CN109401640A - A kind of preparation method of magnetism material silica gel composite and magnetic silica gel health-care eye shade - Google Patents
A kind of preparation method of magnetism material silica gel composite and magnetic silica gel health-care eye shade Download PDFInfo
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- CN109401640A CN109401640A CN201811319838.1A CN201811319838A CN109401640A CN 109401640 A CN109401640 A CN 109401640A CN 201811319838 A CN201811319838 A CN 201811319838A CN 109401640 A CN109401640 A CN 109401640A
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- silica gel
- eyeshade
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 239000000741 silica gel Substances 0.000 title claims abstract description 54
- 229910002027 silica gel Inorganic materials 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 239000002131 composite material Substances 0.000 title claims abstract description 29
- 239000000463 material Substances 0.000 title claims abstract description 16
- 230000005389 magnetism Effects 0.000 title claims description 16
- 238000002156 mixing Methods 0.000 claims abstract description 26
- 230000000694 effects Effects 0.000 claims abstract description 18
- 238000001467 acupuncture Methods 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 14
- QJVKUMXDEUEQLH-UHFFFAOYSA-N [B].[Fe].[Nd] Chemical compound [B].[Fe].[Nd] QJVKUMXDEUEQLH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001172 neodymium magnet Inorganic materials 0.000 claims abstract description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000499 gel Substances 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 239000003292 glue Substances 0.000 claims description 20
- 239000012943 hotmelt Substances 0.000 claims description 17
- 239000004575 stone Substances 0.000 claims description 12
- 239000002103 nanocoating Substances 0.000 claims description 11
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 230000001954 sterilising effect Effects 0.000 claims description 10
- 238000004659 sterilization and disinfection Methods 0.000 claims description 10
- 230000002209 hydrophobic effect Effects 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 7
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 6
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 5
- 230000005684 electric field Effects 0.000 claims description 5
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 235000010755 mineral Nutrition 0.000 claims description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 229920005862 polyol Polymers 0.000 claims description 5
- 150000003077 polyols Chemical class 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 238000009834 vaporization Methods 0.000 claims description 5
- 230000008016 vaporization Effects 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 claims description 4
- 239000011812 mixed powder Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 claims description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- 244000303965 Cyamopsis psoralioides Species 0.000 claims 1
- 239000004831 Hot glue Substances 0.000 claims 1
- 238000010041 electrostatic spinning Methods 0.000 claims 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000000696 magnetic material Substances 0.000 abstract description 11
- 239000006247 magnetic powder Substances 0.000 abstract description 8
- 239000008119 colloidal silica Substances 0.000 abstract description 5
- 230000017531 blood circulation Effects 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 230000004060 metabolic process Effects 0.000 abstract description 3
- 230000004089 microcirculation Effects 0.000 abstract description 3
- 230000002792 vascular Effects 0.000 abstract description 2
- 210000000707 wrist Anatomy 0.000 abstract description 2
- 210000001508 eye Anatomy 0.000 description 29
- 230000006872 improvement Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 7
- 150000004040 pyrrolidinones Chemical class 0.000 description 5
- 229920002907 Guar gum Polymers 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 238000004049 embossing Methods 0.000 description 4
- 229960002154 guar gum Drugs 0.000 description 4
- 235000010417 guar gum Nutrition 0.000 description 4
- 239000000665 guar gum Substances 0.000 description 4
- 210000003128 head Anatomy 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- 208000006011 Stroke Diseases 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 210000003746 feather Anatomy 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000000554 physical therapy Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- QUKRIOLKOHUUBM-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl prop-2-enoate Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCOC(=O)C=C QUKRIOLKOHUUBM-UHFFFAOYSA-N 0.000 description 1
- 206010008190 Cerebrovascular accident Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 230000002008 hemorrhagic effect Effects 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 230000004379 myopia Effects 0.000 description 1
- 208000001491 myopia Diseases 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000002936 tranquilizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F9/00—Methods or devices for treatment of the eyes; Devices for putting-in contact lenses; Devices to correct squinting; Apparatus to guide the blind; Protective devices for the eyes, carried on the body or in the hand
- A61F9/04—Eye-masks ; Devices to be worn on the face, not intended for looking through; Eye-pads for sunbathing
- A61F9/045—Eye-shades or visors; Shields beside, between or below the eyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Ophthalmology & Optometry (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Inorganic Chemistry (AREA)
- Magnetic Treatment Devices (AREA)
- Radiation-Therapy Devices (AREA)
Abstract
The present invention provides a kind of magnetic material silica gel composite and the preparation methods of magnetic silica gel health-care eye shade, include the following steps: first, neodymium iron boron powder are added in liquid-state silicon gel, and be uniformly mixing to obtain mixing liquid；Second, after mixing liquid is poured into mold, carry out the molding that is heating and curing；Magnetic silica gel composite sheet is obtained after demoulding, the new material has following the utility model has the advantages that the magnetic powder in magnetic material silica gel composite is generally evenly distributed in colloidal silica, colloidal silica is the carrier of magnetic powder, magnetic powder is permanent magnet, it can promote the blood circulation and metabolism of human body, there is preferable adjustment effect to the capillary of human body, microcirculation, wherein the magnetic field of permanent magnet can soften capillary, increase the elasticity of vascular wall；The health product that various suitable human bodies are worn, such as eyeshade, Sofa cushion, pillow pad, insole, wrist guard, knee-pad, mattress, underwear can be made in this new material, have preferable health-care effect to the acupuncture point of human body.
Description
Technical field
The present invention relates to field of new materials, the systems of specially a kind of magnetic material silica gel composite and magnetic silica gel health-care eye shade
Preparation Method.
Background technique
In existing health-care method, to achieve the purpose that health care, generally human acupoint is implemented to make using drug or magnetic field
For the method treated.According to the meridian theory in China's traditional medicine, by human acupoint come diseases prevention, cure the disease, have reaction
The features such as fast and high-efficient.There are two types of existing this kind of acupoint stimulation is general: after by doctor's diagnosis and treatment, drug being applied to cave
On position, or with adhesive plaster magnetic powder being pasted on acupuncture point, another kind is to dress magnetic powder (block) sewing on clothing, then by patient,
Both methods operates all more troublesome, can only act on human body the short time, and since the acupuncture point of human body is throughout whole body,
This method does not ensure that magnetic field being capable of all standing human body.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of magnetic material silica gel composite and magnetic silica gel health-care eye shades
Preparation method.
In order to achieve the above object, the present invention is achieved by the following technical programs.
A kind of preparation method of magnetism material silica gel composite, includes the following steps:
First, neodymium iron boron powder is added in liquid-state silicon gel, and be uniformly mixing to obtain mixing liquid；
Second, after mixing liquid is poured into mold, carry out the molding that is heating and curing；Magnetic silica gel composite sheet is obtained after demoulding
Material.
As a kind of improvement of magnetic material silica gel composite preparation method of the invention, in the first step, the neodymium iron boron
Powder has been additionally added negative ion powder, and the two is uniformly mixed to get mixed-powder and is then added in liquid-state silicon gel.
As a kind of improvement of magnetic material silica gel composite preparation method of the invention, in the first step, the mixed powder
Also contain stone needle powder in end.
It further include third step after second step as a kind of improvement of magnetic material silica gel composite preparation method of the invention
Suddenly, it is coated with infrared ray nano coating in the one side of magnetic silica gel composite sheet, infrared ray nano coating is to contain titanium dioxide
With the layer mineral of zirconium dioxide.
A kind of preparation method of magnetism silica gel health-care eye shade, includes the following steps: to above-mentioned magnetic silica gel composite sheet
Be punched out and be processed into eyeshade ontology, the eyeshade ontology include the eye band contacted with human eye portion acupuncture point and with head part cave
The headband of position contact, eye band install at human eye position and are set to hollow cavity, and the headband rear end is provided with multiple for adjusting
The convex buckle wearing the through-hole of elasticity and matching with through-hole.
The preparation method of another magnetism silica gel health-care eye shade, includes the following steps: to prepare in magnetic material silica gel composite
In the second step of method, the mold has the type chamber to match with eyeshade shape, and the upper bottom surface or bottom surface of the type chamber are set
Multiple protrusions are equipped with, mixing liquid pours into after mold and forms the eyeshade sheet with mounting groove in raised position by solidifying demoulding
Body；The stone needle particle that matching is then buckled into the mounting groove of eyeshade ontology, is made eyeshade finished product.
A kind of improvement of preparation method as magnetic silica gel health-care eye shade of the invention, the opening of the mounting groove are less than interior
Portion's cavity.
A kind of improvement of preparation method as magnetic silica gel health-care eye shade of the invention, the headband and eye of the eyeshade ontology
The consistency of thickness of band, with a thickness of 1-3mm.
A kind of improvement of preparation method as magnetic silica gel health-care eye shade of the invention, the headband and eye of the eyeshade ontology
The thickness of band is 2mm.
A kind of improvement of preparation method as silica gel health-care eye shade of the invention magnetic, further includes following steps, and one, in eye
Cover body or eyeshade finished surface are embossed/frosted processing；Two, to embossing face/frosting of eyeshade ontology or eyeshade finished product
By 50~80 degrees Celsius of hot melt glue of web plate silk-screen, the hot melt glue formula number is respectively as follows: n-butanol 20
~30 parts, hydroxypropyl acrylate 24~35,20~30 parts of polyether polyol, 10~15 parts of sodium bicarbonate, 10~20 parts of guar gum,
20~30 parts of vinyltriethoxysilane；Three, to eyeshade ontology or eyeshade finished product be covered with hot melt glue it is laminated carry out it is quiet
Electric flocking processing, is formed on its surface flocking layer and cools and solidifies；Four, to the flocking layer surface of eyeshade ontology or eyeshade finished product into
Parts by weight are respectively 80~90 parts of hydrophobicity fluoride and polypenthylene by row low-temp low-pressure plasma electroplating (PECVD plated film)
The mixing liquid that 20~30 parts of pyrrolidones is heated to 160 degrees Celsius of vaporizations after evenly mixing, through PECVD filming equipment, and passes through
The effect of high-frequency electric field is deposited on flocking layer surface, forms the sterilization of firm nano-sized hydrophobic and receives layer.
The present invention provides a kind of magnetic material silica gel composite and the preparation methods of magnetic silica gel health-care eye shade, have following
The utility model has the advantages that by the present invention in that being integrally formed with magnetic material silica gel composite, magnetic powder therein is generally evenly distributed in colloidal silica
In, colloidal silica is the carrier of magnetic powder, and magnetic powder is permanent magnet, acts on human body correlation cave incessantly using the magnetic line of force of permanent magnet
Position plays the effect at constantly stimulation acupuncture point, is different from Traditional Chinese Medicine to the means of acupoint stimulation, can be 24 hours, 360 degree with whole day
The position of physical therapy is needed on covering human body, and then promotes the blood circulation and metabolism of human body, is had to capillary, microcirculation
Preferable adjustment effect, wherein the magnetic field of permanent magnet can soften capillary, increase the elasticity of vascular wall；This new material can
The product that various suitable human bodies are worn is made, such as eyeshade, Sofa cushion, pillow pad, insole, wrist guard, knee-pad, mattress, underwear
Etc., there is preferable health-care effect to the acupuncture point of human body；Wherein the eyeshade made of this material to prevention ishemic stroke and goes out
Hemorrhagic apoplexy has obvious effect；It is provided on eyeshade hollow out (cavity), when wearing does not influence with eye, eye made of the present invention
Cover is for existing eye vibration massage function product, and structure is simple, and cost is relatively low, and lightweight is soft and smooth, easy to carry, is suitable for pushing away
Extensively, there is good effect to improvement myopia；Preferably, flocking layer is bonded by special hot melt glue in eyeshade finished surface,
The comfort level of wearing is more improved, and flocking layer adhesive force is high, fitting is close, is not easy to lose hair or feathers；Simultaneously in flocking layer surface
It is coated with nano-sized hydrophobic sterilization and receives layer, the cleaning that eyeshade finished surface can be kept permanent, while having the function of sterilization.
Detailed description of the invention
Fig. 1 is the schematic perspective view of eyeshade obtained by embodiment two；
Fig. 2 is the structural schematic diagram after the expansion of eyeshade obtained by embodiment two；
Fig. 3 is the structural schematic diagram of two cross section of embodiment
Fig. 4 is the structural schematic diagram after embodiment two is unfolded；
Fig. 5 is the structural schematic diagram of three cross section of embodiment.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Embodiment one is a kind of preparation method of magnetic material silica gel composite, is included the following steps:
First, by neodymium iron boron powder, negative ion powder is stirred evenly after the mixing of stone needle powder and is added in liquid-state silicon gel,
And it is uniformly mixing to obtain mixing liquid；
Second, after mixing liquid is poured into mold, carry out the molding that is heating and curing；Magnetic silica gel composite sheet is obtained after demoulding
Material；
Third, magnetic silica gel composite sheet one side be coated with infrared ray nano coating, infrared ray nano coating be containing
There is the layer mineral of titanium dioxide and zirconium dioxide.
Embodiment two is a kind of preparation method of magnetic silica gel health-care eye shade, is carried out to above-mentioned magnetic silica gel composite sheet
Eyeshade ontology is made in Punching Technology, as shown in Figure 1-3, the eyeshade ontology 1 include the eye band 11 that is contacted with human eye portion acupuncture point with
And the headband 12 contacted with head part acupuncture point, eye band 11 install at human eye position and are set to hollow cavity 110, after the headband 12
End is provided with multiple preferred for adjusting the through-hole 131 for wearing elasticity and the convex buckle 132 with the matching of through-hole 131, convex buckle 132
Using buckle, the dispersed-powder in the magnetism material silica gel composite is distributed in colloidal silica, the headband of the eyeshade ontology
With the consistency of thickness of eye band, thickness is in 2mm.
The characteristics of this eyeshade, is compared than existing eyeshade, and structure is simple, by the way that neodymium iron boron powder is evenly distributed on silica gel
In vivo, it is in close contact with the acupuncture point of human eyeball's surrounding and head acupuncture point, human body can be covered within 24 hours, 360 degree with whole day
There is good facilitation at acupuncture point to the improvement of the eyesight of people, simultaneously because be set as cavity in the middle part of eyeshade, does not influence with eye, can be with
It uses anywhere or anytime.
Embodiment three provides the preparation method of another magnetic silica gel health-care eye shade, as shown in figure 4, it is in embodiment one
On the basis of, be embedded with multiple stone needle particles in the medial surface of eyeshade ontology and human contact, stone needle have tranquilizing the mind, recuperating qi-blood,
The effect of dredging the channel, stone needle can reach some treatments and health-care effect, stone acupuncture needle by crystallite, infrared and pulse wave band
Stone can issue many far ir rays and ultrasonic pulse beneficial to human body, promote blood microcirculation, conditioning metabolism,
Its effect is equivalent to far infrared therapeutic apparatus+ultrasonic therapeutic apparatus double action.
The eyeshade ontology and the medial surface of human contact are coated with infrared ray nano coating, infrared ray nano coating be containing
There is the layer mineral of titanium dioxide and zirconium dioxide.
Embodiment three provides another eyeshade for eye and head acupuncture point health care and physical therapy, multiple in magnetic silica gel
In the second step of condensation material preparation method, the mold has the type chamber to match with eyeshade shape, the upper bottom surface of the type chamber
Or bottom surface is provided with multiple protrusions, mixing liquid is poured into after mold and is formed in raised position with mounting groove by solidification demoulding
Eyeshade ontology；Wherein the opening of mounting groove is less than internal cavities, and the stone acupuncture needle of matching is then buckled into the mounting groove of eyeshade ontology
Eyeshade finished product is made, as shown in Figure 4 in stone particle.
As shown in figure 5, it is on the basis of example 1, it is covered in the medial surface of eyeshade ontology and human contact infrared
Line nano coating, infrared ray nano coating are the layer mineral containing titanium dioxide and zirconium dioxide, and this coating is the prior art,
This will not be repeated here for its producing principle, and the effect of infrared coating is, it can make human skin generate heat, and accelerates blood circulation,
To reach health-care effect.
Example IV is embossed/frosted processing to eyeshade body surface on the basis of example 2；To eyeshade sheet
Embossing face/frosting of body or eyeshade finished product passes through 50 degrees Celsius of web plate silk-screen of hot melt glue, and the hot melt glue formula is pressed
Parts by weight are respectively as follows: 20 parts of n-butanol, hydroxypropyl acrylate 24,20 parts of polyether polyol, 10 parts of sodium bicarbonate, guar gum 10
Part, 20 parts of vinyltriethoxysilane；The laminated progress electrostatic plant of hot melt glue is covered with to eyeshade ontology or eyeshade finished product
Suede processing, is formed on its surface flocking layer and cools and solidifies；Low temperature is carried out to the flocking layer surface of eyeshade ontology or eyeshade finished product
Parts by weight are respectively 80 parts and 20 parts of polypenthylene pyrrolidones of hydrophobicity fluoride of mixing liquid by low-voltage plasma plating
160 degrees Celsius of vaporizations are heated to through PECVD filming equipment after evenly mixing and effect through high-frequency electric field is deposited on flocking layer table
Face forms the sterilization of firm nano-sized hydrophobic and receives layer, obtains example IV.
Embodiment five is embossed/frosted processing to eyeshade body surface on the basis of example 2；To eyeshade sheet
Embossing face/frosting of body or eyeshade finished product passes through 65 degrees Celsius of web plate silk-screen of hot melt glue, and the hot melt glue formula is pressed
Parts by weight are respectively as follows: 25 parts of n-butanol, hydroxypropyl acrylate 30,25 parts of polyether polyol, 12 parts of sodium bicarbonate, guar gum 15
Part, 25 parts of vinyltriethoxysilane；The laminated progress electrostatic plant of hot melt glue is covered with to eyeshade ontology or eyeshade finished product
Suede processing, is formed on its surface flocking layer and cools and solidifies；Low temperature is carried out to the flocking layer surface of eyeshade ontology or eyeshade finished product
Parts by weight are respectively 85 parts and 25 parts of polypenthylene pyrrolidones of hydrophobicity fluoride of mixing liquid by low-voltage plasma plating
160 degrees Celsius of vaporizations are heated to through PECVD filming equipment after evenly mixing and effect through high-frequency electric field is deposited on flocking layer table
Face forms the sterilization of firm nano-sized hydrophobic and receives layer, obtains embodiment five.
Embodiment six is embossed/frosted processing to eyeshade body surface on the basis of example 2；To eyeshade sheet
Embossing face/frosting of body or eyeshade finished product passes through 65 degrees Celsius of web plate silk-screen of hot melt glue, and the hot melt glue formula is pressed
Parts by weight are respectively as follows: 30 parts of n-butanol, hydroxypropyl acrylate 35,30 parts of polyether polyol, 15 parts of sodium bicarbonate, guar gum 20
Part, 30 parts of vinyltriethoxysilane；The laminated progress electrostatic plant of hot melt glue is covered with to eyeshade ontology or eyeshade finished product
Suede processing, is formed on its surface flocking layer and cools and solidifies；Low temperature is carried out to the flocking layer surface of eyeshade ontology or eyeshade finished product
Parts by weight are respectively 90 parts and 30 parts of polypenthylene pyrrolidones of hydrophobicity fluoride of mixing liquid by low-voltage plasma plating
160 degrees Celsius of vaporizations are heated to through PECVD filming equipment after evenly mixing and effect through high-frequency electric field is deposited on flocking layer table
Face forms the sterilization of firm nano-sized hydrophobic and receives layer, obtains embodiment six.
Above-described embodiment four, five, six is embossed/frosted processing to eyeshade Silica Surface, can increase the silica gel of eyeshade
The bond area and bonding force on surface and glue and fiber (villus), the special hot melt glue of silk-screen is on eyeshade finished product to be bonded
Flocking layer, improves the comfort level with product and human contact, and glue in the prior art can not make silica gel and fiber (suede
Face) firmly fit together, using hot melt glue special in this method, can make flocking layer and silica gel face close adhesion and
It is not easy to lose hair or feathers；One nano-sized hydrophobic is plated in product surface by existing PECVD plasma film coating technology in flocking layer surface simultaneously
Layer is received in sterilization, and hydrophobicity fluoride therein is preferably adopted as 1,1,1,2,2,3,3,4,4,5,5,6,6- ten three fluoro- 8- iodine
Octane and/or 1H, 1H, 2H, 2H- perfluoro decyl acrylate are a kind of hydrophobic polymer coatings, avoid human secretory
Sweat be sticked on eyeshade product, remain the permanent cleaning of product surface, while polypenthylene pyrrolidones is a kind of sterilization
Agent makes nano coating have the effect of sterilization.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (10)
1. a kind of preparation method of magnetism material silica gel composite, which comprises the steps of:
First, neodymium iron boron powder is added in liquid-state silicon gel, and be uniformly mixing to obtain mixing liquid；
Second, after mixing liquid is poured into mold, carry out the molding that is heating and curing；Magnetic silica gel composite sheet is obtained after demoulding.
2. the preparation method of magnetism material silica gel composite according to claim 1, which is characterized in that in the first step,
The neodymium iron boron powder has been additionally added negative ion powder, and the two is uniformly mixed to get mixed-powder and is then added in liquid-state silicon gel.
3. the preparation method of magnetism material silica gel composite according to claim 1, which is characterized in that in the first step,
Also contain stone needle powder in the mixed-powder.
4. the preparation method of magnetism material silica gel composite according to claim 1, which is characterized in that also wrapped after second step
Include third step, magnetic silica gel composite sheet one side be coated with infrared ray nano coating, infrared ray nano coating be containing
The layer mineral of titanium dioxide and zirconium dioxide.
5. a kind of preparation method of magnetism silica gel health-care eye shade, which comprises the steps of: to described in claim 1
Magnetic silica gel composite sheet be punched out and be processed into eyeshade ontology, the eyeshade ontology includes contacting with human eye portion acupuncture point
Headband eye band and contacted with head part acupuncture point, eye band install at human eye position and are set to hollow cavity, the headband rear end
It is provided with multiple for adjusting the convex buckle wearing the through-hole of elasticity and matching with through-hole.
6. the preparation method of another magnetism silica gel health-care eye shade, which comprises the steps of: in claim 1
In second step, the mold design is provided at the type chamber to match with eyeshade shape, the upper bottom surface or bottom surface of the type chamber
Multiple protrusions, mixing liquid pour into after mold and form the eyeshade ontology with mounting groove in raised position by solidifying demoulding；With
The stone needle particle for buckling into matching in the mounting groove of eyeshade ontology afterwards, is made eyeshade finished product.
7. the preparation method of magnetism silica gel health-care eye shade according to claim 6, which is characterized in that the mounting groove is opened
Mouth is less than internal cavities.
8. the preparation method of magnetism silica gel health-care eye shade according to claim 5 or 6, it is characterised in that: the eyeshade sheet
The headband of body and the consistency of thickness of eye band, with a thickness of 1-3mm.
9. the preparation method of magnetism silica gel health-care eye shade according to claim 5 or 6, it is characterised in that: the eyeshade sheet
The headband of body and the thickness of eye band are 2mm.
10. the preparation method of magnetism silica gel health-care eye shade according to claim 5 or 6, which is characterized in that further include as follows
Step: one, in eyeshade ontology or eyeshade finished surface it is embossed/frosted processing；Two, to the pressure of eyeshade ontology or eyeshade finished product
Flower face/frosting passes through 50~80 degrees Celsius of web plate silk-screen of hot melt glue, the hot melt glue formula number difference
Are as follows: 20~30 parts of n-butanol, hydroxypropyl acrylate 24~35,20~30 parts of polyether polyol, 10~15 parts of sodium bicarbonate, Guar
10~20 parts of glue, 20~30 parts of vinyltriethoxysilane；Three, hot melt adhesive water layer is covered with to eyeshade ontology or eyeshade finished product
Electrostatic spinning processing is carried out on one side, is formed on its surface flocking layer and is cooled and solidified；Four, to the plant of eyeshade ontology or eyeshade finished product
Pile layer surface carries out low-temp low-pressure plasma electroplating, is respectively 80~90 parts of hydrophobicity fluoride and polypenthylene pyrrole by parts by weight
The mixing liquid that 20~30 parts of pyrrolidone is heated to 160 degrees Celsius of vaporizations after evenly mixing, through PECVD filming equipment, and through height
The effect of frequency electric field is deposited on flocking layer surface, forms the sterilization of firm nano-sized hydrophobic and receives layer.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110559126A (en) * | 2019-08-13 | 2019-12-13 | 深圳恩必德电子科技有限公司 | waterproof and antibacterial perforated graphene eye patch and manufacturing process thereof |
| CN115472370A (en) * | 2022-09-20 | 2022-12-13 | 北京大学 | Flexible permanent magnetic material, preparation method and application thereof in magnetic biological effect product |
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|---|---|---|---|---|
| CN105013087A (en) * | 2015-07-09 | 2015-11-04 | 林忠义 | Ingredients, a preparation method and application of an organic material comprising magnet, far-infrared and negative ion materials |
| CN105797279A (en) * | 2016-03-03 | 2016-07-27 | 广东顺德安信药业有限公司 | Multifunctional far-infrared ray negative ion magnetic treatment silica gel beauty instrument and associated cosmetics |
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- 2018-11-07 CN CN201811319838.1A patent/CN109401640A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105013087A (en) * | 2015-07-09 | 2015-11-04 | 林忠义 | Ingredients, a preparation method and application of an organic material comprising magnet, far-infrared and negative ion materials |
| CN105797279A (en) * | 2016-03-03 | 2016-07-27 | 广东顺德安信药业有限公司 | Multifunctional far-infrared ray negative ion magnetic treatment silica gel beauty instrument and associated cosmetics |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110559126A (en) * | 2019-08-13 | 2019-12-13 | 深圳恩必德电子科技有限公司 | waterproof and antibacterial perforated graphene eye patch and manufacturing process thereof |
| CN115472370A (en) * | 2022-09-20 | 2022-12-13 | 北京大学 | Flexible permanent magnetic material, preparation method and application thereof in magnetic biological effect product |
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Application publication date: 20190301 |