CN109371372A - A kind of balancing fields Sputting film-plating apparatus - Google Patents

A kind of balancing fields Sputting film-plating apparatus Download PDF

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Publication number
CN109371372A
CN109371372A CN201811576906.2A CN201811576906A CN109371372A CN 109371372 A CN109371372 A CN 109371372A CN 201811576906 A CN201811576906 A CN 201811576906A CN 109371372 A CN109371372 A CN 109371372A
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CN
China
Prior art keywords
pole
magnetic
magnet steel
magnetic pole
target
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CN201811576906.2A
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Chinese (zh)
Inventor
申屠江民
祝宇
龚阳
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Zhejiang Lai Bao Technology Co Ltd
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Zhejiang Lai Bao Technology Co Ltd
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Priority to CN201811576906.2A priority Critical patent/CN109371372A/en
Publication of CN109371372A publication Critical patent/CN109371372A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering

Abstract

The present invention provides a kind of Sputting film-plating apparatus based on balancing fields, including horizontally disposed cathode targets, the cathode targets are rectangle tabular structure, are equipped with substrate above cathode targets in the range of 50-100mm, it is provided with magnet steel below cathode targets, the magnet steel includes magnet steel seat and magnetic pole.By the effect between the magnetic pole of magnet steel, arch magnetic field is formed in cathode targets upper surface.Magnetic inductive block is provided with below the magnetic pole, the magnetic inductive block can make magnetic field coupling on target surface, improve the utilization rate of plating membrane efficiency and target.

Description

A kind of balancing fields Sputting film-plating apparatus
Technical field
The invention belongs to magnetic field control field more particularly to magnetron sputtering plating fields, and in particular to one kind is based on balance The Sputting film-plating apparatus in magnetic field.
Background technique
Current common Sputting film-plating apparatus, as shown in Figure 1, include the cathode targets 2 being horizontally set on pedestal, it is described Cathode targets 2 are rectangle tabular structure, and substrate 3 is equipped with above cathode targets 2, is laid with magnet steel 1, institute below cathode targets 2 It states magnet steel 1 and forms arch or round magnetic field on cathode targets 2.
The working principle of magnetron sputtering refer to electronics under the action of electric field, accelerate fly to substrate during and ar atmo It collides, ionization generates a large amount of Ar ion and new electronics, new electronics keep and Ar atomic collision, generates more Ar ion and electronics.Ar ion accelerates to fly to cathode target under electric field action, and with high-energy bombarding cathode target surface, sputters A large amount of target atom, the target atom or molecule deposition being in neutrality form film on substrate.Ar ion after ionizing is in electricity Under the reciprocation in field and magnetic field, accelerate bombardment target material surface, after energy exchange, the atom of target material surface is detached from original lattice and escapes Out, it is transferred to matrix surface and forms a film.
Magnetron sputtering is the motion path that electronics is fettered and extended with magnetic field, changes the direction of motion of electronics, improves work The ionization rate of gas and the energy of effective use electronics.Secondary electron is during accelerating to fly to substrate by magnetic field Lorentz The influence of power is largely bound in the heating region of target surface, and plasma density is very high in the region, mostly Secondary electron is circled around target surface under the influence of a magnetic field, and the motion path of the electronics is very long.Other parts can be flown to The regions such as substrate, vacuum chamber interior walls and target power supply anode.In spatter film forming, part electronics is flown to rapidly under electric field force effect Substrate surface, will cause electron movement path it is short, bombardment on substrate speed it is fast, cause substrate temperature to increase, to a certain degree On will affect quality of forming film, cause film layer potentially some defects.
Magnetron sputtering includes many types, working principle of having nothing in common with each other and application.According to the field bit of magnetron cathode The difference of shape distribution, is broadly divided into equilibrium state and non-balance magnetically controlled sputter.It is to utilize magnetic field and electricity regardless of balance/unbalance Field reciprocation, makes electronics spiral operation near target surface, to increase the probability that electronic impact argon gas generates ion. Generated ion hits target surface under electric field action to sputter target.
The magnetic flux of the cathode internal-external magnetic steel of equilibrium state magnetron sputtering is roughly equal, and the two poles of the earth magnetic line of force is closed on target, Well by electronics/plasma confinement near target, increases collision probability, improve efficiency of ionization, thus lower Build-up of luminance and glow discharge can be maintained under operating air pressure and voltage, target utilization is relatively high.
But unbalanced magnetron sputtering also has shortcoming, such as: the electronics generated due to magnetic fields, glow discharge and sputtering Secondary electron out is tightly constrained near target surface by parallel magnetic field, and plasma slab is consumingly strapped in target surface about The region of 60mm, with the increase for leaving target surface distance, plasma concentration is reduced rapidly, at this moment can only be work piece in magnetic control In the range of the 50-100mm of target surface, to enhance the effect of ion bombardment.Effective plated film area short in this way limits workpiece to be plated Geometric dimension, be unsuitable for biggish workpiece or batch, constrain the application of magnetron sputtering technique.And it is sputtered in unbalanced magnetron When, the target particle energy to fly out is lower, and in the application of big workpiece, bombardment efficiency is insufficient instead.
Non-balance magnetically controlled sputter is that magnetron cathode outer magnetic pole magnetic flux is allowed to be greater than internal magnetic pole, and the two poles of the earth magnetic line of force is incomplete in target surface Closure, the part magnetic line of force can extend to substrate region along the edge of target, so that part electronics can expand to base along the magnetic line of force Piece increases the plasma density and gas ionization rate of substrate region.
Since non-balance magnetically controlled sputter can increase the plasma density and gas ionization degree of substrate region, generally in base The target particle energy that piece near zone flies out is higher, can enhance the effect of ion bombardment, and film substrate bond strength is also preferable, also more Suitable for biggish film-coating workpiece, therefore, currently unbalanced magnetic field mode is mostly used to carry out magnetron sputtering greatly.However, Nonequilibrium magnetic Magnetron sputtering under field type equally has the problem that
1, to electron confinement deficiency in sputtering process, run duration is short in the plasma for electronics, and electronics participates in gas point The process of son collision and ionization is short, and the ion ionized out is few, and the ionization level of gas is low, the efficiency and deposition rate integrally sputtered Difference.
2, unbalanced magnetic field causes film layer and substrate of the high energy electron bombardment in film forming procedure, causes fine lack that form a film It falls into, influences film quality.
3, the sputtering of target material surface is scanned there are some weakness zones, target utilization is not high.
For the above problem existing for the magnetron sputtering under the conditions of balancing fields and unbalanced magnetic field, it is particularly applied to low In the plated film film formation process of resistance, high-quality ITO or metal targets, under the conditions of unbalanced magnetic field, high energy electron causes film Layer damage, forms size 10-50 microns of interrupted strip, seriously affects product quality.Therefore, it is necessary to develop a kind of at film quality Amount is good, effectively promotes plating piece quality, the high magnetic control sputtering device of target utilization and method.
Summary of the invention
In order to solve unbalanced magnetic field bring substrate damage, the problems such as sputtering yield is poor, target utilization is low, change simultaneously The problems such as kind balancing fields limit the geometric dimension of workpiece to be plated, and the target particle energy to fly out is lower.
The present invention proposes a kind of Sputting film-plating apparatus of balancing fields, including horizontally disposed cathode targets, the cathode Target is rectangle tabular structure, is equipped with substrate above cathode targets in the range of 50-100mm, is provided with below cathode targets Magnet steel, the magnet steel include magnet steel seat and magnetic pole.By the effect between the magnetic pole of magnet steel, arch is formed in cathode targets upper surface Magnetic field.Magnetic inductive block is provided with below the magnetic pole, the magnetic inductive block can make magnetic field coupling on target surface, and raising plated film is imitated The utilization rate of rate and target.
The magnetic field is the balancing fields of standard, and the magnetic line of force between magnetic pole is closed near target, at the both ends of magnet steel It is set as the magnetic pole of two pole N, in the magnetic pole that the middle Position Design of magnet steel is the pole S, i.e., the described pole S to the two of both ends A pole N is equidistant, the magnetic inductive block be set to the underface of the pole S magnetic pole and the pole the N magnetic pole at magnet steel both ends just under Side can make magnetic field be coupled in right above target surface completely, and not extra magnetic field rests on the outside at target surface both ends, improve plating Membrane efficiency.
Balancing fields provided by the invention, make the two poles of the earth magnetic line of force be closed to target surface, do not form redundant space diffusion, it is ensured that electricity Son/plasma constrains near target surface as far as possible, build-up of luminance and aura can be maintained to put under lower operating air pressure and voltage Electricity, it is ensured that plating membrane efficiency.Meanwhile it being compared to unbalanced magnetic field, electric and magnetic fields ensure electricity to the constraint ability of electronics It is sub to be effectively strapped in the region of target surface, essentially eliminate bombardment of the electronics to substrate, target caused by electronics high energy bombards The micro- interrupted shape of material film layer is bad, effectively improves micro- interrupted shape defect in low resistance high-quality target film forming procedure, will improve Preceding about 4% is bad at high proportion, and it is bad to be reduced to about 0.08% minimum ratio, has for the quality of forming film of the target of high-quality It significantly improves, effectively promotion product quality.Magnetic field structure it is perfect so that the increase of the effective sputtering surface of target material surface, simultaneously It is provided with magnetic inductive block below magnetic pole, magnetic field strength is improved by magnetic inductive block, so that the magnetic field strength of balancing fields of the invention It can satisfy the energy requirement of ionization electron bombardment target as sputter film forming.
Detailed description of the invention
Fig. 1 is existing magnetic control sputtering device schematic diagram;
Fig. 2 is the first schematic diagram of magnetic control sputtering device of the invention;
Fig. 3 is the second schematic diagram of magnetic control sputtering device of the invention
Fig. 4 is that target surface static state of the invention etches schematic diagram;
Fig. 5 is that target surface dynamic of the present invention with either-rotation motor etches schematic diagram;
Fig. 6 is the planar structure schematic diagram of magnet steel of the invention.
Appended drawing reference
1- magnet steel, 2- target, 3- substrate, 4- magnetic inductive block.
Specific embodiment
For a better understanding of the present invention, below in conjunction with attached drawing with examples illustrate the present invention, specific embodiment party Formula is as follows.
The present invention proposes a kind of Sputting film-plating apparatus of balancing fields, including horizontally disposed cathode targets 2, the cathode Target 2 is rectangle tabular structure, and substrate 3 is equipped in the range of 2 top 50-100mm of cathode targets, is set below cathode targets 2 It is equipped with magnet steel 1, the magnet steel 1 includes magnet steel seat and magnetic pole.By the effect between the magnetic pole of magnet steel, the magnet steel 1 is in cathode target 2 upper surface of material forms arch magnetic field.Magnetic inductive block 4 is provided with below the magnetic pole, the magnetic inductive block can make magnetic field coupling In on target surface, the utilization rate of plating membrane efficiency and target is improved.
In a particular embodiment, as shown in Fig. 2, the magnetic field is the balancing fields of standard, the magnetic line of force between magnetic pole is closed Near target 2, it is set as the magnetic pole of two pole N at the both ends of magnet steel 1, is a S in the middle Position Design of magnet steel 1 The magnetic pole of pole, i.e., two poles N of the described pole S to both ends are equidistant, and the magnetic inductive block 4 is being set to the pole S magnetic pole just The underface of the pole the N magnetic pole at 1 both ends of lower section and magnet steel, under the conditions of such balancing fields, magnetic field is coupled in completely on entire target surface, The not extra magnetic field waste in the outside at target surface both ends.
In the preferred scheme, the width L of the magnet steel 1 is 150mm, and the wide span of the target is 200mm, described The width L1 of projection of the pole the N magnetic pole on target surface is 10mm, and the width L2 of projection of the pole the S magnetic pole on target surface is 20mm, The pole N magnetic pole and the pole S magnetic pole height be 30mm, the magnetic inductive block 4 be 12mm thickness iron block, and target surface top parallel magnetic field Intensity be 480-550 Gauss.Under the conditions of such balancing fields, magnetic field is coupled in completely on entire target surface, has both ensured target surface The covering of the top magnetic field all position Jun You, while the also not extra magnetic field waste of the outside at target surface both ends, therefore, target utilizes Rate and plating membrane efficiency are higher, and target utilization promotes about 3-5%,.
In preferred technical solution, as shown in Figure 3,4, the magnetic field is the balancing fields of standard, and the magnetic field uses Double course structure is set as the magnetic pole of two pole N at the both ends of magnet steel 1, is in addition designed as one in the middle position of magnet steel 1 The magnetic pole of the pole N, i.e., two poles N of the pole N in the described middle position to both ends are equidistant, at the middle position and both ends In addition the middle of the pole N of position sets two pole S electrodes, i.e., the described pole the S electrode and the two neighbouring pole N electrode distance phases again Deng.Magnetic inductive block 4 is equipped with below the magnet steel 1, the magnetic inductive block 4 is set to 1 both ends of underface and magnet steel of the pole S magnetic pole The underface of the pole N magnetic pole.
In the preferred scheme, the width L of the magnet steel 1 is 150mm, and the wide span of the target is 200mm, described The width L1 of projection of the pole the N magnetic pole at both ends on target surface is 10mm, and the pole N in the pole S magnetic pole and middle position is on target surface The width L2 of projection be 20mm, the pole N magnetic pole and the pole S magnetic pole height are 30mm, magnetic inductive block is equipped with below the magnet steel, The magnetic inductive block 4 is the iron block of 12mm thickness, and the intensity of parallel magnetic field is 480-550 Gauss above target surface.In the present solution, Tetra- positions A1, A2, B1, B2 form etching operation runways on target surface, the distance between each two etching grooves of runway La12 and Lb12 is 44mm, and the distance between two etching grooves in inside of two runways Lab2 is 40mm, and magnetic field component width is 150mm, The design of double course structure, increases target surface etching area, 2 utilization rate of target can be improved.
In preferred technical solution, the magnetic field uses double course structure, meanwhile, it is two-way below magnet steel 1 to be connected with one Motor, the either-rotation motor moving distance is +/- 18mm, as shown in figure 5, i.e. entire 1 width of magnet steel is covering for the magnetic field of 150mm Lid range is 186mm, on target surface four etching runways from linear etching become face type etching, the etching groove of each runway across Spending Le is 36mm, and the distance between each two etching grooves of runway La12 ' and Lb12 ' is 8mm, the inside of two runways two The distance between etching groove Lab2 ' is 4mm, and target surface parallel magnetic field strength is the standard equilibration magnetic field of 480-550 Gauss.
It is that an either-rotation motor can also be connected with below magnet steel 1 in embodiment in single track elements, the either-rotation motor moves Dynamic distance is +/- 18mm.
As shown in fig. 6, design can also be optimized to the magnetic field at 1 both ends of magnet steel in other technical solutions, lead to The magnetic pole length for slightly shortening the pole S of magnet steel 1 is crossed, weakening segmentation is carried out to magnetic pole, to reduce the most fast etch areas in magnetic circuit end Etching speed so that the etching speed of entire target surface all areas reaches unanimously, the utilization rate of raising target 2.For example, described Magnetic field is still balancing fields, and the long span L l1 of the magnet steel 1 is 1114mm, and the span L l2 that the pole the N magnetic pole at the both ends is long is set It is set to 1091mm, the span L l3 for the magnetic pole length for reducing the pole N of the pole S and/or centre is 1044mm.
It is preferred embodiment the above are the mobile balancing fields Sputting film-plating apparatus that mentions of the present invention, can not be interpreted as pair The limitation of rights protection scope of the present invention, those skilled in the art will be appreciated that, without departing from the inventive concept of the premise, go back A variety of improvement or replacement can be done, all improvement or replacement all should be in the scope of the present invention, i.e., power of the invention Sharp protection scope should be subject to the claims.In the absence of conflict, the feature in embodiment and embodiment herein-above set forth It can be combined with each other.

Claims (9)

1. a kind of balancing fields Sputting film-plating apparatus, comprising: horizontally disposed cathode targets (2), magnet steel (1) and substrate (3), institute Stating cathode targets (2) is rectangle tabular structure, and the substrate (3) is located above cathode targets (2) in the range of 50-100mm, It is provided with magnet steel (1) below cathode targets (2), the magnet steel (1) includes magnet steel seat and magnetic pole, and the magnet steel (1) is in cathode target Material (2) upper surface forms arch magnetic field;
It is characterized in that, being provided with magnetic inductive block (4) below the magnetic pole.
2. balancing fields Sputting film-plating apparatus according to claim 1, which is characterized in that the both ends of magnet steel (1) are provided with The magnetic pole of two pole N is equipped with the magnetic pole of the pole S in the middle position of magnet steel (1), and the magnetic inductive block (4) is set to the S The underface of the pole the N magnetic pole of the underface of pole magnetic pole and magnet steel (1) both ends.
3. balancing fields Sputting film-plating apparatus according to claim 2, which is characterized in that the width of the magnet steel (1) is 150mm, the wide span of the target are 200mm, and the width of projection of the pole the N magnetic pole on target surface is 10mm, the pole S The width of projection of the magnetic pole on target surface is 20mm, and the pole N magnetic pole and the pole S magnetic pole height are 30mm, the magnetic inductive block (4) For the iron block of 12mm thickness, and the intensity of parallel magnetic field is 480-550 Gauss above target surface.
4. balancing fields Sputting film-plating apparatus according to claim 3, which is characterized in that the long span of the magnet steel (1) For 1114mm, the long span of the pole the N magnetic pole at the both ends is set as 1091mm, and the long span of the magnetic pole of the reduction pole S is 1044mm.
5. balancing fields Sputting film-plating apparatus according to claim 3, which is characterized in that be connected with below the magnet steel (1) One either-rotation motor, the either-rotation motor moving distance are +/- 18mm.
6. balancing fields Sputting film-plating apparatus according to claim 1, which is characterized in that the magnetic field uses double course knot Structure, is set as the magnetic pole of two pole N at the both ends of magnet steel (1), is in addition designed as the pole N in the middle position of magnet steel (1) Magnetic pole, in addition set two pole S electrodes, the magnetic inductive block again in the middle of the middle position and the pole N of end positions (4) underface of the pole S magnetic pole and the underface of magnet steel (1) edge position are set to.
7. balancing fields Sputting film-plating apparatus according to claim 6, which is characterized in that the width of the magnet steel (1) is 150mm, the wide span of the target are 200mm, and the width of projection of the pole the N magnetic pole at the both ends on target surface is 10mm, The width of projection of the pole N in the pole S magnetic pole and middle position on target surface is 20mm, the pole N magnetic pole and the pole S magnetic pole height It is 30mm, is equipped with magnetic inductive block below the magnet steel, the magnetic inductive block (4) is the iron block of 12mm thickness, and the parallel magnetic in target surface top The intensity of field is 480-550 Gauss.
8. balancing fields Sputting film-plating apparatus according to claim 7, which is characterized in that be connected with below the magnet steel (1) One either-rotation motor, the either-rotation motor moving distance are +/- 18mm.
9. balancing fields Sputting film-plating apparatus according to claim 7, which is characterized in that the long span of the magnet steel (1) For 1114mm, the long span of the pole the N magnetic pole at the both ends is set as 1091mm, the span of the reduction pole S and the intermediate pole N magnetic pole length For 1044mm.
CN201811576906.2A 2018-12-23 2018-12-23 A kind of balancing fields Sputting film-plating apparatus Pending CN109371372A (en)

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CN201811576906.2A CN109371372A (en) 2018-12-23 2018-12-23 A kind of balancing fields Sputting film-plating apparatus

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Application Number Priority Date Filing Date Title
CN201811576906.2A CN109371372A (en) 2018-12-23 2018-12-23 A kind of balancing fields Sputting film-plating apparatus

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109735821A (en) * 2019-03-19 2019-05-10 杭州朗为科技有限公司 A kind of cathode of high field intensity high target utilization ratio

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109735821A (en) * 2019-03-19 2019-05-10 杭州朗为科技有限公司 A kind of cathode of high field intensity high target utilization ratio

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