CN109423171A - A kind of production method of no benzene paint - Google Patents

A kind of production method of no benzene paint Download PDF

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Publication number
CN109423171A
CN109423171A CN201710584729.1A CN201710584729A CN109423171A CN 109423171 A CN109423171 A CN 109423171A CN 201710584729 A CN201710584729 A CN 201710584729A CN 109423171 A CN109423171 A CN 109423171A
Authority
CN
China
Prior art keywords
paint
stirred
benzene
heated
container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710584729.1A
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Chinese (zh)
Inventor
蒋卫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710584729.1A priority Critical patent/CN109423171A/en
Publication of CN109423171A publication Critical patent/CN109423171A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/547Hydroxy compounds containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of production methods of no benzene paint, it is characterized in that 8-12% maleic anhydride, 10-15% phthalic anhydride and 10-16%1,2-- propylene glycol are placed on a container for stirring first, it is heated to 50-80 DEG C, until being completely dissolved, then 1-3% ethylene glycol, 0.5-1% hydroquinone 35-47% polyester resin and 25-30% aromatic solvent naphtha are placed in another container and are stirred, it is heated to 50-100 DEG C, two kinds of solution are stirred at room temperature uniformly again, are then added in grinder and are ground.The paint paint film that the present invention makes is plentiful, and adhesive force is strong.Evaporation rate is moderate, using that will not pollute to the mankind and environment, has environment-friendly function.

Description

A kind of production method of no benzene paint
Technical field
The present invention relates to a kind of production methods of no benzene paint.
Background technique
Current many organic paints are wide in variety, widely used, and existing organic paints use benzene mostly in process of production Solvent, benzene content would seriously pollute the environment in this way 70% or so, influence human health in paint.
Summary of the invention
The object of the invention is in order to overcome the above-mentioned deficiencies of the prior art, provide, a kind of composition is simple, is formulated and closes Reason, reliable performance, the production method of no benzene paint free of contamination to environment and the mankind.
In order to achieve the above objectives, the present invention is realized by the following method:
A kind of production method of environment protection oil paint, it is characterised in that first by 8-12% maleic anhydride, 10-15% adjacent benzene two Formic anhydride and 10-16% 1,2- propylene glycol are placed on a container for stirring, are heated to 50-80 DEG C, until being completely dissolved, then 1-3% ethylene glycol, 0.5-1% hydroquinone 35-47% polyester resin and 25-30% aromatic solvent naphtha are placed on another appearance It is stirred in device, is heated to 50-100 DEG C, then two kinds of solution are stirred at room temperature uniformly, be then added in grinder and carry out Grinding.
The present invention replaces benzene solvent with aromatic solvent naphtha, and boiling point is close to benzene solvent, but it is free of benzene,toluene,xylene. Production and use will not pollute the mankind and environment, have environment-friendly function.Aromatic solvent naphtha of the present invention can be used for producing Column organic paints.
Specific embodiment
Embodiment 1:
1, a container for stirring is placed on by 8kg maleic anhydride, 10kg phthalic anhydride and 10kg 1,2- propylene glycol, It is heated to 50 DEG C.Until being completely dissolved.
2,1.5kg ethylene glycol, 0.3kg hydroquinone 40.2kg polyester resin and 30kg aromatic solvent naphtha are placed on another It is stirred in a container, is heated to 80 DEG C.
3, two kinds of solution for obtaining process flow 1,2 are stirred at room temperature uniformly, are then added in grinder and are ground Mill.
4, finally the mixing liquid that process flow 3 obtains is packed.
The technical process of this environment protection oil paint production and traditional paint are essentially identical, its main feature is that by aromatic solvent naphtha generation For benzene solvent, aromatic solvent naphtha is refined by anphtha distillation, wherein being free of benzene,toluene,xylene.The paint paint film of production is rich Full, adhesive force is strong.Evaporation rate is moderate, using that will not pollute to the mankind and environment, has environment-friendly function.
Embodiment 2:
1, it is placed in a container and is stirred by 12kg maleic anhydride, 13kg phthalic anhydride and 16kg 1,2- propylene glycol It mixes, is heated to 50 DEG C.Until being completely dissolved.
2,2kg ethylene glycol, 1kg hydroquinone 37kg polyester resin and 25kg aromatic solvent naphtha are placed on another container In be stirred, be heated to 80 DEG C.
3, two kinds of solution for obtaining process flow 1,2 are stirred at room temperature uniformly, are then added in grinder and are ground Mill.
4, finally the mixing liquid that process flow 3 obtains is packed.

Claims (1)

1. a kind of production method of no benzene paint, it is characterised in that first by 8-12% maleic anhydride, the adjacent benzene of 10- 15% Dicarboxylic acid anhydride and 10-16%1,2-- propylene glycol are placed on a container for stirring, are heated to 50-80 DEG C, until being completely dissolved, so 1-3% ethylene glycol, 47% polyester resin of 0.5-1% hydroquinone 35- and 25-30% aromatic solvent naphtha are placed on another afterwards Be stirred in container, be heated to 50-100 DEG C, then two kinds of solution are stirred at room temperature uniformly, then be added grinder in into Row grinding.
CN201710584729.1A 2017-07-18 2017-07-18 A kind of production method of no benzene paint Pending CN109423171A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710584729.1A CN109423171A (en) 2017-07-18 2017-07-18 A kind of production method of no benzene paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710584729.1A CN109423171A (en) 2017-07-18 2017-07-18 A kind of production method of no benzene paint

Publications (1)

Publication Number Publication Date
CN109423171A true CN109423171A (en) 2019-03-05

Family

ID=65497624

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710584729.1A Pending CN109423171A (en) 2017-07-18 2017-07-18 A kind of production method of no benzene paint

Country Status (1)

Country Link
CN (1) CN109423171A (en)

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WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190305