CN109400029A - A method of cement pipe pile is processed using carbon fiber and regeneration concrete - Google Patents

A method of cement pipe pile is processed using carbon fiber and regeneration concrete Download PDF

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Publication number
CN109400029A
CN109400029A CN201811401018.7A CN201811401018A CN109400029A CN 109400029 A CN109400029 A CN 109400029A CN 201811401018 A CN201811401018 A CN 201811401018A CN 109400029 A CN109400029 A CN 109400029A
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powder
mixed
regeneration concrete
obtains
cement
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CN109400029B (en
Inventor
刘闯
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Laifeng Sanzhong Building Materials Co ltd
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Yancheng Xinchang New Building Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B21/00Methods or machines specially adapted for the production of tubular articles
    • B28B21/02Methods or machines specially adapted for the production of tubular articles by casting into moulds
    • B28B21/10Methods or machines specially adapted for the production of tubular articles by casting into moulds using compacting means
    • B28B21/22Methods or machines specially adapted for the production of tubular articles by casting into moulds using compacting means using rotatable mould or core parts
    • B28B21/30Centrifugal moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B21/00Methods or machines specially adapted for the production of tubular articles
    • B28B21/56Methods or machines specially adapted for the production of tubular articles incorporating reinforcements or inserts
    • B28B21/60Methods or machines specially adapted for the production of tubular articles incorporating reinforcements or inserts prestressed reinforcements
    • B28B21/62Methods or machines specially adapted for the production of tubular articles incorporating reinforcements or inserts prestressed reinforcements circumferential laterally tensioned
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • C04B7/246Cements from oil shales, residues or waste other than slag from waste building materials, e.g. waste asbestos-cement products, demolition waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

Abstract

The invention discloses a kind of methods using carbon fiber and regeneration concrete processing cement pipe pile, prepare regeneration concrete first, discarded concrete are carried out break process, then broken discarded concrete is crossed 38 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, obtains the first mixed powder, Ball-milling Time 2h;The first mixed powder is added in sodium hydroxide solution again, hydro-thermal 1 day under conditions of hydrothermal temperature is 30 DEG C, with the screen to filtrate of 200 mesh, obtains the second mixed powder;The sodium hydroxide solution is that concentration is 1mol/L.A kind of method using carbon fiber and regeneration concrete processing cement pipe pile is provided in the present invention, the reasonable proportion component of control, so that the mechanical property of the cement pipe pile of preparation is more preferable, while being prepared using discarded concrete as base material, save cost, economic benefits with higher.

Description

A method of cement pipe pile is processed using carbon fiber and regeneration concrete
Technical field
It is specifically a kind of to process cement pipe pile using carbon fiber and regeneration concrete the present invention relates to tubular pole manufacturing field Method.
Background technique
Tubular pole, and it is divided into post-tensioned prestressing stake and pretensioned-prestressed tube pile, prestressed concrete pipe pile (PC pipe Stake) and thin tubular piles produced by prestressed concrete (PTC tubular pole) and high strength prestressed concrete pipe pile (PHC tubular pole), nowadays city It prepares concrete on face using cement mostly, and carries out the manufacture of tubular pole.
Cement can be used for preparing concrete and concrete for various applications, including but not limited to road, parking Field, bridge, aisle and support construction.As Urbanization in China is accelerated, science and technology is more and more progressive, and construction industry enters high speed and sends out Exhibition stage, the following building waste are also constantly increasing, and wherein most is all discarded concrete, this not only gives us Environment bring pollution, also bring great inconvenience to our life.
For above situation, it would be desirable to design a kind of side using carbon fiber and regeneration concrete processing cement pipe pile Method, not only needs to solve the problems, such as the secondary use of discarded concrete, while also needing save the cost, and the chloride ion for reducing tubular pole seeps Saturating rate, this is our urgent problems to be solved.
Summary of the invention
The purpose of the present invention is to provide a kind of methods using carbon fiber and regeneration concrete processing cement pipe pile, with solution Certainly the problems of the prior art.
To achieve the above object, the invention provides the following technical scheme:
A method of cement pipe pile being processed using carbon fiber and regeneration concrete, each raw material component is as follows: with parts by weight Meter, 400-800 parts of cement composition, 1250-1400 parts of aggregate, 150-300 parts of water, 5-35 parts of water-reducing agent, fiber composition 150-250 parts, 9-50 parts of curing agent.
Optimally, each raw material component is as follows: in parts by weight, 500-550 parts of cement composition, aggregate 1300-1350 Part, 200-300 parts of water, 20-35 parts of water-reducing agent, 175-250 parts of fiber composition, 25-50 parts of curing agent.
Optimally, the cement composition each raw material component is as follows: by percentage to the quality, solvent 10-20%, regeneration Concrete 40%-55%, pozzolan cement 20%-35%, sugar 0.05%-0.5%, float stone 25%-50%, silicon ash 0.5%- 1.5%, aluminium hydroxide 0.2%-1%, flyash 0.6%-1.2%.
Optimally, the regeneration concrete each raw material component is as follows: by percentage to the quality, discarded concrete 40%- 50%, slag powders 30%-40%, desulfurized gypsum 20%-35%, steel slag 0.5%-1%, zeolite powder 5%-15%, sodium hydroxide 0.5%-2.2%.
Optimally, the sugar is one of galactolipin, glucose, dextrose, lactose, maltose, sucrose or a variety of.
Optimally, the fiber composition includes cellulose fibre, carbon fiber and pearl filler, the cellulose fiber The weight of dimension: the weight of pearl filler is (1:33)-(10:1);The weight of the carbon fiber: the weight of cellulose fibre is (1:2)-(2:1).
Optimally, the aggregate is one of lime stone, rubble, gravel or a variety of;The curing agent is solid for epoxy Agent.
Optimally, comprising the following steps:
1) regeneration concrete is prepared;
A) it pre-processes;
B) hydro-thermal;
C) primary calcining;
D) it is stirred;
E) secondary clacining;
F) regeneration concrete is obtained;
2) cement composition is prepared;
3) fiber composition is prepared;
4) preparation of tubular pole;
A) weigh cement composition, aggregate, water-reducing agent, fiber composition and curing agent by a certain percentage, and with it is a certain amount of Water mixing, put into blender in carry out high-speed stirred, obtain mixed material;
B) steel reinforcement cage with pile crown is made, and the steel reinforcement cage with pile crown is put into mold;
C) it is poured the mixed material being prepared into lower mold half, upper mold half and lower mold half are tightened, obtains stake Mould;
D) longitudinal tensioning is carried out, and the stake mould after tensioning is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;
E) double of finished product pile tube carries out atmospheric steam curing, then semi-finished product tubular pole is put into still kettle mesohigh steam and is supported Shield;
5) tubular pole is obtained.
Optimally, comprising the following steps:
1) regeneration concrete is prepared;
A) it pre-processes: discarded concrete being subjected to break process, then broken discarded concrete is crossed 38 μm -270 μm Sieve obtains discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, obtains One mixed powder, Ball-milling Time 2-3h;
B) hydro-thermal: the first mixed powder is added in sodium hydroxide solution, under conditions of hydrothermal temperature is 30-100 DEG C Hydro-thermal 1-3 days, with the screen to filtrate of 200-500 mesh, obtain the second mixed powder;The sodium hydroxide solution is that concentration is 1- 3mol/L;
C) primary calcining: the second mixed powder is put into calcining furnace and is once calcined, cement slurry powder is obtained;Institute Stating a calcination temperature is 800-900 DEG C, and a calcination time is 2-2.5h;
D) it is stirred: desulfurized gypsum, steel slag is subjected to break process respectively, then by broken desulfurized gypsum, steel slag 50 μm of -200 μm of sieves are crossed respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Slag powders, steel slag powder are put into ball again Grinding machine ball milling obtains third mixed powder, Ball-milling Time 3-3.5h;
E) secondary clacining: cement slurry powder and third mixed powder are mixed, and are put into and carried out two in calcining furnace Secondary calcining, obtains clinker;The secondary clacining temperature is 700-850 DEG C, and the secondary clacining time is 1-2h;
F) it obtains regeneration concrete: weighing the clinker and desulfurized gypsum powder of required component ratio, the clinker Quality: the quality of desulfurized gypsum powder be 100:(5-10), be mixed, obtain regeneration concrete;
2) cement composition is prepared;
A) float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively, and with 200-500 purpose The screen to filtrate obtains the 4th mixed powder;
B) sugar for weighing certain component, mixes and is stirred with solvent, places and puts into regeneration concrete, the 4th afterwards for 24 hours Mixed powder stirs evenly, and obtains the first mixed material;
C) flyash, the aluminium hydroxide of certain mass are weighed, and successively by the first mixed material, flyash, aluminium hydroxide It is calcined three times in investment calcining furnace, obtains cement composition;Calcination temperature is 800-900 DEG C three times, three times calcination time For 2-2.5h;
3) fiber composition is prepared;
A) fiber and pearl filler are weighed according to a certain percentage, fiber is placed in aqueous environments first, so that fiber Fibrillation, until forming nanometer fibrous gel;
B) pearl filler is mixed again with nanometer fibrous gel, is stirred evenly;Obtain mixed material;
C) a certain amount of carbon fiber is weighed, by mixed material and carbon fibers and is dehydrated, and is manufactured into structuring Material obtains fiber composition;
4) preparation of tubular pole;
A) weigh cement composition, aggregate, water-reducing agent, fiber composition and curing agent by a certain percentage, and with it is a certain amount of Water mixing, put into blender in carry out high-speed stirred, mixing time 1-2h obtains the second mixed material;
B) steel reinforcement cage with pile crown is made, and the steel reinforcement cage with pile crown is put into mold;
C) it is poured the mixed material being prepared into lower mold half, upper mold half and lower mold half are tightened, obtains band Expect stake mould;
D) longitudinal tensioning, and the strip stake mould after tensioning is placed on centrifugal forming on centrifuge, obtain semi-finished product tubular pole;
E) semi-finished product tubular pole carries out atmospheric steam curing, and the atmospheric steam curing time is 2-3h, then by semi-finished product tubular pole
F) it is put into still kettle mesohigh steam curing, temperature is 200-220 DEG C, when autoclave curing in the still kettle Between be 5-8h;
5) tubular pole is obtained.
Compared with prior art, the beneficial effects of the present invention are:
Devised in the present invention it is a kind of using carbon fiber and regeneration concrete processing cement pipe pile method, wherein by pair Discarded concrete carries out secondary use, regeneration concrete is prepared, then by processing to regeneration concrete, obtain cement Composition not only increases the mechanical property of cement pipe pile, reduces simultaneously for serving as the base material for preparing cement pipe pile Cost has high economic benefit, effectively practical;By being processed to carbon fiber and cellulose fibre in the present invention, obtain To fiber composition, fiber composition is easily separated into fibre single thread under the action of the immersion of water and blender frictional force, from And effect of prestressed is played, the mechanical property of cement pipe pile can be effectively improved, the freeze-thaw resistance and impermeability of cement pipe pile are enhanced.
When the present invention prepares regeneration concrete, it is added to zeolite powder, the per unit pore volume in material can be effectively reduced, is sticked Regeneration concrete micro-crack produced during the preparation process is closed or repaired, the bond strength between each component is enhanced, and keeps regeneration mixed Solidifying Soil Interface plot structure tends to be fine and close, compactness when improving cement pipe pile preparation between each component.
The present invention is calcined twice when preparing regeneration concrete, while being carried out before calcination to the first mixed powder Hydro-thermal provides alkaline environment by sodium hydroxide solution for subsequent synthetic reaction, can sufficiently activate in this way to flyash, Improve the aggregate velocity of regeneration concrete.
In the present invention in the secondary use to discarded concrete, by carrying out crushing, stirring to discarded concrete, and add Enter various auxiliary materials and regeneration concrete is made, wherein the proportion of discarded concrete is reduced with the increase that steel slag matches, regenerates coagulation The intensity of soil can be presented one and first increase the trend reduced afterwards, and when the mass percent of steel slag is 0.8%, intensity reaches highest Value continues growing steel slag proportion, and intensity declines instead, so the mass percent of steel slag is selected as 0.8% in the present invention;Addition Steel slag, can provocative reaction when whole system alkalinity, to make whole system there are a most suitable hydrated products in aquation The alkalinity ranges of generation improve the generation of hydrated product.
It also added desulfurized gypsum in the present invention, the intensity of regeneration concrete can be improved.Steel slag can excite in the present invention System alkalinity, slag powders are under the excitation of alkali, and the limestone surfaces in discarded concrete generate a large amount of entringite and C-S-H is solidifying Discarded concrete particle is closely joined together and is formed spacial framework by glue, what the subsequent continuous aquation of slag powders generated C-S-H gel and entringite are constantly filled in the hole of network, final to wrap up discarded concrete particle and cause slurry more It is close, the intensity of regeneration concrete is improved, to improve the intensity of the cement pipe pile prepared using regeneration concrete as raw material.
After preparing regeneration concrete in the present invention, each component is added, cement composition is made again, cement pipe pile can be reduced Chloride ion permeability, increasing flexural strength and module strength, the addition of sucrose reduces cementing needed for preparation process The amount of material, reduces costs, while improving the wearability of cement pipe pile, reduces shrinking percentage.
When preparing cement composition in the present invention, it is added to flyash, can not only cooperate with silicon ash and realize " double-doped " effect Fruit, while flyash can also be cooperated with the zeolite powder in regeneration concrete, between each component for improving cement composition It is compatible;Aluminium hydroxide is added when being calcined three times, the alkaline environment phase interworking in aluminium hydroxide, flyash and regeneration concrete It closes, not only increases the whole activation degree of flyash, while zeolite can also be generated when calcining three times, it is further to improve The compactness of regeneration concrete improves the interfacial structure of regeneration concrete, and when preparing cement composition, it is mixed that regeneration can be improved Degree of cohering between solidifying soil and other components.
When preparing fiber composition in the present invention, pearl filler excessively will affect the formation of gel, we select to control The amount of pearl filler accelerates the formation of gel, this is also convenient for cement pipe pile can preferably mix between each component in the preparation It closes, reduces the amount of colloid, save the cost.
Water-reducing agent selects polycarboxylic acid series high efficiency water reducing agent or naphthalene water reducer, cement composition in the present invention in the present invention In be added to silicon ash, " double-doped " effect is reached by high-efficiency water-reducing agent of poly-carboxylic acid and silicon ash, while in cement admixture preparation It is added to flyash, the Pore Solution for fitting through dilution effect, chemical effect, reducing when material mixing of flyash and silicon ash PH;In the next steps, after material is mixed and semi-finished product tubular pole is prepared, present invention employs normal pressure steamings Vapour maintenance, with the raising of curing temperature, the quickening of hydrated reaction of cement speed, the speed that the basicity in concrete reduces adds Fastly;
Simultaneously because the cooperation of high-efficiency water-reducing agent of poly-carboxylic acid and silicon ash, the cooperation of flyash and slag powders, when prepared by tubular pole Mixed material when being stirred, each component therein quickly dissolves, and quickly improves the basicity in mixed material, simultaneously The hydration temperature of mixed material is also improved, the speed of hydration reaction is accelerated, increases the generation quantity of hydrated product, is improved The demoulding strength of cement pipe pile.
The method that directly molding perfusion is used in the present invention, concrete are directly filled into the inner cavity of mold, avoid the occurrence of The phenomenon that concrete particle is fallen reduces human cost, saves labour;Upper mold, lower mold are tightened when molding simultaneously, is kept away Exempt from the problem of concrete tubular pile joint close spillage occur, ensure that the quality of concrete tubular pile.
A kind of method using carbon fiber and regeneration concrete processing cement pipe pile is provided in the present invention, control is reasonable Component is matched, so that the mechanical property of the cement pipe pile of preparation is more preferable, entire cement is reduced by the preparation of cement composition The chloride permeability rate of tubular pole, while being prepared using discarded concrete as base material, cost is saved, it is with higher Economic benefits.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
Embodiment 1:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake 38 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained To the first mixed powder, Ball-milling Time 2h;The first mixed powder is added in sodium hydroxide solution again, is 30 in hydrothermal temperature Hydro-thermal 1 day under conditions of DEG C obtains the second mixed powder with the screen to filtrate of 200 mesh;The sodium hydroxide solution is that concentration is 1mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;It is described once to forge Burning temperature is 800 DEG C, and a calcination time is 2h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will it is broken after Desulfurized gypsum, steel slag respectively cross 50 μm of sieves, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag powders, steel-making slag powder Body puts into ball mill ball milling, obtains third mixed powder, Ball-milling Time 3h;Again by cement slurry powder and third mixed powder It is mixed, and puts into and carry out secondary clacining in calcining furnace, obtain clinker;The secondary clacining temperature is 700 DEG C, described The secondary clacining time is 1h;Finally weigh the clinker and desulfurized gypsum powder of required component ratio, the matter of the clinker Amount: the quality of desulfurized gypsum powder is 20:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively Mill, and with the screen to filtrate of 200 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times Calcining, obtains cement composition;Calcination temperature is 800 DEG C three times, and calcination time is 2h three times.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 1h Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half The mixed material being prepared, upper mold half and lower mold half are tightened, and obtain strip stake mould;Then longitudinal tensioning, and will open Strip stake mould after drawing is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam Maintenance, the atmospheric steam curing time is 2h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, in the still kettle Temperature is 200 DEG C, and the autoclave curing time is 5h.
In the present embodiment, each raw material component by weight: 525 parts of cement composition, 1325 parts of aggregate, 250 parts of water, diminishing 26 parts of agent, 200 parts of fiber composition, 40 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement 22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag 0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 2:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake 200 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained To the first mixed powder, Ball-milling Time 2h;The first mixed powder is added in sodium hydroxide solution again, is 30 in hydrothermal temperature Hydro-thermal 1 day under conditions of DEG C obtains the second mixed powder with the screen to filtrate of 200 mesh;The sodium hydroxide solution is that concentration is 2mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;It is described once to forge Burning temperature is 850 DEG C, and a calcination time is 2h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will it is broken after Desulfurized gypsum, steel slag respectively cross 50 μm of sieves, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag powders, steel-making slag powder Body puts into ball mill ball milling, obtains third mixed powder, Ball-milling Time 3h;Again by cement slurry powder and third mixed powder It is mixed, and puts into and carry out secondary clacining in calcining furnace, obtain clinker;The secondary clacining temperature is 700 DEG C, described The secondary clacining time is 1h;Finally weigh the clinker and desulfurized gypsum powder of required component ratio, the matter of the clinker Amount: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively Mill, and with the screen to filtrate of 200 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times Calcining, obtains cement composition;Calcination temperature is 850 DEG C three times, and calcination time is 2.2h three times.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, mixing time 1.5h obtains second Mixed material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half The mixed material being prepared is infused, upper mold half and lower mold half are tightened, strip stake mould is obtained;Then longitudinal tensioning, and will Strip stake mould after tensioning is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out normal pressure steaming Vapour maintenance, the atmospheric steam curing time is 2.5h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, the steam pressure Temperature is 210 DEG C in kettle, and the autoclave curing time is 7h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 500 parts of cement composition, 1300 parts of aggregate, 200 parts of water, diminishing 20 parts of agent, 175 parts of fiber composition, 25 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement 22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag 0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 3:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake 270 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained To the first mixed powder, Ball-milling Time 3h;The first mixed powder is added in sodium hydroxide solution again, is in hydrothermal temperature Hydro-thermal 3 days under conditions of 100 DEG C obtain the second mixed powder with the screen to filtrate of 500 mesh;The sodium hydroxide solution is dense Degree is 3mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;Described one Secondary calcination temperature is 900 DEG C, and a calcination time is 2.5h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will Broken desulfurized gypsum, steel slag cross 200 μm of sieves respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag Powder, steel slag powder put into ball mill ball milling, obtain third mixed powder, Ball-milling Time 3.5h;Again by cement slurry powder and Third mixed powder is mixed, and is put into and carried out secondary clacining in calcining furnace, and clinker is obtained;The secondary clacining temperature It is 850 DEG C, the secondary clacining time is 2h;The clinker and desulfurized gypsum powder of required component ratio are finally weighed, it is described The quality of clinker: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively Mill, and with the screen to filtrate of 500 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times Calcining, obtains cement composition;Calcination temperature is 900 DEG C three times, and calcination time is 2.5h three times.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 2h Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half The mixed material being prepared, upper mold half and lower mold half are tightened, and obtain strip stake mould;Then longitudinal tensioning, and will open Strip stake mould after drawing is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam Maintenance, the atmospheric steam curing time is 3h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, in the still kettle Temperature is 220 DEG C, and the autoclave curing time is 8h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing 35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement 22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag 0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 4:
Cement composition is prepared first, and first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively Mill, and with the screen to filtrate of 200 mesh, obtain mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent, It places and puts into portland cement, mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh the fine coal of certain mass Ash, and the first mixed material, flyash are successively put into calcining furnace and calcined, obtain cement composition;Calcination temperature is 800 DEG C, calcination time 2h.
Fiber composition is prepared again, weighs fiber and pearl filler first, in accordance with certain proportion, and fiber is placed in water Property environment so that fiber fibrillation, until forming nanometer fibrous gel;Pearl filler and nanometer fibrous gel are mixed again It closes, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is weighed, by mixed material and carbon fibers and is dehydrated, And manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent, fiber composition by a certain percentage And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 1h Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;Preparation is poured into lower mold half Obtained mixed material, upper mold half and lower mold half are tightened, and obtain strip stake mould;Longitudinal tensioning, and by the band after tensioning Material stake mould is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Semi-finished product tubular pole carries out atmospheric steam curing, atmospheric steam Curing time is 2h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, and temperature is 200 DEG C in the still kettle, The autoclave curing time is 5h;Obtain the tubular pole.
Each raw material component is by weight in the present embodiment: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing 35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, silicate concrete 40%, pozzolan cement 22%, sugared 0.05%, float stone 26%, silicon ash 1.2%, flyash 0.75%.
Embodiment 5:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake 270 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained To the first mixed powder, Ball-milling Time 3h;The first mixed powder is added in sodium hydroxide solution again, is in hydrothermal temperature Hydro-thermal 3 days under conditions of 100 DEG C obtain the second mixed powder with the screen to filtrate of 500 mesh;The sodium hydroxide solution is dense Degree is 3mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;Described one Secondary calcination temperature is 900 DEG C, and a calcination time is 2.5h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will Broken desulfurized gypsum, steel slag cross 200 μm of sieves respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag Powder, steel slag powder put into ball mill ball milling, obtain third mixed powder, Ball-milling Time 3.5h;Again by cement slurry powder and Third mixed powder is mixed, and is put into and carried out secondary clacining in calcining furnace, and clinker is obtained;The secondary clacining temperature It is 850 DEG C, the secondary clacining time is 2h;The clinker and desulfurized gypsum powder of required component ratio are finally weighed, it is described The quality of clinker: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Then cement composition is prepared, first float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively Mill, and with the screen to filtrate of 500 mesh, obtain the 4th mixed powder;The sugar for weighing certain component again, mixes and is stirred with solvent It mixes, places and put into regeneration concrete, the 4th mixed powder afterwards for 24 hours, stir evenly, obtain the first mixed material;Weigh certain matter Flyash, the aluminium hydroxide of amount, and the first mixed material, flyash, aluminium hydroxide are successively put into calcining furnace and carried out three times Calcining, obtains cement composition;Calcination temperature is 900 DEG C three times, and calcination time is 2.5h three times.
The preparation for finally carrying out tubular pole, first weighs cement composition, aggregate, water-reducing agent and curing agent by a certain percentage, and It is mixed with a certain amount of water, puts into blender and carry out high-speed stirred, mixing time 2h obtains the second mixed material;It makes again Make the steel reinforcement cage with pile crown, and the steel reinforcement cage with pile crown is put into mold;Into lower mold half, casting is prepared immediately Mixed material tightens upper mold half and lower mold half, obtains strip stake mould;Then longitudinal tensioning, and by the strip after tensioning Stake mould is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam curing, and normal pressure steams Vapour curing time is 3h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, and temperature is 220 in the still kettle DEG C, the autoclave curing time is 8h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing 35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement 22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag 0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Embodiment 6:
Regeneration concrete is prepared first, discarded concrete is subjected to break process, then by broken discarded concrete mistake 270 μm of sieves, obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, is obtained To the first mixed powder, Ball-milling Time 3h;The first mixed powder is added in sodium hydroxide solution again, is in hydrothermal temperature Hydro-thermal 3 days under conditions of 100 DEG C obtain the second mixed powder with the screen to filtrate of 500 mesh;The sodium hydroxide solution is dense Degree is 3mol/L;Then the second mixed powder is put into calcining furnace and is once calcined, obtain cement slurry powder;Described one Secondary calcination temperature is 900 DEG C, and a calcination time is 2.5h;Desulfurized gypsum, steel slag are subjected to break process respectively, then will Broken desulfurized gypsum, steel slag cross 200 μm of sieves respectively, respectively obtain desulfurized gypsum powder, steel slag powder;Again by slag Powder, steel slag powder put into ball mill ball milling, obtain third mixed powder, Ball-milling Time 3.5h;Again by cement slurry powder and Third mixed powder is mixed, and is put into and carried out secondary clacining in calcining furnace, and clinker is obtained;The secondary clacining temperature It is 850 DEG C, the secondary clacining time is 2h;The clinker and desulfurized gypsum powder of required component ratio are finally weighed, it is described The quality of clinker: the quality of desulfurized gypsum powder is 10:1, is mixed, obtains regeneration concrete.
Fiber composition is prepared again, is first weighed fiber and pearl filler according to a certain percentage, is first placed in fiber Aqueous environments, so that fiber fibrillation, until forming nanometer fibrous gel;Again by pearl filler and nanometer fibrous gel Mixing, stirs evenly;Obtain mixed material;A certain amount of carbon fiber is finally weighed, mixed material and carbon fibers are gone forward side by side Row dehydration, and manufacture into structured material, obtain fiber composition.
The preparation for finally carrying out tubular pole, first weighs regeneration concrete, aggregate, water-reducing agent, fiber composition by a certain percentage And curing agent, and mixed with a certain amount of water, it puts into blender and carries out high-speed stirred, it is mixed to obtain second by mixing time 2h Close material;The steel reinforcement cage with pile crown is made again, and the steel reinforcement cage with pile crown is put into mold;It is poured immediately into lower mold half The mixed material being prepared, upper mold half and lower mold half are tightened, and obtain strip stake mould;Then longitudinal tensioning, and will open Strip stake mould after drawing is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;Last semi-finished product tubular pole carries out atmospheric steam Maintenance, the atmospheric steam curing time is 3h, then semi-finished product tubular pole is put into still kettle mesohigh steam curing, in the still kettle Temperature is 220 DEG C, and the autoclave curing time is 8h, obtains required tubular pole.
In the present embodiment, each raw material component by weight: 550 parts of cement composition, 1350 parts of aggregate, 300 parts of water, diminishing 35 parts of agent, 250 parts of fiber composition, 50 parts of curing agent.
Wherein each raw material component of cement composition includes: solvent 10%, regeneration concrete 40%, pozzolan cement 22%, sugared 0.05%, float stone 25%, silicon ash 1.2%, aluminium hydroxide 1%, flyash 0.75%.
Regeneration concrete each raw material component: discarded concrete 40%, slag powders 30%, desulfurized gypsum 20%, steel slag 0.8%, zeolite powder 7%, sodium hydroxide 2.2%.
Test experience:
Embodiment 1-6 is comparative experiments, and wherein embodiment 1, embodiment 2, the cement composition in embodiment 3 pass through again Growing concrete preparation, and regeneration concrete has been changed into silicate concrete in embodiment 4, fiber group is not added in embodiment 5 Object is closed, and directly carries out the preparation of cement pipe pile by cement composition, and does not carry out the system of cement composition in embodiment 6 It is standby, tubular pole is directly prepared by regeneration concrete and fiber composition, the influence of remaining control parameter can be ignored.
Test 1: chloride diffusion coefficient detection
It is 100mm, with a thickness of the cylinder sample of 50 ± 2mm that concrete, which is cut into diameter, first, then by sample in ultrasound It is cleaned in bath, the sample after cleaning is mounted on specimen holder, injection test solution, connecting test host;Open NJ-RCM Chloride diffusion coefficient analyzer host carries out electromigration experiment;Then the sample after electromigration is rived along axial direction, is being rived Surface on spray silver nitrate solution, determine diffusion depth, and calculate diffusion coefficient;Wherein anodic dissolution selects 0.3mol/l's Sodium hydroxide solution, the sodium chloride solution of cathode solution selection 10%, soaking solution select calcium hydroxide solution.
Diffusion coefficient calculation formula:
Wherein D is the transport coefficient of concrete chloride ion, and t is the time of Therapy lasted, and M is the flat of chloride ion penetration depth Mean value, T are anodic dissolution initial temperature and the average value for terminating temperature, and U is the absolute value of applied voltage.
Test 2: compression strength
Concrete is cut into the cuboid sample that side length is 100mm first, by press machine with 0.5-0.8MPa/s's Loading velocity loads sample, writes down the peak load that concrete is able to bear, and calculate the intensity of concrete, surveys strong Degree obtains final compression strength multiplied by 0.95 reduction coefficient.
Test 3: mechanical property and electric flux
The detection of mechanical property is carried out to the tubular pole that embodiment 1-6 is prepared, while detecting electric flux detection.
To the cement pipe pile being prepared in embodiment 1, embodiment 2, embodiment 3, embodiment 4, embodiment 5, embodiment 6 Mechanics properties testing is carried out, and will test result and be compared:
As shown above, regeneration concrete has been changed into silicate concrete in embodiment 4, and directly pass through cement composition Object carries out the preparation of cement pipe pile, experiment is contrasted with embodiment 1-3, in contrast to the data of tubular pole obtained in embodiment 4 From the point of view of, the properties for the tubular pole that the present invention is prepared all are improved, and anti-bending strength is strong, and compression strength is improved, Chloride diffusion coefficient reduces;The cement composition in embodiment 1-3 is prepared by regeneration concrete simultaneously, in embodiment 5 It is not added with fiber composition, from the point of view of the data of embodiment 1-3 are compared with embodiment 5, there is significantly compression strength in embodiment 5 It reduces, this has absolutely proved that the preparation of fiber composition substantially increases the compression strength of tubular pole;Water is not carried out in embodiment 6 The preparation of mud composition, by comparative example 1-3 with the data of embodiment 6, the chloride diffusion coefficient in embodiment 6 has It significantly improves, this has absolutely proved that the preparation of cement composition reduces the diffusion coefficient of chloride ion, increases bending and resistance to compression Ability, and the compression strength for the cement pipe pile being prepared in embodiment 1-3, bending ability and anti-pressure ability have and obviously mention Height, and effectively prevent the diffusion of chloride ion.
By above data and experiment, we, which can be concluded that in the present invention, controls reasonable proportion component, makes The mechanical property for the cement pipe pile that must be prepared is more preferable, and the chloride ion of entire cement pipe pile is reduced by the preparation of cement composition Permeability, while being prepared using discarded concrete as base material, cost is saved, the pressure resistance of cement pipe pile is improved The mechanical properties such as degree, bending resistance have biggish practicability.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.Any label in claim should not be construed as limiting the claims involved.

Claims (9)

1. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile, it is characterised in that: each raw material component is as follows: In parts by weight, cement composition 400-800 parts, 1250-1400 parts of aggregate, 150-300 parts of water, 5-35 parts of water-reducing agent, fiber 150-250 parts of composition, 9-50 parts of curing agent.
2. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile according to claim 1, feature Be: each raw material component is as follows: in parts by weight, 500-550 parts of cement composition, 1300-1350 parts of aggregate, water 200-300 Part, 20-35 parts of water-reducing agent, 175-250 parts of fiber composition, 25-50 parts of curing agent.
3. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile according to claim 2, feature Be: the cement composition each raw material component is as follows: by percentage to the quality, solvent 10-20%, regeneration concrete 40%- 55%, pozzolan cement 20%-35%, sugar 0.05%-0.5%, float stone 25%-50%, silicon ash 0.5%-1.5%, hydroxide Aluminium 0.2%-1%, flyash 0.6%-1.2%.
4. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile according to claim 3, feature Be: the regeneration concrete each raw material component is as follows: by percentage to the quality, discarded concrete 40%-50%, slag powders 30%-40%, desulfurized gypsum 20%-35%, steel slag 0.5%-1%, zeolite powder 5%-15%, sodium hydroxide 0.5%-2.2%.
5. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile according to claim 3, feature Be: the sugar is one of galactolipin, glucose, dextrose, lactose, maltose, sucrose or a variety of.
6. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile according to claim 2, feature Be: the fiber composition includes cellulose fibre, carbon fiber and pearl filler, the weight of the cellulose fibre: carbon The weight of sour calcium filler is (1:33)-(10:1);The weight of the carbon fiber: the weight of cellulose fibre is (1:2)-(2:1).
7. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile according to claim 2, feature Be: the aggregate is one of lime stone, rubble, gravel or a variety of;The curing agent is epoxy hardener.
8. a kind of side using carbon fiber and regeneration concrete processing cement pipe pile described in any one of -7 according to claim 1 Method, it is characterised in that: the following steps are included:
1) regeneration concrete is prepared;
A) it pre-processes;
B) hydro-thermal;
C) primary calcining;
D) it is stirred;
E) secondary clacining;
F) regeneration concrete is obtained;
2) cement composition is prepared;
3) fiber composition is prepared;
4) preparation of tubular pole;
A) weigh cement composition, aggregate, water-reducing agent, fiber composition and curing agent by a certain percentage, and with a certain amount of water Mixing puts into blender and carries out high-speed stirred, obtains mixed material;
B) steel reinforcement cage with pile crown is made, and the steel reinforcement cage with pile crown is put into mold;
C) it is poured the mixed material being prepared into lower mold half, upper mold half and lower mold half are tightened, obtains a mould;
D) longitudinal tensioning is carried out, and the stake mould after tensioning is placed on centrifugal forming on centrifuge, obtains semi-finished product tubular pole;
E) double of finished product pile tube carries out atmospheric steam curing, then tubular pole is put into still kettle mesohigh steam curing;
5) tubular pole is obtained.
9. a kind of method using carbon fiber and regeneration concrete processing cement pipe pile according to claim 8, feature It is: the following steps are included:
1) regeneration concrete is prepared;
A) it pre-processes: discarded concrete being subjected to break process, then broken discarded concrete is crossed into 38 μm of -270 μm of sieves, Obtain discarded concrete powder;Zeolite powder is mixed with discarded concrete powder, and puts into ball mill ball milling, obtains the first mixing Powder, Ball-milling Time 2-3h;
B) hydro-thermal: the first mixed powder is added in sodium hydroxide solution, hydro-thermal under conditions of hydrothermal temperature is 30-100 DEG C 1-3 days, with the screen to filtrate of 200-500 mesh, obtain the second mixed powder;The sodium hydroxide solution is that concentration is 1-3mol/ L;
C) primary calcining: the second mixed powder is put into calcining furnace and is once calcined, cement slurry powder is obtained;Described one Secondary calcination temperature is 800-900 DEG C, and a calcination time is 2-2.5h;
D) it is stirred: desulfurized gypsum, steel slag being subjected to break process respectively, then broken desulfurized gypsum, steel slag are distinguished 50 μm of -200 μm of sieves are crossed, desulfurized gypsum powder, steel slag powder are respectively obtained;Slag powders, steel slag powder are put into ball mill again Ball milling obtains third mixed powder, Ball-milling Time 3-3.5h;
E) secondary clacining: cement slurry powder and third mixed powder are mixed, and are put into and carried out secondary forge in calcining furnace It burns, obtains clinker;The secondary clacining temperature is 700-850 DEG C, and the secondary clacining time is 1-2h;
F) it obtains regeneration concrete: weighing the clinker and desulfurized gypsum powder of required component ratio, the matter of the clinker Amount: the quality of desulfurized gypsum powder is 100:(5-10), it is mixed, obtains regeneration concrete;
2) cement composition is prepared;
A) float stone, pozzolan cement, silicon ash are put into grinder grind respectively respectively, and with the sieve of 200-500 mesh Filtering, obtains the 4th mixed powder;
B) sugar for weighing certain component, mixes and is stirred with solvent, places and puts into regeneration concrete, the 4th mixing afterwards for 24 hours Powder stirs evenly, and obtains the first mixed material;
C) flyash, the aluminium hydroxide of certain mass are weighed, and the first mixed material, flyash, aluminium hydroxide are successively put into It is calcined three times in calcining furnace, obtains cement composition;Calcination temperature is 800-900 DEG C three times, and calcination time is 2- three times 2.5h;
3) fiber composition is prepared;
A) fiber and pearl filler are weighed according to a certain percentage, fiber is placed in aqueous environments first, so that cellulose fibrils Change, until forming nanometer fibrous gel;
B) pearl filler is mixed again with nanometer fibrous gel, is stirred evenly;Obtain mixed material;
C) a certain amount of carbon fiber is weighed, by mixed material and carbon fibers and is dehydrated, and is manufactured into structured material, Obtain fiber composition;
4) preparation of tubular pole;
A) weigh cement composition, aggregate, water-reducing agent, fiber composition and curing agent by a certain percentage, and with a certain amount of water Mixing puts into blender and carries out high-speed stirred, and mixing time 1-2h obtains the second mixed material;
B) steel reinforcement cage with pile crown is made, and the steel reinforcement cage with pile crown is put into mold;
C) it is poured the mixed material being prepared into lower mold half, upper mold half and lower mold half are tightened, obtains strip stake Mould;
D) longitudinal tensioning, and the strip stake mould after tensioning is placed on centrifugal forming on centrifuge, obtain semi-finished product tubular pole;
E) semi-finished product tubular pole carries out atmospheric steam curing, and the atmospheric steam curing time is 2-3h, then semi-finished product tubular pole is put into steaming The steam curing of kettle mesohigh is pressed, temperature is 200-220 DEG C in the still kettle, and the autoclave curing time is 5-8h;
5) tubular pole is obtained.
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Publication number Priority date Publication date Assignee Title
CN110253750A (en) * 2019-05-30 2019-09-20 阜阳市双顺预制构件有限公司 A method of hollow circular tube is made using discarded concrete
CN114890757A (en) * 2022-06-30 2022-08-12 深圳市衡骏环保科技有限公司 Recycled aggregate concrete and preparation method thereof
CN115057641A (en) * 2022-06-30 2022-09-16 深圳市衡骏环保科技有限公司 Engineering waste soil-based regenerative functional aggregate and preparation method thereof

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CN1990410A (en) * 2005-12-27 2007-07-04 尹小林 Cement regeneration technique by activating discarded concrete
CN102869831A (en) * 2010-04-27 2013-01-09 Omya发展股份公司 Process for the production of gel-based composite materials
CN104926234A (en) * 2015-06-08 2015-09-23 李彩琴 Concrete used for pipe pile and having good bonding performance with reinforcing steel bars
CN105541223A (en) * 2015-12-22 2016-05-04 连云港艾可新型建材有限公司 PHC pipe pile concrete and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1990410A (en) * 2005-12-27 2007-07-04 尹小林 Cement regeneration technique by activating discarded concrete
CN102869831A (en) * 2010-04-27 2013-01-09 Omya发展股份公司 Process for the production of gel-based composite materials
CN104926234A (en) * 2015-06-08 2015-09-23 李彩琴 Concrete used for pipe pile and having good bonding performance with reinforcing steel bars
CN105541223A (en) * 2015-12-22 2016-05-04 连云港艾可新型建材有限公司 PHC pipe pile concrete and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110253750A (en) * 2019-05-30 2019-09-20 阜阳市双顺预制构件有限公司 A method of hollow circular tube is made using discarded concrete
CN114890757A (en) * 2022-06-30 2022-08-12 深圳市衡骏环保科技有限公司 Recycled aggregate concrete and preparation method thereof
CN115057641A (en) * 2022-06-30 2022-09-16 深圳市衡骏环保科技有限公司 Engineering waste soil-based regenerative functional aggregate and preparation method thereof

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