CN109403034A - A kind of antibacterial fabric - Google Patents

A kind of antibacterial fabric Download PDF

Info

Publication number
CN109403034A
CN109403034A CN201811475834.2A CN201811475834A CN109403034A CN 109403034 A CN109403034 A CN 109403034A CN 201811475834 A CN201811475834 A CN 201811475834A CN 109403034 A CN109403034 A CN 109403034A
Authority
CN
China
Prior art keywords
antibacterial
added
preparation
speed stirred
antimicrobial fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811475834.2A
Other languages
Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201811475834.2A priority Critical patent/CN109403034A/en
Publication of CN109403034A publication Critical patent/CN109403034A/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
    • D06M11/42—Oxides or hydroxides of copper, silver or gold
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/228—Cyclic esters, e.g. lactones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides

Abstract

A kind of antibacterial fabric, it is characterised in that its manufacturing method the following steps are included: step 1. antimicrobial fluid preparation；The manufacture of step 2. antibacterial substrate；Step 3. filtering shaping.

Description

A kind of antibacterial fabric
The application is entitled a kind of manufacturing method of anti-biotic material application No. is 201610386898X, the applying date For the divisional application of the application for a patent for invention of 2016.06.02.
Technical field
The present invention relates to a kind of antibacterial fabric and its manufacturing methods.
Background technique
Anti-biotic material refers to that itself has a kind of new function material killed or inhibit microbial function.It is led in medical treatment There is extremely wide application prospect in the fields such as domain, household supplies, household electrical appliance, food packaging, in people to environmental sanitation requirement Increasing today, the application of anti-biotic material is by more extensive concern.Current antibiotic finish technology mainly has three classes 1. co-blended spinning method: first antibacterial agent being added in spinning material, anti-bacterial fibre is made, antibacterial fabric is then made.The method antibacterial Effect is lasting, and washability is good, but with high content of technology, and difficulty is big, and it is wide to be related to field, and antibacterial agent requires high；It is commonly used to production synthesis Fiber product.2. finishing method: antibacterial agent (being commonly referred to as antibacterial finishing agent) is added during fabric printing final finishing, Then various antibacterial fabrics are made.The method working process is relatively simple, and washability and durable antibacterial effect are poor.3. Antibacterial agent: being first added in spinning material and anti-bacterial fibre be made by composite finishing method, is added during fabric printing final finishing Then antibacterial fabric is made in antibacterial finishing agent, this method only uses in the specialities with high antibacterial performance requirement, Limit use scope.Current method all cannot concurrently reach the performance of air-moisture-permeable, Durable antibacterial.
Summary of the invention
In order to solve the above problem, the invention adopts the following technical scheme:
The preparation of step 1. antimicrobial fluid
The first step, the methylated cellulose aqueous solution and mass percent concentration that preparation mass percent concentration is 5-10% respectively are The copper-bath of 8-11%, it is spare；
Second step in Xiang Shangshu copper salt solution, is slowly added to chitosan, and keep micro- under microwave concussion or high-speed stirred Wave concussion or high-speed stirred 30-120min, obtain mixed solution A；Wherein, mass fraction of the chitosan in mixed solution A For 7-10%；
Third step, under ultrasonic oscillation or high-speed stirred, the ratio of 7 ︰, 4 ~ 5 ︰ 9, above-mentioned mixed solution A is delayed by volume Slowly it is added in above-mentioned methylated cellulose aqueous solution；
Then, at 40 DEG C, in the ratio for being 1 ︰ 1.2 with the molar ratio of copper ion, ascorbic acid is added and reacts 30 ~ 45min, so It is that 2-3% pectin, 5-8% sodium alginate obtain mixed liquor that mass fraction is added afterwards, then by the de-bubble of gained liquid negative pressure, stand, It is aged 36h again, obtains antimicrobial fluid；
The manufacture of step 2. antibacterial substrate
1) mass ratio is dissolved in organic solvent for 1: 1~50 polylactic acid and thermoplastic polymer and forms spinning solution；
2) polylactic acid thermoplastic polymer spinning solution is placed in electrostatic spinning machine syringe, under 8~30kV voltage, in connecing It receives and obtains polylactic acid polymer composite cellulosic membrane on electrode；
3) organic solvent is removed under 50~100 DEG C of vacuum condition, obtains polylactic acid polymer composite cellulosic membrane；
Thermoplastic polymer in preparation method step 1) provided by the invention be polyether ketone ketone, polyether-ether-ketone, polyetherimide, Polysulfones, polyether sulfone, phenolphthalein modified poly (ether-sulfone), polyphenylene sulfide, polyphenylene oxide or polyamide.
Organic solvent in preparation method step 1) provided by the invention is tetrahydrofuran, dichloroethanes, tetrachloroethanes, two Chloromethanes, chloroform, n,N-Dimethylformamide, n,N-dimethylacetamide or N, N- dimethyl pyrrolidone.
Receiving electrode in preparation method step 2) provided by the invention between emission electrode at a distance from be 8~23cm.
Polylactic acid polymer composite fibre made from electrostatic spinning machine is straight in preparation method step 2) provided by the invention Diameter is 10~50nm.
Polylactic acid polymer composite cellulosic membrane obtained with a thickness of 5~50 in preparation method step 3) provided by the invention μm, width is 5~40cm.
Step 3. filtering shaping
The antibacterial gel liquid of polylactic acid polymer composite fibre membrane filtration step 1, filtration yield every square centimeter made from step 2 For 3-9ml, bottom is filtered at room temperature using suction filtration machine, and suction filtration machine is moved back and forth with 1-2 points ms/min of speed, Filtration time is 1-2 hour, passes through 160~180 DEG C of drying tunnels after the completion of filtering, retention time 15 minutes, drying tunnel was after cooling out It is made.
Compared with the latest prior art, technical solution provided by the invention has the advantages that
1) polylactic acid polymer composite cellulosic membrane provided by the invention is conducive to when polyurethane heats because it is with porous structure in layer Between flowing, improve the uniformity of material internal structure；
2) polylactic acid polymer composite cellulosic membrane is because it with porous structure ensure that the gas permeability of material is excellent；
3) using methylcellulose as continuous phase, doping deposition nano cuprous oxide, prepare good biocompatibility, good permeability, The excellent composite antibacterial film medical material of anti-microbial property.
4) gas permeability of product, good water absorption have quick antibacterial and Durable antibacterial performance good.
5) process flow is short, technology controlling and process is easy, low production cost.
Specific embodiment
Embodiment 1
The preparation of step 1. antimicrobial fluid
The first step, the methylated cellulose aqueous solution and mass percent concentration that preparation mass percent concentration is 5% respectively are 8% Copper-bath, it is spare；
Second step in Xiang Shangshu copper salt solution, is slowly added to chitosan, and keep micro- under microwave concussion or high-speed stirred Wave concussion or high-speed stirred 30-120min, obtain mixed solution A；Wherein, mass fraction of the chitosan in mixed solution A It is 10%；
Third step, under ultrasonic oscillation or high-speed stirred, the ratio of 7 ︰ 4, above-mentioned mixed solution A is slowly added by volume Enter into above-mentioned methylated cellulose aqueous solution；
Then, at 40 DEG C, in the ratio for being 1 ︰ 1.2 with the molar ratio of copper ion, ascorbic acid is added and reacts 45min, then Addition mass fraction is 2-3% pectin, 5-8% sodium alginate obtains mixed liquor, then by the de-bubble of gained gel negative pressure, standing, then It is aged 36h, obtains antimicrobial fluid；
The preparation of step 2. antibacterial substrate
1) mass ratio is dissolved in organic solvent for 1: 1~50 polylactic acid and polyamide and forms spinning solution；
2) polylactic acid thermoplastic polymer spinning solution is placed in electrostatic spinning machine syringe, under 8~30kV voltage, in connecing It receives and obtains polylactic acid polymer composite cellulosic membrane on electrode；
3) organic solvent is removed under 50~100 DEG C of vacuum condition, obtains polylactic acid polymer composite cellulosic membrane；
Step 3. filtering shaping
The antimicrobial fluid of polylactic acid polymer composite fibre membrane filtration step 1 made from step 2, filtration yield every square centimeter are 3- 9ml, bottom are filtered using suction filtration machine, and suction filtration machine is moved back and forth with 1-2 points ms/min of speed, and filtration time is 1-2 hours, the composite cellulosic membrane of polyurethane resin is attached with after the completion of filtering by 160 DEG C of drying tunnels, retention time 15 minutes, out Drying tunnel is made after cooling.
Embodiment 2
The preparation of step 1. antimicrobial fluid
The first step, the methylated cellulose aqueous solution and mass percent concentration that preparation mass percent concentration is 10% respectively are 11% copper-bath, it is spare；
Second step in Xiang Shangshu copper salt solution, is slowly added to chitosan, and keep micro- under microwave concussion or high-speed stirred Wave concussion or high-speed stirred 120min, obtain mixed solution A；Wherein, mass fraction of the chitosan in mixed solution A is 10%；
Third step, under ultrasonic oscillation or high-speed stirred, the ratio of 7 ︰ 4, above-mentioned mixed solution A is slowly added by volume Enter into above-mentioned methylated cellulose aqueous solution；
Then, at 40 DEG C, in the ratio for being 1 ︰ 1.2 with the molar ratio of copper ion, ascorbic acid is added and reacts 45min, then Addition mass fraction is 2-3% pectin, 5-8% sodium alginate obtains mixed liquor, then by the de-bubble of gained gel negative pressure, standing, then It is aged 36h, obtains antimicrobial fluid；
The preparation of step 2. antibacterial substrate
1) mass ratio is dissolved in tetrahydrofuran for 1: 1~50 polylactic acid and polysulfones and forms spinning solution；
2) polylactic acid thermoplastic polymer spinning solution is placed in electrostatic spinning machine syringe, under 8~30kV voltage, in connecing It receives and obtains polylactic acid polymer composite cellulosic membrane on electrode；
3) organic solvent is removed under 50~100 DEG C of vacuum condition, obtains polylactic acid polymer composite cellulosic membrane；
Step 3. filtering shaping
The antimicrobial fluid of polylactic acid polymer composite fibre membrane filtration step 1 made from step 2, filtration yield every square centimeter are 3- 9ml, bottom are filtered using suction filtration machine, and suction filtration machine is moved back and forth with 1-2 points ms/min of speed, and filtration time is 1-2 hours, by 130 DEG C of drying tunnels after the completion of filtering, retention time 15 minutes, drying tunnel was made after cooling out.
Comparative example 1
Step 2 base fabric uses polyester superfine fibre film, other steps are the same as embodiment 1.
Comparative example 2
Antimicrobial fluid is by 5~9 parts of chitosan, 0.1~1 part of probenazole, 0.1~3 part of polyethylene glycol, methyl hydantoin in step 1 0.1~2 part of class compound, 2~5 parts of Peracetic acid compositions.Other steps are the same as embodiment 2.
Specific embodiment is tested for the property, using this field traditional test methods, test result is as shown in table 1, real It tests and shows that anti-biotic material of the invention can realize fast onset antibacterial effect and good in the case where keeping fine air permeability Antibacterial durability.
1 anti-biotic material permeability of table
Embodiment 1 Embodiment 2 Comparative example 1 Comparative example 2
Gas permeability (dm3/ min) 2.8 2.7 0.95 0.8
2 anti-biotic material of table does not wash antibiotic rate
Note: antibiotic rate " * * * ":>=99%, " * * ":>=90%, " * ">=50%, "-":<50%
The antibiotic rate of the anti-biotic material after 50 washings of table 3

Claims (2)

1. a kind of antibacterial fabric, it is characterised in that its manufacturing method the following steps are included: step 1. antimicrobial fluid preparation；Step 2. the manufacture of antibacterial substrate；Step 3. filtering shaping.
2. antibacterial fabric as described in claim 1, which is characterized in that specifically comprise the following steps:
The preparation of antimicrobial fluid
The first step, the methylated cellulose aqueous solution and mass percent concentration that preparation mass percent concentration is 5-10% respectively are The copper-bath of 8-11%, it is spare；
Second step in Xiang Shangshu copper salt solution, is slowly added to chitosan, and keep micro- under microwave concussion or high-speed stirred Wave concussion or high-speed stirred 30-120min, obtain mixed solution A；Wherein, mass fraction of the chitosan in mixed solution A For 7-10%；
Third step, under ultrasonic oscillation or high-speed stirred, the ratio of 7 ︰, 4 ~ 5 ︰ 9, above-mentioned mixed solution A is delayed by volume Slowly it is added in above-mentioned methylated cellulose aqueous solution；
Then, at 40 DEG C, in the ratio for being 1 ︰ 1.2 with the molar ratio of copper ion, ascorbic acid is added and reacts 30 ~ 45min, so It is that 2-3% pectin, 5-8% sodium alginate obtain mixed liquor that mass fraction is added afterwards, then by the de-bubble of gained liquid negative pressure, stand, It is aged 36h again, obtains antimicrobial fluid.
CN201811475834.2A 2016-06-02 2016-06-02 A kind of antibacterial fabric Pending CN109403034A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811475834.2A CN109403034A (en) 2016-06-02 2016-06-02 A kind of antibacterial fabric

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201811475834.2A CN109403034A (en) 2016-06-02 2016-06-02 A kind of antibacterial fabric
CN201610386898.XA CN105803777B (en) 2016-06-02 2016-06-02 A kind of manufacturing method of anti-biotic material

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201610386898.XA Division CN105803777B (en) 2016-06-02 2016-06-02 A kind of manufacturing method of anti-biotic material

Publications (1)

Publication Number Publication Date
CN109403034A true CN109403034A (en) 2019-03-01

Family

ID=56428264

Family Applications (3)

Application Number Title Priority Date Filing Date
CN201811475822.XA Withdrawn CN109537281A (en) 2016-06-02 2016-06-02 A kind of manufacturing method of antibacterial fabric
CN201610386898.XA Active CN105803777B (en) 2016-06-02 2016-06-02 A kind of manufacturing method of anti-biotic material
CN201811475834.2A Pending CN109403034A (en) 2016-06-02 2016-06-02 A kind of antibacterial fabric

Family Applications Before (2)

Application Number Title Priority Date Filing Date
CN201811475822.XA Withdrawn CN109537281A (en) 2016-06-02 2016-06-02 A kind of manufacturing method of antibacterial fabric
CN201610386898.XA Active CN105803777B (en) 2016-06-02 2016-06-02 A kind of manufacturing method of anti-biotic material

Country Status (1)

Country Link
CN (3) CN109537281A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107881648A (en) * 2016-09-29 2018-04-06 南京林业大学 The preparation of multi-functional grafting electrospun fibers membrane material
CN108642713A (en) * 2018-07-09 2018-10-12 合肥洁诺医疗用品有限公司 A kind of preparation method of medical antibacterial non-woven fabrics
CN112251912B (en) * 2020-10-19 2022-10-18 新疆大学 Capparis spinosa drug-loaded nanofiber membrane as well as preparation method and application thereof

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1311695A (en) * 1998-07-28 2001-09-05 美国3M公司 Method for mfg. antimicrobial articles
CN101189971A (en) * 2006-11-20 2008-06-04 北京崇高纳米科技有限公司 Inorganic/organic nano composite antibacterial agent and its fabric product application
CN102094319A (en) * 2009-12-11 2011-06-15 国家纳米技术与工程研究院 Antibacterial agent for textiles and preparation and application thereof
CN102258064A (en) * 2011-05-12 2011-11-30 赵正坤 Antibacterial composition and application thereof
CN102921035A (en) * 2012-11-09 2013-02-13 无锡中科光远生物材料有限公司 Antiseptic dressing for deep infected wounds
CN103114438A (en) * 2011-11-17 2013-05-22 王晓薇 Special marine organism anti-bacterial and odor-resistant finishing agent for textiles
CN104288827A (en) * 2014-09-29 2015-01-21 张亚丽 Haemostatic wound dressing
CN104524866A (en) * 2014-12-04 2015-04-22 上海洁晟环保科技有限公司 Composite antibacterial air filtration material and preparation method thereof
CN105012991A (en) * 2015-07-17 2015-11-04 清华大学 Antibacterial-hemostatic material with non-woven fabric fiber fabric structure and production method of antibacterial-hemostatic material
CN105200663A (en) * 2015-11-04 2015-12-30 上海洁晟环保科技有限公司 Preparation method of antibacterial nanofiber membrane
CN105316933A (en) * 2015-11-16 2016-02-10 清华大学 Preparation method of antibacterial electrospun fibrous membrane
CN105463837A (en) * 2014-09-25 2016-04-06 三菱制纸株式会社 Humidification filtering material and humidification filter
CN105568556A (en) * 2015-12-15 2016-05-11 上海洁晟环保科技有限公司 Preparation method of super-hydrophobic or super-hydrophilic nanofiber membrane with antibacterial performance
CN105561403A (en) * 2016-03-02 2016-05-11 青岛大学 Preparation method of alginate-graphene-nano cuprous oxide composite antibacterial film

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008115503A (en) * 2006-11-07 2008-05-22 Toyohashi Univ Of Technology Method for making stereocomplex polylactic acid material by application of electric field

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1311695A (en) * 1998-07-28 2001-09-05 美国3M公司 Method for mfg. antimicrobial articles
CN101189971A (en) * 2006-11-20 2008-06-04 北京崇高纳米科技有限公司 Inorganic/organic nano composite antibacterial agent and its fabric product application
CN102094319A (en) * 2009-12-11 2011-06-15 国家纳米技术与工程研究院 Antibacterial agent for textiles and preparation and application thereof
CN102258064A (en) * 2011-05-12 2011-11-30 赵正坤 Antibacterial composition and application thereof
CN103114438A (en) * 2011-11-17 2013-05-22 王晓薇 Special marine organism anti-bacterial and odor-resistant finishing agent for textiles
CN102921035A (en) * 2012-11-09 2013-02-13 无锡中科光远生物材料有限公司 Antiseptic dressing for deep infected wounds
CN105463837A (en) * 2014-09-25 2016-04-06 三菱制纸株式会社 Humidification filtering material and humidification filter
CN104288827A (en) * 2014-09-29 2015-01-21 张亚丽 Haemostatic wound dressing
CN104524866A (en) * 2014-12-04 2015-04-22 上海洁晟环保科技有限公司 Composite antibacterial air filtration material and preparation method thereof
CN105012991A (en) * 2015-07-17 2015-11-04 清华大学 Antibacterial-hemostatic material with non-woven fabric fiber fabric structure and production method of antibacterial-hemostatic material
CN105200663A (en) * 2015-11-04 2015-12-30 上海洁晟环保科技有限公司 Preparation method of antibacterial nanofiber membrane
CN105316933A (en) * 2015-11-16 2016-02-10 清华大学 Preparation method of antibacterial electrospun fibrous membrane
CN105568556A (en) * 2015-12-15 2016-05-11 上海洁晟环保科技有限公司 Preparation method of super-hydrophobic or super-hydrophilic nanofiber membrane with antibacterial performance
CN105561403A (en) * 2016-03-02 2016-05-11 青岛大学 Preparation method of alginate-graphene-nano cuprous oxide composite antibacterial film

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
余序芬: "《纺织材料实验技术》", 31 March 2004, 中国纺织出版社 *
温辉梁: "《化工助剂》", 3 December 2009, 江西科学技术出版社 *

Also Published As

Publication number Publication date
CN105803777B (en) 2019-02-12
CN109537281A (en) 2019-03-29
CN105803777A (en) 2016-07-27

Similar Documents

Publication Publication Date Title
CN104892969B (en) A kind of chitin fiber element composite membrane and its preparation method and application
CN110144124B (en) Composite material of quaternized chitin and silk fibroin and preparation and application thereof
CN108993167B (en) Preparation and application of antibacterial electrostatic spinning nanofiber air filtering material
CN107556495B (en) A kind of preparation method of functional nano cellulose composite aerogel
CN105803777B (en) A kind of manufacturing method of anti-biotic material
CN106120015B (en) A kind of copper base metal organic backbone anti-bacterial fibre and preparation method thereof
CN107753996B (en) Moisture-absorbing antibacterial 3D nanofiber medical dressing and preparation method thereof
CN111379161B (en) Preparation method of silver ion antibacterial non-woven fabric
CN105887241B (en) A kind of phase-changing and temperature-regulating chitosan composite fiber and preparation method thereof
CN105536032A (en) Preparation method of nanofiber antimicrobial dressing blended from nano-silver containing sericin and polyoxyethylene
CN105497969A (en) Multilayer composite film dressing and preparation method thereof
CN102493014B (en) A kind of epsilon-polylysine polyvinyl alcohol compound bio anti-bacterial fibre and preparation method thereof
CN109806771B (en) Nanofiber-based composite hemodialysis membrane and preparation method thereof
CN106007544B (en) A kind of antibacterial building concrete manufacture craft
CN105019142A (en) Preparation method for micro and nano PET fiber with large pore volumes
CN103451849B (en) Containing the poly butylene succinate nano fibrous membrane and its preparation method and application of Nano Silver
CN105839229A (en) Copper ion modified chitosan fiber and preparation method thereof
CN113445155B (en) Chitosan-based nanofiber and preparation method thereof
CN1837435B (en) Composite nano-grade silk fiber product and method for preparing the same
JP2013194329A (en) Method for producing nanocomposite-nanofiber
CN106988016B (en) Antibacterial aqueous polyurethane nanofiber film and preparation method
CN110152049A (en) A kind of preparation method for the chitosan-based medicament-carrying nano-fiber membrane can be applied to medical wound dressing
CN103554367A (en) Beta-cyclodextrin containing halogen amine antimicrobial agent copolymer as well as preparation method and application of copolymer
KR101111226B1 (en) Nanofiber nonwoven fabric having chitosan layer and manufacturing method thereof
CN103495354B (en) A kind of hollow fiber internal pressure film and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190301

WD01 Invention patent application deemed withdrawn after publication