CN109370734A - A kind of general oil emulsion - Google Patents
A kind of general oil emulsion Download PDFInfo
- Publication number
- CN109370734A CN109370734A CN201811445516.1A CN201811445516A CN109370734A CN 109370734 A CN109370734 A CN 109370734A CN 201811445516 A CN201811445516 A CN 201811445516A CN 109370734 A CN109370734 A CN 109370734A
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- China
- Prior art keywords
- oil emulsion
- oil
- general oil
- general
- emulsion according
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/52—Base number [TBN]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
Abstract
The present invention discloses a kind of general oil emulsion, belongs to oil emulsion technical field, is grouped as by mass percentage by following groups: base oil 65-80%, antiwear additive is 2-6%, emulsifier 12-22%, antirust agent 0.5-4.5%, fungicide is 0.2-1.0%, preservative 0.5-4.2%.The general oil emulsion of invention can be used for the intermetallic composite coating of aluminium alloy, steel, glass material, copper or iron, and abrasion-resistance is far more than oil product, the cutting liquid product better than existing 95%, and place not smelly in 15 days；Working solution is nontoxic, is conducive to environment, to be environmentally friendly, to environment and human body without any harm.
Description
Technical field
The present invention relates to oil emulsion technical field, in particular to a kind of general oil emulsion.
Background technique
Oil emulsion (Emulsified oil) is the oil or fat particles that there is (non-rising, not agglomerate) with stable state, partial size
About between 0.5~25 μm, to be filbert to dark brown liquid or semisolid, belong to one kind of metal-cutting oil.Effect is with cold
But it based on, lubricates to be secondary, for vehicle system, sawed-off, the metals roughing such as drill, grind.General missible oil of the invention is mainly used for
In the processing such as component of machine Precision Machining, vehicle, mill, suitable for the cutting process of various metal materials.
Existing oil emulsion is primarily present following problems:
1. existing emulsion standing time is easily smelly and low in cost long；
2. the existing emulsion alkalinity retentivity time is short, and mobility is bad；
3. existing emulsion contains nitrite, unfavorable to human body and environment.
Summary of the invention
In view of the above technical problems, the present invention provides a kind of general oil emulsions, solve existing oil emulsion easily smelly and alkali
Property retentivity time short problem.
In order to solve the above technical problems, the technical solution of the present invention is as follows:
The present invention provides a kind of general oil emulsion, is grouped as by mass percentage by following groups: base oil 65-
80%, antiwear additive 2-6%, emulsifier 12-22%, antirust agent 0.5-4.5%, fungicide 0.2-1.0%, preservative
For 0.5-4.2%.
Wherein it is preferred to any one in oil 60N, 7# white oil based on the base oil, 10# white oil, 32# base oil
Kind is several.
Wherein it is preferred to which the antiwear additive is chlorinated paraffin, olefine sulfide, phosphite ester and its derivative, phosphorus sulfuric acid is multiple
Any one or a few in ester and its derivative, thiophosphate and its derivative, borate.
Wherein it is preferred to which the emulsifier is petroleum sodium sulfonate, alkyl phenol polyoxyethylene ether, polyoxyethylene sorbitol rouge
Any one in fat acid esters or two kinds.
Wherein it is preferred to which the antirust agent is petroleum sulfonate, carboxylate, borate, zinc naphthenate, laurylene base fourth
Any one or a few in diacid.
Wherein it is preferred to which the fungicide is imidazolidine, glutaraldehyde, trihydroxy methyl-nitromethane or dibromo salicyloyl
Amine.
Wherein it is preferred to which the preservative is double octyl zinc dithiophosphates and/or fourth octyl zinc dithiophosphate.
Beneficial effects of the present invention:
General oil emulsion of the invention can be used for the intermetallic composite coating of aluminium alloy, steel, glass material, copper or iron, abrasion-resistance
It far is more than oil product, the cutting liquid product better than existing 95%, and place not smelly in 15 days；Working solution is nontoxic, is conducive to
Environment, to be environmentally friendly, to environment and human body without any harm.
Specific embodiment
Below in conjunction with the specific embodiment of the invention, technical solution of the present invention is clearly and completely described, is shown
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
In following embodiments, general oil emulsion is made of following preparation methods: room temperature stirs after Mixer pot is added in base oil
It mixes, antiwear additive then is added, emulsifier is, antirust agent, fungicide and preservative, control temperature mix 30- at 30-40 DEG C
40min, filtering removal impurity.
Embodiment 1
The present embodiment provides the present invention to provide a kind of general oil emulsion, is grouped as by mass percentage by following groups: base
Plinth oil 60N is 72%, chlorinated paraffin 4%, petroleum sodium sulfonate 18%, petroleum sulfonate 3.0%, and bromine salicylamide is
0.6%, double octyl zinc dithiophosphates are 2.4%.
The general oil emulsion of the present embodiment is tested for the property, as a result as follows:
| Detection project | Testing result | Detection method |
| Iron filings antirust tests (36 DEG C, 48h) | 1 grade | ASTM D4627 |
| PH value | 8.5 | SH/T0069 |
| Appearance | Milky white liquid | Range estimation |
| Maximum nonseizure load PB value/N | 280 | GB/T3142 |
| Constant temperature corrodes (55 DEG C, 8h) copper | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 8h) aluminium | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 48h) 45# steel | A grades | SH/T0088 |
Above-mentioned experimental data shows that the general oil emulsion of the present embodiment has excellent abrasion-resistance and resistance to corrosion.
Embodiment 2
The present embodiment provides the present invention to provide a kind of general oil emulsion, is grouped as by mass percentage by following groups: 7#
White oil is 73.1%, olefine sulfide 6%, alkyl phenol polyoxyethylene ether 12%, borate 4.5%, trihydroxy methyl-nitro
Methane is 0.2%, and double octyl zinc dithiophosphates are 4.2%.
The general oil emulsion of the present embodiment is tested for the property, as a result as follows:
| Detection project | Testing result | Detection method |
| Iron filings antirust tests (36 DEG C, 48h) | 1 grade | ASTM D4627 |
| PH value | 8.6 | SH/T0069 |
| Appearance | Milky white liquid | Range estimation |
| Maximum nonseizure load PB value/N | 285 | GB/T3142 |
| Constant temperature corrodes (55 DEG C, 8h) copper | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 8h) aluminium | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 48h) 45# steel | A grades | SH/T0088 |
Above-mentioned experimental data shows that the general oil emulsion of the present embodiment has excellent abrasion-resistance and resistance to corrosion.
Embodiment 3
The present embodiment provides the present invention to provide a kind of general oil emulsion, is grouped as by mass percentage by following groups: 0#
White oil is 74%, phosphite ester 2%, alkyl phenol polyoxyethylene ether 22%, dodecenylsuccinic acid 0.5%, three hydroxyl first
Base-nitromethane is 1.0%, and fourth octyl zinc dithiophosphate is 1.5%.
The general oil emulsion of the present embodiment is tested for the property, as a result as follows:
| Detection project | Testing result | Detection method |
| Iron filings antirust tests (36 DEG C, 48h) | 1 grade | ASTM D4627 |
| PH value | 8.4 | SH/T0069 |
| Appearance | Milky white liquid | Range estimation |
| Maximum nonseizure load PB value/N | 290 | GB/T3142 |
| Constant temperature corrodes (55 DEG C, 8h) copper | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 8h) aluminium | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 48h) 45# steel | A grades | SH/T0088 |
Above-mentioned experimental data shows that the general oil emulsion of the present embodiment has excellent abrasion-resistance and resistance to corrosion.
Embodiment 4
The present embodiment provides the present invention to provide a kind of general oil emulsion, is grouped as by mass percentage by following groups: 32#
Base oil is 70%, and it is 5% that phosphorus sulfuric acid, which answers ester, Polyoxyethylene Sorbitol Fatty Acid Esters 17.6%, zinc naphthenate 3.5%,
Glutaraldehyde is 0.7%, and fourth octyl zinc dithiophosphate is 3.2%.
The general oil emulsion of the present embodiment is tested for the property, as a result as follows:
| Detection project | Testing result | Detection method |
| Iron filings antirust tests (36 DEG C, 48h) | 1 grade | ASTM D4627 |
| PH value | 8.2 | SH/T0069 |
| Appearance | Milky white liquid | Range estimation |
| Maximum nonseizure load PB value/N | 275 | GB/T3142 |
| Constant temperature corrodes (55 DEG C, 8h) copper | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 8h) aluminium | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 48h) 45# steel | A grades | SH/T0088 |
Above-mentioned experimental data shows that the general oil emulsion of the present embodiment has excellent abrasion-resistance and resistance to corrosion.
Embodiment 5
The present embodiment provides the present invention to provide a kind of general oil emulsion, is grouped as by mass percentage by following groups: 7#
White oil 45%, 10# white oil 35%, thiophosphate 3%, petroleum sodium sulfonate 10%, alkyl phenol polyoxyethylene ether 4%, carboxylic
Hydrochlorate antirust agent is 1%, glutaraldehyde 0.5%, double octyl zinc dithiophosphates 1.0%, and fourth octyl zinc dithiophosphate is
0.5%.
The general oil emulsion of the present embodiment is tested for the property, as a result as follows:
| Detection project | Testing result | Detection method |
| Iron filings antirust tests (36 DEG C, 48h) | 1 grade | ASTM D4627 |
| PH value | 8.4 | SH/T0069 |
| Appearance | Milky white liquid | Range estimation |
| Maximum nonseizure load PB value/N | 275 | GB/T3142 |
| Constant temperature corrodes (55 DEG C, 8h) copper | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 8h) aluminium | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 48h) 45# steel | A grades | SH/T0088 |
Above-mentioned experimental data shows that the general oil emulsion of the present embodiment has excellent abrasion-resistance and resistance to corrosion.
Embodiment 6
The present embodiment provides the present invention to provide a kind of general oil emulsion, is grouped as by mass percentage by following groups: base
Plinth oil 60N 50%, 7# white oil 25%, borate 5%, petroleum sodium sulfonate 15%, borate 2%, zinc naphthenate antirust agent
It is 1%, imidazolidine 0.3%, double octyl zinc dithiophosphates are 0.7%, and fourth octyl zinc dithiophosphate is 1.0%.
The general oil emulsion of the present embodiment is tested for the property, as a result as follows:
| Detection project | Testing result | Detection method |
| Iron filings antirust tests (36 DEG C, 48h) | 1 grade | ASTM D4627 |
| PH value | 8.2 | SH/T0069 |
| Appearance | Milky white liquid | Range estimation |
| Maximum nonseizure load PB value/N | 285 | GB/T3142 |
| Constant temperature corrodes (55 DEG C, 8h) copper | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 8h) aluminium | A grades | SH/T0088 |
| Constant temperature corrodes (55 DEG C, 48h) 45# steel | A grades | SH/T0088 |
Above-mentioned experimental data shows that the general oil emulsion of the present embodiment has excellent abrasion-resistance and resistance to corrosion.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of general oil emulsion, it is characterised in that be grouped as by mass percentage by following groups: base oil 65-80%,
Antiwear additive is 2-6%, emulsifier 12-22%, antirust agent 0.5-4.5%, fungicide 0.2-1.0%, and preservative is
0.5-4.2%.
2. a kind of general oil emulsion according to claim 1, it is characterised in that: oil 60N, 7# are white based on the base oil
Any one or a few in oil, 10# white oil, 32# base oil.
3. a kind of general oil emulsion according to claim 1, it is characterised in that: the antiwear additive is chlorinated paraffin, vulcanization
Alkene, phosphite ester and its derivative, phosphorus sulfuric acid are answered in ester and its derivative, thiophosphate and its derivative, borate
Any one or a few.
4. a kind of general oil emulsion according to claim 1, it is characterised in that: the emulsifier is petroleum sodium sulfonate, alkane
Any one in base phenol polyethenoxy ether, Polyoxyethylene Sorbitol Fatty Acid Esters or two kinds.
5. a kind of general oil emulsion according to claim 1, it is characterised in that: the antirust agent is petroleum sulfonate, carboxylic
Hydrochlorate, borate, zinc naphthenate, any one or a few in dodecenylsuccinic acid.
6. a kind of general oil emulsion according to claim 1, it is characterised in that: the fungicide be imidazolidine, glutaraldehyde,
Trihydroxy methyl-nitromethane or dibromo salicylamide.
7. a kind of general oil emulsion according to claim 1, it is characterised in that: the preservative is the thio phosphorus of double octyls two
Sour zinc and/or fourth octyl zinc dithiophosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811445516.1A CN109370734A (en) | 2018-11-29 | 2018-11-29 | A kind of general oil emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811445516.1A CN109370734A (en) | 2018-11-29 | 2018-11-29 | A kind of general oil emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109370734A true CN109370734A (en) | 2019-02-22 |
Family
ID=65375106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811445516.1A Pending CN109370734A (en) | 2018-11-29 | 2018-11-29 | A kind of general oil emulsion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109370734A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113652280A (en) * | 2021-08-10 | 2021-11-16 | 希玛石油制品（镇江）有限公司 | Environment-friendly chlorine-free titanium alloy cutting oil and preparation method thereof |
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| CN104342261A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Emulsified oil composition and use thereof |
| CN105143420A (en) * | 2013-03-12 | 2015-12-09 | 埃莱万斯可再生能源科学股份有限公司 | Maleinized ester derivatives |
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| CN108410557A (en) * | 2018-03-30 | 2018-08-17 | 南京工程学院 | A kind of steel pipe drawing oil emulsion and preparation method thereof with superelevation greasy property |
| CN108559600A (en) * | 2018-01-03 | 2018-09-21 | 无锡市恒利弘实业有限公司 | A kind of steel workpiece retrofit emulsion and preparation method thereof and aftertreatment technology |
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2018
- 2018-11-29 CN CN201811445516.1A patent/CN109370734A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110237471A1 (en) * | 2004-03-26 | 2011-09-29 | Council Of Scientific & Industrial Research | Process for metalworking fluid from heavy alkylate |
| US20080269086A1 (en) * | 2007-04-30 | 2008-10-30 | Atanu Adhvaryu | Functionalized nanosphere lubricants |
| US20120201962A1 (en) * | 2009-06-24 | 2012-08-09 | Fujifilm Corporation | Composition, compound and film forming method |
| CN105143420A (en) * | 2013-03-12 | 2015-12-09 | 埃莱万斯可再生能源科学股份有限公司 | Maleinized ester derivatives |
| CN104293443A (en) * | 2014-09-24 | 2015-01-21 | 中国石油化工股份有限公司 | Rolling emulsified oil composition and application thereof |
| CN104342261A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Emulsified oil composition and use thereof |
| CN106833846A (en) * | 2017-01-23 | 2017-06-13 | 上海帕卡兴产化工有限公司 | One kind exempts from degreasing autobody sheet and cleans oil and preparation method thereof with punching press |
| CN108559600A (en) * | 2018-01-03 | 2018-09-21 | 无锡市恒利弘实业有限公司 | A kind of steel workpiece retrofit emulsion and preparation method thereof and aftertreatment technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113652280A (en) * | 2021-08-10 | 2021-11-16 | 希玛石油制品（镇江）有限公司 | Environment-friendly chlorine-free titanium alloy cutting oil and preparation method thereof |
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