CN109411649A - A kind of encapsulating method of battery post - Google Patents

A kind of encapsulating method of battery post Download PDF

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Publication number
CN109411649A
CN109411649A CN201710707026.3A CN201710707026A CN109411649A CN 109411649 A CN109411649 A CN 109411649A CN 201710707026 A CN201710707026 A CN 201710707026A CN 109411649 A CN109411649 A CN 109411649A
Authority
CN
China
Prior art keywords
pole
battery
cylinder
hole
cap
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710707026.3A
Other languages
Chinese (zh)
Inventor
秦学
吕军
王丽
陶蕾
周琴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU JINYI NEW ENERGY TECHNOLOGY Co Ltd
Original Assignee
JIANGSU JINYI NEW ENERGY TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU JINYI NEW ENERGY TECHNOLOGY Co Ltd filed Critical JIANGSU JINYI NEW ENERGY TECHNOLOGY Co Ltd
Priority to CN201710707026.3A priority Critical patent/CN109411649A/en
Publication of CN109411649A publication Critical patent/CN109411649A/en
Withdrawn legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/172Arrangements of electric connectors penetrating the casing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The present invention relates to a kind of encapsulating methods of battery post, it is to realize pole (01) and cap (02) by sealing sleeve pipe (04) to seal.Battery post (01) is in screw-like, and end (09) cross section is greater than cylinder cross section.By argon arc or laser seal welding, hollow cylinder (03) aperture is greater than pole outer diameter and is less than pole end (09) cross-sectional outer diameter for the through hole of battery case cap and hollow cylinder (03).Pole (01) is inserted into the cylinder through hole on battery case cap, then compression seal casing (04), insulation spacer (05), insulating washer (06), metal washer (07) successively are assembled in pole, sealing sleeve pipe (04) sealing pole (01) and through hole are compressed by compression locking nut (08), reaches the close effect of liquid.

Description

A kind of encapsulating method of battery post
Technical field
The present invention relates to field of chemical power source, and in particular to a kind of encapsulating method of battery post.
Background technique
It in recent years, is the secondary accumulator battery of representative due to can using lithium-ions battery, nickel hydrogen storage battery and lead-acid accumulator It is recycled for multiple times with charging and has and have been widely used, obtained in fields such as consumer electronics, electric vehicle, electric tool, energy storage It is widely popularized and uses.The shape of battery is designed to cylindrical and rectangular according to application, wherein in prismatic cell In have connection the inside and outside configuration of accumulator housing pole.
All there is electrolyte in battery, lithium-ions battery uses organic electrolyte, nickel hydrogen storage battery to use Be that alkaline electrolyte, lead-acid accumulator use acidic electrolysis bath, these electrolyte are due to being liquid, in battery case It can climb and be attached to battery electrode column surface.If the sealing of cap through hole that pole is inserted into is not exclusively, battery use in long-time or During storage, climbs and be attached to the electrolyte on battery electrode column surface and can leak into outside batteries along battery electrode column and leakage occurs, make It fails at electric insulation and accident occurs.
Sealing between battery post and cap at present generally by select suitable sealant be fills up to pole with Gap between cap, and reach sealing effect, but sealing adhesiveness is big, coating filling is made troubles to production process, and Battery easily fails using with high/low temperature storage for a long time.
Summary of the invention
The purpose of the present invention is to provide a kind of inhibition electrolyte to climb the attached sealing for escaping to outside batteries along pole surface Method.
The technical scheme is that a kind of encapsulating method of battery post, it is by sealing sleeve pipe (04) by pole Column (01) and cap (02), which are realized, to be sealed.Battery post (01) is in screw-like, and end (09) cross section is greater than cylinder cross section. By argon arc or laser seal welding, hollow cylinder (03) aperture is greater than for the through hole of battery case cap and hollow cylinder (03) Pole outer diameter and be less than pole end (09) cross-sectional outer diameter.Pole (01) is inserted into the cylinder through hole on battery case cap, so Compression seal casing (04), insulation spacer (05), insulating washer (06), metal washer (07) successively are assembled in pole afterwards, is passed through It compresses locking nut (08) and compresses sealing sleeve pipe (04) sealing pole (01) and through hole, reach the close effect of liquid.
Further, compression seal casing (Fig. 2) is in the sub- shape of back taper, and sealing sleeve pipe (04) internal diameter is less than pole (01) column External diameter, material are to contain one or more of rubber, polytetrafluoroethylene (PTFE), nylon, polypropylene composite material.
Further, the surface roughness of the sealing surface of pole (01) and cap cylinder through hole is 20 μm or smaller.
The beneficial effects of the present invention are: method for sealing polar post according to the present invention, compared with the past technique is simpler, can The fluid tight of battery post is greatly improved with the synergistic action effect by each component, prevents leakage.
Detailed description of the invention
Referring to attached drawing, from following description of a preferred embodiment, above and other objects of the present invention, feature and advantage are bright Aobvious, similar appended drawing reference is for indicating similar components in attached drawing, in which:
Fig. 1 is present invention electrode column sealing assembling sectional view according to the embodiment;
Fig. 2 is present invention sealing sleeve pipe sectional view according to the embodiment.
Label declaration:
01 pole
02 battery case cap
03 hollow cylinder
04 sealing sleeve pipe
05 insulation spacer
06 insulating washer
07 metal washer
08 nut
09 pole end
Specific embodiment
(embodiment 1): it will illustrate the present embodiment referring to as the encapsulation of lithium-ions battery pole.
A. positive plate makes
By positive electrode (LiCoO in proportion2: Super P:PVDF=93:4:3) mixing, with NMP (NMP: solid matter Weight=810:1500) it is mixed, anode sizing agent viscosity is controlled in 6000cps.Anode sizing agent is uniformly coated in Aluminium foil surface, drying roll, are cropped to the technological parameter of design and be fabricated to positive plate.
B. negative electrode tab makes
Negative electrode material is mixed in proportion (C:Super P:SBR:CMC=94:1:2.5:2.5), with H2O(H2O: solids Matter weight=1600:1420) it is mixed, negative electrode slurry viscosity is controlled in 5000~6000cps.Negative electrode slurry is uniform Be coated in copper foil surface, drying rolls, is cropped to the technological parameter of design and be fabricated to negative electrode tab.
C. electrolyte configures
By LiPF6, EC (ethylene carbonate), EMC (methyl ethyl carbonate), EB (ethyl butyrate) and toluene mixing, be made LiPF6Organic solution, when mixing, contain solute 1.0molLiPF according to every liter of electrolyte6;Solvent EC percent by volume 60%, EMC percent by volume is 40%.
D. the assembling of lithium ion battery
By the positive plate, diaphragm, negative electrode tab of acquisition in such a way that diaphragm is between positive plate and negative electrode tab helical form Ground winds poling group, pole group is welded on pole using ultrasonic welding method, pole is assembled into cubic battery body, pole side Into the cylinder through hole being inserted on battery case cap, compression seal casing, insulating washer, metal successively then are assembled in pole Washer compresses sealing sleeve pipe by compression locking nut and seals pole and through hole, then by rectangular 10Ah battery cover board and electricity The sealing of pond shell, configured electrolyte is then injected into battery case, that is, completes the assembling of lithium ion battery.
E. the chemical conversion of battery and the test of cycle performance
Fertilizer alleviant:
A) 0.2C electric current constant-current charge turns 4.2V constant-voltage charge to electric current 0.01C to 4.2V
B) 30min is shelved
C) 0.5C constant-current discharge is to 2.75V
D) 0.2C electric current constant-current charge turns 4.2V constant-voltage charge to electric current 0.01C to 4.2V
E) 30min is shelved
F) 1C constant-current discharge is to 2.75V
Loop test system:
Charging: electric discharge state battery is turned into 4.2V constant-voltage charge to electricity with 1C electric current constant-current charge to 4.2V under normal temperature environment Flow 0.01C.
Electric discharge: by battery with 1C electric current constant-current discharge to 2.75V, discharge capacity is recorded, monitors pole leakage situation.
Test result:
(embodiment 2): it will illustrate the present embodiment referring to as the encapsulation of nickel hydrogen storage battery pole.
A. positive plate makes
Positive electrode is mixed in proportion (nickel hydroxide: CoO:PTFE:HPMC=50:5:2:9), anode slurry Expect viscosity control in 10000cps~12000cps.Anode sizing agent is uniformly coated in foam nickel surface, drying, roll, It is cropped to the technological parameter of design and is fabricated to positive plate.
B. negative electrode tab makes
Negative electrode material is mixed in proportion (MH: acetylene black: PTFE:CMC=50:1:1:8), negative electrode slurry is viscous Degree control is in 15000cps~16000cps.Negative electrode slurry is uniformly coated in perforation nickel plated steel strip surface, drying, stone roller It presses, be cropped to the technological parameter of design and be fabricated to negative electrode tab.
C. electrolyte configures
By electrolyte material (KOH:NaOH:LiOHH in proportion2O=300:39:20 it) is mixed with deionized water, Sufficiently dissolution cooled and filtered, electro-hydraulic specific gravity are 1.30~1.31g/cm3.D. the assembling of nickel hydrogen storage battery
By the positive plate, diaphragm, negative electrode tab of acquisition in such a way that diaphragm is between positive plate and negative electrode tab lamination at Pole group is welded on pole by pole group using resistance welding method, and pole is assembled into cubic battery body, and pole direction is inserted into In cylinder through hole on battery case cap, compression seal casing, insulating washer, metal washer successively then are assembled in pole, is led to Overcompression locking nut compresses sealing sleeve pipe sealing pole and through hole, then seals rectangular 10Ah battery cover board and battery case Mouthful, configured electrolyte is then injected into battery case, that is, completes the assembling of nickel hydrogen storage battery.
E. the chemical conversion of battery and the test of cycle performance
Fertilizer alleviant:
A) 0.1C electric current constant-current charge 13h
B) 30min is shelved
C) 0.2C constant-current discharge is to 1.0V
D) 0.2C electric current constant-current charge 6h
E) 30min is shelved
F) 1C constant-current discharge is to 1.0V
G) 0.2C electric current constant-current charge 6h
H) 30min is shelved
I) 1C constant-current discharge is to 1.0V
Loop test system:
Charging: by electric discharge state battery with 1C electric current constant-current charge 1.2h or-△ V=5mV under normal temperature environment.
Electric discharge: by battery with 1C electric current constant-current discharge to 1.0V, discharge capacity is recorded, monitors pole leakage situation.
Test result:
The present invention is not limited to the embodiments of above-mentioned embodiment, are also possible to lead-acid accumulator, the system of battery It is not particularly limited.

Claims (3)

1. a kind of encapsulating method of battery post, it is by sealing sleeve pipe (04) that pole (01) and cap (02) realization is close Envelope, which is characterized in that battery post (01) is in screw-like, and end (09) cross section is greater than cylinder cross section;Battery case cap By argon arc or laser seal welding, hollow cylinder (03) aperture is small greater than pole outer diameter for through hole and hollow cylinder (03) In pole end (09) cross-sectional outer diameter;Pole (01) is inserted into the cylinder through hole on battery case cap, then successively in pole Assemble compression seal casing (04), insulating washer 05), insulating washer (06), metal washer (07), pass through compression locking nut (08) sealing sleeve pipe (04) sealing pole (01) and through hole are compressed, the close effect of liquid is reached.
2. a kind of encapsulating method of battery post according to claim 1, which is characterized in that compression seal casing (04) In the sub- shape of back taper, sealing sleeve pipe (04) internal diameter is less than pole (01) cylinder outer diameter, material be containing rubber, polytetrafluoroethylene (PTFE), One or more of nylon, polypropylene composite material.
3. according to claim 2) described in a kind of battery post encapsulating method, which is characterized in that pole (01) and cap The surface roughness of the sealing surface of cylinder through hole is 20 μm or smaller.
CN201710707026.3A 2017-08-17 2017-08-17 A kind of encapsulating method of battery post Withdrawn CN109411649A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102020128167B3 (en) 2020-10-27 2022-03-10 Dr. Ing. H.C. F. Porsche Aktiengesellschaft Battery module for a traction battery of a motor vehicle, traction battery and method for producing a battery module

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4241152A (en) * 1978-11-14 1980-12-23 Deutsch Automobilgesellschaft Mbh Disconnectable gas-tight and pressure-resistant electrical lead-out
CN2587064Y (en) * 2002-12-04 2003-11-19 春兰(集团)公司 Metal housing secondary cell post column sealing arrangement
CN101079498A (en) * 2006-05-23 2007-11-28 丰田自动车株式会社 Alkaline storage battery
CN103125032A (en) * 2010-09-21 2013-05-29 新神户电机株式会社 Nonaqueous electrolyte secondary battery
CN105070534A (en) * 2015-09-08 2015-11-18 上海空间电源研究所 Polar column sealing device for spatial super capacitor
CN204857798U (en) * 2015-07-31 2015-12-09 浙江天能电池江苏新能源有限公司 Battery utmost point post seal structure

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4241152A (en) * 1978-11-14 1980-12-23 Deutsch Automobilgesellschaft Mbh Disconnectable gas-tight and pressure-resistant electrical lead-out
CN2587064Y (en) * 2002-12-04 2003-11-19 春兰(集团)公司 Metal housing secondary cell post column sealing arrangement
CN101079498A (en) * 2006-05-23 2007-11-28 丰田自动车株式会社 Alkaline storage battery
CN103125032A (en) * 2010-09-21 2013-05-29 新神户电机株式会社 Nonaqueous electrolyte secondary battery
CN204857798U (en) * 2015-07-31 2015-12-09 浙江天能电池江苏新能源有限公司 Battery utmost point post seal structure
CN105070534A (en) * 2015-09-08 2015-11-18 上海空间电源研究所 Polar column sealing device for spatial super capacitor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102020128167B3 (en) 2020-10-27 2022-03-10 Dr. Ing. H.C. F. Porsche Aktiengesellschaft Battery module for a traction battery of a motor vehicle, traction battery and method for producing a battery module

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Application publication date: 20190301