CN109368923A - A kind of pharmaceutical wastewater treatment process - Google Patents

A kind of pharmaceutical wastewater treatment process Download PDF

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Publication number
CN109368923A
CN109368923A CN201811350501.7A CN201811350501A CN109368923A CN 109368923 A CN109368923 A CN 109368923A CN 201811350501 A CN201811350501 A CN 201811350501A CN 109368923 A CN109368923 A CN 109368923A
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CN
China
Prior art keywords
waste water
cabinet
spring
wastewater treatment
axis
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CN201811350501.7A
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Chinese (zh)
Inventor
不公告发明人
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Lin Fangjie
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Lin Fangjie
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Priority to CN201811350501.7A priority Critical patent/CN109368923A/en
Publication of CN109368923A publication Critical patent/CN109368923A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/343Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the pharmaceutical industry, e.g. containing antibiotics
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/023Reactive oxygen species, singlet oxygen, OH radical
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/026Fenton's reagent
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)

Abstract

The invention belongs to technical field of waste water processing, specifically a kind of pharmaceutical wastewater treatment process, the technique uses wastewater treatment equipment, and wastewater treatment equipment includes cabinet;It further include driving unit, agitating unit, rotating disc, expansion box and controller.The technological operation is succinct, flexibly, can effectively be handled pharmaceutical wastewater, and treated that waste water can be discharged effectively, will not damage to the ecological environment on periphery, be conducive to the sustainable health development of ecological environment.

Description

A kind of pharmaceutical wastewater treatment process
Technical field
The invention belongs to technical field of waste water processing, specifically a kind of pharmaceutical wastewater treatment process.
Background technique
It is raw that medicine producing wastewater generally comprises medicine intermediate industry, medical material medicine synthesis industry and pharmaceutical preparation industry The organic wastewater waste water discharged during producing, not only organic concentration is high in this kind of waste water, but also containing poisonous and harmful to biology The substance of effect, and with the quickening of China's process of industrialization, the discharge amount of this kind of waste water is increasing, to our environment Serious pollution is caused, human life and health is threatened.Since this kind of waste water has complicated component, very high concentrations, to micro- life Object has stronger toxicity and is difficult to biodegrade.
Also occur a kind of technical solution of the patent about pharmaceutical wastewater treatment process, such as application number in the prior art Disclose wastewater treatment equipment, including inlet tank for 2015103355185 Chinese patent, be equipped at the top of inlet tank into Water pipe, integrally connected between water inlet pipe and inlet tank are equipped with clarifier in inlet tank, and inlet tank lower surface is at two sides It is connected with support tube, support tube top and inlet tank integrally connected, bottom is fixed on a support tube socket, between two support tubes Equipped with discharge casing, discharge casing both ends are fixed on two support tubes by clip, and discharge casing is connect by built-in tube body with inlet tank, Strainer is horizontally installed in discharge casing, strainer is detachably connected on discharge casing, and stirring pipe is vertically equipped in discharge casing, is stirred Pipe is equipped with stirring blade, integrally connected between stirring blade and stirring pipe.
The wastewater treatment equipment of the technical solution can be stirred waste water.But in the technical solution, to waste water Stir insufficient, and the power source that generates utilize in cannot stirring to waste water, but increase additional power-equipment, thus Increase the manufacturing cost of wastewater treatment equipment;Meanwhile the treatment and purification of waste water is insufficient;So that the technical solution is limited System.
Summary of the invention
In order to make up for the deficiencies of the prior art, it solves the waste water insufficient, utilization of resources of stirring and wastewater treatment purification is not filled The problem of dividing;The invention proposes a kind of pharmaceutical wastewater treatment process.
The technical solution adopted by the present invention to solve the technical problems is: a kind of pharmaceutical wastewater processing work of the present invention Skill, the technique the following steps are included:
S1: fine fack is mounted at water inlet pipe mouth, and fine fack is equipped with link, by fine fack to depositing in pharmaceutical wastewater Larger particles floating material and hair etc. intercepted, avoid into water blockage;
S2: on the basis of S1, PH reagent is launched into cabinet, passes through the pH value of waste water in PH reagent regulating box body;Together When, domestic sludge is launched into cabinet, is started wastewater treatment equipment so that domestic sludge and waste water are sufficiently mixed and is utilized cabinet Hydrolysis of organic matter insoluble in waste water is dissolved organic matter by interior hydrolysis acid and acid-producing bacteria, by the macromolecular of difficult for biological degradation Substance is converted into the small-molecule substance of easily biological-degradable, changes the biodegradability of waste water;
S3: on the basis of S2, being passed through air into cabinet by aspiration pump, so that aerobic environment is maintained in cabinet, benefit The organic matter in waste water is decomposed with case intracorporal aerobic bacteria;
S4: on the basis of S1, S2 and S3, purified treatment is carried out to waste water using wastewater treatment equipment;
The wastewater treatment equipment that the present invention uses includes cabinet;It further include driving unit, agitating unit, rotating disc, gas storage Case and controller;The controller is used to control the work of wastewater treatment equipment;The top of the box is equipped with water inlet pipe and gas storage Case, the bottom of box are equipped with outlet pipe;The driving unit is fixedly mounted at the top of the box body, and driving unit includes motor, No.1 Axis, No.1 cam and No.1 air bag;The No.1 axis is rotatablely installed by bearing and motor output shaft, and motor is connected by bracket On cabinet;The No.1 cam is set on No.1 axis;No.1 air bag one end is connected on the lateral wall of expansion box, and one Number air bag other end and No.1 cam contact pass through the rotation of No.1 cam and squeeze No.1 air bag, and the gas of No.1 air bag bulging is made For agitating unit;The rotating disc is set on the outer ring of No.1 axis;The agitating unit is mounted at the top of rotating disc, is stirred Mixing unit includes double end cylinder, scissor device and filter plate;The quantity of the scissor device is two, and scissor device is along No.1 axis pair Claim setting, scissor device includes several No.1 bars and No. two bars;It is hinged in the middle part of the No.1 bar and No. two bars, No.1 bar Between be hinged, and the No.1 bar being located above is hinged on filter plate, and underlying No.1 bar is hinged on rotating disc, two It is hinged between number bar, and be located above No. two bar hingedly connects on filter plate, underlying No. two bars are in fixed disk On, symmetrically arranged No. two bars in lower section are connected by double end cylinder;The both ends of the filter plate are arc-shaped, and and wall box Contact;The double end cylinder is connected in fixed disk, is transferred to double end cylinder by the gas for generating No.1 air bag, is controlled scissor Stretching for device, is stirred waste water.Industrial wastewater refers to the waste water, sewage and waste liquid generated in industrial processes, with The rapid development of industry, the type and quantity of waste water rapidly increase, and the pollution of waste water is also increasingly extensively and serious, threaten the mankind Health and safety.Therefore, it is necessary to handle the waste water of industry, a kind of wastewater treatment equipment exists in the prior art, but It is existing wastewater treatment equipment Shortcomings, on the one hand, it is insufficient to the stirring of waste water in existing wastewater treatment equipment, from And influence the treatment effect of waste water;On the other hand, the power source generated in cannot stirring to waste water utilizes, but increases volume Outer power-equipment, to increase the manufacturing cost of wastewater treatment equipment;The present invention is single by setting driving unit, stirring Member, rotating disc, expansion box and controller;On the one hand, right by the mutual cooperation between driving unit, agitating unit and rotating disc Waste water had not only carried out the stirring on circumferencial direction, but also carried out the stirring on vertical direction, was adequately and uniformly stirred to waste water, To improve waste water treatment efficiency;On the other hand, by waste water stir in the power source that generates utilize, avoid increasing additional Power-equipment, to reduce the manufacturing cost of wastewater treatment equipment.
Firstly, waste water to be treated is passed into cabinet from water inlet pipe, at this point, driving motor, motor drives No.1 Axis rotation, so that No.1 cam and turn disc;In the rotation of No.1 cam, No.1 cam extrusion No.1 air bag, No.1 gas Capsule is squeezed outside air-blowing, and the gas of bulging acts on agitating unit;Since agitating unit is mounted on rotating disc, a side Face, rotating disc drive scissor device and filter plate to be rotated, and the filter plate and scissor device of rotation carry out circumference side to waste water Upward stirring;On the other hand, the gas that No.1 air bag generates is acted on into double end cylinder, the cylinder at double end cylinder a is axial Outer stretching, extension, cylinder axis at double end cylinder b is to contract;During cylinder axis at double end cylinder a flexes outward, with double end The scissor device of cylinder axis connection is opened at cylinder a so that filter plate is to moving far from rotating disc side, filter plate by waste water to Upper promotion, and the impurity being adhered on wall box is cleared up at the both ends of filter plate;Meanwhile the gas at double end cylinder b It in the inside telescopic process of cylinder shaft, is shunk with the scissor device of cylinder axis connection at double end cylinder b, so that filter plate is to close to rotation The movement of disk side, filter plate push down on waste water, and filter board ends and clear up wall box;Utilize two scissor devices Filter plate is driven to carry out the movement in opposite direction, so that waste water is uniformly stirred;By carrying out circumferencial direction to waste water On stirring and vertical direction on stirring so that waste water is adequately reacted;Waste water sufficiently after reaction passes through outlet pipe Discharge.
Preferably, the rotating disc is gear, and rotating disc two sides are equipped with No.1 spring and No. two springs;The No.1 spring It is mounted on wall box with No. two spring pivotals, oppositely oriented, and No.1 spring and No. two of No.1 spring and No. two springs Spring and rotating disc engaged transmission, are arranged with mounting blocks on No.1 spring and No. two springs respectively;The mounting blocks are in No.1 bullet Be uniformly distributed on spring and No. two springs, opened up on mounting blocks it is fluted, groove section shape and No.1 spring and No. two springs Wire cross sectional is consistent;The groove is made of No.1 arc, No. two arcs and symmetrically arranged No.1 circular arc;The No.1 arc and two Number arc is relative to each other;The No.1 circular arc is connect with No.1 arc and No. two arcs respectively;It is uniformly provided with stirring rod on the mounting blocks, By the mutual cooperation between rotating disc, No.1 spring and No. two springs, increase the stirring dynamics to waste water.The present invention by using No.1 spring and No. two springs, and the rotation direction of No.1 spring and No. two springs is set as opposite, on the one hand, No.1 spring and No. two Cheap, the easy acquisition of spring, to reduce the manufacturing cost of wastewater treatment equipment;Meanwhile the No.1 bullet of different rotation directions The rotation of opposite direction may be implemented in spring and No. two springs, and waste water is adequately stirred in the cooperation with mounting blocks and stirring rod It mixes, to improve the stirring efficiency of waste water;On the other hand, by the steel of groove and No.1 spring and No. two springs on mounting blocks Silk cross section is set as unanimously, so that mounting blocks follow No.1 spring and No. two springs to carry out the circular-rotation on vertical direction, is kept away Exempt to shake in mounting blocks rotation, influences mounting blocks and carry out circular-rotation in the vertical direction, increase waste water and be stirred model It encloses, to improve water treatment effect.
In the rotation of rotating disc, since rotating disc is engaged with No.1 spring and No. two springs, so that No.1 spring up time Needle rotation, No. two springs rotate counterclockwise;In No.1 spring rotates clockwise, the mounting blocks on No.1 spring are driven to carry out suitable Hour hands rotation, stirring rod stir waste water clockwise, in No. two springs rotate counterclockwise, drive the peace on No. two springs Dress block is rotated counterclockwise, and stirring rod stirs waste water counterclockwise, is located at stirring rod and No. two springs on No.1 spring On stirring rod do not interfere, waste water is adequately stirred.
Preferably, the end of the No.1 axis is equipped with auxiliary unit;The auxiliary unit is used to carry out waste water auxiliary to stir It mixes, auxiliary unit includes fixed disk, No. two air bags, fixed block and No.1 cylinder;No.1 cylinder one end ball connects at cabinet bottom Portion, the No.1 cylinder other end are hinged on fixed block;The fixed disk is connected in No.1 shaft end portion;No. two air bags are for connecting Fixed disk and fixed block are connect, No. two air bag original states are compressive state;The side wall of the cabinet is equipped with No.1 slot, No.1 slot In be equipped with movable block;The movable block is connected in No.1 slot by spring, and one side of the movable block far from No.1 slot is circular arc Face, by the way that the gas generated in movable block activity is transferred to No. two air bags, so that No.1 Telescopic-cylinder, passes through No.1 Telescopic-cylinder The gas of generation carries out Air Exposure to waste water.The present invention by by auxiliary unit be set as fixed disk, No. two air bags, fixed block and No.1 cylinder;On the one hand, since No.1 cylinder one end ball connects in the bottom of box, the No.1 cylinder other end is hinged on fixed block, And fixed block is connected by No. two air bags and fixed disk, so that generation while carrying out circular-rotation with No.1 axis of No.1 cylinder It swings, waste water is stirred, to improve the mixing effect of waste water;On the other hand, due to No. two air bag initial shapes State is compressive state, and by the way that the gas generated in movable block activity is transferred to No. two air bags, No. two air bags are heaved, and No.1 gas is pushed The activity of cylinder axis in cylinder, the gas auxiliary waste water stirring of generation, to improve waste water stirring efficiency.
When the gas generated in movable block activity is acted on No. two air bags, No. two air bags are heaved, heave No. two gas Capsule pushes the cylinder in No.1 cylinder to move axially away from fixed disk side, the stirring of the gas auxiliary waste water generated in movement; When stopping conveying gas to No. two air bags, No. two air-pocket resets, so that the cylinder in No.1 cylinder is axially adjacent to fixed disk one Side moves, and the gas generated in movement, which transfers in expansion box, to be stored.
Preferably, the No.1 axis is hollow shaft;Cavity is offered inside the fixed disk, and is set on the outer ring of fixed disk There is spray head, the No.1 axis outer ring at cavity is equipped with spray orifice and fan-shaped rotor plate;The sector rotor plate is rotatably installed in On the outer ring of No.1 axis, and spray head is blocked under fan-shaped rotor plate original state, passes through No.1 axis, fan-shaped rotor plate and fixed disk Between mutual cooperation, Fenton reagent is sprayed in the middle part of the cabinet, wastewater treatment is accelerated.The present invention is tried by hollow sprinkling Fenton Agent, on the one hand, hollow investment Fenton reagent accelerates waste water and Fenton reagent reaction efficiency;On the other hand, it is tried using Fenton Agent, Fenton reagent can generate the hydroxyl radical free radical of strong oxidizing property, and generating organic free radical with hardly degraded organic substance in waste water makes Structure destroy, final oxygenolysis, to improve waste water treatment efficiency.
Preferably, control unit is equipped with inside the fixed disk;Described control unit is used to control turning for fan-shaped rotor plate Dynamic, control unit includes No. two cams and impeller;No. two cams are rotatablely installed on the sidewalls of the cavities by shaft, and No. two Cam is contacted with fan-shaped rotor plate, and impeller is set in the shaft of No. two cams, and shaft is equipped with torsional spring, by acting on gas In impeller, so that No. two cam rotations.The present invention is by setting control unit, by control unit, so that Fenton reagent is two Interregional abundant pressure accumulation between fan-shaped rotor plate, to increase the range of Fenton reagent sprinkling.
After the completion of Fenton reagent pressure accumulation in the region that two fan-shaped rotor plates are formed, the gas in expansion box is acted on Impeller, so that No. two cam rotations, No. two cams are detached from fan-shaped rotor plate, and Fenton reagent pushes fan-shaped rotor plate rotation, Fenton Reagent sprays from spray head, after the Fenton reagent between two fan-shaped rotor plates has sprayed, stops conveying gas to impeller, No. two convex Wheel resets under the action of torsional spring.
Preferably, the fan-shaped rotor plate is equipped with water-proof elastic cloth;The water-proof elastic cloth is by fan-shaped rotor plate and empty Chamber side wall is connected, and water-proof elastic cloth is used to reduce the friction between fan-shaped rotor plate and cavity sidewalls.The present invention passes through setting waterproof Elastical cloth had not only made the region between two fan-shaped rotor plates carry out sufficient pressure accumulation, but also has avoided fan-shaped rotation using water-proof elastic cloth Abrasion in plate rotation, to improve the service life of fan-shaped rotor plate.
Beneficial effects of the present invention are as follows:
1. a kind of pharmaceutical wastewater treatment process of the present invention, operation is succinct, flexible, can have to pharmaceutical wastewater The processing of effect, and treated that waste water can be discharged effectively, will not damage to the ecological environment on periphery, favorably In the sustainable health development of ecological environment.
2. a kind of pharmaceutical wastewater treatment process of the present invention, which uses wastewater treatment equipment, wastewater treatment dress Set that structure is simple, easily operated, by waste water stir in the power source that generates utilize, avoid increasing additional power source, drop The manufacturing cost of the low device, while improving the utilization rate of resource.
3. a kind of pharmaceutical wastewater treatment process of the present invention, which uses wastewater treatment equipment, wastewater treatment dress It sets through the mutual cooperation between driving unit, agitating unit and rotating disc, had not only carried out the stirring on circumferencial direction to waste water, but also into Stirring on row vertical direction adequately and uniformly stirs waste water, to improve waste water treatment efficiency.
Detailed description of the invention
The present invention will be further explained below with reference to the attached drawings.
Fig. 1 is process flow chart of the invention;
Fig. 2 is the main view of wastewater treatment equipment of the present invention;
Fig. 3 is the cross-sectional view of A-A in Fig. 2;
Fig. 4 is the cross-sectional view of B-B in Fig. 2;
Fig. 5 is the partial enlarged view in Fig. 3 at C;
Fig. 6 is the cross-sectional view of D-D in Fig. 4;
In figure: cabinet 1, movable block 11, driving unit 2, No.1 axis 21, No.1 cam 22, No.1 air bag 23, agitating unit 3, double end cylinder 31, scissor device 32,321, No. two bars 322 of No.1 bar, filter plate 33, rotating disc 4, No.1 spring 41, two Spring 42, groove 44,441, No. two arcs 442 of No.1 arc, No.1 circular arc 443, stirring rod 45, auxiliary unit 5, is consolidated mounting blocks 43 Price fixing 51, cavity 511,512, No. two air bags 52 of fan-shaped rotor plate, No.1 cylinder 53, control unit 6, No. two cams 61, impeller 62, water-proof elastic cloth 63.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Specific embodiment is closed, the present invention is further explained.
As shown in Figures 1 to 6, a kind of pharmaceutical wastewater treatment process of the present invention, the technique the following steps are included:
S1: fine fack is mounted at water inlet pipe mouth, and fine fack is equipped with link, by fine fack to depositing in pharmaceutical wastewater Larger particles floating material and hair etc. intercepted, avoid into water blockage;
S2: on the basis of S1, PH reagent is launched into cabinet, passes through the pH value of waste water in PH reagent regulating box body;Together When, domestic sludge is launched into cabinet, is started wastewater treatment equipment so that domestic sludge and waste water are sufficiently mixed and is utilized cabinet Hydrolysis of organic matter insoluble in waste water is dissolved organic matter by interior hydrolytic bacteria and acid-producing bacteria, by the macromolecular of difficult for biological degradation Substance is converted into the small-molecule substance of easily biological-degradable, changes the biodegradability of waste water;
S3: on the basis of S2, being passed through air into cabinet by aspiration pump, so that aerobic environment is maintained in cabinet, benefit The organic matter in waste water is decomposed with case intracorporal aerobic bacteria;
S4: on the basis of S1, S2 and S3, purified treatment is carried out to waste water using wastewater treatment equipment;
The wastewater treatment equipment that the present invention uses includes cabinet 1;Further include driving unit 2, agitating unit 3, rotating disc 4, Expansion box and controller;The controller is used to control the work of wastewater treatment equipment;At the top of the cabinet 1 be equipped with water inlet pipe and Expansion box, 1 bottom of cabinet are equipped with outlet pipe;The driving unit 2 is fixedly mounted on the top of cabinet 1, and driving unit 2 includes electricity Machine, No.1 axis 21, No.1 cam 22 and No.1 air bag 23;The No.1 axis 21 is rotatablely installed by bearing and motor output shaft, Motor is connected on cabinet 1 by bracket;The No.1 cam 22 is set on No.1 axis 21;Described 23 one end of No.1 air bag is solid It is connected on the lateral wall of expansion box, 23 other end of No.1 air bag is contacted with No.1 cam 22, is rotated and is squeezed by No.1 cam 22 No.1 air bag 23, the gas that No.1 air bag 23 bloats act on agitating unit 3;The rotating disc 4 is set in No.1 axis 21 On outer ring;The agitating unit 3 is mounted on the top of rotating disc 4, and agitating unit 3 includes double end cylinder 31,32 and of scissor device Filter plate 33;The quantity of the scissor device 32 is two, and scissor device 32 is symmetrical arranged along No.1 axis 21, and scissor device 32 includes Several No.1 bars 321 and No. two bars 322;The middle part of the No.1 bar 321 and No. two bars 322 is hinged, 321 phases of No.1 bar It is mutually hinged, and the No.1 bar 321 being located above is hinged on filter plate 33, underlying No.1 bar 321 is hinged on rotating disc 4 On, it is hinged between No. two bars 322, and be located above No. two bar 322 hingedly connects on filter plate 33, underlying No. two Bar 322 is in fixed disk 51, and symmetrically arranged No. two bars 322 in lower section are connected by double end cylinder 31;The filter plate 33 Both ends are arc-shaped, and are contacted with 1 side wall of cabinet;The double end cylinder 31 is connected in fixed disk 51, by by No.1 air bag 23 gases generated transfer to double end cylinder 31, and stretching for control scissor device 32 is stirred waste water.Industrial wastewater refers to work Waste water, sewage and the waste liquid generated in industry production process, with the rapid development of industry, the type and quantity of waste water rapidly increase Add, the pollution of waste water is also increasingly extensively and serious, threatens the health and safety of the mankind.Therefore, it is necessary to the waste water progress to industry Processing, exists in the prior art a kind of wastewater treatment equipment, but existing wastewater treatment equipment Shortcomings, on the one hand, existing It is insufficient to the stirring of waste water in some wastewater treatment equipments, to influence the treatment effect of waste water;It on the other hand, cannot be to useless The power source generated in water stirring is utilized, but increases additional power-equipment, to increase wastewater treatment equipment Manufacturing cost;The present invention passes through setting driving unit 2, agitating unit 3, rotating disc 4, expansion box and controller;On the one hand, pass through Mutual cooperation between driving unit 2, agitating unit 3 and rotating disc 4 had not only carried out the stirring on circumferencial direction to waste water, but also had carried out Stirring on vertical direction adequately and uniformly stirs waste water, to improve waste water treatment efficiency;On the other hand, By waste water stir in the power source that generates utilize, avoid increasing additional power-equipment, to reduce wastewater treatment dress The manufacturing cost set.
Firstly, waste water to be treated is passed into cabinet 1 from water inlet pipe, at this point, driving motor, motor drives No.1 Axis 21 rotates, so that No.1 cam 22 and rotating disc 4 rotate;In the rotation of No.1 cam 22, No.1 cam 22 squeezes No.1 gas Capsule 23, No.1 air bag 23 are squeezed outside air-blowing, and the gas of bulging acts on agitating unit 3;Since agitating unit 3 is mounted on On rotating disc 4, on the one hand, rotating disc 4 drives scissor device 32 and filter plate 33 to be rotated, the filter plate 33 and scissor of rotation Device 32 carries out the stirring on circumferencial direction to waste water;On the other hand, the gas that No.1 air bag 23 generates is acted on into double end gas Cylinder 31, the cylinder axis at double end cylinder 31a flex outward, and the cylinder axis at double end cylinder 31b is to contract;In double end cylinder During cylinder axis at 31a flexes outward, opened with the scissor device 32 of cylinder axis connection at double end cylinder 31a, so that mistake For filter plate 33 to moving far from 4 side of rotating disc, filter plate 33 pushes up waste water, and the both ends of filter plate 33 are to being adhered to case Impurity on 1 side wall of body is cleared up;Meanwhile in the inside telescopic process of cylinder axis at double end cylinder 31b, with double end cylinder The scissor device 32 of cylinder axis connection is shunk at 31b, so that filter plate 33 is moved to close to 4 side of rotating disc, filter plate 33 will Waste water pushes down on, and 1 side wall of cabinet is cleared up at 33 both ends of filter plate;Using two scissor devices 32 drive filter plate 33 into Movement in row opposite direction, so that waste water is uniformly stirred;By carrying out the stirring on circumferencial direction to waste water and erecting The upward stirring of histogram, so that waste water is adequately reacted;Waste water sufficiently after reaction is discharged by outlet pipe.
As one embodiment of the present invention, the rotating disc 4 is gear, and 4 two sides of rotating disc are equipped with No.1 spring 41 With No. two springs 42;The No.1 spring 41 and No. two springs 42 are rotatably installed on 1 side wall of cabinet, No.1 spring 41 and No. two Oppositely oriented, and No.1 spring 41 and No. two springs 42 and 4 engaged transmission of rotating disc, No.1 spring 41 and No. two bullets of spring 42 Mounting blocks 43 are arranged on spring 42 respectively;The mounting blocks 43 are uniformly distributed on No.1 spring 41 and No. two springs 42, installation Fluted 44 are opened up on block 43,44 cross sectional shape of groove is consistent with the wire cross sectional of No.1 spring 41 and No. two springs 42;Institute Groove 44 is stated to be made of 441, No. two arcs 442 of No.1 arc and symmetrically arranged No.1 circular arc 443;The No.1 arc 441 and No. two Arc 442 is relative to each other;The No.1 circular arc 443 is connect with No.1 arc 441 and No. two arcs 442 respectively;On the mounting blocks 43 Even to be equipped with stirring rod 45, by the mutual cooperation between rotating disc 4, No.1 spring 41 and No. two springs 42, waste water is stirred in increase Mix dynamics.The present invention is by using No.1 spring 41 and No. two springs 42, and by the rotation direction of No.1 spring 41 and No. two springs 42 It is set as opposite, on the one hand, cheap, the easy acquisition of No.1 spring 41 and No. two springs 42, to reduce wastewater treatment dress The manufacturing cost set;Meanwhile the rotation of opposite direction may be implemented in the No.1 spring 41 of different rotation directions and No. two springs 42, with peace The cooperation for filling block 43 and stirring rod 45, adequately stirs waste water, to improve the stirring efficiency of waste water;Another party The wire cross sectional of groove 44 and No.1 spring 41 and No. two springs 42 on mounting blocks 43 is set as unanimously by face, so that installation Block 43 follows No.1 spring 41 and No. two springs 42 to carry out the circular-rotation on vertical direction, avoids occurring in the rotation of mounting blocks 43 It shakes, influences mounting blocks 43 and carry out circular-rotation in the vertical direction, increase waste water and be stirred range, to improve waste water Treatment effect.
In the rotation of rotating disc 4, since rotating disc 4 is engaged with No.1 spring 41 and No. two springs 42, so that No.1 bullet Spring 41 rotates clockwise, and No. two springs 42 rotate counterclockwise;In No.1 spring 41 rotates clockwise, drive on No.1 spring 41 Mounting blocks 43 rotated clockwise, stirring rod 45 stirs waste water clockwise, rotates counterclockwise in No. two springs 42 In, drive the mounting blocks 43 on No. two springs 42 to be rotated counterclockwise, stirring rod 45 stirs waste water counterclockwise, is located at Stirring rod 45 on No.1 spring 41 on stirring rod 45 and No. two springs 42 does not interfere, and is adequately stirred to waste water.
As one embodiment of the present invention, the end of the No.1 axis 21 is equipped with auxiliary unit 5;The auxiliary unit 5 for carrying out auxiliary stirring to waste water, and auxiliary unit 5 includes 51, No. two air bags 52 of fixed disk, fixed block and No.1 cylinder 53; 53 one end ball of No.1 cylinder connects in 1 bottom of cabinet, and 53 other end of No.1 cylinder is hinged on fixed block;The fixed disk 51 It is connected in 21 end of No.1 axis;No. two air bags 52 are for being connected and fixed disk 51 and fixed block, No. two 52 original states of air bag For compressive state;The side wall of the cabinet 1 is equipped with No.1 slot, is equipped with movable block 11 in No.1 slot;The movable block 11 passes through Spring is connected in No.1 slot, and one side of the movable block 11 far from No.1 slot is arc surface, by will produce in 11 activity of movable block Raw gas transfers to No. two air bags 52, so that No.1 cylinder 53 is flexible, by the flexible gas generated of No.1 cylinder 53 to waste water Carry out Air Exposure.The present invention is by being set as 51, No. two air bags 52 of fixed disk, fixed block and No.1 cylinder 53 for auxiliary unit 5; On the one hand, since 53 one end ball of No.1 cylinder connects in 1 bottom of cabinet, 53 other end of No.1 cylinder is hinged on fixed block, and solid Determine block to be connected by No. two air bags 52 and fixed disk 51, so that No.1 cylinder 53 is while carrying out circular-rotation with No.1 axis 21 It swings, waste water is stirred, to improve the mixing effect of waste water;On the other hand, due to No. two air bags 52 Original state is compressive state, by the way that the gas generated in 11 activity of movable block is transferred to No. two air bags 52, No. two drums of air bag 52 It rises, pushes the activity of cylinder axis in No.1 cylinder 53, the gas auxiliary waste water stirring of generation, to improve waste water stirring effect Rate.
When the gas generated in 11 activity of movable block is acted on No. two air bags 52, No. two air bags 52 are heaved, and are heaved No. two air bags 52 push the cylinder in No.1 cylinder 53 to move axially away from 51 side of fixed disk, the gas auxiliary generated in movement The stirring of waste water;When stopping conveying gas to No. two air bags 52, No. two air bags 52 reset, so that the cylinder in No.1 cylinder 53 It is moved axially adjacent to 51 side of fixed disk, the gas generated in movement, which transfers in expansion box, to be stored.
As one embodiment of the present invention, the No.1 axis 21 is hollow shaft;It is offered inside the fixed disk 51 Cavity 511, and the outer ring of fixed disk 51 is equipped with spray head, 21 outer ring of No.1 axis at cavity 511 is equipped with spray orifice and fan Shape rotor plate 512;The sector rotor plate 512 is rotatably installed on the outer ring of No.1 axis 21, and 512 initial shape of fan-shaped rotor plate Spray head is blocked under state, by the mutual cooperation between No.1 axis 21, fan-shaped rotor plate 512 and fixed disk 51, by Fenton reagent from It is sprayed in the middle part of cabinet 1, accelerates wastewater treatment.The present invention passes through hollow sprinkling Fenton reagent, on the one hand, hollow investment Fenton examination Agent accelerates waste water and Fenton reagent reaction efficiency;On the other hand, using Fenton reagent, Fenton reagent can generate strong oxidizing property Hydroxyl radical free radical, in waste water with hardly degraded organic substance generate organic free radical be allowed to structure destroy, final oxygenolysis, from And improve waste water treatment efficiency.
As one embodiment of the present invention, control unit 6 is equipped with inside the fixed disk 51;Described control unit 6 For controlling the rotation of fan-shaped rotor plate 512, control unit 6 includes No. two cams 61 and impeller 62;No. two cams 61 are logical It crosses shaft to be rotatably installed on the side wall of cavity 511, No. two cams 61 are contacted with fan-shaped rotor plate 512, and impeller 62 is set in two In the shaft of number cam 61, shaft is equipped with torsional spring, by the way that gas is acted on impeller 62, so that No. two cams 61 rotate.This Invention is by setting control unit 6, by control unit 6, so that interregional between two fan-shaped rotor plates 512 of Fenton reagent fills Divide pressure accumulation, to increase the range of Fenton reagent sprinkling.
After the completion of Fenton reagent pressure accumulation in the region that two fan-shaped rotor plates 512 are formed, the gas in expansion box is made For impeller 62, so that No. two cams 61 rotate, No. two cams 61 are detached from fan-shaped rotor plate 512, and Fenton reagent pushes fan-shaped turn Movable plate 512 rotates, and Fenton reagent sprays from spray head, after the Fenton reagent between two sector rotor plates 512 has sprayed, stop to Impeller 62 conveys gas, and No. two cams 61 reset under the action of torsional spring.
As one embodiment of the present invention, the sector rotor plate 512 is equipped with water-proof elastic cloth 63;The waterproof Fan-shaped rotor plate 512 and 511 side wall of cavity are connected by elastical cloth 63, water-proof elastic cloth 63 for reduce fan-shaped rotor plate 512 with Friction between 511 side wall of cavity.The present invention had both made two fan-shaped turns by setting water-proof elastic cloth 63, using water-proof elastic cloth 63 Region between movable plate 512 carries out sufficient pressure accumulation, and avoids the abrasion in the fan-shaped rotation of rotor plate 512, to improve sector The service life of rotor plate 512.
In use, firstly, being carried out by fine fack to the floating material of larger particles present in pharmaceutical wastewater and hair etc. It intercepts, when waste water to be treated is passed into cabinet 1 from water inlet pipe, PH reagent and domestic sludge is launched into cabinet, and Air is opened inwards by aspiration pump, keeps aerobic environment, it is right by the mutual cooperation between hydrolytic bacteria, acid-producing bacteria and aerobic bacteria Waste water is adequately purified;Meanwhile driving motor, motor drives No.1 axis 21 to rotate, so that No.1 cam 22 and rotating disc 4 Rotation, and Fenton reagent is put into from No.1 axis 21, Fenton reagent is sprayed onto cabinet 1 by the way that spray head is hollow;It is convex in No.1 In 22 rotation of wheel, No.1 cam 22 squeezes No.1 air bag 23, and No.1 air bag 23 is squeezed outside air-blowing, and the gas of bulging acts on On agitating unit 3;Since agitating unit 3 is mounted on rotating disc 4, on the one hand, rotating disc 4 drives scissor device 32 and filter plate 33 are rotated, and the filter plate 33 and scissor device 32 of rotation carry out the stirring on circumferencial direction to waste water;On the other hand, by one The gas that number air bag 23 generates acts on double end cylinder 31, and the cylinder axis at double end cylinder 31a flexes outward, double end cylinder 31b The cylinder axis at place is to contract;During cylinder axis at double end cylinder 31a flexes outward, with cylinder at double end cylinder 31a The scissor device 32 of axis connection is opened, so that filter plate 33 is moved to far from 4 side of rotating disc, filter plate 33 pushes up waste water It is dynamic, and the impurity being adhered on 1 side wall of cabinet is cleared up at the both ends of filter plate 33;Meanwhile the gas at double end cylinder 31b It in the inside telescopic process of cylinder shaft, is shunk with the scissor device 32 of cylinder axis connection at double end cylinder 31b, so that filter plate 33 is to leaning on Nearly 4 side of rotating disc movement, filter plate 33 pushes down on waste water, and 1 side wall of cabinet is cleared up at 33 both ends of filter plate;Benefit Filter plate 33 is driven to carry out the movement in opposite direction with two scissor devices 32, so that waste water is uniformly stirred;Meanwhile In the rotation of rotating disc 4, since rotating disc 4 is engaged with No.1 spring 41 and No. two springs 42, so that No.1 spring 41 is clockwise Rotation, No. two springs 42 rotate counterclockwise;In No.1 spring 41 rotates clockwise, the mounting blocks 43 on No.1 spring 41 are driven It is rotated clockwise, stirring rod 45 stirs waste water clockwise, in No. two springs 42 rotate counterclockwise, drives No. two Mounting blocks 43 on spring 42 are rotated counterclockwise, and stirring rod 45 stirs waste water counterclockwise, are located at No.1 spring 41 Stirring rod 45 on upper stirring rod 45 and No. two springs 42 does not interfere, and is adequately stirred to waste water;By to waste water The stirring on circumferencial direction, the stirring of the circumference in stirring and vertical direction on vertical direction are carried out, so that waste water carries out sufficiently Reaction;Waste water sufficiently after reaction is discharged by outlet pipe.
Above-mentioned front, back, left, right, up, down is mark according to personage's observation visual angle on the basis of Fig. 2 in Figure of description Standard, device surface are defined as a left side on the left of observer to before being defined as on one side of observer, and so on.
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", "front", "rear", The orientation or positional relationship of the instructions such as "left", "right", "vertical", "horizontal", "top", "bottom" "inner", "outside" is based on attached drawing institute The orientation or positional relationship shown, is merely for convenience of description of the present invention and simplification of the description, rather than the dress of indication or suggestion meaning It sets or element must have a particular orientation, be constructed and operated in a specific orientation, therefore should not be understood as protecting the present invention The limitation of range.
Finally it is noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations.To the greatest extent Present invention has been described in detail with reference to the aforementioned embodiments for pipe, those skilled in the art should understand that: it is still It is possible to modify the technical solutions described in the foregoing embodiments, or part of technical characteristic is equally replaced It changes;And these are modified or replaceed, the essence for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution Mind and range.Every other embodiment obtained by those of ordinary skill in the art without making creative efforts, It shall fall within the protection scope of the present invention.

Claims (6)

1. a kind of pharmaceutical wastewater treatment process, it is characterised in that: the technique the following steps are included:
S1: fine fack is mounted at water inlet pipe mouth, and fine fack is equipped with link, by fine fack to present in pharmaceutical wastewater Floating material and hair of larger particles etc. are intercepted, and are avoided into water blockage;
S2: on the basis of S1, PH reagent is launched into cabinet, passes through the pH value of waste water in PH reagent regulating box body;Meanwhile to Domestic sludge is launched in cabinet, is started wastewater treatment equipment so that domestic sludge and waste water are sufficiently mixed and is utilized the intracorporal water of case It is dissolved organic matter that bacterium and acid-producing bacteria, which are solved, by hydrolysis of organic matter insoluble in waste water, and the macromolecular substances of difficult for biological degradation are turned The small-molecule substance for turning to easily biological-degradable changes the biodegradability of waste water;
S3: on the basis of S2, being passed through air into cabinet by aspiration pump, so that maintaining aerobic environment in cabinet, utilizes case Intracorporal aerobic bacteria decomposes the organic matter in waste water;
S4: on the basis of S1, S2 and S3, purified treatment is carried out to waste water using wastewater treatment equipment;
The wastewater treatment equipment that the present invention uses includes cabinet (1);It further include driving unit (2), agitating unit (3), rotating disc (4), expansion box and controller;The controller is used to control the work of wastewater treatment equipment;Be equipped at the top of the cabinet (1) into Water pipe and expansion box, cabinet (1) bottom are equipped with outlet pipe;The driving unit (2) is fixedly mounted on the top of cabinet (1), drives Moving cell (2) includes motor, No.1 axis (21), No.1 cam (22) and No.1 air bag (23);The No.1 axis (21) passes through axis It holds and is rotatablely installed with motor output shaft, motor is connected on cabinet (1) by bracket;The No.1 cam (22) is set in No.1 On axis (21);Described No.1 air bag (23) one end is connected on the lateral wall of expansion box, No.1 air bag (23) other end and No.1 Cam (22) contact, is rotated by No.1 cam (22) and squeezes No.1 air bag (23), the gas effect of No.1 air bag (23) bulging In on agitating unit (3);The fixed disk (51) is set on the outer ring of No.1 axis (21);The agitating unit (3) is mounted on The top of fixed disk (51), agitating unit (3) include double end cylinder (31), scissor device (32) and filter plate (33);It is described to cut The quantity of fork device (32) is two, and scissor device (32) is symmetrical arranged along No.1 axis (21), and scissor device (32) includes several one Number bar (321) and No. two bars (322);It is hinged in the middle part of the No.1 bar (321) and No. two bars (322), No.1 bar (321) Between be hinged, and the No.1 bar (321) being located above is hinged on filter plate (33), underlying No.1 bar (321) hinge It connects on rotating disc (4), is hinged between No. two bars (322), and be located above No. two bar (322) hingedly connects in filter plate (33) on, underlying No. two bars (322) are on fixed disk (51), and symmetrically arranged No. two bars (322) in lower section pass through double Head cylinder (31) connects;The both ends of the filter plate (33) are arc-shaped, and are contacted with cabinet (1) side wall;The double end cylinder (31) it is connected on fixed disk (51), is transferred to double end cylinder (31) by the gas for generating No.1 air bag (23), control scissor Stretching for device (32), is stirred waste water.
2. a kind of pharmaceutical wastewater treatment process according to claim 1, it is characterised in that: the rotating disc (4) is gear, Rotating disc (4) two sides are equipped with No.1 spring (41) and No. two springs (42);The No.1 spring (41) and No. two springs (42) turn It is dynamic to be mounted on cabinet (1) side wall, oppositely oriented, and No.1 spring (41) and two of No.1 spring (41) and No. two springs (42) Number spring (42) and rotating disc (4) engaged transmission are arranged with mounting blocks on No.1 spring (41) and No. two springs (42) respectively (43);The mounting blocks (43) are uniformly distributed on No.1 spring (41) and No. two springs (42), and mounting blocks offer on (43) Groove (44), groove (44) cross sectional shape are consistent with the wire cross sectional of No.1 spring (41) and No. two springs (42);It is described recessed Slot (44) is made of No.1 arc (441), No. two arcs (442) and symmetrically arranged No.1 circular arc (443);The No.1 arc (441) It is relative to each other with No. two arcs (442);The No.1 circular arc (443) connect with No.1 arc (441) and No. two arcs (442) respectively;Institute It states and is uniformly provided with stirring rod (45) on mounting blocks (43), by between rotating disc (4), No.1 spring (41) and No. two springs (42) It cooperates, increases the stirring dynamics to waste water.
3. a kind of pharmaceutical wastewater treatment process according to claim 1, it is characterised in that: the end of the No.1 axis (21) Equipped with auxiliary unit (5);For the auxiliary unit (5) for carrying out auxiliary stirring to waste water, auxiliary unit (5) includes fixed disk (51), No. two air bags (52), fixed block and No.1 cylinder (53);Described No.1 cylinder (53) one end ball connects in cabinet (1) bottom, No.1 cylinder (53) other end is hinged on fixed block;The fixed disk (51) is connected in No.1 axis (21) end;Described No. two Air bag (52) is compressive state for being connected and fixed disk (51) and fixed block, No. two air bag (52) original states;The cabinet (1) Side wall be equipped with No.1 slot, be equipped with movable block (11) in No.1 slot;The movable block (11) is connected in No.1 slot by spring In, one side of the movable block (11) far from No.1 slot is arc surface, by transferring to the gas generated in movable block (11) activity No. two air bags (52) expose waste water by No.1 cylinder (53) flexible gas generated so that No.1 cylinder (53) is flexible Gas disposal.
4. a kind of pharmaceutical wastewater treatment process according to claim 1, it is characterised in that: the No.1 axis (21) is hollow Axis;It is offered cavity (511) inside the fixed disk (51), and the outer ring of fixed disk (51) is equipped with spray head, is located at cavity (511) No.1 axis (21) outer ring at is equipped with spray orifice and fan-shaped rotor plate (512);The sector rotor plate (512) rotates peace Spray head is blocked on the outer ring of No.1 axis (21), and under fan-shaped rotor plate (512) original state, by No.1 axis (21), Fenton reagent is sprayed in the middle part of cabinet (1), accelerates waste water by the mutual cooperation between fan-shaped rotor plate (512) and fixed disk (51) Processing.
5. a kind of pharmaceutical wastewater treatment process according to claim 4, it is characterised in that: set inside the fixed disk (51) There are control unit (6);Described control unit (6) is used to control the rotation of fan-shaped rotor plate (512), and control unit (6) includes two Number cam (61) and impeller (62);No. two cams (61) are rotatably installed on the side wall of cavity (511) by shaft, and No. two Cam (61) is contacted with fan-shaped rotor plate (512), and impeller (62) is set in the shaft of No. two cams (61), and shaft, which is equipped with, to be turned round Spring, by the way that gas is acted on impeller (62), so that No. two cam (61) rotations.
6. a kind of pharmaceutical wastewater treatment process according to claim 5, it is characterised in that: the sector rotor plate (512) It is equipped with water-proof elastic cloth (63);Fan-shaped rotor plate (512) and cavity (511) side wall are connected by the water-proof elastic cloth (63), Water-proof elastic cloth (63) is used to reduce the friction between fan-shaped rotor plate (512) and cavity (511) side wall.
CN201811350501.7A 2018-11-14 2018-11-14 A kind of pharmaceutical wastewater treatment process Withdrawn CN109368923A (en)

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CN112456628A (en) * 2020-11-04 2021-03-09 恩宜瑞(江苏)环境发展有限公司 Cooling reactor with slag dragging function for acid-base neutralization of wastewater and application thereof

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CN208008523U (en) * 2017-11-28 2018-10-26 李若愚 A kind of sanitary sewage disposal equipment with disturbance function up and down
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KR100934350B1 (en) * 2009-02-05 2009-12-30 이알엠 코리아 주식회사 Movable apparatus for treating landfill leachate
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