenes (" close
Shape ") be exposed to UV radiation when can carry out intramolecular rearrangement to form (Z) -2- (3,3- diphenyl acrol) naphthalene -1
(2H) -one (" open form "), wherein the rearrangement can be by being exposed to thermoreversion.It is colourless for closing shape structure, and is radiated in UV
When exposure, the structural rearrangement becomes the open form of purple.From the absorption spectrum of every kind of form, this is apparent.Additional rearrangement
It can be occurred by the electromagnetic radiation and/or being exposed in different molecular for heat of different wave length.For example, Fig. 2 discloses intramolecular
Reset, the intramolecular rearrangement includes a) anti-form-1 0b, 10c- dimethyl -10b, 10c- dihydropyrene, b) 5a, 6,6- trimethyls -
5a, 6- dihydro -12H- benzo [5,6] [1,3] oxazines simultaneously [3,2-a] indoles, c) (E) -3- (1- (furans -3- base) ethylidene) -
4- (propyl- 2- subunit) dihydrofuran -2,5- diketone and d) 5- ((2Z, 4E) -5- (dimethylamino) -2- hydroxyl -2,4- diene -
1- subunit) -2,2- dimethyl -1,3- dioxanes -4,6- diketone.
UV radioactive exposure
According to some embodiments, this disclosure relates to skin sensor, the skin sensor includes polymeric substrates；UV
Radioactive exposure indicator (that is, photochromic dyes)；And adhesive, wherein wearable UV sensor is exposed to the UV of doses
Radiation can cause photochromic response in the wearable UV sensor.Dosage can be according to wearable UV sensor to UV
The intensity of the exposure of radiation and the length of time and change.For example, if exposure longer time, wearable UV sensor can be with
Than the UV radiation that the corresponding wearable UV sensor of exposed short period receives larger dose.Dosage can pass through the production of application
The application of product (for example, sunscreen, UVA filter or UVB filter) is reduced.For example, being coated with wearing for the product applied
Wearing UV sensor can be than being not coated by the product of application or being coated with the different productions applied with lower sun protection factor (SPF)
The corresponding wearable UV sensor of product receives the UV radiation of relatively low-dose.Photochromic response can be according to doses change.Example
Such as, wearable UV sensor can carry out photochromic response and radiating time-varying purple in the UV for receiving doses,
Wherein the wearable UV sensor can be transformed into darker or deeper purple in the UV radiation for receiving larger dose.It can wear
Performance photochromic response selective for UV radiated wavelength range can be formulated to by wearing UV sensor.For example, can
Wearing UV sensor can show photochromic response in the UV-A radiation for receiving doses, wherein the wearable UV is passed
Sensor can not show photochromic response when receiving the uv b radiation of doses.Wearable UV sensor is by with certain
Photochromic response can be showed when the UV radiation treatment of dosage with gradient or in a binary fashion.For example, certain being exposed to
When the UV radiation of dosage, wearable UV sensor can start to transform to lavender, wherein the wearable UV sensor will be with
UV, which is obtained, with the dosage radiates directly related gradient transition into darker purple.In some embodiments, wearable UV is passed
Sensor can have photochromic response in the UV radiation for reaching threshold value.For example, wearable UV sensor can keep colourless
UV radioactive exposure until reaching threshold value changes color then in the UV radioactive exposure for reaching threshold value.Threshold value may include UV
The summation of radioactive exposure, the summation of the length of the time of UV radioactive exposure, the summation of the intensity of UV radioactive exposure, or combinations thereof.
Exposure may include the direct or indirect exposure that wearable UV sensor radiates UV.
According to some embodiments, UV radioactive exposure indicator can indicate that gradient or threshold value UV radioactive exposure are horizontal.Example
Such as, UV radioactive exposure indicator can be indicated with joule/cm2For the threshold value UV radiant energy density of unit or with watt/cm2For
The threshold irradiance of unit.UV radioactive exposure indicator can be adjusted or be adjusted to sense or indicate different degrees of exposure.
For example, the mixture of photochromic dyes can be with different formula combinations to express light under the UV radioactive exposure of different threshold values
Mutagens colour response.In some embodiments, UV radioactive exposure indicator may desirably sense UV radioactive exposure in real time.Example
Such as, UV radioactive exposure indicator may desirably sense the product (for example, sunscreen, UVA filter or UVB filter) of application
The effect of with take precautions against in real time UV radiation.
Method for determining UV radiation protection effect of the product applied
According to some embodiments, this disclosure relates to the method for determining UV radiation protection effect.Wearable UV sensing
Device (for example, transcutaneous sensor, skin sensor) can be coated with application product (for example, sunscreen, UVA filter or
UVB filter), and it is then exposed to UV radiation, wherein the wearable UV sensor is in the UV spoke for reaching threshold value exposure value
Photochromic response can be provided when penetrating.Wearable UV sensor can show photochromic response, the photochromic response
The product or opacifier that can quantitatively or qualitatively measure application absorb or the ability of reflection UV radiation.Photochromic response can
To indicate the reduction for the effect of product applied absorbs or reflect the destruction or ability of the ability of UV radiation.It is applied for example, being coated with
The wearable UV sensor of the product added can not show photochromic response initially when being exposed to UV radiation, but can be
Photochromic response is showed when being exposed to UV radiation for a long time, may be since the product of application absorbs or the energy of reflection UV radiation
The destruction of power.The effect of product of application absorbs or reflection UV is radiated can be passed by being coated with the wearable UV of the product applied
The response measurement of the delay of sensor or lasting photochromic response.
A method of for sensing the UV radioactive exposure of threshold dose, the method includes provide include polymeric substrates and
The wearable UV sensor of UV radioactive exposure indicator；The wearable UV sensor is exposed to the UV radiation of at least dose
To form the wearable UV sensor of postdose；And there is light-induced variable by the wearable UV sensor sensing of the postdose
The UV of the threshold dose of colour response is radiated, wherein the photochromic response is by including from about 290nm to about 400nm
The UV radiation of wavelength causes.
A method of for determining the radiation proof size of UV of the product applied, which comprises (a) provides packet
Include the skin sensor of polymeric substrates, UV radioactive exposure indicator and adhesive phase；(b) at least one layer of UV protective agent is applied
To the surface of the skin sensor, to generate the skin sensor of UV protective agent coating；(c) by UV protective agent coating
Skin sensor is exposed to the UV radiation of at least dose to form the skin sensor of postdose, wherein the exposure passes through institute
Stating skin sensor leads to photochromic response；And (d) the photochromic variation of the measurement relative to reference, to determine
The radiation proof size of the UV of the product of application is stated, wherein the UV radiation of the first dosage includes from about 290nm to about
The wave-length coverage of 400nm.The level for measuring photochromic response may include being measured by instrument or human eye.For example, instrument can
To include colorimeter or spectrophotometer.
Method may include sensing the electromagnetic radiation of threshold dose.The electromagnetic radiation of doses may include being greater than or equal to
10m, or from about 10cm to about 10m, or from about 1mm to about 10cm, or from about 30 μm to about 1mm, or from about 3 μm to about 30 μm,
Or from about 700nm to about 3 μm, or from about 400nm to about 700nm, or from about 200nm to about 400nm, or from about 280nm to about
290nm, from about 290nm to about 400nm, or about 10nm to about 200nm, or about 0.01nm is to the wavelength of about 10nm or combinations thereof.
In some embodiments, the electromagnetic radiation of doses may include having fixed wavelength or wave-length coverage in certain time
Or the exposure of the electromagnetic radiation of different wavelength or wave-length coverages, the time include from about 1.2 × 10-17S to about 1s, or from
About 1s to about 60s, or from about 60s to about 1 hour, or from about 1 hour to about 4 hour, or from about 4 hours to about 8 hour, or from
About 8 hours to about 12 hours, or from about 12 hours to about 16 hour, or from about 16 hours to about 24 hour.A period of time exposure
Can be ceaselessly, it is interval, fixed intervals or combinations thereof.
Method for determining UV radiation protection effect may include the first wearable UV for being coated with the product applied
Sensor is compared with the second band of the product for being not coated by application.In some embodiments, for determining UV radiation protection
The method of effect may include the first wearable UV sensor for being coated with the product applied and the product for being not coated by application
Second band is compared.The method for determining UV radiation protection effect may include that will be exposed to UV radiation or be not exposed to UV
The wearable UV sensor of radiation is compared with numberical range, ladder diagram, comparison chart or combinations thereof.It is numberical range, trapezoidal
Figure or comparison chart can describe the result of the wearable UV sensor in the case where different UV radioactive exposures are horizontal.For example, numerical value model
It encloses, ladder diagram or comparison chart can describe the gradients of tones for including the purple from lilac to darkviolet a series of and wear
UV sensor is worn, it is related that the dose response of UV radiation of high dose is directly radiated to low dosage UV.Numberical range, ladder diagram
Or comparison chart may include and the horizontal directly related multiple color of UV radioactive exposure.For example, colourless wearable UV sensor
Can be related to no UV exposure, the wearable UV sensor of green can be related to low dosage UV exposure, and red wearable UV
Sensor can be related to high dose UV exposure.
System for sensing UV radioactive exposure
According to some embodiments, this disclosure relates to which the system for sensing UV radioactive exposure may include multiple wearable
UV sensor, UV radiation source and chart, wherein the UV radiation that the chart can be used for wearable UV sensor described in comparison is sudden and violent
Reveal dosage level.System may include single wearable UV sensor and numberical range.System may include that at least one can wear
Wear UV sensor and numberical range, wherein the wearable UV sensor can be it is disposable or disposable.
The system that UV for sensing an at least threshold dose is radiated may include wearable UV sensor, wherein described can wear
Wearing UV sensor includes polymeric substrates.Polymeric substrates may include polyethylene, high density polyethylene (HDPE), low density polyethylene (LDPE),
Polypropylene, poly- (methyl methacrylate), nylon, polytetrafluoroethylene (PTFE), polyureas, polystyrene, polysiloxanes, gathers polyvinyl chloride
Acrylonitrile, its copolymer or combinations thereof.Polymeric substrates can be the form of resin.For example, resin may include polyvinyl chloride
With the solvent comprising methyl ethyl ketone, tetrahydrofuran, acetone, cyclohexanone or combinations thereof.Polymeric substrates can be in every kind of feelings
In condition, by least one wearable UV sensor weight from about 5% to about 10%, or from about 10% to about 20%, or from
About 20% to about 30%, or from about 30% to about 40%, or from about 40% to about 50%, or the concentration presence more than about 50%.
The skin sensor system that UV for sensing an at least threshold dose is radiated may include skin sensor, wherein institute
Stating skin sensor includes adhesive, and described adhesive includes solvent type adhesive, polymer dispersing binder, hot melt adhesive
Agent, contact adhesive, reaction-ing adhesive, structural adhesive, epoxy adhesive, hot-melt adhesive, elastomer bonded
Agent, elastomer contact type adhesive, melamino-formaldehyde adhesive, aerodux, vestopal binder, one pack system
Adhesive, UV solidification adhesive, moisture curable adhesive, hot setting adhesive, plant amylum adhesive, casein based adhesive,
Cyanoacrylate adhesive, spray adhesive, silicone based adhesive or combinations thereof.Adhesive can be by skin sensor
Weight from about 1 weight % to about 10 weight %, or from about 10 weight % to about 20 weight %, or from about 20 weight % to about 30
Weight %, or from about 30 weight % to about 40 weight %, or from about 40 weight % to about 50 weight %, or from about 50 weight % to
About 60 weight %, or from about 60 weight % to about 70 weight %, or from about 70 weight % to about 80 weight %, or from about 80 weights
% to about 90 weight % is measured, or is existed from about 90 weight % to the concentration of about 99 weight %.
The system that UV for sensing an at least threshold dose is radiated may include wearable UV sensor, the wearable UV
Sensor includes UV radioactive exposure indicator, and the UV radioactive exposure indicator includes photochromic dyes, described photochromic
Dyestuff includes spirooxazine, spiral shell indoline oxazines, spiro-pyrans, diarylethene, azobenzene, photochromic quinone, inorganic photochromic
Material, photochromic complex or combinations thereof.UV radioactive exposure indicator can be by least one wearable UV sensing
The weight of device from about 1 weight % to about 10 weight %, or from about 10 weight % to about 20 weight %, or from about 20 weight % to
About 30 weight %, or from about 30 weight % to about 40 weight %, or from about 40 weight % to about 50 weight %, or from about 50 weights
% to about 60 weight % is measured, or from about 70 weight % of about 60 weight %, or from about 70 weight % to about 80 weight %, or from about 80
Weight % to about 90 weight %, or exist from about 90 weight % to the concentration of about 99 weight %.
Chart may include color gradient, wherein the color gradient corresponds to the photochromic response of UV reconditioning.Example
Such as, chart may include the color gradient from the first color transition to the second color, wherein each step of the color gradient
It is marked with opposite UV exposure level.In some embodiments, with the UV of color similar with the first color of color gradient
Radioactive exposure indicator may be almost without UV radioactive exposure be received, wherein having similar to the second color of the color gradient
Color corresponding UV radioactive exposure indicator may relative to have it is similar to first color of the color gradient
The UV radioactive exposure indicator of color have received that high UV radioactive exposure.
The system that UV for sensing an at least threshold dose is radiated may include ring, bracelet, wrist strap, armband, necklace, ear
The shape of ring, waistband, coat, cap, sunglasses or combinations thereof.
Specific embodiment embodiment
Fig. 3-5 is illustrated, and according to the specific embodiment embodiment of the disclosure, there is and be not present ultraviolet light spoke
Wearable UV sensor in the case where penetrating.Wearable UV sensor may include polymer and UV radioactive exposure indicator, institute
Stating polymer includes polyvinyl chloride.Wearable UV sensor can be white or colourless in the case where ultraviolet radiation is not present
's.When exposed to light, wearable UV sensor can become purple, wherein wearable UV is passed when removing from UV radiation source
Sensor can become white again.As shown in fig. 6, at least part of wearable UV sensor may desirably adhere to fell
Skin, wherein wearable UV sensor is substantially flat relative to application on human skin.
As by had benefited from present disclosure those skilled in the art understand that, other are for qualitatively or quantitatively
The equivalent or interchangeable composition and method for measuring radioactive exposure can be conceived to, and be retouched without departing from what is be contained herein
It states.Correspondingly, it will be only interpreted as with the mode of the implementation disclosure of description as shown illustrative.
Those skilled in the art can shape to component, size, quantity and/or configuration carry out various changes, without carrying on the back
From the scope of the present disclosure.According to some embodiments, each method being disclosed and method and step can be with any other quilts
It disclosed method or method and step and is combined and is performed in any order.Unless otherwise specified, verb " can be with
(may) " in the case where occurring, it is intended to convey condition that is a kind of optional and/or allowing, but the use of the word is not intended to secretly
Show any shortage of operability.When using such as opening term of " having " or " comprising ", have benefited from this field of the disclosure
Ordinarily skilled artisan will understand that disclosed feature or step can optionally be combined with additional feature or step.It is such
Selection can not be performed, and in fact in some embodiments, disclosed system, composition, device and/or method can
To exclude to exceed any other feature or step of those disclosed herein.Unlisted element, composition, equipment, system, side
Method and method and step can be because it is expected or requiring to be included or excluded.Those skilled in the art can be to making and using the disclosure
Composition, device and/or system method carry out various changes.For example, composition, device and/or system can be produced
And/or it is used as being suitable for animal and/or mankind's use (for example, for wholesomeness, infectiousness, safety, toxicity, biometer
Amount and other considerations).
Moreover, in the case where range has been provided, as by specific embodiment is desired or requiring, is disclosed
Endpoint can be considered as accurate and/or approximation.In the case where endpoint is approximate situation, degree of flexibility can be with range
The proportional variation of the order of magnitude.For example, on the one hand, in the context of the range of about 5 to about 50, about 50 endpoints of ranges can
It to include 50.5, but does not include 52.5 or 55, and on the other hand, in the context of the range of about 0.5 to about 50, about 50
Endpoints of ranges may include 55, but not include 60 or 75.In addition, in some embodiments, mixing and pairing endpoints of ranges can
Be meet it is desired.Moreover, in some embodiments, figure that every width is disclosed is (for example, in embodiment, table and/or attached
In one or more in figure) range can be formed (for example, description value is +/- about 10%, description value is +/- about 50%, description value
It is +/- about 100%) and/or the basis of endpoints of ranges.For the former, for example, described in embodiment, table and/or attached drawing
Value 50 can form about 45 to about 55, about 25 to about 100, and/or the basis of the range of about 0 to about 100.In addition to otherwise indicated
In the case where, disclosed percentage is weight percent.
For qualitatively or quantitatively measure radioactive exposure composition and method device and/or system whole or one
Part can be configured and disposed to disposable, durable, interchangeable and/or interchangeable.These equivalents and
Alternative is intended to include within the scope of this disclosure together with substantially changeing and modify.Correspondingly, foregoing disclose content quilt
It is intended to be illustrative, but is not limited to, the scope of the present disclosure as illustrated by the claim being attached.
Topic, abstract, background and title (headings) are provided according to the rules and/or for convenience of reader.They are not
Including for the prior art range and content recognize, and do not include the limit for being applicable to all embodiments being disclosed
System.
Embodiment
Some specific embodiment embodiments of the disclosure can be illustrated by examples provided herein.
Embodiment 1: wearable UV sensor is prepared
The general process for preparing wearable UV sensor is described in the present embodiment.By include high polymeric PVC and
The PVC solution of the resin of cyclohexanone is combined with spiral shell-Metro (spiro-mero) photochromic material.The ratio of PVC and dyestuff is
About 70:30.Then, PVC and dye mixture are applied in polyethylene terephthalate (PET) substrate.Then by base
All cyclohexanone are evaporated to generate cured PVC film in sheet.Then aqueous acrylic adhesives are applied to cured PVC film
On.Bonding peeling paper is applied to the top of adhesive.Then, PET base is removed from PVC film, and then rolls up PVC film
In rolls.
Claims (47)
1. a kind of wearable UV sensor, the wearable UV sensor is used to detect the UV radiation of threshold dose, described wearable
UV sensor includes:
(a) first layer, the first layer include polymeric substrates, and the polymeric substrates include UV radioactive exposure indicator；With
And
(b) second layer, the second layer include adhesive；
Wherein the UV radioactive exposure indicator is exposed to the UV radiation of the threshold dose, indicates in the UV radioactive exposure
Photochromic response is generated in agent,
Wherein the wearable UV sensor is configured to be worn on the size in people experimenter,
Wherein UV radiation includes the wave-length coverage from about 290nm to about 400nm, and the wherein wearable UV sensor
Be configured as by with application on human skin it is comparable in a manner of receive the product of application.
2. a kind of wearable UV sensor, the wearable UV sensor is used to detect the UV radiation of doses, described to wear
Wearing UV sensor includes:
(a) first layer, the first layer include polymeric substrates；And
(b) second layer, the second layer include UV radioactive exposure indicator；
Wherein the UV radioactive exposure indicator is exposed to the UV radiation of the dosage, in the UV radioactive exposure indicator
It is middle to generate photochromic response,
Wherein the wearable UV sensor is configured to be worn on the size in people experimenter, and
Wherein the UV radiation includes the wave-length coverage from about 290nm to about 400nm.
3. wearable UV sensor according to claim 2, further includes third layer, the third layer includes a certain amount of foot
So that at least part of the wearable UV sensor adheres to the adhesive of application on human skin.
4. wearable UV sensor according to claim 2, wherein the polymeric substrates include that polyethylene, high density are poly-
Ethylene, polypropylene, polyvinyl chloride, poly- (methyl methacrylate), nylon, polytetrafluoroethylene (PTFE), polyureas, gathers low density polyethylene (LDPE)
Styrene, polysiloxanes, polyacrylonitrile, its copolymer or combinations thereof.
5. wearable UV sensor according to claim 2, wherein the UV radioactive exposure indicator includes photochromic
Dyestuff, the photochromic dyes include spirooxazine, spiral shell indoline oxazines, spiro-pyrans, diarylethene, azobenzene, light-induced variable
Color quinone, inorganic photochromic material, photochromic complex or combinations thereof.
6. wearable UV sensor according to claim 3, wherein described adhesive includes solvent type adhesive, polymer
Dispersing binder, hot-melt adhesive, contact adhesive, reaction-ing adhesive, structural adhesive, epoxy adhesive, heat
Hot melt adhesive, elastomeric adhesive, elastomer contact type adhesive, melamino-formaldehyde adhesive, aerodux,
Vestopal binder, one-package adhesive, UV solidification adhesive, moisture curable adhesive, hot setting adhesive, plant amylum are viscous
Mixture, casein based adhesive, cyanoacrylate adhesive, spray adhesive, silicone based adhesive or combinations thereof.
7. wearable UV sensor according to claim 2, wherein the polymeric substrates are sensed with the wearable UV
Device exists from about 70 weight % to the concentration of about 90 weight %.
8. wearable UV sensor according to claim 2, wherein the UV radioactive exposure indicator is with described wearable
UV sensor exists from about 10 weight % to the concentration of about 30 weight %.
9. wearable UV sensor according to claim 3, wherein described adhesive is with the wearable UV sensor
Exist from about 1 weight % to the concentration of about 10 weight %.
10. wearable UV sensor according to claim 2, wherein the wearable UV sensor has ring, bracelet, wrist
The shape of band, armband, necklace, earrings, waistband, coat, cap, sunglasses or combinations thereof.
11. wearable UV sensor according to claim 2, wherein the wearable UV sensor further includes from about
0.1cm2To about 5cm2Area.
12. wearable UV sensor according to claim 2, wherein the dosage of UV radiation is threshold dose.
13. a kind of skin sensor, the skin sensor is used to detect the UV radiation of doses, the skin sensor packet
It includes:
(a) polymeric substrates, the polymeric substrates include at least one polymer and at least one UV radioactive exposure indicator；
And
(b) adhesive,
Wherein the skin sensor is exposed to the UV radiation of the dosage, generates light-induced variable in the polymeric substrates
Colour response,
Wherein the skin sensor is configured to be worn on the size in people experimenter,
Wherein the UV radiation includes the wave-length coverage from about 290nm to about 400nm.
14. skin sensor according to claim 13, wherein at least one polymer is selected from by polyethylene, highly dense
It spends polyethylene, low density polyethylene (LDPE), polypropylene, polyvinyl chloride, poly- (methyl methacrylate), nylon, polytetrafluoroethylene (PTFE), gather
The group of urea, polystyrene, polysiloxanes, polyacrylonitrile and its copolymer composition.
15. skin sensor according to claim 13, wherein at least one UV radioactive exposure indicator includes light
Cause chromotropic dye, the photochromic dyes include spirooxazine, spiral shell indoline oxazines, spiro-pyrans, diarylethene, azobenzene,
Photochromic quinone, inorganic photochromic material, photochromic complex or combinations thereof.
16. skin sensor according to claim 13, wherein described adhesive includes solvent type adhesive, polymer point
Dissipate adhesive, hot-melt adhesive, contact adhesive, reaction-ing adhesive, structural adhesive, epoxy adhesive, hot melt
Property adhesive, elastomeric adhesive, elastomer contact type adhesive, melamino-formaldehyde adhesive, aerodux, poly-
Ester resin binder, one-package adhesive, UV solidification adhesive, moisture curable adhesive, hot setting adhesive, plant amylum bonding
Agent, casein based adhesive, cyanoacrylate adhesive, spray adhesive, silicone based adhesive or combinations thereof.
17. skin sensor according to claim 13, wherein at least one polymer is with the polymeric substrates
From about 70 weight % to the concentration of about 90 weight % exist.
18. skin sensor according to claim 13, wherein the UV radioactive exposure indicator is with the polymer matrix
Bottom exists from about 10 weight % to the concentration of about 30 weight %.
19. skin sensor according to claim 13, wherein described adhesive is with the skin sensor from about 1 weight
The concentration for measuring % to about 10 weight % exists.
20. skin sensor according to claim 13, wherein the skin sensor further includes from about 0.1cm2To about
5cm2Area.
21. skin sensor according to claim 13, wherein the dosage of UV radiation is threshold dose.
22. a kind of method for sensing the UV radioactive exposure of doses, which comprises
(a) the wearable UV sensor including polymeric substrates and UV radioactive exposure indicator is provided；
(b) UV that the wearable UV sensor is exposed at least dose is radiated, to form the wearable of postdose
UV sensor；And
(c) the photochromic sound that the wearable UV sensor of the postdose radiates the UV of at least dose is measured
It answers, to sense the UV radioactive exposure of the dosage,
Wherein the photochromic response is by including causing from about 290nm to the exposure that the UV of the wavelength of about 400nm is radiated.
23. according to the method for claim 22, wherein the wearable UV sensor of the measurement postdose is to described
The photochromic response of at least UV radiation of dose with the UV radioactive exposure for sensing the dosage further includes
The photochromic response is compared with the chart for including the photochromic response of UV reconditioning.
24. according to the method for claim 22, wherein the wearable UV sensor further includes adhesive.
25. according to the method for claim 24, wherein the method also includes being applied to the wearable UV sensor
Skin contacts the skin along with described adhesive layer.
26. according to the method for claim 22, wherein the polymeric substrates include polyethylene, it is high density polyethylene (HDPE), low
Density polyethylene, polypropylene, polyvinyl chloride, poly- (methyl methacrylate), nylon, polytetrafluoroethylene (PTFE), polyureas, polystyrene,
Polysiloxanes, polyacrylonitrile, its copolymer or combinations thereof.
27. according to the method for claim 24, wherein described adhesive includes solvent type adhesive, polymer dispersion adhesive
Agent, hot-melt adhesive, contact adhesive, reaction-ing adhesive, structural adhesive, epoxy adhesive, hot melt adhesive
Agent, elastomeric adhesive, elastomer contact type adhesive, melamino-formaldehyde adhesive, aerodux, polyester resin
Adhesive, one-package adhesive, UV solidification adhesive, moisture curable adhesive, hot setting adhesive, plant amylum adhesive, junket
Albumen based adhesive, cyanoacrylate adhesive, spray adhesive, silicone based adhesive or combinations thereof.
28. according to the method for claim 22, wherein at least one UV radioactive exposure indicator includes photochromic
Dyestuff, the photochromic dyes include spirooxazine, spiral shell indoline oxazines, spiro-pyrans, diarylethene, azobenzene, light-induced variable
Color quinone, inorganic photochromic material, photochromic complex or combinations thereof.
29. according to the method for claim 22, wherein the dosage of UV radiation is threshold dose.
30. a kind of method for determining the radiation proof size of UV of the product applied, which comprises
(a) provide includes polymeric substrates, UV radioactive exposure indicator and the optionally wearable UV sensor of adhesive phase；
(b) product of the application of the first amount is contacted to the surface of the wearable UV sensor to the sensing for generating contact
Device surface；
(c) UV that the sensor surface of the contact is exposed to the first dosage is radiated, to form the sensor surface of postdose,
Wherein described be exposed on the sensor surface of the postdose leads to photochromic variation；And
(d) the photochromic variation of the measurement relative to reference, with the UV radiation protection of the product of the determination application
The size,
Wherein the UV radiation of first dosage includes the wave-length coverage from about 290nm to about 400nm.
31. according to the method for claim 30, wherein the reference include (i) do not contacted with the product of the application and
(ii) it is exposed to the identical or other wearable UV sensing of the UV radiation of first dosage or the UV radiation of phase dosing
The photochromic variation on the surface of device.
32. according to the method for claim 30, wherein the reference includes that (i) and the product of the application of the second amount connect
Identical or in addition wearable touching and that (ii) is exposed to the UV radiation of first dosage or the UV of phase dosing is radiated
The photochromic variation on the surface of UV sensor, second amount are more or less than first amount.
33. according to the method for claim 30, wherein the reference include be exposed to first dosage UV radiation or
The chart of the photochromic variation on the surface of the identical or other wearable UV sensor of the UV radiation of phase dosing.
34. according to the method for claim 30, wherein the wearable UV sensor includes the optional adhesive phase,
And the method also includes the wearable UV sensor is applied to skin, the skin is contacted along with described adhesive layer
Skin.
35. according to the method for claim 30, wherein the polymeric substrates include polyethylene, it is high density polyethylene (HDPE), low
Density polyethylene, polypropylene, polyvinyl chloride, poly- (methyl methacrylate), nylon, polytetrafluoroethylene (PTFE), polyureas, polystyrene,
Polysiloxanes, polyacrylonitrile, its copolymer or combinations thereof.
36. according to the method for claim 30, wherein described adhesive includes solvent type adhesive, polymer dispersion adhesive
Agent, hot-melt adhesive, contact adhesive, reaction-ing adhesive, structural adhesive, epoxy adhesive, hot melt adhesive
Agent, elastomeric adhesive, elastomer contact type adhesive, melamino-formaldehyde adhesive, aerodux, polyester resin
Adhesive, one-package adhesive, UV solidification adhesive, moisture curable adhesive, hot setting adhesive, plant amylum adhesive, junket
Albumen based adhesive, cyanoacrylate adhesive, spray adhesive, silicone based adhesive or combinations thereof.
37. according to the method for claim 30, wherein at least one UV radioactive exposure indicator includes photochromic
Dyestuff, the photochromic dyes include spirooxazine, spiral shell indoline oxazines, spiro-pyrans, diarylethene, azobenzene, light-induced variable
Color quinone, inorganic photochromic material, photochromic complex or combinations thereof.
38. a kind of system that the UV for sensing at least dose is radiated, the system comprises:
(a) at least one skin sensor, the skin sensor include polymeric substrates, at least one UV radioactive exposure instruction
Agent and adhesive；And
(b) include UV dose of radiation response chart,
Wherein at least one skin sensor is configured as radiating when progress in the UV of the sensing at least dose
Photochromic response,
Wherein the UV radiation includes the wavelength from about 290nm to about 400nm, and
Wherein at least one skin sensor is configured to be worn on the size in people experimenter.
39. the system according to claim 38, wherein the polymeric substrates include polyethylene, it is high density polyethylene (HDPE), low
Density polyethylene, polypropylene, polyvinyl chloride, poly- (methyl methacrylate), nylon, polytetrafluoroethylene (PTFE), polyureas, polystyrene,
Polysiloxanes, polyacrylonitrile, its copolymer or combinations thereof.
40. the system according to claim 38, wherein at least one UV radioactive exposure indicator includes photochromic
Dyestuff, the photochromic dyes include spirooxazine, spiral shell indoline oxazines, spiro-pyrans, diarylethene, azobenzene, light-induced variable
Color quinone, inorganic photochromic material, photochromic complex or combinations thereof.
41. the system according to claim 38, wherein described adhesive includes solvent type adhesive, polymer dispersion adhesive
Agent, hot-melt adhesive, contact adhesive, reaction-ing adhesive, structural adhesive, epoxy adhesive, hot melt adhesive
Agent, elastomeric adhesive, elastomer contact type adhesive, melamino-formaldehyde adhesive, aerodux, polyester resin
Adhesive, one-package adhesive, UV solidification adhesive, moisture curable adhesive, hot setting adhesive, plant amylum adhesive, junket
Albumen based adhesive, cyanoacrylate adhesive, spray adhesive, silicone based adhesive or combinations thereof.
42. the system according to claim 38, wherein at least one polymeric substrates can be worn at least one
That wears UV sensor exists from about 50 weight % to the concentration of about 90 weight %.
43. the system according to claim 38, wherein UV exposure indicator is passed with the wearable UV of at least one
Sensor exists from about 1 weight % to the concentration of about 10 weight %.
44. the system according to claim 38, wherein described adhesive is at least one wearable UV sensor
Exist from about 1 weight % to the concentration of about 10 weight %.
45. the system according to claim 38, wherein at least one skin sensor may include transcutaneous sensor,
The transcutaneous sensor includes ring, bracelet, wrist strap, armband, necklace, earrings, waistband, coat, cap, sunglasses or combinations thereof
Shape.
46. the system according to claim 38, wherein at least one skin sensor further includes from about 0.1cm2To about
5cm2Area.
47. system according to claim 35, wherein UV dose of radiation response includes color gradient, wherein the face
Color gradient corresponds to the photochromic response of UV reconditioning.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762549859P | 2017-08-24 | 2017-08-24 | |
| US62/549,859 | 2017-08-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109425428A true CN109425428A (en) | 2019-03-05 |
Family
ID=65513729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711347280.3A Pending CN109425428A (en) | 2017-08-24 | 2017-12-15 | Wearable UV exposure sensor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109425428A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI810669B (en) * | 2020-10-05 | 2023-08-01 | 日商花王股份有限公司 | Adhesive sheet for skin, method of use, ultraviolet detection method, and ultraviolet protection performance evaluation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6130435A (en) * | 1998-03-20 | 2000-10-10 | Rocklin; Erik P. | Apparatus and method for measuring the effectiveness of a sunscreen composition |
| CN201090973Y (en) * | 2007-09-17 | 2008-07-23 | 黄志勤 | Transfer printing structure capable of detecting and displaying ultraviolet light intensity |
| CN202075232U (en) * | 2011-05-24 | 2011-12-14 | 李霓虹 | Indicator used for detecting sunscreen |
| CN106974422A (en) * | 2016-01-19 | 2017-07-25 | 联妤生化科技有限公司 | Light sensation makeup module |
-
2017
- 2017-12-15 CN CN201711347280.3A patent/CN109425428A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6130435A (en) * | 1998-03-20 | 2000-10-10 | Rocklin; Erik P. | Apparatus and method for measuring the effectiveness of a sunscreen composition |
| CN201090973Y (en) * | 2007-09-17 | 2008-07-23 | 黄志勤 | Transfer printing structure capable of detecting and displaying ultraviolet light intensity |
| CN202075232U (en) * | 2011-05-24 | 2011-12-14 | 李霓虹 | Indicator used for detecting sunscreen |
| CN106974422A (en) * | 2016-01-19 | 2017-07-25 | 联妤生化科技有限公司 | Light sensation makeup module |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI810669B (en) * | 2020-10-05 | 2023-08-01 | 日商花王股份有限公司 | Adhesive sheet for skin, method of use, ultraviolet detection method, and ultraviolet protection performance evaluation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2009186486A (en) | Integrating ultraviolet exposure detection device | |
| US6060321A (en) | Sun tan dosimeter | |
| CN105828766B (en) | Absorbent article including one or more colored regions | |
| FI85644B (en) | OEGONSKYDD. | |
| US20210259940A1 (en) | Ultraviolet Indicators, Formulations, and Suncare Kits Comprising the Same | |
| US20030008409A1 (en) | Method and apparatus for determining sunlight exposure | |
| US20100268112A1 (en) | Thermocromatic patch for monitoring/detecting body temperature | |
| CA2616459A1 (en) | Ultra violet radiation monitoring device and a method of using the same | |
| CN109425428A (en) | Wearable UV exposure sensor | |
| EP2252867A2 (en) | Disposable measuring device for uv radiation | |
| US20070269496A1 (en) | Patch for Reducing Exposure of Skin to Ultraviolet Radiation | |
| US20070010776A1 (en) | Cosmetic bandage | |
| WO2005014085A2 (en) | Cosmetic bandage | |
| US20210156739A1 (en) | Wearable UV Exposure Sensor | |
| JP2019510235A (en) | Method and apparatus for detection of exposure to ultraviolet light | |
| CN212394090U (en) | Intelligent girdle band and bracelet | |
| US20130131540A1 (en) | Thermocromatic patch for monitoring/detecting body temperature | |
| WO2013177112A1 (en) | Thermocromatic patch for monitoring/detecting body temperature | |
| JP2002122476A (en) | Device for measuring amount of exposure to ultraviolet radiation | |
| US20220257915A1 (en) | Skin Protection Device | |
| JP7166877B2 (en) | absorbent article | |
| CN203234895U (en) | Hydrogel laser eye protection pad | |
| RU2107266C1 (en) | Personal ultraviolet radiation dosimeter | |
| CN115597709A (en) | Real-time naked eye ultraviolet monitoring patch suitable for different skin colors and preparation method thereof | |
| CN108904301A (en) | Containing the cosmetics for being soaked with the cosmetic composition with anti-ultraviolet function on water-insoluble sponge |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190305 |