CN109402508A - A kind of low-carbon microalloyed Q690 grade high-strength weathering steel and preparation method thereof - Google Patents

A kind of low-carbon microalloyed Q690 grade high-strength weathering steel and preparation method thereof Download PDF

Info

Publication number
CN109402508A
CN109402508A CN201811338543.9A CN201811338543A CN109402508A CN 109402508 A CN109402508 A CN 109402508A CN 201811338543 A CN201811338543 A CN 201811338543A CN 109402508 A CN109402508 A CN 109402508A
Authority
CN
China
Prior art keywords
steel
low
grade high
strength
weathering steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811338543.9A
Other languages
Chinese (zh)
Other versions
CN109402508B (en
Inventor
刘悦
吴红艳
杜林秀
张彬
高秀华
高彩茹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Northeastern University China
Original Assignee
Northeastern University China
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Northeastern University China filed Critical Northeastern University China
Priority to CN201811338543.9A priority Critical patent/CN109402508B/en
Publication of CN109402508A publication Critical patent/CN109402508A/en
Application granted granted Critical
Publication of CN109402508B publication Critical patent/CN109402508B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0231Warm rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

A kind of low-carbon microalloyed Q690 grade high-strength weathering steel and preparation method thereof, ingredient contains C 0.03~0.10% by weight percentage, Si 0.10~0.50%, Mn 1.20~2.00%, S 0.002~0.010%, P 0.003~0.015%, Al 0.01~0.05%, V 0.05~0.15%, N 0.01~0.02%, Cr 0.30~0.80%, Ni 0.30~0.80%, Cu 0.15~0.55%, Mo 0.15~0.55%, surplus Fe, 700~798MPa of yield strength, 795~950MPa of tensile strength, elongation percentage 15.5~18.6%;The preparation method comprises the following steps: (1) smelting molten steel, casts and forges;(2) 1100~1200 DEG C of heat preservation solid solutions are heated to;(3) roughing and finish rolling are carried out;Then water cooling is to 400~520 DEG C;(4) slow cooling of insulation quilt slot is to room temperature.Steel grade rolling operations of the invention are simple, handle without Q-tempering, atmospheric corrosion resistance, obdurability good combination property, have good low temperature impact properties.

Description

A kind of low-carbon microalloyed Q690 grade high-strength weathering steel and preparation method thereof
Technical field
The invention belongs to metallurgical technology field, in particular to a kind of low-carbon microalloyed Q690 grade high-strength weathering steel and its system Preparation Method.
Background technique
The weathering steel accepted extensively in recent years by market is mainly 295MPa grades 09CuPTiRE, 345MPa grades 09CuPCrNi, 450MPa grades of Q450NQR1 several types, and the multiple field such as be widely used in railway, building, bridge, can Resist the corrosion of industrial atmosphere, acid rain, marine atmosphere and seawater.But the intensity of weather-resistant steel plate is there are also to be hoisted, due to tradition High-strength steel not only impact flexibility, weldability, fatigability are poor, but also be not resistant to atmosphere, marine environment, it is therefore, potential The market demand promote to develop and high-intensitive have both the Thin Strip Steel of good weatherability properties to replace low-intensity Deformation in thick to become main Research and development direction proposes the concept of high-performance weather-proof steel both at home and abroad;Weathering steel, which refers to, has protection rusty scale and resistance to atmosphere The low-alloy structural steel of corrosion;For straight carbon steel, weathering steel supports erosion-resisting property with more excellent in atmospheric environment Can, compared to for stainless steel, weathering steel can greatly reduce the additive amount of alloying element, the alloying elements such as P, Cu, Cr, V, Mo Total amount only account for a few percent, steel product cost is effectively reduced.
Up to the present, domestic weathering steel and its manufacturing method about high-strength and high-weather-resistance has been applied multinomial; The patent of application number 200710045329.X, describes a kind of high-corrosion resistant high-strength weather resisting steel and its manufacturing method, this method are adopted It is designed, with the Cr-Ni-Cu set member of Ultra-low carbon, low manganese, middle chromium using Ti microalloying, produces yield strength and be greater than High-weatherability high-strength weathering steel of 700MPa, 72h the alternate-immersion rate less than 25% (compared with Q345 straight carbon steel);But it should Cr content is up to 4.50% or more in scheme, be easy to cause cost of alloy higher, welding performance is bad;Application number 201010246778.2 patent, describe a kind of 700MPa grade Micro Alloyings of inexpensive yield strength handle high-strength weathering steels and its Manufacturing method, this method are designed using high Ti ingredient, increase strengthening effect;The patent of application number 201410236616.9 is introduced A kind of 700MPa grades of type of resistance to industrial atmospheric martensite steel plate and preparation method thereof;This method is tied to form using Nb-Ti to be set up separately Meter makes the steel plate yield strength range prepared in 695~720MPa, tensile strength >=800MPa, elongation percentage >=18%, and -40 DEG C low-temperature impact work > 100J, resistance to industrial atmosphere year corrosion loss < 350g/m2
The high-strength air corrosion-resistant steel of above-mentioned yield strength 700MPa intensity rank has been all made of low-carbon (or Ultra-low carbon)- Based on silico-manganese steel, and the alloying elements microalloying route such as add suitable Cu, Ni, Cr, stress using Nb-Ti microalloying Final products are obtained in conjunction with TMCP technology;But it is deposited using the high strength steel plate that Nb-Ti microalloy component system is produced In drawback, hot rolling load weight, hot rolling technology control difficulty are big, steel yield tensile ratio is high, cost of alloy is high and strip rolls Heat treatment procedure after system can also improve production cost.
Summary of the invention
For the above problem existing for existing weathering steel technology of preparing, the present invention provides a kind of low-carbon microalloyed Q690 grades High-strength weathering steel and preparation method thereof designs the content for reducing alloying component by ingredient using V-N-Cr micro-alloying technology, Promote Intragranular Acicular Ferrite forming core during billet rolling simultaneously, promotes plate center portion toughness and tenacity, pass through crystal grain refinement and analysis Strengthen preparation Q690 grade high-strength weathering steel out.
The ingredient of low-carbon microalloyed Q690 grade high-strength weathering steel of the invention contain by weight percentage C 0.03~ 0.10%, Si0.10~0.50%, Mn 1.20~2.00%, S 0.002~0.010%, P 0.003~0.015%, Al 0.01~0.05%, V 0.05~0.15%, N 0.01~0.02%, Cr 0.30~0.80%, Ni 0.30~0.80%, Cu 0.15~0.55%, Mo 0.15~0.55%, surplus are Fe and other inevitable impurity;Its yield strength 700~ 798MPa, 795~950MPa of tensile strength, elongation percentage 15.5~18.6%, -60 DEG C of ballistic work >=100J, yield tensile ratio 0.84~ 0.88。
Above-mentioned low-carbon microalloyed Q690 grade high-strength weathering steel with a thickness of 4~14mm.
The tissue of above-mentioned low-carbon microalloyed Q690 grade high-strength weathering steel is polygonal ferrite, acicular ferrite and grain Shape bainite.
The preparation method of low-carbon microalloyed Q690 grade high-strength weathering steel of the invention the following steps are included:
1, set component smelting molten steel is pressed, then cast and is forged to 60~140mm of thickness, steel billet, ingredient are obtained By weight percentage contain C 0.03~0.10%, Si 0.10~0.50%, Mn 1.20~2.00%, S 0.002~ 0.010%, P 0.003~0.015%, Al 0.01~0.05%, V 0.05~0.15%, N 0.01~0.02%, Cr 0.30~0.80%, Ni 0.30~0.80%, Cu 0.15~0.55%, Mo 0.15~0.55%, surplus be Fe and other not Evitable impurity;
2, using heating furnace by steel billet with stove heating to 1100~1200 DEG C and keep the temperature 2~4h, to guarantee that steel billet is sufficiently difficult to understand Family name's body and microalloy element are sufficiently dissolved;
3, the steel billet after heat preservation is subjected to roughing and finish rolling;Wherein the start rolling temperature of roughing is 1050~1160 DEG C, finish to gauge Temperature is 960~1080 DEG C;Finish rolling start rolling temperature is 860~900 DEG C, and finish rolling finishing temperature is 810~850 DEG C;Finish rolling is completed Water cooling obtains hot rolled plate to 400~520 DEG C afterwards;
4, it puts hot rolled plate into insulation quilt slot slow cooling and low-carbon microalloyed Q690 grade high-strength weathering steel is made to room temperature.
In the above method, the rolling pass of roughing is 2~4 times, and reduction ratio is 24~28.6% per pass.
In the above method, the rolling pass of finish rolling is 6~7 times, and reduction ratio is 13~28% per pass.
In the above method, control cooling velocity is 25~45 DEG C/s when water cooling.
Weathering steel requires the ability of higher intensity and atmospheric corrosion resistance, while having both good impact flexibility and weldering Connect performance;The present invention obtains the optimal effect of steel by the way of compound addition alloying element, passes through the members such as addition Cr, Mo The atmospheric corrosion resistance of steel is usually significantly improved, while adding micro alloying element to improve the toughness of steel;The present invention Ingredient design principle it is as follows:
C:C is most economical, most effective intensified element in steel, and the height of C content directly affects the intensity rank of steel, but It is the atmospheric corrosion resistance that excessively high C content can not only destroy steel, also will affect the welding performance, toughness and punching performance of steel Deng;Therefore the C content range used is 0.03~0.10%, by other alloying elements such as addition Si, Mn come compensation intensity;
Si:Si is conducive to improve intensity, yield point and the wearability of steel, and the solubility in α-Fe and γ-Fe is larger, rises To solution strengthening effect, ferrite volume fraction in steel can be increased, refine crystal grain, be conducive to improve toughness;Si can also be improved The resistivity of steel forms rich Si protective film in steel surface, improves corrosion resistance, with other elements such as Cu, Cr, P with the use of can be with Improve the corrosion resistance of steel;The Si content range of use all can between 0.10~0.50% below or above this range The toughness and plasticity of Resistance of Weld Metal have an adverse effect;
Mn:Mn is that one of most effective element of intensity of steel is compensated in the case where reducing C content, is added in steel appropriate Mn, the harden ability of steel can be increased, play solution strengthening and Grain refinement, can also be reduced while improving intensity crisp Sex reversal temperature is conducive to that middle temperature transformation occurs, but the excessive Mn content that increases can deteriorate the solderability of steel and welding heat affected The toughness in area;Using Mn content range 1.20~2.00%, to obtain optimal acicular ferrite content and tough optimal Match;
The presence of S:S can deteriorate the atmospheric corrosion resistance of steel, and S content is lower under the same terms, and the corrosion resistance of steel is better; But Cu can obviously offset the illeffects of S in steel, the content of S is higher, and the effect that Cu reduces corrosion rate is more obvious, the two The hole that rusty scale is filled in conjunction with insoluble compound is capable of forming prevents the further occurrence of corrosion;Therefore by the range of S content Control is between 0.002~0.01%;
P:P is to improve one of most effective alloying element of steel weatherability, and the rusty scale of weathering steel is promoted to have amorphous nature Fe3O4, have special effect;But the P of high-content will increase the cold brittleness of steel, deteriorate welding performance, cold-bending property;? Under the conditions of atmospheric corrosion, the P in steel is anode depolarizing agent, can accelerate the uniform dissolution and Fe of steel2+Oxidation rate, facilitate Uniform FeOOH rusty scale is formed in steel surface and promotes to generate the FeO for being rich in amorphous state FeOOHX(OH)3-2xFine and close protect Cuticula makes to become the protective barrier that tissue corrosive medium enters steel matrix from atmospheric corrosion inside steel, therefore use P content range is between 0.003~0.01%.
Al: the effect of fixed nitrogen and deoxidation is primarily served, Al, which engages the AlN to be formed with N, can effectively refine crystal grain, but Al Too high levels can damage the tough of steel, therefore control its content in 0.01~0.05% range;
Cu:Cu is the key element for improving the atmospheric corrosion resistance of steel, when combining in addition steel with P, is shown excellent The weather-proof effect of collaboration, improve the weather-resistant performance of steel;The Cu that face-centred cubic structure is added can make the cold short transformation of steel Temperature improves, and increases amount containing Cu, and the yield strength of weathering steel is also accordingly increased;Therefore the Cu content used is in 0.15%- In 0.55% range;
V: compared with Nb, the cracked probability of microalloy continuous casting billet is low, and V and N affinity are strong, easily combines, promotes VN's It is precipitated, so that the V in steel is changed into precipitation state by solid solution state, significantly improve intensity, precipitation strength is up to 250~300MPa;V is still Most economical micro alloying element, it can convert useful cheap alloying element for harmful N element originally, can be effective Cost is reduced, therefore is 0.05~0.15% using the range of V content;
N: it is similar with the effect of C element, the intensity of steel can be improved in such a way that gap is dissolved, but be dissolved the N of state There is biggish harm to plasticity, the toughness of steel, therefore the N content range used is 0.01~0.02%;
Ni:Ni is a kind of more stable element, and Ni, which is added, can be such that the corrosion potential of steel changes to positive direction, is increased The stability of steel can improve toughness while improving intensity again, and improve harden ability, can effectively prevent the hot-short of Cu from causing Check crack phenomenon;But excessively high Ni will increase cost, improve the adhesiveness of oxide skin, therefore by N content control 0.30~ In 0.80% range.
Cr:Cr has significant effect to the passivation ability for improving steel, can promote steel surface formed fine and close passivating film or Person's protective rust, the enrichment in rusty scale can effectively improve rusty scale and penetrate characteristic to the selectivity of corrosive media, with When Cu is added in steel simultaneously, effect is particularly evident, and Cr content is generally 0.4%~1.0% (up to 1.3%) in weathering steel; The increase of Cr content can promote the yield strength of steel slightly to rise, but strengthening effect is not so good as Cu, and conjunction can be improved in the addition of Cr The Cold Brittleness Transition Temperature of gold, therefore the range of Cr content is 0.30~0.80%.
Mo:Mo element can improve the brittleness of steel while increasing intensity, reduce the toughness of steel;When containing 0.4% in steel When~0.5% Mo, the atmospheric corrosion rate of steel may be decreased half or less;Preferably, when Mo is in 0.1~0.25% model In enclosing, there is steel excellent intensity and plasticity to match;Comprehensive various conditions, the content range of the Mo of use is 0.15~ 0.55%.
Compared with prior art, present invention has an advantage that
(1) V-N-Cr micro-alloying technology is utilized, VN, V (C, N) nano-scale precipitate can be with during billet rolling Promote Intragranular Acicular Ferrite forming core, promotes plate center portion toughness and tenacity, it is raw by the refining effect of crystal grain and the principle of precipitation strength Produce Q690 grade high-strength weathering steel;The carbon content of the weathering steel is low, and weight percentage is 0.03~0.10%, and low-carbon design reduces Carbon equivalent, can improving welding property, and avoid by controlled rolling and controlled cooling the formation of coarse cementite in steel plate tissue, steel plate is low Warm impact flexibility is good.For the steel plate of different-thickness specification, optimize and have adjusted the content of the alloys such as Cr, Ni, V, Mo, saves Cost, for iron and steel enterprise's product up-gradation, energy-saving significant;
(2) rolling operations are simple, using two-phase control rolling, roll state delivery, handle without Q-tempering, to equipment and Technical requirements are not harsh, have atmospheric corrosion resistance, and obdurability good combination property has good low temperature impact properties, hold It is easy to realize industrial production and promotes.
Steel prepared by the present invention after the alternate-immersion experiment of 360 hours simulation industrial atmospheric environments, lose by corrosion Weight speed ratio straight carbon steel Q345B is slow, more obvious in the initial stage difference of abrasion cycle, using Q345B as control sample Relatively corrosive rate reduces by 50% within 72 hours.
Steel grade rolling operations of the invention are simple, handle without Q-tempering, atmospheric corrosion resistance, and obdurability is comprehensive Can be good, there are good low temperature impact properties, industrialized production easy to accomplish can be used for rolling stock manufacturing.
Detailed description of the invention
Fig. 1 is the preparation method flow diagram of the low-carbon microalloyed Q690 grade high-strength weathering steel of the present invention;
Fig. 2 is the OM organization chart of the low-carbon microalloyed Q690 grade high-strength weathering steel of embodiment 1;
Fig. 3 is the transmission shape appearance figure of the low-carbon microalloyed Q690 grade high-strength weathering steel of embodiment 2;
Fig. 4 is the low-carbon microalloyed Q690 grade high-strength weathering steel OM organization chart of embodiment 3.
Specific embodiment
Following non-limiting embodiments can with a person of ordinary skill in the art will more fully understand the present invention, but not with Any mode limits the present invention.
Test method described in the embodiment of the present invention is unless otherwise specified conventional method;The reagent and material, Unless otherwise specified, it commercially obtains.
Hot-rolling mill used in the embodiment of the present invention is that Northeastern University's rolling technique and tandem rolling automate National Key Laboratory Φ 450mm hot-rolling mill.
The heating furnace used when furnace cooling in the embodiment of the present invention is high temperature box type resistance furnace, model RX4-85- 13B。
Transmission electron microscope used is FEI Tecnai G in the embodiment of the present invention2F20 Flied emission transmission electron microscopy Mirror;
Scanning electron microscope used is LEICA-DMIRM optical electron microscope in the embodiment of the present invention.
Atmospheric corrosion resistance test is that " TB/T 2375-93 railway is used according to railroad industry standard in the embodiment of the present invention Weathering steel alternate-immersion test method ".
The standard of welding crack sensibility index foundation is GB/T 1591-2008 in the embodiment of the present invention.
Embodiment 1
Process is as shown in Figure 1;
By set component smelting molten steel, is then cast and forged to thickness 140mm, obtain steel billet, ingredient is by weight Percentage contains C 0.03%, Si 0.50%, Mn 2.00%, S 0.002%, P 0.010%, Al 0.04%, V 0.15%, N 0.02%, Cr 0.80%, Ni 0.80%, Cu 0.45%, Mo 0.55%, surplus are Fe and other inevitable impurity;
Steel billet to 1200 DEG C and is kept the temperature with stove heating by 2h using heating furnace, to guarantee the abundant austenitizing of steel billet and micro- conjunction Gold element is sufficiently dissolved;
Steel billet after heat preservation is subjected to roughing and finish rolling;Wherein the start rolling temperature of roughing is 1160 DEG C, and finishing temperature is 1080℃;The rolling pass of roughing is 2 times, and reduction ratio is respectively 24% and 28.6%, roughing plate thickness 76mm per pass;Finish rolling Start rolling temperature is 900 DEG C, and finish rolling finishing temperature is 850 DEG C;The rolling pass of finish rolling be 6 times, per pass reduction ratio be 13~ 28%, total reduction 81%;Water cooling is to 520 DEG C (red temperature) after the completion of finish rolling, and control average cooling rate is 25 when water cooling DEG C/s, obtain hot rolled plate, thickness 14mm;
It puts hot rolled plate into insulation quilt slot slow cooling and low-carbon microalloyed Q690 grade high-strength weathering steel is made to room temperature;
The yield strength 700MPa of low-carbon microalloyed Q690 grade high-strength weathering steel, tensile strength 795MPa, elongation percentage 18.6%, -60 DEG C of ballistic work 188J, yield tensile ratio 0.88;Tissue be polygonal ferrite, acicular ferrite and granular bainite, OM tissue is as shown in Figure 2;Welding crack sensibility indices P cm is 0.27%;
Atmospheric corrosion resistance test is carried out, and as a comparison with ordinary carbon steel Q345B, each steel grade chooses 3 pieces of samples Parallel test is carried out, the corrosion weight loss amount of every piece of sample per area per time is calculated, is averaged to obtain average corrosion Rate;By above-mentioned weathering steel compared with the average corrosion rate of Q345B, its relatively corrosive rate is obtained;Above-mentioned weathering steel is put down Equal corrosion weight loss rate is 2.896g/ (m2H), the average corrosion weight-loss ratio of Q345B straight carbon steel is 6.102g/ (m2H), relatively Corrosion rate is 47.5%, illustrates that above-mentioned weathering steel also possesses apparent corrosion resisting property while intensity is greatly improved, Corrosion resisting property is about twice of Q345B straight carbon steel.
Embodiment 2
With embodiment 1, difference is method:
(1) steel billet thickness 90mm, ingredient contain C 0.06%, Si 0.40%, Mn 1.60%, S by weight percentage 0.005%, P 0.015%, Al 0.05%, V 0.11%, N 0.015%, Cr 0.60%, Ni 0.50%, Cu 0.55%, Mo 0.35%;
(2) to 1150 DEG C and 3h is kept the temperature with stove heating;
(3) start rolling temperature of roughing is 1080 DEG C, and finishing temperature is 980 DEG C;The rolling pass of roughing is 3 times, per pass Reduction ratio is respectively 25%, 26% and 27%, roughing plate thickness 36.5mm;Finish rolling start rolling temperature is 900 DEG C, finish rolling finishing temperature It is 810 DEG C;The rolling pass of finish rolling is 6 times, and reduction ratio is 13~28% per pass, total reduction 78%;Water after the completion of finish rolling It is cooled to 460 DEG C, control average cooling rate is 36 DEG C/s, hot rolling plate thickness 8mm when water cooling;
(4) the yield strength 769MPa of low-carbon microalloyed Q690 grade high-strength weathering steel, tensile strength 910MPa, elongation percentage 16.2%, -60 DEG C of ballistic work 161J, yield tensile ratio 0.85;It is as shown in Figure 3 to transmit pattern;Welding crack sensibility indices P cm is 0.25%;
(5) atmospheric corrosion resistance test result are as follows: the average corrosion weight-loss ratio of above-mentioned weathering steel is 2.655g/ (m2· H), relatively corrosive rate is 43.5%.
Embodiment 3
With embodiment 1, difference is method:
(1) steel billet thickness 60mm, ingredient contain C 0.10%, Si 0.10%, Mn 1.20%, S by weight percentage 0.010%, P 0.003%, Al 0.01%, V 0.05%, N 0.01%, Cr 0.30%, Ni 0.30%, Cu 0.15%, Mo 0.15%;
(2) to 1100 DEG C and 4h is kept the temperature with stove heating;
(3) start rolling temperature of roughing be 1050~DEG C, finishing temperature be 960 DEG C;The rolling pass of roughing is 4 times, per pass Secondary reduction ratio is 28%, 25%, 25% and 25%, roughing plate thickness 18mm;;Finish rolling start rolling temperature is 860 DEG C, finish rolling finish to gauge temperature Degree is 810 DEG C;The rolling pass of finish rolling is 7 times, and reduction ratio is 13~28% per pass, total reduction 78%;After the completion of finish rolling Water cooling is to 400 DEG C, and control average cooling rate is 45 DEG C/s, hot rolling plate thickness 4mm when water cooling;
(4) the yield strength 798MPa of low-carbon microalloyed Q690 grade high-strength weathering steel, tensile strength 950MPa, elongation percentage 15.5%, -60 DEG C of ballistic work 100J, yield tensile ratio 0.84;OM tissue is as shown in Figure 4;Welding crack sensibility indices P cm is 0.21%;
(5) atmospheric corrosion resistance test result are as follows: the average corrosion weight-loss ratio of above-mentioned weathering steel is 2.504g/ (m2· H), relatively corrosive rate is 41.0%.

Claims (7)

1. a kind of low-carbon microalloyed Q690 grade high-strength weathering steel, it is characterised in that ingredient contain by weight percentage C 0.03~ 0.10%, Si 0.10~0.50%, Mn 1.20~2.00%, S 0.002~0.010%, P 0.003~0.015%, Al 0.01~0.05%, V 0.05~0.15%, N 0.01~0.02%, Cr 0.30~0.80%, Ni 0.30~0.80%, Cu 0.15~0.55%, Mo 0.15~0.55%, surplus are Fe and other inevitable impurity;Its yield strength 700~ 798MPa, 795~950MPa of tensile strength, elongation percentage 15.5~18.6%, -60 DEG C of ballistic work >=100J, yield tensile ratio 0.84~ 0.88。
2. low-carbon microalloyed Q690 grade high-strength weathering steel according to claim 1, it is characterised in that low-carbon microalloyed Q690 grade high-strength weathering steel with a thickness of 4~14mm.
3. low-carbon microalloyed Q690 grade high-strength weathering steel according to claim 1, it is characterised in that low-carbon microalloyed The tissue of Q690 grade high-strength weathering steel is polygonal ferrite, acicular ferrite and granular bainite.
4. a kind of preparation method of low-carbon microalloyed Q690 grade high-strength weathering steel, it is characterised in that the following steps are included:
(1) set component smelting molten steel is pressed, then cast and is forged to 60~140mm of thickness, obtains steel billet, ingredient is by weight It measures percentage and contains C 0.03~0.10%, Si 0.10~0.50%, Mn 1.20~2.00%, S 0.002~0.010%, P 0.003~0.015%, Al 0.01~0.05%, V 0.05~0.15%, N 0.01~0.02%, Cr 0.30~0.80%, Ni 0.30~0.80%, Cu 0.15~0.55%, Mo 0.15~0.55%, surplus are Fe and other inevitable impurity;
(2) using heating furnace by steel billet with stove heating to 1100~1200 DEG C and keep the temperature 2~4h, to guarantee the abundant austenite of steel billet Change and microalloy element is sufficiently dissolved;
(3) steel billet after heat preservation is subjected to roughing and finish rolling;Wherein the start rolling temperature of roughing is 1050~1160 DEG C, finishing temperature It is 960~1080 DEG C;Finish rolling start rolling temperature is 860~900 DEG C, and finish rolling finishing temperature is 810~850 DEG C;Water after the completion of finish rolling It is cooled to 400~520 DEG C, obtains hot rolled plate;
(4) it puts hot rolled plate into insulation quilt slot slow cooling and low-carbon microalloyed Q690 grade high-strength weathering steel is made to room temperature.
5. the preparation method of low-carbon microalloyed Q690 grade high-strength weathering steel according to claim 4, it is characterised in that step Suddenly the rolling pass of roughing is 2~4 times in (3), and reduction ratio is 24~28.6% per pass.
6. the preparation method of low-carbon microalloyed Q690 grade high-strength weathering steel according to claim 4, it is characterised in that step Suddenly the rolling pass of finish rolling is 6~7 times in (3), and reduction ratio is 13~28% per pass.
7. the preparation method of low-carbon microalloyed Q690 grade high-strength weathering steel according to claim 4, it is characterised in that step Suddenly controlling cooling velocity in (3) when water cooling is 25~45 DEG C/s.
CN201811338543.9A 2018-11-12 2018-11-12 Low-carbon microalloyed Q690-grade high-strength weathering steel and preparation method thereof Active CN109402508B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811338543.9A CN109402508B (en) 2018-11-12 2018-11-12 Low-carbon microalloyed Q690-grade high-strength weathering steel and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811338543.9A CN109402508B (en) 2018-11-12 2018-11-12 Low-carbon microalloyed Q690-grade high-strength weathering steel and preparation method thereof

Publications (2)

Publication Number Publication Date
CN109402508A true CN109402508A (en) 2019-03-01
CN109402508B CN109402508B (en) 2020-09-29

Family

ID=65472612

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811338543.9A Active CN109402508B (en) 2018-11-12 2018-11-12 Low-carbon microalloyed Q690-grade high-strength weathering steel and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109402508B (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110205565A (en) * 2019-06-01 2019-09-06 东莞市东莞理工科技创新研究院 A kind of 690 steel of disperse nano reinforcement and its manufacturing method
CN110863143A (en) * 2019-11-27 2020-03-06 东北大学 960MPa grade ultra-high strength steel with excellent low temperature toughness and manufacturing method thereof
CN111020409A (en) * 2019-12-31 2020-04-17 苏州雷格姆海洋石油设备科技有限公司 High-strength microalloyed steel, underwater oil and gas pipeline quick connector and manufacturing method
CN111020376A (en) * 2019-11-14 2020-04-17 舞阳钢铁有限责任公司 Low-yield-ratio high-toughness 770 MPa-grade weather-resistant bridge steel plate and production method thereof
CN111101071A (en) * 2020-02-25 2020-05-05 湖南华菱涟源钢铁有限公司 High-strength weathering steel and production method thereof
CN111172458A (en) * 2020-01-15 2020-05-19 北京科技大学 High-temperature-resistant high-humidity high-salt-spray-resistant weather-resistant steel for marine atmospheric environment and preparation method thereof
CN113106335A (en) * 2021-03-11 2021-07-13 邯郸钢铁集团有限责任公司 800 MPa-grade high-strength weather-resistant girder steel belt and preparation method thereof
CN113249659A (en) * 2021-04-15 2021-08-13 首钢集团有限公司 High-strength anti-crack steel with excellent ductility and preparation method thereof
CN113278869A (en) * 2021-05-07 2021-08-20 石横特钢集团有限公司 Smelting process and production method of blank for atmospheric corrosion resistant steel bar
CN113549834A (en) * 2021-07-22 2021-10-26 中国铁道科学研究院集团有限公司金属及化学研究所 Weather-resistant steel for bogie frame and preparation method thereof
US20220025474A1 (en) * 2020-12-22 2022-01-27 Northeastern University 785 MPa LEVEL EXTRA-THICK QUENCHED AND TEMPERED RACK STEEL PLATE FOR OFFSHORE PLATFORMS AND PREPARATION METHOD THEREFOR
CN114875299A (en) * 2022-05-25 2022-08-09 湖南华菱湘潭钢铁有限公司 Production method of Q690 high-corrosion-resistance high-strength offshore structural steel
CN116043108A (en) * 2022-12-13 2023-05-02 东北大学 Low-yield-ratio V-N microalloyed 690 MPa-level medium plate and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101892431A (en) * 2010-07-07 2010-11-24 江苏省沙钢钢铁研究院有限公司 Hot-rolled weather-proof bridge steel with yield strength of 500MPa and manufacturing method thereof
CN102534417A (en) * 2012-02-08 2012-07-04 东北大学 High-performance bridge weathering steel containing Mo and preparation method thereof
JP2015516505A (en) * 2012-03-14 2015-06-11 バオシャン アイアン アンド スティール カンパニー リミテッド Manufacturing method of 700MPa class high strength weathering steel by continuous strip casting method
CN106947913A (en) * 2017-03-21 2017-07-14 马钢(集团)控股有限公司 A kind of high-strength high-toughness hot rolls weather-resistant steel plate and preparation method thereof
CN108193141A (en) * 2017-12-29 2018-06-22 东北大学 A kind of Q550 rank hot-strips of V-N-Cr microalloyings and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101892431A (en) * 2010-07-07 2010-11-24 江苏省沙钢钢铁研究院有限公司 Hot-rolled weather-proof bridge steel with yield strength of 500MPa and manufacturing method thereof
CN102534417A (en) * 2012-02-08 2012-07-04 东北大学 High-performance bridge weathering steel containing Mo and preparation method thereof
JP2015516505A (en) * 2012-03-14 2015-06-11 バオシャン アイアン アンド スティール カンパニー リミテッド Manufacturing method of 700MPa class high strength weathering steel by continuous strip casting method
CN106947913A (en) * 2017-03-21 2017-07-14 马钢(集团)控股有限公司 A kind of high-strength high-toughness hot rolls weather-resistant steel plate and preparation method thereof
CN108193141A (en) * 2017-12-29 2018-06-22 东北大学 A kind of Q550 rank hot-strips of V-N-Cr microalloyings and preparation method thereof

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110205565A (en) * 2019-06-01 2019-09-06 东莞市东莞理工科技创新研究院 A kind of 690 steel of disperse nano reinforcement and its manufacturing method
CN111020376A (en) * 2019-11-14 2020-04-17 舞阳钢铁有限责任公司 Low-yield-ratio high-toughness 770 MPa-grade weather-resistant bridge steel plate and production method thereof
CN110863143A (en) * 2019-11-27 2020-03-06 东北大学 960MPa grade ultra-high strength steel with excellent low temperature toughness and manufacturing method thereof
CN111020409B (en) * 2019-12-31 2021-11-05 苏州雷格姆海洋石油设备科技有限公司 High-strength microalloyed steel, underwater oil and gas pipeline quick connector and manufacturing method
CN111020409A (en) * 2019-12-31 2020-04-17 苏州雷格姆海洋石油设备科技有限公司 High-strength microalloyed steel, underwater oil and gas pipeline quick connector and manufacturing method
CN111172458A (en) * 2020-01-15 2020-05-19 北京科技大学 High-temperature-resistant high-humidity high-salt-spray-resistant weather-resistant steel for marine atmospheric environment and preparation method thereof
CN111101071A (en) * 2020-02-25 2020-05-05 湖南华菱涟源钢铁有限公司 High-strength weathering steel and production method thereof
US20220025474A1 (en) * 2020-12-22 2022-01-27 Northeastern University 785 MPa LEVEL EXTRA-THICK QUENCHED AND TEMPERED RACK STEEL PLATE FOR OFFSHORE PLATFORMS AND PREPARATION METHOD THEREFOR
CN113106335A (en) * 2021-03-11 2021-07-13 邯郸钢铁集团有限责任公司 800 MPa-grade high-strength weather-resistant girder steel belt and preparation method thereof
CN113249659A (en) * 2021-04-15 2021-08-13 首钢集团有限公司 High-strength anti-crack steel with excellent ductility and preparation method thereof
CN113249659B (en) * 2021-04-15 2022-01-18 首钢集团有限公司 High-strength anti-crack steel with excellent ductility and preparation method thereof
CN113278869A (en) * 2021-05-07 2021-08-20 石横特钢集团有限公司 Smelting process and production method of blank for atmospheric corrosion resistant steel bar
CN113549834A (en) * 2021-07-22 2021-10-26 中国铁道科学研究院集团有限公司金属及化学研究所 Weather-resistant steel for bogie frame and preparation method thereof
CN113549834B (en) * 2021-07-22 2022-03-22 中国铁道科学研究院集团有限公司金属及化学研究所 Weather-resistant steel for bogie frame and preparation method thereof
CN114875299A (en) * 2022-05-25 2022-08-09 湖南华菱湘潭钢铁有限公司 Production method of Q690 high-corrosion-resistance high-strength offshore structural steel
CN116043108A (en) * 2022-12-13 2023-05-02 东北大学 Low-yield-ratio V-N microalloyed 690 MPa-level medium plate and preparation method thereof

Also Published As

Publication number Publication date
CN109402508B (en) 2020-09-29

Similar Documents

Publication Publication Date Title
CN109402508A (en) A kind of low-carbon microalloyed Q690 grade high-strength weathering steel and preparation method thereof
CN100455692C (en) High-strength weathering steel and method of manufacturing same
CN108486466B (en) A kind of yield strength 550MPa grade high ductility weather-resistant steel plate and preparation method thereof
CN110318006B (en) Cold-rolled weathering steel and preparation method thereof
CN101168826B (en) High-performance low-carbon bainite structural steel and production method thereof
CN101660099B (en) High-strength low-alloy hot-rolled ferrite bainite weathering steel and production method thereof
CN103361569B (en) A kind of Ultralow temperature weather-proof structural steel plate and production method thereof
CN103103458B (en) High strength weathering resistant steel and preparation method
CN101892431A (en) Hot-rolled weather-proof bridge steel with yield strength of 500MPa and manufacturing method thereof
CN109112419A (en) Quenched and tempered EH550 super-thick steel plate for ocean engineering and manufacturing method thereof
CN109881091A (en) High-strength weather-resistant steel thin strip and production method thereof
CN107475624A (en) Titaniferous think gauge weathering steel and its production method
CN110527915A (en) A kind of 460MPa grades of hot rolled H-shaped and its production method
US20150361518A1 (en) 500 MPa GRADE LONGITUDINALLY WELDED STEEL PIPE WITH LOW YIELD RATIO AND MANUFACTURING METHOD THEREFOR
CN108796370A (en) A kind of the welding structure fire-resistant and weather-resistant steel and its production method of yield strength &gt;=690MPa
CN113846269B (en) Cold-rolled high-weather-resistance steel plate with high strength and plasticity and preparation method thereof
CN110578085A (en) Hot-rolled steel plate with yield strength of 500MPa and atmospheric corrosion resistance
CN103468905A (en) 485 MPa-grade pipeline steel hot-rolled coil and manufacturing method thereof
CN101376950A (en) Superhigh intensity cold rolling weather resisting steel plate and manufacturing method thereof
CN107841689A (en) A kind of weather-resistant steel plate and its manufacture method
CN109207854A (en) Super-wide-specification high-strength high-toughness steel for ocean engineering and manufacturing method thereof
CN108193141A (en) A kind of Q550 rank hot-strips of V-N-Cr microalloyings and preparation method thereof
CN110066969A (en) A kind of high anti-corrosion high aluminium content low density steel and preparation method thereof
CN110358970A (en) 1100MPa grades of yield strength of welding structure bainite high-strength steel and preparation method thereof
CN105018856B (en) The vertically and horizontally little structural steel for bridge plate of mechanical property difference and its manufacture method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant