CN109385124A - Tunnel multifunctional coating - Google Patents

Tunnel multifunctional coating Download PDF

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Publication number
CN109385124A
CN109385124A CN201811096045.8A CN201811096045A CN109385124A CN 109385124 A CN109385124 A CN 109385124A CN 201811096045 A CN201811096045 A CN 201811096045A CN 109385124 A CN109385124 A CN 109385124A
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parts
powder
tree root
multifunctional coating
moringa tree
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王羽
张庆明
吴中正
杨旋
胡珍
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Chongqing Jiaotong University
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Chongqing Jiaotong University
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention provides a kind of tunnel multifunctional coating, by by silicone acrylic emulsion, lithium metasilicate, glycidyl methacrylate, polyvinyl alcohol, talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seawood meal, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder, zinc borate, tangerine peel powder, hydroxypropyl methyl cellulose, mineral oil antifoam agent, the raw material components such as aluminate coupling agent and deionized water, it is compounded by specific dosage relation, in conjunction with specific preparation method, each raw material component can sufficiently be merged, and then play the mutual synergistic effect between each raw material component, realize the enhancing and complementation in performance, being made has excellent fire protecting performance, adhesion property, acid-proof alkaline, weatherability, the tunnel multifunctional coating of waterproof performance and antimildew and antibacterial performance.

Description

Tunnel multifunctional coating
Technical field
The present invention relates to tunnel Material Fields, and in particular to a kind of tunnel multifunctional coating.
Background technique
It is dust more than one, environment easy to pollute, relative humidity is high in tunnel, tunnel inner wall skin-material requires easily The functions such as cleaning, durable, fire resisting, mould proof, play it is easy to clean maintenance, it is energy-saving and provide safety environment make With.Currently, tunnel inner wall skin-material is mainly based on coating and ceramic tile.And coating used in constructing tunnel, substantially Inorganic heat insulation mortar class thick coated type coating, although its coating has good refractory heat-insulating performance, there is also be difficult to gram The shortcomings that taking is easy to be easy to produce mildew after corroding by mould, adhesiveness reduces, coating if coating waterproof, seepage control is poor Crack, fall off, binding strength of coating is lower, to high speed traveling generate powerful air-flow, wind pressure and resonance shock wave resistance compared with It is weak, Yi Yinfa coating crack, etc..
Therefore, in order to meet the requirement of this Special use environment in tunnel, it is excellent, viscous to need to develop a kind of fire protecting performance Attached performance is good, good weatherability, water proof anti-seepage, antimildew and antibacterial, environmentally protective tunnel coating.
Summary of the invention
In view of this, the present invention provides, a kind of fire protecting performance is excellent, adhesion property is good, good weatherability, water proof anti-seepage, mould proof Antibacterial, environmentally protective tunnel multifunctional coating.
Tunnel multifunctional coating provided by the invention, by weight, including the following raw material component: silicone acrylic emulsion 65~ 70 parts, 30~35 parts of lithium metasilicate, 10~12 parts of glycidyl methacrylate, 20~22 parts of polyvinyl alcohol, talcum powder 30~ 35 parts, 30~35 parts of kaolinite, 20~25 parts of vermiculite, 20~25 parts of mica powder, 15~20 parts of pyrophillite, jade powder 10~15 Part, 10~15 parts of Peitou mountain flour, 10~12 parts of seawood meal, 10~12 parts of charcoal powder, 15~20 parts of Moringa tree root powder, flaccid knotweed herb 15~20 parts of powder, 8~10 parts of zinc borate, 8~10 parts of tangerine peel powder, 5~10 parts of hydroxypropyl methyl cellulose, mineral oil antifoam agent 2~4 parts, 1.5~2 parts of aluminate coupling agent, 60~65 parts of deionized water;
Further, by weight, including the following raw material component: 68 parts of silicone acrylic emulsion, 32 parts of lithium metasilicate, methacrylic acid 11 parts of ethylene oxidic ester, 21 parts of polyvinyl alcohol, 32 parts of talcum powder, 32 parts of kaolinite, 23 parts of vermiculite, 23 parts of mica powder, pyrophillite 18 parts, 12 parts of jade powder, 12 parts of Peitou mountain flour, 11 parts of seawood meal, 11 parts of charcoal powder, 18 parts of Moringa tree root powder, polygonum flaccidum grass meal Last 18 parts, 9 parts of zinc borate, 9 parts of tangerine peel powder, 7 parts of hydroxypropyl methyl cellulose, 3 parts of mineral oil antifoam agent, aluminate coupling agent 1.5 parts, 63 parts of deionized water;
Further, the Moringa tree root powder by Moringa tree root it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm.
The invention also discloses a kind of preparation methods for the tunnel multifunctional coating, include the following steps:
A, after deionized water being heated to 35~38 DEG C, hydroxypropyl methyl cellulose and zinc borate are added thereto, with After stirring 20~25min, talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, north is added in the revolving speed of 1000rpm Lapidation powder, seawood meal, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed point 30~45min is dissipated, mixed material is made;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicon is added thereto again Sour lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent, with the revolving speed of 1000rpm, stirring 45~ 60min can be prepared by tunnel multifunctional coating.
Beneficial effects of the present invention:
Present invention employs silicone acrylic emulsion, lithium metasilicate, glycidyl methacrylate, polyvinyl alcohol, talcum powder, kaolinites Stone, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seawood meal, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder, The raw material components such as zinc borate, tangerine peel powder, hydroxypropyl methyl cellulose, mineral oil antifoam agent, aluminate coupling agent and deionized water, It is compounded by specific dosage relation, in conjunction with specific preparation method, can sufficiently merge each raw material component, and then play each original Expect the mutual synergistic effect between component, realize enhancing and complementation in performance, being made has excellent fire protecting performance, adhesiveness Energy, acid-proof alkaline, weatherability, waterproof performance and antimildew and antibacterial performance tunnel multifunctional coating.
In the present invention, each raw material component can play multi-efficiency, by reasonably arranging in pairs or groups, each component can be made to realize Preferable compatible and dispersion, the component for keeping each component corresponding to having effects that carries out coordinated, to preferably play its institute The excellent properties having, and then achieve the purpose that synergy.Wherein, by raw materials such as silicone acrylic emulsion, lithium metasilicate and polyvinyl alcohol After component is compounded by specific dosage relation, each raw material component can be made to realize that enhancing and complementation, preparation are provided in performance There are excellent weatherability, water resistance, heat resistance, resistance to acid and alkali, a resistant to pollution high adhesion paint binder, and other components add Add, hardness, adhesive force, fire resistance, weatherability, water resistance, resistance to acid and alkali, the heat-resisting quantity of film can not only be further increased Deng, additionally it is possible to assign the excellent antimildew and antibacterial performance of film and certain absorption property, water retention property and the effect for purifying air; Such as: the addition of glycidyl methacrylate, hydroxypropyl methyl cellulose can further increase the hardness, attached of film Put forth effort and against weather;Talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seawood meal, charcoal The addition of the fillers such as powder, zinc borate, Moringa tree root powder and flaccid knotweed herb powder, can not only further increase film hardness, Intensity, adhesive force, weatherability, water resistance, resistance to acid and alkali, heat-resisting quantity, frost resistance and fire resistance etc., and utilize talcum Powder, kaolinite, vermiculite, mica powder, jade powder, Peitou mountain flour, charcoal powder, Moringa tree root powder and flaccid knotweed herb powder are in coating Abundant fusion, additionally it is possible to greatly improve coating antimildew and antibacterial performance, using hydroxypropyl methyl cellulose, seawood meal and its The mutual cooperation of its raw material components, additionally it is possible to make coating that there is certain water-retaining property, utilize talcum powder, kaolinite, vermiculite, charcoal The mutual cooperation of powder and other raw material components, additionally it is possible to make coating that there is certain absorption property, utilize Peitou mountain flour, tangerine peel powder With the mutual cooperation of other raw material components, additionally it is possible to coating be made to have the effect of certain purification air.
Raw material sources of the present invention are abundant, inexpensive, and preparation process is easy to operate, can carry out the life of continuous high-efficient It produces, the product cost provided is low, and therefore, the technical program has broad application prospects.
Specific embodiment
The following are specific embodiments:
Embodiment one
The present embodiment provides a kind of tunnel multifunctional coatings, by weight, including the following raw material component: silicone acrylic emulsion 65 parts, 30 parts of lithium metasilicate, 10 parts of glycidyl methacrylate, 20 parts of polyvinyl alcohol, 30 parts of talcum powder, 30 parts of kaolinite, 20 parts of vermiculite, 20 parts of mica powder, 15 parts of pyrophillite, 10 parts of jade powder, 10 parts of Peitou mountain flour, 10 parts of seawood meal, 10 parts of charcoal powder, 15 parts of Moringa tree root powder, 15 parts of flaccid knotweed herb powder, 8 parts of zinc borate, 8 parts of tangerine peel powder, 5 parts of hydroxypropyl methyl cellulose, mineral 2 parts of oily defoaming agent, 1.5 parts of aluminate coupling agent, 60 parts of deionized water.
In the present embodiment, the Moringa tree root powder by Moringa tree root it is freeze-dried after, cryogenic ultramicro pulverization be made, grain Diameter is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm;
Specifically, freeze-drying temperature is -30 DEG C, cooling time 12h;Crushing temperature is -20 DEG C, and grinding time is 45min。
Preparation method provided in this embodiment for the tunnel multifunctional coating, includes the following steps:
A, after deionized water being heated to 38 DEG C, hydroxypropyl methyl cellulose and zinc borate is added, thereto with 1000rpm Revolving speed, stir 20min after, be added talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seaweed Powder, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed dispersion 30min, system Obtain mixed material;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicon is added thereto again Sour lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent stir 45min, i.e., with the revolving speed of 1000rpm Tunnel multifunctional coating can be made.Resulting coating is placed in container, is in uniform stiff fluid, no agglomeration after agitated.
Embodiment two
The present embodiment provides a kind of tunnel multifunctional coatings, by weight, including the following raw material component: silicone acrylic emulsion 70 parts, 35 parts of lithium metasilicate, 10 parts of glycidyl methacrylate, 22 parts of polyvinyl alcohol, 35 parts of talcum powder, 35 parts of kaolinite, 20 parts of vermiculite, 25 parts of mica powder, 20 parts of pyrophillite, 10 parts of jade powder, 12 parts of Peitou mountain flour, 10 parts of seawood meal, 12 parts of charcoal powder, 18 parts of Moringa tree root powder, 18 parts of flaccid knotweed herb powder, 10 parts of zinc borate, 8 parts of tangerine peel powder, 8 parts of hydroxypropyl methyl cellulose, mineral 3 parts of oily defoaming agent, 1.5 parts of aluminate coupling agent, 65 parts of deionized water.
In the present embodiment, the Moringa tree root powder by Moringa tree root it is freeze-dried after, cryogenic ultramicro pulverization be made, grain Diameter is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm;
Specifically, freeze-drying temperature is -25 DEG C, cooling time 16h;Crushing temperature is -15 DEG C, and grinding time is 60min。
Preparation method provided in this embodiment for the tunnel multifunctional coating, includes the following steps:
A, after deionized water being heated to 38 DEG C, hydroxypropyl methyl cellulose and zinc borate is added, thereto with 1000rpm Revolving speed, stir 20min after, be added talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seaweed Powder, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed dispersion 30min, system Obtain mixed material;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicon is added thereto again Sour lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent stir 45min, i.e., with the revolving speed of 1000rpm Tunnel multifunctional coating can be made.Resulting coating is placed in container, is in uniform stiff fluid, no agglomeration after agitated.
Embodiment three
The present embodiment provides a kind of tunnel multifunctional coatings, by weight, including the following raw material component: silicone acrylic emulsion 70 parts, 35 parts of lithium metasilicate, 12 parts of glycidyl methacrylate, 22 parts of polyvinyl alcohol, 35 parts of talcum powder, 35 parts of kaolinite, 25 parts of vermiculite, 25 parts of mica powder, 20 parts of pyrophillite, 15 parts of jade powder, 15 parts of Peitou mountain flour, 12 parts of seawood meal, 12 parts of charcoal powder, 20 parts of Moringa tree root powder, 20 parts of flaccid knotweed herb powder, 10 parts of zinc borate, 10 parts of tangerine peel powder, 10 parts of hydroxypropyl methyl cellulose, mine 4 parts of object oil defoaming agent, 2 parts of aluminate coupling agent, 65 parts of deionized water.
In the present embodiment, the Moringa tree root powder by Moringa tree root it is freeze-dried after, cryogenic ultramicro pulverization be made, grain Diameter is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm;
Specifically, freeze-drying temperature is -30 DEG C, cooling time 12h;Crushing temperature is -20 DEG C, and grinding time is 45min。
Preparation method provided in this embodiment for the tunnel multifunctional coating, includes the following steps:
A, after deionized water being heated to 35 DEG C, hydroxypropyl methyl cellulose and zinc borate is added, thereto with 1000rpm Revolving speed, stir 25min after, be added talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seaweed Powder, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed dispersion 45min, system Obtain mixed material;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicon is added thereto again Sour lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent stir 60min, i.e., with the revolving speed of 1000rpm Tunnel multifunctional coating can be made.Resulting coating is placed in container, is in uniform stiff fluid, no agglomeration after agitated.
Example IV
The present embodiment provides a kind of tunnel multifunctional coatings, by weight, including the following raw material component: silicone acrylic emulsion 65 parts, 35 parts of lithium metasilicate, 10 parts of glycidyl methacrylate, 22 parts of polyvinyl alcohol, 30 parts of talcum powder, 35 parts of kaolinite, 20 parts of vermiculite, 25 parts of mica powder, 15 parts of pyrophillite, 15 parts of jade powder, 10 parts of Peitou mountain flour, 12 parts of seawood meal, 10 parts of charcoal powder, 20 parts of Moringa tree root powder, 15 parts of flaccid knotweed herb powder, 10 parts of zinc borate, 8 parts of tangerine peel powder, 10 parts of hydroxypropyl methyl cellulose, mine 2 parts of object oil defoaming agent, 2 parts of aluminate coupling agent, 60 parts of deionized water.
In the present embodiment, the Moringa tree root powder by Moringa tree root it is freeze-dried after, cryogenic ultramicro pulverization be made, grain Diameter is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm;
Specifically, freeze-drying temperature is -30 DEG C, cooling time 12h;Crushing temperature is -20 DEG C, and grinding time is 45min。
Preparation method provided in this embodiment for the tunnel multifunctional coating, includes the following steps:
A, after deionized water being heated to 35 DEG C, hydroxypropyl methyl cellulose and zinc borate is added, thereto with 1000rpm Revolving speed, stir 25min after, be added talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seaweed Powder, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed dispersion 45min, system Obtain mixed material;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicon is added thereto again Sour lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent stir 60min, i.e., with the revolving speed of 1000rpm Tunnel multifunctional coating can be made.Resulting coating is placed in container, is in uniform stiff fluid, no agglomeration after agitated.
Embodiment five
The present embodiment provides a kind of tunnel multifunctional coatings, by weight, including the following raw material component: silicone acrylic emulsion 68 parts, 32 parts of lithium metasilicate, 11 parts of glycidyl methacrylate, 21 parts of polyvinyl alcohol, 32 parts of talcum powder, 32 parts of kaolinite, 23 parts of vermiculite, 23 parts of mica powder, 18 parts of pyrophillite, 12 parts of jade powder, 12 parts of Peitou mountain flour, 11 parts of seawood meal, 11 parts of charcoal powder, 18 parts of Moringa tree root powder, 18 parts of flaccid knotweed herb powder, 9 parts of zinc borate, 9 parts of tangerine peel powder, 7 parts of hydroxypropyl methyl cellulose, mineral 3 parts of oily defoaming agent, 1.5 parts of aluminate coupling agent, 63 parts of deionized water.
In the present embodiment, the Moringa tree root powder by Moringa tree root it is freeze-dried after, cryogenic ultramicro pulverization be made, grain Diameter is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm;
Specifically, freeze-drying temperature is -25 DEG C, cooling time 16h;Crushing temperature is -15 DEG C, and grinding time is 60min。
Preparation method provided in this embodiment for the tunnel multifunctional coating, includes the following steps:
A, after deionized water being heated to 38 DEG C, hydroxypropyl methyl cellulose and zinc borate is added, thereto with 1000rpm Revolving speed, stir 20min after, be added talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seaweed Powder, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed dispersion 30min, system Obtain mixed material;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicon is added thereto again Sour lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent stir 45min, i.e., with the revolving speed of 1000rpm Tunnel multifunctional coating can be made.Resulting coating is placed in container, is in uniform stiff fluid, no agglomeration after agitated.
Embodiment six
The present embodiment provides a kind of tunnel multifunctional coatings, by weight, including the following raw material component: silicone acrylic emulsion 70 parts, 30 parts of lithium metasilicate, 12 parts of glycidyl methacrylate, 20 parts of polyvinyl alcohol, 35 parts of talcum powder, 30 parts of kaolinite, 25 parts of vermiculite, 20 parts of mica powder, 20 parts of pyrophillite, 10 parts of jade powder, 15 parts of Peitou mountain flour, 10 parts of seawood meal, 12 parts of charcoal powder, 15 parts of Moringa tree root powder, 20 parts of flaccid knotweed herb powder, 8 parts of zinc borate, 10 parts of tangerine peel powder, 5 parts of hydroxypropyl methyl cellulose, mineral 4 parts of oily defoaming agent, 1.5 parts of aluminate coupling agent, 65 parts of deionized water.
In the present embodiment, the Moringa tree root powder by Moringa tree root it is freeze-dried after, cryogenic ultramicro pulverization be made, grain Diameter is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm;
Specifically, freeze-drying temperature is -30 DEG C, cooling time 12h;Crushing temperature is -20 DEG C, and grinding time is 45min。
Preparation method provided in this embodiment for the tunnel multifunctional coating, includes the following steps:
A, after deionized water being heated to 35 DEG C, hydroxypropyl methyl cellulose and zinc borate is added, thereto with 1000rpm Revolving speed, stir 25min after, be added talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, seaweed Powder, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed dispersion 45min, system Obtain mixed material;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicon is added thereto again Sour lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent stir 60min, i.e., with the revolving speed of 1000rpm Tunnel multifunctional coating can be made.Resulting coating is placed in container, is in uniform stiff fluid, no agglomeration after agitated.
Coating made from one~embodiment of embodiment six is tested for the property using existing standard, as a result such as following table institute Show:
As seen from the above table, coating made from above-described embodiment has excellent fire protecting performance, adhesion property, resistance to acid and alkali Energy, weatherability, waterproof performance and antimildew and antibacterial performance are highly suitable for using in tunnel environment.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this In the scope of the claims of invention.

Claims (4)

1. a kind of tunnel multifunctional coating, it is characterised in that: by weight, including the following raw material component: silicone acrylic emulsion 65 ~70 parts, 30~35 parts of lithium metasilicate, 10~12 parts of glycidyl methacrylate, 20~22 parts of polyvinyl alcohol, talcum powder 30 ~35 parts, 30~35 parts of kaolinite, 20~25 parts of vermiculite, 20~25 parts of mica powder, 15~20 parts of pyrophillite, jade powder 10~15 Part, 10~15 parts of Peitou mountain flour, 10~12 parts of seawood meal, 10~12 parts of charcoal powder, 15~20 parts of Moringa tree root powder, flaccid knotweed herb 15~20 parts of powder, 8~10 parts of zinc borate, 8~10 parts of tangerine peel powder, 5~10 parts of hydroxypropyl methyl cellulose, mineral oil antifoam agent 2~4 parts, 1.5~2 parts of aluminate coupling agent, 60~65 parts of deionized water.
2. tunnel multifunctional coating according to claim 1, it is characterised in that: by weight, including the following raw material Component: 68 parts of silicone acrylic emulsion, 32 parts of lithium metasilicate, 11 parts of glycidyl methacrylate, 21 parts of polyvinyl alcohol, talcum powder 32 Part, 32 parts of kaolinite, 23 parts of vermiculite, 23 parts of mica powder, 18 parts of pyrophillite, 12 parts of jade powder, 12 parts of Peitou mountain flour, seawood meal 11 Part, 11 parts of charcoal powder, 18 parts of Moringa tree root powder, 18 parts of flaccid knotweed herb powder, 9 parts of zinc borate, 9 parts of tangerine peel powder, hydroxypropyl methyl 7 parts of cellulose, 3 parts of mineral oil antifoam agent, 1.5 parts of aluminate coupling agent, 63 parts of deionized water.
3. tunnel multifunctional coating according to claim 1, it is characterised in that: the Moringa tree root powder is by Moringa tree After root is freeze-dried, cryogenic ultramicro pulverization is made, and partial size is 0.5~1 μm;
The flaccid knotweed herb powder by polygonum flaccidum blade of grass it is freeze-dried after, cryogenic ultramicro pulverization be made, partial size be 0.5~1 μm.
4. a kind of preparation method for tunnel multifunctional coating described in claim 1, it is characterised in that: including walking as follows It is rapid:
A, after deionized water being heated to 35~38 DEG C, hydroxypropyl methyl cellulose and zinc borate is added, thereto with 1000rpm Revolving speed, stir 20~25min after, be added talcum powder, kaolinite, vermiculite, mica powder, pyrophillite, jade powder, Peitou mountain flour, Seawood meal, charcoal powder, Moringa tree root powder, flaccid knotweed herb powder and tangerine peel powder, then with the revolving speed of 1500rpm, high speed dispersion 30~ Mixed material is made in 45min;
B, mixed material is ground to fineness to 40 μm hereinafter, aluminate coupling agent, silicone acrylic emulsion, silicic acid is added thereto again Lithium, glycidyl methacrylate, polyvinyl alcohol and mineral oil antifoam agent stir 45~60min with the revolving speed of 1000rpm, It can be prepared by tunnel multifunctional coating.
CN201811096045.8A 2018-09-19 2018-09-19 Tunnel multifunctional coating Pending CN109385124A (en)

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