A method of cement pipe pile is processed using carbon fiber and regeneration concrete
Technical field
It is specifically a kind of to process cement pipe pile using carbon fiber and regeneration concrete the present invention relates to tubular pole manufacturing field
Method.
Background technique
Tubular pole, and it is divided into post-tensioned prestressing stake and pretensioned-prestressed tube pile, prestressed concrete pipe pile (PC pipe
Stake) and thin tubular piles produced by prestressed concrete (PTC tubular pole) and high strength prestressed concrete pipe pile (PHC tubular pole), nowadays city
It prepares concrete on face using cement mostly, and carries out the manufacture of tubular pole.
Cement can be used for preparing concrete and concrete for various applications, including but not limited to road, parking
Field, bridge, aisle and support construction.As Urbanization in China is accelerated, science and technology is more and more progressive, and construction industry enters high speed and sends out
Exhibition stage, the following building waste are also constantly increasing, and wherein most is all discarded concrete, this not only gives us
Environment bring pollution, also bring great inconvenience to our life.
For above situation, it would be desirable to design a kind of side using carbon fiber and regeneration concrete processing cement pipe pile
Method, not only needs to solve the problems, such as the secondary use of discarded concrete, while also needing save the cost, and the chloride ion for reducing tubular pole seeps
Saturating rate, this is our urgent problems to be solved.
Summary of the invention
The purpose of the present invention is to provide a kind of methods using carbon fiber and regeneration concrete processing cement pipe pile, with solution
Certainly the problems of the prior art.
To achieve the above object, the invention provides the following technical scheme:
A method of cement pipe pile being processed using carbon fiber and regeneration concrete, each raw material component is as follows: with parts by weight
Meter, 400-800 parts of cement composition, 1250-1400 parts of aggregate, 150-300 parts of water, 5-35 parts of water-reducing agent, fiber composition
150-250 parts, 9-50 parts of curing agent.
Optimally, each raw material component is as follows: in parts by weight, 500-550 parts of cement composition, aggregate 1300-1350
Part, 200-300 parts of water, 20-35 parts of water-reducing agent, 175-250 parts of fiber composition, 25-50 parts of curing agent.
Optimally, the cement composition each raw material component is as follows: by percentage to the quality, solvent 10-20%, regeneration
Concrete 40%-55%, pozzolan cement 20%-35%, sugar 0.05%-0.5%, float stone 25%-50%, silicon ash 0.5%-
1.5%, aluminium hydroxide 0.2%-1%, flyash 0.6%-1.2%.
Optimally, the regeneration concrete each raw material component is as follows: by percentage to the quality, discarded concrete 40%-
50%, slag powders 30%-40%, desulfurized gypsum 20%-35%, steel slag 0.5%-1%, zeolite powder 5%-15%, sodium hydroxide
0.5%-2.2%.
Optimally, the sugar is one of galactolipin, glucose, dextrose, lactose, maltose, sucrose or a variety of.
Optimally, the fiber composition includes cellulose fibre, carbon fiber and pearl filler, the cellulose fiber
The weight of dimension: the weight of pearl filler is (1:33)-(10:1);The weight of the carbon fiber: the weight of cellulose fibre is
(1:2)-(2:1).
Optimally, the aggregate is one of lime stone, rubble, gravel or a variety of;The curing agent is solid for epoxy
Agent.
Optimally, comprising the following steps:
1) regeneration concrete is prepared;
A) it pre-processes;
B) hydro-thermal;
C) primary calcining;
D) it is stirred;
E) secondary clacining;
F) regeneration concrete is obtained;
2) cement composition is prepared;
3) fiber composition is prepared;
4) preparation of tubular pole;
A) weigh cement composition, aggregate, water-reducing agent, fiber composition and curing agent by a certain percentage, and with it is a certain amount of
Water mixing, put into blender in carry out high-speed stirred, obtain mixed material;
B) steel reinforcement cage with pile crown is made, and the steel reinforcement cage with pile crown is put into mold;
C) it is poured the mixed material being prepared into lower mold half, upper mold half and lower mold half are tightened, obtains stake
Mould;
D) longitudinal tensioning is carried out, and the stake mould after tensioning is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;
E) double of finished product pile tube carries out atmospheric steam curing, then semi-finished product tubular pole is put into still kettle mesohigh steam and is supported
Shield;
5) tubular pole is obtained.
Optimally, comprising the following steps:
1) regeneration concrete is prepared;
A) it pre-processes: discarded concrete being subjected to break process, then broken discarded concrete is crossed 38 μm -270 μm
Sieve obtains discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, obtains
One mixed powder, Ball-milling Time 2-3h;
B) hydro-thermal: the first mixed powder is added in sodium hydroxide solution, under conditions of hydrothermal temperature is 30-100 DEG C
Hydro-thermal 1-3 days, with the screen to filtrate of 200-500 mesh, obtain the second mixed powder;The sodium hydroxide solution is that concentration is 1-
3mol/L;
C) primary calcining: the second mixed powder is put into calcining furnace and is once calcined, cement slurry powder is obtained;Institute
Stating a calcination temperature is 800-900 DEG C, and a calcination time is 2-2.5h;
D) it is stirred: desulfurized gypsum, steel slag is subjected to break process respectively, then by broken desulfurized gypsum, steel slag
50 μm of -200 μm of sieves are crossed respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Slag powders, steel slag powder are put into ball again
Grinding machine ball milling obtains third mixed powder, Ball-milling Time 3-3.5h;
E) secondary clacining: cement slurry powder and third mixed powder are mixed, and are put into and carried out two in calcining furnace
Secondary calcining, obtains clinker;The secondary clacining temperature is 700-850 DEG C, and the secondary clacining time is 1-2h;
F) it obtains regeneration concrete: weighing the clinker and desulfurized gypsum powder of required component ratio, the clinker
Quality: the quality of desulfurized gypsum powder be 100:(5-10), be mixed, obtain regeneration concrete;
2) cement composition is prepared;
A) float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively, and with 200-500 purpose
The screen to filtrate obtains the 4th mixed powder;
B) sugar for weighing certain component, mixes and is stirred with solvent, places and puts into regeneration concrete, the 4th afterwards for 24 hours
Mixed powder stirs evenly, and obtains the first mixed material;
C) flyash, the aluminium hydroxide of certain mass are weighed, and successively by the first mixed material, flyash, aluminium hydroxide
It is calcined three times in investment calcining furnace, obtains cement composition;Calcination temperature is 800-900 DEG C three times, three times calcination time
For 2-2.5h;
3) fiber composition is prepared;
A) fiber and pearl filler are weighed according to a certain percentage, fiber is placed in aqueous environments first, so that fiber
Fibrillation, until forming nanometer fibrous gel;
B) pearl filler is mixed again with nanometer fibrous gel, is stirred evenly;Obtain mixed material;
C) a certain amount of carbon fiber is weighed, by mixed material and carbon fibers and is dehydrated, and is manufactured into structuring
Material obtains fiber composition;
4) preparation of tubular pole;
A) weigh cement composition, aggregate, water-reducing agent, fiber composition and curing agent by a certain percentage, and with it is a certain amount of
Water mixing, put into blender in carry out high-speed stirred, mixing time 1-2h obtains the second mixed material;
B) steel reinforcement cage with pile crown is made, and the steel reinforcement cage with pile crown is put into mold;
C) it is poured the mixed material being prepared into lower mold half, upper mold half and lower mold half are tightened, obtains band
Expect stake mould;
D) longitudinal tensioning, and the strip stake mould after tensioning is placed on centrifugal forming on centrifuge, obtain semi-finished product tubular pole;
E) semi-finished product tubular pole carries out atmospheric steam curing, and the atmospheric steam curing time is 2-3h, then by semi-finished product tubular pole
F) it is put into still kettle mesohigh steam curing, temperature is 200-220 DEG C, when autoclave curing in the still kettle
Between be 5-8h;
5) tubular pole is obtained.
Compared with prior art, the beneficial effects of the present invention are:
Devised in the present invention it is a kind of using carbon fiber and regeneration concrete processing cement pipe pile method, wherein by pair
Discarded concrete carries out secondary use, regeneration concrete is prepared, then by processing to regeneration concrete, obtain cement
Composition not only increases the mechanical property of cement pipe pile, reduces simultaneously for serving as the base material for preparing cement pipe pile
Cost has high economic benefit, effectively practical;By being processed to carbon fiber and cellulose fibre in the present invention, obtain
To fiber composition, fiber composition is easily separated into fibre single thread under the action of the immersion of water and blender frictional force, from
And effect of prestressed is played, the mechanical property of cement pipe pile can be effectively improved, the freeze-thaw resistance and impermeability of cement pipe pile are enhanced.
When the present invention prepares regeneration concrete, it is added to zeolite powder, the per unit pore volume in material can be effectively reduced, is sticked
Regeneration concrete micro-crack produced during the preparation process is closed or repaired, the bond strength between each component is enhanced, and keeps regeneration mixed
Solidifying Soil Interface plot structure tends to be fine and close, compactness when improving cement pipe pile preparation between each component.
The present invention is calcined twice when preparing regeneration concrete, while being carried out before calcination to the first mixed powder
Hydro-thermal provides alkaline environment by sodium hydroxide solution for subsequent synthetic reaction, can sufficiently activate in this way to flyash,
Improve the aggregate velocity of regeneration concrete.
In the present invention in the secondary use to discarded concrete, by carrying out crushing, stirring to discarded concrete, and add
Enter various auxiliary materials and regeneration concrete is made, wherein the proportion of discarded concrete is reduced with the increase that steel slag matches, regenerates coagulation
The intensity of soil can be presented one and first increase the trend reduced afterwards, and when the mass percent of steel slag is 0.8%, intensity reaches highest
Value continues growing steel slag proportion, and intensity declines instead, so the mass percent of steel slag is selected as 0.8% in the present invention;Addition
Steel slag, can provocative reaction when whole system alkalinity, to make whole system there are a most suitable hydrated products in aquation
The alkalinity ranges of generation improve the generation of hydrated product.
It also added desulfurized gypsum in the present invention, the intensity of regeneration concrete can be improved.Steel slag can excite in the present invention
System alkalinity, slag powders are under the excitation of alkali, and the limestone surfaces in discarded concrete generate a large amount of entringite and C-S-H is solidifying
Discarded concrete particle is closely joined together and is formed spacial framework by glue, what the subsequent continuous aquation of slag powders generated
C-S-H gel and entringite are constantly filled in the hole of network, final to wrap up discarded concrete particle and cause slurry more
It is close, the intensity of regeneration concrete is improved, to improve the intensity of the cement pipe pile prepared using regeneration concrete as raw material.
After preparing regeneration concrete in the present invention, each component is added, cement composition is made again, cement pipe pile can be reduced
Chloride ion permeability, increasing flexural strength and module strength, the addition of sucrose reduces cementing needed for preparation process
The amount of material, reduces costs, while improving the wearability of cement pipe pile, reduces shrinking percentage.
When preparing cement composition in the present invention, it is added to flyash, can not only cooperate with silicon ash and realize " double-doped " effect
Fruit, while flyash can also be cooperated with the zeolite powder in regeneration concrete, between each component for improving cement composition
It is compatible;Aluminium hydroxide is added when being calcined three times, the alkaline environment phase interworking in aluminium hydroxide, flyash and regeneration concrete
It closes, not only increases the whole activation degree of flyash, while zeolite can also be generated when calcining three times, it is further to improve
The compactness of regeneration concrete improves the interfacial structure of regeneration concrete, and when preparing cement composition, it is mixed that regeneration can be improved
Degree of cohering between solidifying soil and other components.
When preparing fiber composition in the present invention, pearl filler excessively will affect the formation of gel, we select to control
The amount of pearl filler accelerates the formation of gel, this is also convenient for cement pipe pile can preferably mix between each component in the preparation
It closes, reduces the amount of colloid, save the cost.
Water-reducing agent selects polycarboxylic acid series high efficiency water reducing agent or naphthalene water reducer, cement composition in the present invention in the present invention
In be added to silicon ash, " double-doped " effect is reached by high-efficiency water-reducing agent of poly-carboxylic acid and silicon ash, while in cement admixture preparation
It is added to flyash, the Pore Solution for fitting through dilution effect, chemical effect, reducing when material mixing of flyash and silicon ash
PH;In the next steps, after material is mixed and semi-finished product tubular pole is prepared, present invention employs normal pressure steamings
Vapour maintenance, with the raising of curing temperature, the quickening of hydrated reaction of cement speed, the speed that the basicity in concrete reduces adds
Fastly;
Simultaneously because the cooperation of high-efficiency water-reducing agent of poly-carboxylic acid and silicon ash, the cooperation of flyash and slag powders, when prepared by tubular pole
Mixed material when being stirred, each component therein quickly dissolves, and quickly improves the basicity in mixed material, simultaneously
The hydration temperature of mixed material is also improved, the speed of hydration reaction is accelerated, increases the generation quantity of hydrated product, is improved
The demoulding strength of cement pipe pile.
The method that directly molding perfusion is used in the present invention, concrete are directly filled into the inner cavity of mold, avoid the occurrence of
The phenomenon that concrete particle is fallen reduces human cost, saves labour;Upper mold, lower mold are tightened when molding simultaneously, is kept away
Exempt from the problem of concrete tubular pile joint close spillage occur, ensure that the quality of concrete tubular pile.
A kind of method using carbon fiber and regeneration concrete processing cement pipe pile is provided in the present invention, control is reasonable
Component is matched, so that the mechanical property of the cement pipe pile of preparation is more preferable, entire cement is reduced by the preparation of cement composition
The chloride permeability rate of tubular pole, while being prepared using discarded concrete as base material, cost is saved, it is with higher
Economic benefits.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake
38 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained
To the first mixed powder, Ball-milling Time 2h;The first mixed powder is added in sodium hydroxide solution again, is 30 in hydrothermal temperature
Hydro-thermal 1 day under conditions of DEG C obtains the second mixed powder with the screen to filtrate of 200 mesh;The sodium hydroxide solution is that concentration is
1mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;It is described once to forge
Burning temperature is 800 DEG C, and a calcination time is 2h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will it is broken after
Desulfurized gypsum, steel slag respectively cross 50 μm of sieves, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag powders, steel-making slag powder
Body puts into ball mill ball milling, obtains third mixed powder, Ball-milling Time 3h;Again by cement slurry powder and third mixed powder
It is mixed, and puts into and carry out secondary clacining in calcining furnace, obtain clinker;The secondary clacining temperature is 700 DEG C, described
The secondary clacining time is 1h;Finally weigh the clinker and desulfurized gypsum powder of required component ratio, the matter of the clinker
Amount: the quality of desulfurized gypsum powder is 20:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively
Mill, and with the screen to filtrate of 200 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent
It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter
Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times
Calcining, obtains cement composition;Calcination temperature is 800 DEG C three times, and calcination time is 2h three times.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber
Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel
Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side
Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage
And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 1h
Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half
The mixed material being prepared, upper mold half and lower mold half are tightened, and obtain strip stake mould;Then longitudinal tensioning, and will open
Strip stake mould after drawing is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam
Maintenance, the atmospheric steam curing time is 2h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, in the still kettle
Temperature is 200 DEG C, and the autoclave curing time is 5h.
In the present embodiment, each raw material component by weight: 525 parts of cement composition, 1325 parts of aggregate, 250 parts of water, diminishing
26 parts of agent, 200 parts of fiber composition, 40 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement
22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag
0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 2:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake
200 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained
To the first mixed powder, Ball-milling Time 2h;The first mixed powder is added in sodium hydroxide solution again, is 30 in hydrothermal temperature
Hydro-thermal 1 day under conditions of DEG C obtains the second mixed powder with the screen to filtrate of 200 mesh;The sodium hydroxide solution is that concentration is
2mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;It is described once to forge
Burning temperature is 850 DEG C, and a calcination time is 2h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will it is broken after
Desulfurized gypsum, steel slag respectively cross 50 μm of sieves, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag powders, steel-making slag powder
Body puts into ball mill ball milling, obtains third mixed powder, Ball-milling Time 3h;Again by cement slurry powder and third mixed powder
It is mixed, and puts into and carry out secondary clacining in calcining furnace, obtain clinker;The secondary clacining temperature is 700 DEG C, described
The secondary clacining time is 1h;Finally weigh the clinker and desulfurized gypsum powder of required component ratio, the matter of the clinker
Amount: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively
Mill, and with the screen to filtrate of 200 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent
It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter
Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times
Calcining, obtains cement composition;Calcination temperature is 850 DEG C three times, and calcination time is 2.2h three times.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber
Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel
Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side
Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage
And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, mixing time 1.5h obtains second
Mixed material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half
The mixed material being prepared is infused, upper mold half and lower mold half are tightened, strip stake mould is obtained;Then longitudinal tensioning, and will
Strip stake mould after tensioning is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out normal pressure steaming
Vapour maintenance, the atmospheric steam curing time is 2.5h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, the steam pressure
Temperature is 210 DEG C in kettle, and the autoclave curing time is 7h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 500 parts of cement composition, 1300 parts of aggregate, 200 parts of water, diminishing
20 parts of agent, 175 parts of fiber composition, 25 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement
22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag
0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 3:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake
270 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained
To the first mixed powder, Ball-milling Time 3h;The first mixed powder is added in sodium hydroxide solution again, is in hydrothermal temperature
Hydro-thermal 3 days under conditions of 100 DEG C obtain the second mixed powder with the screen to filtrate of 500 mesh;The sodium hydroxide solution is dense
Degree is 3mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;Described one
Secondary calcination temperature is 900 DEG C, and a calcination time is 2.5h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will
Broken desulfurized gypsum, steel slag cross 200 μm of sieves respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag
Powder, steel slag powder put into ball mill ball milling, obtain third mixed powder, Ball-milling Time 3.5h;Again by cement slurry powder and
Third mixed powder is mixed, and is put into and carried out secondary clacining in calcining furnace, and clinker is obtained;The secondary clacining temperature
It is 850 DEG C, the secondary clacining time is 2h;The clinker and desulfurized gypsum powder of required component ratio are finally weighed, it is described
The quality of clinker: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively
Mill, and with the screen to filtrate of 500 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent
It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter
Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times
Calcining, obtains cement composition;Calcination temperature is 900 DEG C three times, and calcination time is 2.5h three times.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber
Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel
Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side
Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage
And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 2h
Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half
The mixed material being prepared, upper mold half and lower mold half are tightened, and obtain strip stake mould;Then longitudinal tensioning, and will open
Strip stake mould after drawing is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam
Maintenance, the atmospheric steam curing time is 3h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, in the still kettle
Temperature is 220 DEG C, and the autoclave curing time is 8h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing
35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement
22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag
0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 4:
Cement composition is prepared first, and first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively
Mill, and with the screen to filtrate of 200 mesh, obtain mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent,
It places and puts into portland cement, mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh the fine coal of certain mass
Ash, and the first mixed material, flyash are successively put into calcining furnace and calcined, obtain cement composition;Calcination temperature is
800 DEG C, calcination time 2h.
Fiber composition is prepared again, weighs fiber and pearl filler first, in accordance with certain proportion, and fiber is placed in water
Property environment so that fiber fibrillation, until forming nanometer fibrous gel;Pearl filler and nanometer fibrous gel are mixed again
It closes, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is weighed, by mixed material and carbon fibers and is dehydrated,
And manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage
And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 1h
Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;Preparation is poured into lower mold half
Obtained mixed material, upper mold half and lower mold half are tightened, and obtain strip stake mould;Longitudinal tensioning, and by the band after tensioning
Material stake mould is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Semi-finished product tubular pole carries out atmospheric steam curing, atmospheric steam
Curing time is 2h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, and temperature is 200 DEG C in the still kettle,
The autoclave curing time is 5h;Obtain the tubular pole.
Each raw material component is by weight in the present embodiment: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing
35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, silicate concrete 40%, pozzolan cement
22%, sugared 0.05%, float stone 26%, silicon ash 1.2%, flyash 0.75%.
Embodiment 5:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake
270 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained
To the first mixed powder, Ball-milling Time 3h;The first mixed powder is added in sodium hydroxide solution again, is in hydrothermal temperature
Hydro-thermal 3 days under conditions of 100 DEG C obtain the second mixed powder with the screen to filtrate of 500 mesh;The sodium hydroxide solution is dense
Degree is 3mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;Described one
Secondary calcination temperature is 900 DEG C, and a calcination time is 2.5h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will
Broken desulfurized gypsum, steel slag cross 200 μm of sieves respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag
Powder, steel slag powder put into ball mill ball milling, obtain third mixed powder, Ball-milling Time 3.5h;Again by cement slurry powder and
Third mixed powder is mixed, and is put into and carried out secondary clacining in calcining furnace, and clinker is obtained;The secondary clacining temperature
It is 850 DEG C, the secondary clacining time is 2h;The clinker and desulfurized gypsum powder of required component ratio are finally weighed, it is described
The quality of clinker: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively
Mill, and with the screen to filtrate of 500 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent
It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter
Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times
Calcining, obtains cement composition;Calcination temperature is 900 DEG C three times, and calcination time is 2.5h three times.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent and curing agent by a certain percentage, and
It is mixed with a certain amount of water, puts into blender and carry out high-speed stirred, mixing time 2h obtains the second mixed material;It makes again
Make the steel reinforcement cage with pile crown, and the steel reinforcement cage with pile crown is put into mold;Into lower mold half, casting is prepared immediately
Mixed material tightens upper mold half and lower mold half, obtains strip stake mould;Then longitudinal tensioning, and by the strip after tensioning
Stake mould is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam curing, and normal pressure steams
Vapour curing time is 3h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, and temperature is 220 in the still kettle
DEG C, the autoclave curing time is 8h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing
35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement
22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag
0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 6:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake
270 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained
To the first mixed powder, Ball-milling Time 3h;The first mixed powder is added in sodium hydroxide solution again, is in hydrothermal temperature
Hydro-thermal 3 days under conditions of 100 DEG C obtain the second mixed powder with the screen to filtrate of 500 mesh;The sodium hydroxide solution is dense
Degree is 3mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;Described one
Secondary calcination temperature is 900 DEG C, and a calcination time is 2.5h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will
Broken desulfurized gypsum, steel slag cross 200 μm of sieves respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag
Powder, steel slag powder put into ball mill ball milling, obtain third mixed powder, Ball-milling Time 3.5h;Again by cement slurry powder and
Third mixed powder is mixed, and is put into and carried out secondary clacining in calcining furnace, and clinker is obtained;The secondary clacining temperature
It is 850 DEG C, the secondary clacining time is 2h;The clinker and desulfurized gypsum powder of required component ratio are finally weighed, it is described
The quality of clinker: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber
Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel
Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side
Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs regeneration concrete, aggregate, water-reducing agent, fiber composition by a certain percentage
And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 2h
Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half
The mixed material being prepared, upper mold half and lower mold half are tightened, and obtain strip stake mould;Then longitudinal tensioning, and will open
Strip stake mould after drawing is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam
Maintenance, the atmospheric steam curing time is 3h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, in the still kettle
Temperature is 220 DEG C, and the autoclave curing time is 8h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing
35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement
22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag
0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Test experience:
Embodiment 1-6 is comparative experiments, and wherein embodiment 1, embodiment 2, the cement composition in embodiment 3 pass through again
Growing concrete preparation, and regeneration concrete has been changed into silicate concrete in embodiment 4, fiber group is not added in embodiment 5
Object is closed, and directly carries out the preparation of cement pipe pile by cement composition, and does not carry out the system of cement composition in embodiment 6
It is standby, tubular pole is directly prepared by regeneration concrete and fiber composition, the influence of remaining control parameter can be ignored.
Test 1: chloride diffusion coefficient detection
It is 100mm, with a thickness of the cylinder sample of 50 ± 2mm that concrete, which is cut into diameter, first, then by sample in ultrasound
It is cleaned in bath, the sample after cleaning is mounted on specimen holder, injection test solution, connecting test host;Open NJ-RCM
Chloride diffusion coefficient analyzer host carries out electromigration experiment;Then the sample after electromigration is rived along axial direction, is being rived
Surface on spray silver nitrate solution, determine diffusion depth, and calculate diffusion coefficient;Wherein anodic dissolution selects 0.3mol/l's
Sodium hydroxide solution, the sodium chloride solution of cathode solution selection 10%, soaking solution select calcium hydroxide solution.
Diffusion coefficient calculation formula:
Wherein D is the transport coefficient of concrete chloride ion, and t is the time of Therapy lasted, and M is the flat of chloride ion penetration depth
Mean value, T are anodic dissolution initial temperature and the average value for terminating temperature, and U is the absolute value of applied voltage.
Test 2: compression strength
Concrete is cut into the cuboid sample that side length is 100mm first, by press machine with 0.5-0.8MPa/s's
Loading velocity loads sample, writes down the peak load that concrete is able to bear, and calculate the intensity of concrete, surveys strong
Degree obtains final compression strength multiplied by 0.95 reduction coefficient.
Test 3: mechanical property and electric flux
The detection of mechanical property is carried out to the tubular pole that embodiment 1-6 is prepared, while detecting electric flux detection.
To the cement pipe pile being prepared in embodiment 1, embodiment 2, embodiment 3, embodiment 4, embodiment 5, embodiment 6
Mechanics properties testing is carried out, and will test result and be compared:
As shown above, regeneration concrete has been changed into silicate concrete in embodiment 4, and directly pass through cement composition
Object carries out the preparation of cement pipe pile, experiment is contrasted with embodiment 1-3, in contrast to the data of tubular pole obtained in embodiment 4
From the point of view of, the properties for the tubular pole that the present invention is prepared all are improved, and anti-bending strength is strong, and compression strength is improved,
Chloride diffusion coefficient reduces;The cement composition in embodiment 1-3 is prepared by regeneration concrete simultaneously, in embodiment 5
It is not added with fiber composition, from the point of view of the data of embodiment 1-3 are compared with embodiment 5, there is significantly compression strength in embodiment 5
It reduces, this has absolutely proved that the preparation of fiber composition substantially increases the compression strength of tubular pole;Water is not carried out in embodiment 6
The preparation of mud composition, by comparative example 1-3 with the data of embodiment 6, the chloride diffusion coefficient in embodiment 6 has
It significantly improves, this has absolutely proved that the preparation of cement composition reduces the diffusion coefficient of chloride ion, increases bending and resistance to compression
Ability, and the compression strength for the cement pipe pile being prepared in embodiment 1-3, bending ability and anti-pressure ability have and obviously mention
Height, and effectively prevent the diffusion of chloride ion.
By above data and experiment, we, which can be concluded that in the present invention, controls reasonable proportion component, makes
The mechanical property for the cement pipe pile that must be prepared is more preferable, and the chloride ion of entire cement pipe pile is reduced by the preparation of cement composition
Permeability, while being prepared using discarded concrete as base material, cost is saved, the pressure resistance of cement pipe pile is improved
The mechanical properties such as degree, bending resistance have biggish practicability.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.Any label in claim should not be construed as limiting the claims involved.