CN109400738A - The preparation and the application in reactive dyeing of a kind of modified burdock polysaccharide - Google Patents
The preparation and the application in reactive dyeing of a kind of modified burdock polysaccharide Download PDFInfo
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- CN109400738A CN109400738A CN201811256845.1A CN201811256845A CN109400738A CN 109400738 A CN109400738 A CN 109400738A CN 201811256845 A CN201811256845 A CN 201811256845A CN 109400738 A CN109400738 A CN 109400738A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0003—General processes for their isolation or fractionation, e.g. purification or extraction from biomass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Abstract
The present invention relates to kind of the preparation of modified burdock polysaccharide and the applications in reactive dyeing, belong to staining technique field, modified burdock polysaccharide the preparation method comprises the following steps: fructus arctii is dried in vacuo, it is ground into powder, it is placed in reactor and is extracted with sodium hydroxide, supernatant salt acid for adjusting pH value to 3.0 after extraction, supernatant is collected by centrifugation, supernatant is concentrated under reduced pressure, it is mixed again with ethanol solution, after sediment is precipitated, gained supernatant is centrifuged again, collect precipitating, 60 DEG C drying to constant weight, up to burdock polysaccharide, burdock polysaccharide is modified with 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride, up to modified burdock polysaccharide.The present invention is extracted burdock polysaccharide from natural plants fructus arctii, then burdock polysaccharide is carried out etherification modified, and modified burdock polysaccharide has been prepared, has improved its filming performance, crosslinked action can be generated between dyestuff, fiber, to play good tint retention.
Description
Technical field
The present invention relates to staining technique fields, and in particular to the preparation of a kind of modified burdock polysaccharide and in reactive dyeing
In application.
Background technique
There are some water soluble groups in the molecular structure of reactive dye, and dyefastness especially color fastness to washing is often
It is bad, it needs to take fixation mode to improve its dyefastness.China's dyeing uses more color fixing agent equal for a long time
It is not only big to environmental hazard containing free formaldehyde, it also will cause and injure human health when wearing.It develops in recent years some novel
In color fixing agent, such as resin cation type color fixing agent, quaternary ammonium salt aldehyde-free colour stabilizer, quaternized response type aldehyde-free colour stabilizer, though
So all reach formaldehydeless, but its moisture-proof colorfastness to rubbing is still not ideal enough, for reactive dye, also not up to its is resistance to
Wash color fastness and moisture-proof colorfastness to rubbing and excellent requirement.Therefore, it is necessary to develop a kind of novel color fixing agent, can not only mention
The dyefastness of high fabric, it is also necessary to the characteristic with Environmental Safety.
Summary of the invention
Technical problems to be solved:
For problem and the shortcomings of the prior art pointed in background technique, the object of the present invention is to provide one kind
The preparation and the application in reactive dyeing of modified burdock polysaccharide.
Technical solution:
The present invention provides a kind of preparation methods of modified burdock polysaccharide, including following preparation steps:
(1) fructus arctii is dried in vacuo, was then crushed to 40 mesh holes with pulverizer, then by fructus arctii powder drying for standby；
(2) sodium hydroxide solution is added in reactor in the fructus arctii powder after taking drying, controls solid-liquid ratio, extracts
Reaction；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min from
Heart 20min collects supernatant；
(4) supernatant is concentrated under reduced pressure, is concentrated into the half of original volume, it is then that concentrate and 90wt% ethyl alcohol is molten
Sediment is precipitated in liquid mixing, -4 DEG C of placement 12h；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, collects precipitating, 60 DEG C drying to constant weight, i.e.,
Obtain burdock polysaccharide；
(6) burdock polysaccharide is dissolved in aqueous isopropanol, adds sodium hydroxide and the chloro- 2- Hydroxyproyl Trimethyl chlorination of 3-
Ammonium carries out etherification reaction, is cooled to room temperature after the reaction was completed, filters removal surplus liquid, with distilled water by product cleaning 4 times,
Modified burdock polysaccharide obtained by drying.
Preferably, solid-liquid ratio is 1:(30-40 in step (2)), solid-liquid ratio unit is g/mL.
Preferably, the temperature that reaction is extracted in step (2) is 60-90 DEG C, extraction time 4-8h.
Preferably, the volume ratio of concentrate and 90wt% ethanol solution is 1:1 in step (4).
Preferably, in step (6) burdock polysaccharide, sodium hydroxide and 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride weight ratio
Are as follows: 1:(0.1-0.2): (0.05-0.15).
Preferably, the temperature of etherification reaction is 50-70 DEG C in step (6), time 3-5h.
The present invention also provides a kind of application method of modified burdock polysaccharide in reactive dyeing, including following step
It is rapid: cotton fabric is dyed using active black, dyeing time 30s, the cotton fabric after dyeing is dried, it is spare；It will modified ox
Burdock polysaccharide, which is dissolved in deionized water, obtains modified burdock polysaccharide solution；It is molten that cotton fabric after dyeing is impregnated in modified burdock polysaccharide
Second dipping and rolling in liquid, pick-up 75% bake 3min at 135 DEG C again after drying, after washing 10min, 90 DEG C of drying.
The utility model has the advantages that
(1) by test result it is found that burdock polysaccharide is extracted from natural plants in the present invention, safe and environment-friendly, preparation changes
Property burdock polysaccharide can be in the surface-crosslinked film forming of cotton-textile fibres, and crosslinked action can be generated between dyestuff, fiber, from
And play good tint retention.
(2) raw material sources of the present invention are extensive, at low cost, and without harmful substances such as formaldehyde, preparation process is simple to operation, nothing
Any environmental pollution, has broad application prospects.
Specific embodiment
The following examples can make those skilled in the art that the present invention be more fully understood, but not limit this in any way
Invention.
Embodiment 1
(1) by 70 DEG C of vacuum drying 4h of fructus arctii, 40 mesh holes then were crushed to pulverizer, it is dry by 60 DEG C of fructus arctii powder
Dry 12h is spare；
(2) sodium hydroxide solution of 1wt% is added in reactor in the fructus arctii powder after taking drying, and control solid-liquid ratio is
1:40, solid-liquid ratio unit are g/mL, are warming up to 60 DEG C, extract 8h；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min from
Heart 20min collects supernatant；
(4) supernatant is concentrated under reduced pressure at 60 DEG C, is concentrated into the half of original volume, then by concentrate with
90wt% ethanol solution is mixed according to 1:1, -4 DEG C of placement 12h, and sediment is precipitated；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, 4000r/min is centrifuged 20min, and it is heavy to collect
It forms sediment, 60 DEG C drying to constant weight to get burdock polysaccharide；
(6) 10g burdock polysaccharide is dissolved in 2L80wt% aqueous isopropanol, adds 1g sodium hydroxide and 1.5g3- is chloro-
2- hydroxypropyl-trimethyl ammonium chloride, etherification reaction 5h, then cools to room temperature at 50 DEG C, removal surplus liquid is filtered, with steaming
By product cleaning 4 times, 55 DEG C are dried for 24 hours up to modified burdock polysaccharide distilled water.
The application method of above-mentioned modified burdock polysaccharide are as follows: cotton fabric is dyed using active black W-NNHC, dyestuff is used
Amount is 5% (o.m.f), bath raio 1:20, dyeing time 30s, and the cotton fabric after dyeing is dried, spare；It is more fructus arctii will to be modified
Sugar is dissolved in deionized water, is uniformly mixed and is obtained the modification burdock polysaccharide solution of 2wt%；Cotton fabric after dyeing is impregnated in and is changed
Property burdock polysaccharide solution in second dipping and rolling, pick-up 75% bakes 3min after 90 DEG C of drying at 135 DEG C again, washes 10min
Afterwards, 90 DEG C of drying.
Embodiment 2
(1) by 70 DEG C of vacuum drying 4h of fructus arctii, 40 mesh holes then were crushed to pulverizer, it is dry by 60 DEG C of fructus arctii powder
Dry 12h is spare；
(2) sodium hydroxide solution of 1wt% is added in reactor in the fructus arctii powder after taking drying, and control solid-liquid ratio is
1:30, solid-liquid ratio unit are g/mL, are warming up to 90 DEG C, extract 4h；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min from
Heart 20min collects supernatant；
(4) supernatant is concentrated under reduced pressure at 60 DEG C, is concentrated into the half of original volume, then by concentrate with
90wt% ethanol solution is mixed according to 1:1, -4 DEG C of placement 12h, and sediment is precipitated；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, 4000r/min is centrifuged 20min, and it is heavy to collect
It forms sediment, 60 DEG C drying to constant weight to get burdock polysaccharide；
(6) 10g burdock polysaccharide is dissolved in 2L80wt% aqueous isopropanol, adds 2g sodium hydroxide and 0.5g3- is chloro-
2- hydroxypropyl-trimethyl ammonium chloride, etherification reaction 3h, then cools to room temperature at 70 DEG C, removal surplus liquid is filtered, with steaming
By product cleaning 4 times, 55 DEG C are dried for 24 hours up to modified burdock polysaccharide distilled water.
The application method of above-mentioned modified burdock polysaccharide are as follows: cotton fabric is dyed using active black W-NNHC, dyestuff is used
Amount is 5% (o.m.f), bath raio 1:20, dyeing time 30s, and the cotton fabric after dyeing is dried, spare；It is more fructus arctii will to be modified
Sugar is dissolved in deionized water, is uniformly mixed and is obtained the modification burdock polysaccharide solution of 2wt%；Cotton fabric after dyeing is impregnated in and is changed
Property burdock polysaccharide solution in second dipping and rolling, pick-up 75% bakes 3min after 90 DEG C of drying at 135 DEG C again, washes 10min
Afterwards, 90 DEG C of drying.
Embodiment 3
(1) by 70 DEG C of vacuum drying 4h of fructus arctii, 40 mesh holes then were crushed to pulverizer, it is dry by 60 DEG C of fructus arctii powder
Dry 12h is spare；
(2) sodium hydroxide solution of 1wt% is added in reactor in the fructus arctii powder after taking drying, and control solid-liquid ratio is
1:38, solid-liquid ratio unit are g/mL, are warming up to 70 DEG C, extract 7h；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min from
Heart 20min collects supernatant；
(4) supernatant is concentrated under reduced pressure at 60 DEG C, is concentrated into the half of original volume, then by concentrate with
90wt% ethanol solution is mixed according to 1:1, -4 DEG C of placement 12h, and sediment is precipitated；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, 4000r/min is centrifuged 20min, and it is heavy to collect
It forms sediment, 60 DEG C drying to constant weight to get burdock polysaccharide；
(6) 10g burdock polysaccharide is dissolved in 2L80wt% aqueous isopropanol, adds 1.4g sodium hydroxide and 1.2g3-
Chloro-2-hydroxypropyl-trimethyl ammonium chloride, etherification reaction 4.5h, then cools to room temperature at 55 DEG C, filters removal surplus liquid,
With distilled water by product cleaning 4 times, 55 DEG C are dried for 24 hours up to modified burdock polysaccharide.
The application method of above-mentioned modified burdock polysaccharide are as follows: cotton fabric is dyed using active black W-NNHC, dyestuff is used
Amount is 5% (o.m.f), bath raio 1:20, dyeing time 30s, and the cotton fabric after dyeing is dried, spare；It is more fructus arctii will to be modified
Sugar is dissolved in deionized water, is uniformly mixed and is obtained the modification burdock polysaccharide solution of 2wt%；Cotton fabric after dyeing is impregnated in and is changed
Property burdock polysaccharide solution in second dipping and rolling, pick-up 75% bakes 3min after 90 DEG C of drying at 135 DEG C again, washes 10min
Afterwards, 90 DEG C of drying.
Embodiment 4
(1) by 70 DEG C of vacuum drying 4h of fructus arctii, 40 mesh holes then were crushed to pulverizer, it is dry by 60 DEG C of fructus arctii powder
Dry 12h is spare；
(2) sodium hydroxide solution of 1wt% is added in reactor in the fructus arctii powder after taking drying, and control solid-liquid ratio is
1:32, solid-liquid ratio unit are g/mL, are warming up to 80 DEG C, extract 5h；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min from
Heart 20min collects supernatant；
(4) supernatant is concentrated under reduced pressure at 60 DEG C, is concentrated into the half of original volume, then by concentrate with
90wt% ethanol solution is mixed according to 1:1, -4 DEG C of placement 12h, and sediment is precipitated；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, 4000r/min is centrifuged 20min, and it is heavy to collect
It forms sediment, 60 DEG C drying to constant weight to get burdock polysaccharide；
(6) 10g burdock polysaccharide is dissolved in 2L80wt% aqueous isopropanol, adds 1.6g sodium hydroxide and 0.8g3-
Chloro-2-hydroxypropyl-trimethyl ammonium chloride, etherification reaction 3.5h, then cools to room temperature at 65 DEG C, filters removal surplus liquid,
With distilled water by product cleaning 4 times, 55 DEG C are dried for 24 hours up to modified burdock polysaccharide.
The application method of above-mentioned modified burdock polysaccharide are as follows: cotton fabric is dyed using active black W-NNHC, dyestuff is used
Amount is 5% (o.m.f), bath raio 1:20, dyeing time 30s, and the cotton fabric after dyeing is dried, spare；It is more fructus arctii will to be modified
Sugar is dissolved in deionized water, is uniformly mixed and is obtained the modification burdock polysaccharide solution of 2wt%；Cotton fabric after dyeing is impregnated in and is changed
Property burdock polysaccharide solution in second dipping and rolling, pick-up 75% bakes 3min after 90 DEG C of drying at 135 DEG C again, washes 10min
Afterwards, 90 DEG C of drying.
Embodiment 5
(1) by 70 DEG C of vacuum drying 4h of fructus arctii, 40 mesh holes then were crushed to pulverizer, it is dry by 60 DEG C of fructus arctii powder
Dry 12h is spare；
(2) sodium hydroxide solution of 1wt% is added in reactor in the fructus arctii powder after taking drying, and control solid-liquid ratio is
1:36, solid-liquid ratio unit are g/mL, are warming up to 75 DEG C, extract 6h；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min from
Heart 20min collects supernatant；
(4) supernatant is concentrated under reduced pressure at 60 DEG C, is concentrated into the half of original volume, then by concentrate with
90wt% ethanol solution is mixed according to 1:1, -4 DEG C of placement 12h, and sediment is precipitated；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, 4000r/min is centrifuged 20min, and it is heavy to collect
It forms sediment, 60 DEG C drying to constant weight to get burdock polysaccharide；
(6) 10g burdock polysaccharide is dissolved in 2L80wt% aqueous isopropanol, adds 1.5g sodium hydroxide and 1g3- is chloro-
2- hydroxypropyl-trimethyl ammonium chloride, etherification reaction 4h, then cools to room temperature at 60 DEG C, removal surplus liquid is filtered, with steaming
By product cleaning 4 times, 55 DEG C are dried for 24 hours up to modified burdock polysaccharide distilled water.
The application method of above-mentioned modified burdock polysaccharide are as follows: cotton fabric is dyed using active black W-NNHC, dyestuff is used
Amount is 5% (o.m.f), bath raio 1:20, dyeing time 30s, and the cotton fabric after dyeing is dried, spare；It is more fructus arctii will to be modified
Sugar is dissolved in deionized water, is uniformly mixed and is obtained the modification burdock polysaccharide solution of 2wt%；Cotton fabric after dyeing is impregnated in and is changed
Property burdock polysaccharide solution in second dipping and rolling, pick-up 75% bakes 3min after 90 DEG C of drying at 135 DEG C again, washes 10min
Afterwards, 90 DEG C of drying.
Comparative example 1
This comparative example is not the difference from embodiment 1 is that be modified burdock polysaccharide.Specifically:
(1) by 70 DEG C of vacuum drying 4h of fructus arctii, 40 mesh holes then were crushed to pulverizer, it is dry by 60 DEG C of fructus arctii powder
Dry 12h is spare；
(2) sodium hydroxide solution of 1wt% is added in reactor in the fructus arctii powder after taking drying, and control solid-liquid ratio is
1:40, solid-liquid ratio unit are g/mL, are warming up to 60 DEG C, extract 8h；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min from
Heart 20min collects supernatant；
(4) supernatant is concentrated under reduced pressure at 60 DEG C, is concentrated into the half of original volume, then by concentrate with
90wt% ethanol solution is mixed according to 1:1, -4 DEG C of placement 12h, and sediment is precipitated；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, 4000r/min is centrifuged 20min, and it is heavy to collect
It forms sediment, 60 DEG C drying to constant weight to get burdock polysaccharide.
The application method of above-mentioned burdock polysaccharide are as follows: cotton fabric is dyed using active black W-NNHC, dye dosage is
5% (o.m.f), bath raio 1:20, dyeing time 30s dry the cotton fabric after dyeing, spare；Burdock polysaccharide is dissolved in
In ionized water, it is uniformly mixed and obtains the burdock polysaccharide solution of 2wt%；It is molten that cotton fabric after dyeing is impregnated in modified burdock polysaccharide
Second dipping and rolling in liquid, pick-up 75% bake 3min after 90 DEG C of drying at 135 DEG C again, and after washing 10min, 90 DEG C of drying are
It can.
Comparative example 2
This comparative example the difference from embodiment 1 is that, without using modified burdock polysaccharide processing.Specifically:
Cotton fabric is dyed using active black W-NNHC, dye dosage is 5% (o.m.f), bath raio 1:20, dyeing
Cotton fabric after dyeing is dried, then bakes 3min at 135 DEG C by time 30s, after washing 10min, 90 DEG C of drying.
The cotton fabric handled well in embodiment 1-5 and comparative example 1-2 is tested for the property: color fastness to washing is by GB/
T3921-4-1997, crock fastness press GB/T3920-1997 standard test, and test result see the table below:
It is safe and environment-friendly by test result it is found that burdock polysaccharide is extracted from natural plants in the present invention, the modification of preparation
Burdock polysaccharide can be in the surface-crosslinked film forming of cotton-textile fibres, and crosslinked action can be generated between dyestuff, fiber, thus
Play good tint retention.The modification burdock polysaccharide that preparation process is prepared in embodiment 5 has best tint retention,
Burdock polysaccharide treated cotton fabric in embodiment 5,4 grades of color fastness to washing, xerotripsis crock fastness is 5 grades, wet rubbing friction jail
Degree is 4-5 grades.It is not handled using modified burdock polysaccharide in comparative example 2,1-2 grades of color fastness to washing, xerotripsis crock fastness
It is 2 grades, wet rubbing crock fastness is 1-2 grades, it was demonstrated that modified burdock polysaccharide is a kind of effective color fixing agent in the present invention.Comparative example 1
Middle to be handled using unmodified burdock polysaccharide, performance increases compared with comparative example 2, but not as good as the fixation in embodiment 1
Effect illustrates that unmodified burdock polysaccharide can also play certain tint retention.
Claims (7)
1. a kind of preparation method of modified burdock polysaccharide, which is characterized in that including following preparation steps:
(1) fructus arctii is dried in vacuo, was then crushed to 40 mesh holes with pulverizer, then by fructus arctii powder drying for standby；
(2) sodium hydroxide solution is added in reactor in the fructus arctii powder after taking drying, controls solid-liquid ratio, extracts reaction；
(3) extracting solution in step (2) is filtered, takes supernatant salt acid for adjusting pH value to 3.0, then 4000r/min is centrifuged
20min collects supernatant；
(4) supernatant is concentrated under reduced pressure, is concentrated into the half of original volume, then mix concentrate and 90wt% ethanol solution
It closes, -4 DEG C of placement 12h, sediment is precipitated；
(5) supernatant after the sediment being precipitated in step (4) is centrifuged, collects precipitating, 60 DEG C drying to constant weight to get ox
Burdock polysaccharide；
(6) burdock polysaccharide is dissolved in aqueous isopropanol, adds sodium hydroxide and 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride,
Etherification reaction is carried out, is cooled to room temperature after the reaction was completed, removal surplus liquid, with distilled water by product cleaning 4 times, drying are filtered
Up to modified burdock polysaccharide.
2. a kind of preparation method of modified burdock polysaccharide according to claim 1, which is characterized in that feed liquid in step (2)
Than for 1:(30-40), solid-liquid ratio unit is g/mL.
3. a kind of preparation method of modified burdock polysaccharide according to claim 1, which is characterized in that extracted in step (2)
The temperature of reaction is 60-90 DEG C, extraction time 4-8h.
4. a kind of preparation method of modified burdock polysaccharide according to claim 1, which is characterized in that concentration in step (4)
The volume ratio of liquid and 90wt% ethanol solution is 1:1.
5. a kind of preparation method of modified burdock polysaccharide according to claim 1, which is characterized in that fructus arctii in step (6)
The weight ratio of polysaccharide, sodium hydroxide and 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride are as follows: 1:(0.1-0.2): (0.05-0.15).
6. a kind of preparation method of modified burdock polysaccharide according to claim 1, which is characterized in that etherificate in step (6)
The temperature of reaction is 50-70 DEG C, time 3-5h.
7. a kind of application method of the modified burdock polysaccharide according to claim 1 in reactive dyeing, feature exist
In, comprising the following steps: cotton fabric is dyed using active black, dyeing time 30s, the cotton fabric after dyeing is dried,
It is spare；Modified burdock polysaccharide is dissolved in deionized water and obtains modified burdock polysaccharide solution；Cotton fabric after dyeing is impregnated in
Second dipping and rolling in modified burdock polysaccharide solution, pick-up 75% bake 3min at 135 DEG C again after drying, after washing 10min,
90 DEG C of drying.
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| CN115010820A (en) * | 2021-09-24 | 2022-09-06 | 江苏省农业科学院 | Extraction and optimization method of burdock polysaccharide |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2631318A1 (en) * | 1976-07-12 | 1978-01-19 | Sandoz Ag | Printing or dyeing of polyamide carpeting with anionic dyes - using polysaccharide thickener and fixing accelerator |
| US4502867A (en) * | 1981-12-24 | 1985-03-05 | Hoechst Aktiengesellschaft | Pad-dyeing and printing synthetic fiber materials using disperse dye and carboxyl synthetic polymer and polysaccharide thickener combination |
| CN101166765A (en) * | 2005-05-03 | 2008-04-23 | 埃沃尼克德古萨有限责任公司 | Method for chemically modifying polysaccharides |
| CN105064082A (en) * | 2015-09-08 | 2015-11-18 | 湖州新创丝织品有限公司 | Novel natural polysaccharide printing thicknener |
| CN105862468A (en) * | 2016-04-29 | 2016-08-17 | 绍兴文理学院 | Dyeing method for starch cation modified cotton fabric |
| CN106188340A (en) * | 2016-07-26 | 2016-12-07 | 五邑大学 | A kind of reactive chitosan quaternary ammonium salt and its preparation method and application |
-
2018
- 2018-10-27 CN CN201811256845.1A patent/CN109400738B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2631318A1 (en) * | 1976-07-12 | 1978-01-19 | Sandoz Ag | Printing or dyeing of polyamide carpeting with anionic dyes - using polysaccharide thickener and fixing accelerator |
| US4502867A (en) * | 1981-12-24 | 1985-03-05 | Hoechst Aktiengesellschaft | Pad-dyeing and printing synthetic fiber materials using disperse dye and carboxyl synthetic polymer and polysaccharide thickener combination |
| CN101166765A (en) * | 2005-05-03 | 2008-04-23 | 埃沃尼克德古萨有限责任公司 | Method for chemically modifying polysaccharides |
| CN105064082A (en) * | 2015-09-08 | 2015-11-18 | 湖州新创丝织品有限公司 | Novel natural polysaccharide printing thicknener |
| CN105862468A (en) * | 2016-04-29 | 2016-08-17 | 绍兴文理学院 | Dyeing method for starch cation modified cotton fabric |
| CN106188340A (en) * | 2016-07-26 | 2016-12-07 | 五邑大学 | A kind of reactive chitosan quaternary ammonium salt and its preparation method and application |
Non-Patent Citations (6)
| Title |
|---|
| CHATHA SAS等: ""SIGNIFICANCE OF CHITOSAN TO IMPROVE THE SUBSTANTIVITY OF REACTIVE DYES"", 《JOURNAL OF THE CHILEAN CHEMICAL SOCIETY》 * |
| HUIQUN YU等: ""Preparation and characterization of a quaternary ammonium derivative of konjac glucomannan"", 《CARBOHYDRATE POLYMERS》 * |
| SAMINATHAN RATNAPANDIAN等: ""Colouration of cotton by combining natural colourants and bio-polysaccharide"", 《JOURNAL OF THE TEXTILE INSTITUTE》 * |
| 刘建平主编: "《染整助剂综合实训》", 30 September 2011, 东华大学出版社 * |
| 周浓等: ""牛蒡多糖提取工艺及其体外抗氧化活性的研究"", 《食品研究与开发》 * |
| 汤陈鹏等: ""天然多糖改性方法研究进展"", 《渔业研究》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115010820A (en) * | 2021-09-24 | 2022-09-06 | 江苏省农业科学院 | Extraction and optimization method of burdock polysaccharide |
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