CN109422440A - A kind of innoxious drying device and method of sulfur-bearing sludge - Google Patents

A kind of innoxious drying device and method of sulfur-bearing sludge Download PDF

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Publication number
CN109422440A
CN109422440A CN201710731950.5A CN201710731950A CN109422440A CN 109422440 A CN109422440 A CN 109422440A CN 201710731950 A CN201710731950 A CN 201710731950A CN 109422440 A CN109422440 A CN 109422440A
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CN
China
Prior art keywords
sulfur
gas
bearing sludge
sludge
bearing
Prior art date
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Pending
Application number
CN201710731950.5A
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Chinese (zh)
Inventor
张分电
王红宾
吴明畏
李代柏
吴红旗
冯逍
张功臣
张广晶
王贵波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Sinopec Zhongyuan Oilfield Co Puguang Branch
Original Assignee
China Petroleum and Chemical Corp
Sinopec Zhongyuan Oilfield Co Puguang Branch
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Publication date
Application filed by China Petroleum and Chemical Corp, Sinopec Zhongyuan Oilfield Co Puguang Branch filed Critical China Petroleum and Chemical Corp
Priority to CN201710731950.5A priority Critical patent/CN109422440A/en
Publication of CN109422440A publication Critical patent/CN109422440A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Treatment Of Sludge (AREA)
  • Drying Of Solid Materials (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of innoxious drying device of sulfur-bearing sludge and methods.The drying device includes the sulfur-bearing sludge heating device being linked in sequence, to the condensing unit that sulfur-bearing sludge adds thermogenetic gas to be condensed, and condensation Flash Gas Compression Skid System.The innoxious drying device of sulfur-bearing sludge of the invention carries out gas-liquid separation by the gas that condensing unit generates heating device, to effectively remove the vapor and part sulfurous gas in dry gas, improves the treatment effeciency of subsequent condensation gas sulphur removal process;Condensing gas sulphur-containing substance concentration is high, after simply removing sulphuring treatment, can conveniently reach discharge standard.

Description

A kind of innoxious drying device and method of sulfur-bearing sludge
Technical field
The invention belongs to the process fields of sludge, and in particular to a kind of innoxious drying device and method of sulfur-bearing sludge.
Background technique
Sludge is the waste generated in wastewater treatment process, dirty containing a large amount of bacterium, chemical agent residue and moisture Mud can generate corruption during storage, form stench, pollute environment.The sulfur-bearing sludge generated in sulfur Gas Fields water treatment procedure Also containing impurity such as a large amount of elemental sulfurs, sulfated polymers, processing difficulty is big, treatment process degree of danger is high.
Currently, mainly pass through filter press is pressed into mud cake for sludge to sulfur-bearing Treatment of Sludge, then transhipment is handled, due to mud cake Moisture content is higher, and containing poisonous and harmful substances such as corrosion inhibiter, retarder, coagulant, elemental sulfurs, there is dirt in transport process Leaked water, the risk of the hazardous gases such as hydrogen sulfide, sulfur dioxide evolution are easy to cause the things such as environmental pollution, personnel's poisoning, explosion Therefore occur.
The patent that application publication number is CN106746468A discloses a kind of sludge treating system and treatment process.The technique Sludge is stablized into shale quality through sludge concentration tank first, enters sludge conditioning pond later by conditioner and adds carry out sludge Broken wall, then entering high-pressure machinery plate and frame filter press filters pressing to moisture content is 55%~60%, and it is dry to subsequently enter drying sludge furnace Dry to water content is 10% hereinafter, the sludge after dry prepares charcoal through charing again.
In the treatment process of sludge, the drying of sludge is important link, by drying sludge to moisture content be 10% hereinafter, It not only contributes to improve the safety of operation process, is also conducive to improve the efficiency of subsequent burning process.The toxic of sulfur-bearing sludge has Evil content of material is higher, and the prior art lacks a kind of innoxious dry technology of sulfur-bearing sludge.
Summary of the invention
The purpose of the present invention is to provide a kind of innoxious drying devices of sulfur-bearing sludge, to solve the nothing of sulfur-bearing sludge Evilization dries problem.Present invention simultaneously provides a kind of innoxious drying means of sulfur-bearing sludge.
To achieve the above object, the technical solution of the innoxious drying device of sulfur-bearing sludge of the invention is:
A kind of innoxious drying device of sulfur-bearing sludge, the sulfur-bearing sludge heating device including sequential connection, to sulfur-bearing dirt The condensing unit that mud adds thermogenetic gas to be condensed, and condensation Flash Gas Compression Skid System.
The innoxious drying device of sulfur-bearing sludge of the invention is carried out by the gas that condensing unit generates heating device Gas-liquid separation improves the place of subsequent condensation gas sulphur removal process to effectively remove the vapor and part sulfurous gas in dry gas Manage efficiency;Condensing gas sulphur-containing substance concentration is high, after simply removing sulphuring treatment, can conveniently reach discharge standard.
The condensing unit includes the drainer being arranged inside and outside and circulation water pot, has between drainer and circulation water pot and supplies The circulation passage of cooling medium circulation, drainer are connected with the sulfur-bearing sludge heating device.Using the condensation of this kind of form Device, structure is simple, cost of layout is low, condensation effect is good, drainer and circulation can be adjusted flexibly according to condensing gas process demand Water tank capacity.
Preferably, the drainer is also connected with condensing hot air furnace tank, condensing hot air furnace tank and condensation Flash Gas Compression Skid System it Between be connected with for the gas in condensed water recycling can be discharged into condensation Flash Gas Compression Skid System connecting pipe.
Preferably, multiple baffles are equipped at intervals with along length of tank direction in drainer, baffle top and opposed inner walls face it Between the interval flowed through of gas that is generated with supplying/heating system, the two neighboring drainer two sides that are spaced in are oppositely arranged to form confession The U-shaped channel that the gas that heating device generates passes through drainer.U-shaped channel is constituted using the baffle of this kind of form, gas can be increased Condensation time and heat exchange area of the body in drainer improve condensation effect.
It is described condensation Flash Gas Compression Skid System include be linked in sequence lye in and device and activated carbon adsorption device.Pass through this kind The condensation Flash Gas Compression Skid System of combination can effectively remove sulfurous gas and other toxic and harmful gas in condensing gas, through handling Gas afterwards is much higher than national emission standard.
The connecting pipe of sulfur-bearing sludge heating device and condensing unit is equipped with for detecting the wet of sulfur-bearing moisture percentage in sewage sludge Spend detection device.The nitrogen that sulfur-bearing sludge heating device includes heating tank and purged for being passed through nitrogen into heating tank Tank.Nitrogen purging is carried out to heating tank by setting nitrogen gas tank, can effectively displace remaining toxic and harmful gas in heating tank, Further promote operational security.
The sulfur-bearing sludge heating device includes heating tank and the sludge barrel in heating tank.The sulfur-bearing of this kind of form is dirty Mud heating device, structure is simple, and sludge barrel is easy to change.
In the connecting pipe of the sulfur-bearing sludge heating device and condensing unit and outlet of condensation Flash Gas Compression Skid System is equipped with Gas-detecting device.Whether the gas that gas-detecting device is used to detect in drying device reaches discharge standard.
The technical solution of the innoxious drying means of sulfur-bearing sludge of the invention is:
A kind of innoxious drying means of sulfur-bearing sludge, comprising the following steps: by sulfur-bearing sludge heat drying, heat drying The gas of generation separates condensed water and condensing gas after condensation process, puts to condensation gas disposal heel row.
The innoxious drying means of sulfur-bearing sludge provided by the invention by the heat drying to sulfur-bearing sludge, and will add The gas (dry gas) that heated drying generates separates condensed water and condensing gas through condensation process, steams to effectively remove the water in dry gas Gas and part aqueous ingredient improve the treatment effeciency of subsequent condensation gas sulphur removal process;Condensing gas sulphur-containing substance concentration is high, through letter After list removes sulphuring treatment, it can conveniently reach discharge standard.The innoxious drying means of the sulfur-bearing sludge, the processing to sulfur-bearing sludge High-efficient, high treating effect can effectively avoid the environmental pollution occurred during sulfur-bearing drying sludge, personnel's poisoning and explosion wind Danger, operation safe operation process, convenient.
In the innoxious drying means of above-mentioned sulfur-bearing sludge, sulfur-bearing sludge heat drying to moisture content is not higher than 10% Afterwards, nitrogen is passed through into system to be purged, to displace remaining toxic and harmful gas in system.
The condensation is that the gas for generating heat drying is condensed to 30 DEG C or less.
In the innoxious drying means of above-mentioned sulfur-bearing sludge, the processing to condensing gas includes successively carrying out lye neutralisation treatment It is handled with activated carbon adsorption.The sulfurous gas in condensing gas can be effectively removed by this kind of combination progress sulphur removal has with other Malicious pernicious gas, gas after processing are much higher than national emission standard.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the innoxious drying device of the sulfur-bearing sludge of the first embodiment of the present invention;
Fig. 2 is the structural schematic diagram of the innoxious drying device of the sulfur-bearing sludge of the second embodiment of the present invention;
Fig. 3 is the structural schematic diagram of the innoxious drying device of the sulfur-bearing sludge of the third embodiment of the present invention.
Specific embodiment
Embodiments of the present invention are described further with reference to the accompanying drawing.
The embodiment of the innoxious drying device of sulfur-bearing sludge of the invention, structural schematic diagram is as shown in Figure 1, include sequence Sulfur-bearing sludge heating device 1, condensing unit 2 and the condensation Flash Gas Compression Skid System 3 of connection, sulfur-bearing sludge heating device 1 includes heating Tank 101 and nitrogen gas tank 105, heating tank 101 is interior to be equipped with sludge barrel 102, and heating tank 101 includes the tank body and cover board of sealing cooperation, Partition is equipped in tank body, tank inner chamber is separated into heating chamber 103 and superposed sludge barrel positioned at lower part by the partition Accommodating cavity has gap between sludge barrel and tank body, the gap, which is formed, accommodates the gas space that heat drying process generates gas Between;Nitrogen gas tank 105 is connected by connecting line with the gas compartment of sulfur-bearing sludge heating device, and connecting line is equipped with first Valve 104.
Condensing unit 2 includes the drainer 204 being arranged inside and outside, circulation water pot 201, the clear water being arranged in parallel with circulation water pot Tank 203, and the condensing hot air furnace tank 209 being arranged in parallel with drainer 204;Drainer 204 is dirty by connecting pipe and sulfur-bearing The gas compartment of mud heating device is connected, and connecting pipe is equipped with humidity detector 106, the second valve 107 and the first gas Physical examination side valve door 108;Multiple baffles, baffle top and opposed inner walls face are equipped at intervals with along length of tank direction in drainer 204 Between there is the gap crossed for dry gas stream, the two neighboring drainer two sides that are spaced in are oppositely arranged to form supplying/heating system production The U-shaped channel that raw gas passes through drainer;The bottom of drainer is connected with multiple for the condensed water of formation to be discharged into condensation The drainpipe of water recovery tank 209, drainpipe are equipped with third valve 208, the top of condensing hot air furnace tank 209 by exhaust pipe with Condensation Flash Gas Compression Skid System 3 is connected, and exhaust pipe is equipped with the 4th valve 305.Clean water tank 203 passes through outlet pipe and water inlet pipe and follows Ring water pot 201 is connected, and water pump 202 and the 5th valve 205 are in series on outlet pipe, and water inlet pipe is equipped with the 6th valve 206;It is cold There is gap, the gap forms recirculated water together with clean water tank 203 and its inlet and outlet pipes and follows between solidifying tank 204, circulation water pot 201 Ring flow channel.
Condensation Flash Gas Compression Skid System includes the gas vent of drainer in lye and device 301 and activated carbon adsorption device 302 It is connected with the entrance in lye with device by connecting pipe, connecting pipe is equipped with the 7th valve 207;In lye and device 301 are connected with activated carbon adsorption device 302 by connecting pipe, and connecting pipe is equipped with the 8th valve 303, activated carbon adsorption The outlet of device is equipped with second gas detection valve 306 and emptying valve 304.
The course of work of the innoxious drying device of the sulfur-bearing sludge of the present embodiment is as follows: filling the sludge barrel of sulfur-bearing sludge The heat drying in heating tank, until moisture content be lower than 10%, heat drying process generate drying gas by connecting pipe into Enter drainer, dry gas carries out heat exchange with outer loop water in the serpentine channel of drainer, and dry air cooling is coagulated to 30 DEG C Hereinafter, condensed water caused by condensing enters condensing hot air furnace tank, the gas and condensing gas in condensing hot air furnace tank enter condensation Flash Gas Compression Skid System carries out sulphur removal, and condensing gas is neutralized through lye, after activated carbon adsorption processing, after gas detection meets discharge standard Emptying discharge;After the moisture content of sulfur-bearing sludge after detection is up to standard, nitrogen is passed through into drying device from nitrogen gas tank and is purged, To displace remaining toxic and harmful gas in drying device, discharged after gas detection meets discharge standard.
In the other embodiments of the drying device of sulfur-bearing sludge of the invention, other shapes are can be used in sulfur-bearing sludge heating device Formula is such as not provided with partition, and arranges heater strip on the cylindrical inner wall of tank body;The shape of cooling water jecket can be used in condensing unit Formula;It can be not provided with nitrogen gas tank, and the pipeline by the way that connection compressed gas is arranged on heating tank carries out the gas in heating tank Purging displacement (as shown in Figure 2);It can be not provided with condensing hot air furnace tank, it can (as shown in Figure 3) to the processing of condensed water centralized collection; Condensing Flash Gas Compression Skid System can be individually using lye absorption or activated carbon adsorption, other, which can also be used, can remove the dress of sulfurous gas It sets.
Above-mentioned drying device is that sulfur-bearing sludge is dried using following drying means, comprising: heats sulfur-bearing sludge Dry, the gas that heat drying generates separates condensed water and condensing gas after condensation process, puts to condensation gas disposal heel row.
Condensation process coagulates dry air cooling to 30 DEG C hereinafter, successively carrying out at lye neutralisation treatment and activated carbon adsorption again Reason can effectively remove sulfurous gas and other toxic and harmful gas in condensing gas.Sulfur-bearing sludge after drying it is poisonous and harmful Substance largely reduces, and effectively prevents environmental pollution, personnel's poisoning and risk of explosion.

Claims (10)

1. a kind of innoxious drying device of sulfur-bearing sludge, which is characterized in that the sulfur-bearing sludge heating device including sequential connection, To the condensing unit that sulfur-bearing sludge adds thermogenetic gas to be condensed, and condensation Flash Gas Compression Skid System.
2. the innoxious drying device of sulfur-bearing sludge as described in claim 1, which is characterized in that the condensing unit includes interior The drainer and circulation water pot of outer setting, have the circulation passage for condensing flow of media between drainer and circulation water pot, cold Solidifying tank is connected with the sulfur-bearing sludge heating device.
3. the innoxious drying device of sulfur-bearing sludge as claimed in claim 2, which is characterized in that the drainer is also connected with Condensing hot air furnace tank is connected between condensing hot air furnace tank and condensation Flash Gas Compression Skid System and is discharged into for the gas in condensed water recycling can Condense the connecting pipe of Flash Gas Compression Skid System.
4. the innoxious drying device of sulfur-bearing sludge as claimed in claim 2, which is characterized in that along length of tank in drainer Direction is equipped at intervals with multiple baffles, between the gas generated between baffle top and opposed inner walls face with supplying/heating system flows through Every the two neighboring drainer two sides that are spaced in are oppositely arranged to form the U-shaped that the gas of supplying/heating system generation passes through drainer Channel.
5. the innoxious drying device of sulfur-bearing sludge as described in claim 1, which is characterized in that the condensation Flash Gas Compression Skid System In lye including sequential connection and device and activated carbon adsorption device.
6. the innoxious drying device of sulfur-bearing sludge as described in claim 1, which is characterized in that sulfur-bearing sludge heating device and The connecting pipe of condensing unit is equipped with the humidity detector for detecting sulfur-bearing moisture percentage in sewage sludge.
7. the innoxious drying device of sulfur-bearing sludge as described in claim 1 or 6, which is characterized in that sulfur-bearing sludge heating dress The nitrogen gas tank set including heating tank and purged for being passed through nitrogen into heating tank.
8. a kind of innoxious drying means of sulfur-bearing sludge, which comprises the following steps: heat sulfur-bearing sludge dry Dry, the gas that heat drying generates separates condensed water and condensing gas after condensation process, puts to condensation gas disposal heel row.
9. the innoxious drying means of sulfur-bearing sludge as claimed in claim 8, which is characterized in that by sulfur-bearing sludge heat drying After being not higher than 10% to moisture content, nitrogen is passed through into system and is purged, to displace remaining poisonous and harmful gas in system Body.
10. the innoxious drying means of sulfur-bearing sludge as claimed in claim 8, which is characterized in that the processing packet of condensing gas It includes and successively carries out lye neutralisation treatment and activated carbon adsorption processing.
CN201710731950.5A 2017-08-23 2017-08-23 A kind of innoxious drying device and method of sulfur-bearing sludge Pending CN109422440A (en)

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CN201710731950.5A CN109422440A (en) 2017-08-23 2017-08-23 A kind of innoxious drying device and method of sulfur-bearing sludge

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB443452A (en) * 1933-12-02 1936-02-28 Chemical Construction Corp Production of sulphur dioxide from acid sludge
US5215670A (en) * 1990-02-26 1993-06-01 Bio Gro Systems, Inc. Process of drying and pelletizing sludge in indirect dryer having recycled sweep air
CN202237750U (en) * 2011-08-25 2012-05-30 浙江大学 Odor pollutant control system in city sludge drying process
CN207619242U (en) * 2017-08-23 2018-07-17 中国石油化工股份有限公司 A kind of innoxious drying device of sulfur-bearing sludge

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB443452A (en) * 1933-12-02 1936-02-28 Chemical Construction Corp Production of sulphur dioxide from acid sludge
US5215670A (en) * 1990-02-26 1993-06-01 Bio Gro Systems, Inc. Process of drying and pelletizing sludge in indirect dryer having recycled sweep air
CN202237750U (en) * 2011-08-25 2012-05-30 浙江大学 Odor pollutant control system in city sludge drying process
CN207619242U (en) * 2017-08-23 2018-07-17 中国石油化工股份有限公司 A kind of innoxious drying device of sulfur-bearing sludge

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
天津市跃进化工厂编: "《二甲基亚砜的制造》", vol. 1, 30 April 1973, 天津人民出版社, pages: 84 *
徐志毅主编: "《环境保护技术和设备》", vol. 1, 31 December 1999, 上海交通大学出版社, pages: 312 *

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