CN109367161A - A kind of complex layered materials and its preparation method and application - Google Patents

A kind of complex layered materials and its preparation method and application Download PDF

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Publication number
CN109367161A
CN109367161A CN201811549799.4A CN201811549799A CN109367161A CN 109367161 A CN109367161 A CN 109367161A CN 201811549799 A CN201811549799 A CN 201811549799A CN 109367161 A CN109367161 A CN 109367161A
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China
Prior art keywords
layer
frangible
colo
coat
layered materials
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CN201811549799.4A
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Chinese (zh)
Inventor
聂佳伦
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Shanghai Liangzi Intelligent Technology Co Ltd
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Shanghai Liangzi Intelligent Technology Co Ltd
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Priority to CN201811549799.4A priority Critical patent/CN109367161A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10779—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
    • B32B13/04—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B13/042—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/04—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/18—Layered products comprising a layer of natural or synthetic rubber comprising butyl or halobutyl rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/04—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by at least one layer folded at the edge, e.g. over another layer ; characterised by at least one layer enveloping or enclosing a material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/08—Interconnection of layers by mechanical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of complex layered materials, it is characterised in that: from outside to inside successively include outer layer, frangible frangible material layer and coat of colo(u)r, the outer layer is transparent or semitransparent toughness material.The present invention provides a kind of complex layered materials and its preparation method and application, which can satisfy the public demand unique for material.Its outer layer is resistance to be fallen, after frangible layer is broken can with the color mixing in coat of colo(u)r and generate unique decorative pattern, wherein the broken of frangible frangible material layer can be completed also voluntarily be completed by consumer by the producer.The present invention makes have unique appearance using product made of material provided by the invention.

Description

A kind of complex layered materials and its preparation method and application
Technical field
The invention belongs to field of material technology, it is related to a kind of complex layered materials and its preparation method and application.
Background technique
In the prior art, for a product, since its surfacing is identical and usual appearance having the same, This is not able to satisfy requirement of the people to personalized material appearance；In addition, if product surface material encounters the external force such as shock and causes When damage, often influences the beauty of product and destroy the aesthetic values of entire product and be dropped.It is Chinese to come in the past few decades, state The uniqueness need of people is constantly rising, and Social Culture is also constantly rising unique high praise.China from people's cloud also Cloud develops to pursue the unique epoch, and the uniqueness need for how meeting consumer has become an important need.Just as Clothes is not desired to resemblance in wearing, and name is not desired to bear the same name, and the unicity of material class appearance allows the beautiful artistry of product itself to reduce.It produces simultaneously Product damaged surfaces are not meant to it unsightly, and unique lines possesses aesthetic value, and is often dropped now.
It is not yet found to have the material for meeting people's the demand in the prior art.
Summary of the invention
It is an object of the invention to provide a kind of complex layered materials and its preparation side to overcome the shortcomings of existing technologies Method and purposes.
To achieve the above object, the invention adopts the following technical scheme:
A kind of complex layered materials, successively include outer layer, frangible frangible material layer and coat of colo(u)r from outside to inside, and the outer layer is transparent Or translucent toughness material.
Preferably, the complex layered materials further include internal layer, and the internal layer is set to the inside of coat of colo(u)r.It is described Internal layer be used to support raw material layer, so that it is guaranteed that coat of colo(u)r stable structure.
Preferably, if the coat of colo(u)r is covered with single layer, coloring matter or the coat of colo(u)r with mobility are equipped with Dry partition is respectively respectively arranged with the coloring matter with mobility of identical or different color in partition；It is further preferred that institute The partition stated is uniform polygonal mesh；It is highly preferred that being hexagonal mesh or quadrilateral mesh.
Preferably, the coloring matter is selected from pigment, dyestuff or dissolved with the solution of pigments or dyes or lotion etc..
Preferably, the height of the insulating course material is identical as pigment layer height.
Preferably, the frangible frangible material layer can be ruptured, then the coat of colo(u)r is directly filled in institute in production Between the rupture stated, so that the coat of colo(u)r combines together with the frangible frangible material layer.
Preferably, the outer layer, internal layer or the material of partition are selected from transparent or semitransparent toughness material.
Preferably, the impact strength of the toughness material >=1.5KJ/m2；It is further preferred that the impact strength >= 3KJ/m²；It is highly preferred that selected from elongation (elongation percentage) >=6.4% plastics, jewel, glass, rubber, mineral or nanometer material Material；It is further preferred that the plastics are selected from AES resin (acrylonitrile-EPDM rubber-styrol copolymer), AS resin (third Alkene nitrile-styrol copolymer), ABS plastic (acrylonitrile-butadiene-styrene copolymer), HDPE(high density polyethylene (HDPE)), LDPE(low density polyethylene (LDPE)), MDPE(medium density polyethylene), LLDPE(linear low density polyethylene), ULDPE(extremely-low density Polyethylene), 3 third polypropylene of PPR(), HIPS(high impact polystyrene), SMMA(styrene methyl methacrylate copolymerization Object), PVC(polyvinyl chloride), PET(polyethylene terephthalate), PETG(polyethylene terephthalate -1,4- ring Hexane diformazan alcohol ester), PBT(polybutylene terephthalate (PBT)), POM(acetal resin), PSU(polysulfones), the poly- carbonic acid of PC( Ester), PPO(polyphenylene oxide), PP(polypropylene), PES(polyethersulfone resin), PI(polyimides), PEI(polyetherimide), PEEK (polyether-ether-ketone), PTFE(polytetrafluoroethylene (PTFE)), PMMA(polymethyl methacrylate), PFA(Meltability polytetrafluorethyletubular), PPO (polyphenylene oxide or polyphenylene ether), PBT(polybutylene terephthalate (PBT)), PCT(poly terephthalic acid 1,4- hexamethylene Alkane diformazan alcohol ester), PCTG(armorphous copolyester), PPSU(polyphenylene sulphone resin), POE plastics (polyolefin elastomer), altogether Polyester, FRP(fiber-reinforced polymer), CPVC(chliorinated polyvinyl chloride), COC(cyclenes hydrocarbon type copolymer), UHMWPE(superelevation Molecular weight polyethylene), UPE(ultra high molecular polyethylene), -1 true qualities of TPX(poly 4-methylpene-1 monomer 4- methylpentene it is poly- 4- methylpentene -1), sarin resin, PVDF(Kynoar), EVA(ethylene-vinyl acetate copolymer), MS(styrene-first Base methyl acrylate copolymer)；
The jewel is selected from nephrite, Khotan jade, amphibole jade, Huanglong's jade, green lardite；
The glass is selected from tempered glass；
The rubber be selected from EPR(EP rubbers), NR(natural rubber), BR(butadiene rubber), SBR(butadiene-styrene rubber), IIR (butyl rubber), NBR(nitrile rubber), fluorubber, silica gel, TPR(thermoplastic elastomer), TPV(thermoplastic vulcanizates), TPO (thermoplastic polyolefin), TPE(1,1,2,2- tetraphenyl ethylene), TPEE(thermoplastic polyester elastomer), TPU(thermoplastic polyurethane Elastomer rubber)；
The mineral are selected from mica；
The nano material is selected from graphene.
Preferably, the frangible frangible material layer is fragile material, impact strength < 1.5KJ/m2 of the fragile material and is stretched Long rate (elongation percentage) < 5%；It is further preferred that impact strength < the 1KJ/m2 and elongation (elongation percentage) < 3% of fragile material； It is highly preferred that fragile material is selected from brick, stone material, ceramics, glass, concrete, cast iron, gypsum, calcite, natural marble, cunning Stone, lime stone, ceramics, fluorite, coloured glaze, white stone, emerald, emerald, moonstone, sunstone, Topaz, opal, coral, point Spar, smooth Sang Shi, demantoid, chrome diopside, tsavolite, cordierite, rosy quartz, apatite, amber, diamond, emerald, Tourmaline, sapphire, ruby, sea blue treasured, resin, crystal, quartz, garnet, agate, olivine, cat's eye, opal, south Positive jade, ice coloured silk calcedony, Lantian jade, malachite, chrysocolla, turquoise, Dongling stone, lapis lazuli；It is still more preferably glass； Much further preferably from ground glass.
Preferably, each layer of the complex layered materials is engaged by modes such as splicing, heating or pressurizations.
A kind of complex layered materials include from top to bottom top layer, bottom, are wherein additionally provided between top layer and bottom frangible Material layer and coat of colo(u)r.
Preferably, if the coat of colo(u)r is covered with single layer, coloring matter or the coat of colo(u)r with mobility are equipped with Dry partition is respectively respectively arranged with the coloring matter with mobility of identical or different color in partition；It is further preferred that institute The partition stated is uniform polygonal mesh；It is highly preferred that being hexagonal mesh or quadrilateral mesh.
Preferably, the coloring matter is selected from pigment, dyestuff or dissolved with the solution of pigments or dyes or lotion etc..
Preferably, the height of the insulating course material is identical as pigment layer height.
Preferably, the frangible frangible material layer can be ruptured, then the coat of colo(u)r is directly filled in institute in production Between the rupture stated, so that the coat of colo(u)r combines together with the frangible frangible material layer.
Preferably, the top layer, bottom or the material of partition are transparent or semitransparent toughness material.
Preferably, the impact strength of the toughness material >=1.5KJ/m2；It is further preferred that the impact strength >= 3KJ/m²；It is highly preferred that selected from elongation (elongation percentage) >=6.4% plastics, jewel, glass, rubber, mineral or nanometer material Material；It is further preferred that the plastics are selected from AES resin (acrylonitrile-EPDM rubber-styrol copolymer), AS resin (acrylonitritrile-styrene resin), ABS plastic (acrylonitrile-butadiene-styrene copolymer), HDPE(high density polyethylene (HDPE)), LDPE(low density polyethylene (LDPE)), MDPE(medium density polyethylene), LLDPE(linear low density polyethylene), ULDPE(extremely-low density Polyethylene), 3 third polypropylene of PPR(), HIPS(high impact polystyrene), SMMA(styrene methyl methacrylate copolymerization Object), PVC(polyvinyl chloride), PET(polyethylene terephthalate), PETG(polyethylene terephthalate -1,4- ring Hexane diformazan alcohol ester), PBT(polybutylene terephthalate (PBT)), POM(acetal resin), PSU(polysulfones), the poly- carbonic acid of PC( Ester), PPO(polyphenylene oxide), PP(polypropylene), PES(polyethersulfone resin), PI(polyimides), PEI(polyetherimide), PEEK (polyether-ether-ketone), PTFE(polytetrafluoroethylene (PTFE)), PMMA(polymethyl methacrylate), PFA(Meltability polytetrafluorethyletubular), PPO (polyphenylene oxide or polyphenylene ether), PBT(polybutylene terephthalate (PBT)), PCT(poly terephthalic acid 1,4- hexamethylene Alkane diformazan alcohol ester), PCTG(armorphous copolyester), PPSU(polyphenylene sulphone resin), POE plastics (polyolefin elastomer), altogether Polyester, FRP(fiber-reinforced polymer), CPVC(chliorinated polyvinyl chloride), COC(cyclenes hydrocarbon type copolymer), UHMWPE(superelevation Molecular weight polyethylene), UPE(ultra high molecular polyethylene), -1 true qualities of TPX(poly 4-methylpene-1 monomer 4- methylpentene it is poly- 4- methylpentene -1), sarin resin, PVDF(Kynoar), EVA(ethylene-vinyl acetate copolymer), MS(styrene-first Base methyl acrylate copolymer)；
The jewel is selected from nephrite, Khotan jade, amphibole jade, Huanglong's jade, green lardite；
The glass is selected from tempered glass；
The rubber be selected from EPR(EP rubbers), NR(natural rubber), BR(butadiene rubber), SBR(butadiene-styrene rubber), IIR (butyl rubber), NBR(nitrile rubber), fluorubber, silica gel, TPR(thermoplastic elastomer), TPV(thermoplastic vulcanizates), TPO (thermoplastic polyolefin), TPE(1,1,2,2- tetraphenyl ethylene), TPEE(thermoplastic polyester elastomer), TPU(thermoplastic polyurethane Elastomer rubber)；
The mineral are selected from mica；
The nano material is selected from graphene.
Preferably, each layer of the complex layered materials is engaged by modes such as splicing, pressurization or heating.
Preferably, the side of the complex layered materials is additionally provided with bound edge for sealing coat of colo(u)r.
It is further preferred that the material of the bound edge is toughness material.
A kind of preparation method of above-mentioned complex layered materials includes the following steps: to be laid with bottom and top layer, in top layer and bottom Frangible frangible material layer and coat of colo(u)r are placed between layer；The position that is connected between each layer is equipped with binder.
Preferably, the complex layered materials are being heated under vacuum conditions, are being pressurizeed.
It is further preferred that heating temperature is 90 DEG C~130 DEG C；When pressure is 1Mpa~1Mpa, heating and pressurization Between be 1h~1.5h.
Preferably, complex layered materials are subjected to bound edge, the bound edge material is toughness material.
The present invention also provides a kind of above-mentioned complex layered materials to be used as product subsurface material, product packaging material, ornament The purposes of material.
Preferably, the product surface material is selected from electronic equipment casing material, furniture alien invasion, cosmetics containers table Plane materiel material, ornament etc..
The invention has the following advantages: the present invention provides a kind of complex layered materials and its preparation method and application, The stratified material can satisfy the public demand unique for material.Its outer layer is resistance to be fallen, and can be matched after frangible layer is broken It closes coat of colo(u)r and generates unique decorative pattern, wherein the broken of frangible frangible material layer can be also voluntarily complete by consumer by producer's completion At.The present invention makes have unique appearance using product made of material provided by the invention.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of a preferred embodiment of complex layered materials shown in the present invention.
Fig. 2 be include internal layer complex layered materials of the present invention structural schematic diagram.
Fig. 3 (a) is the structural schematic diagram of another preferred embodiment of complex layered materials shown in the present invention.
Fig. 3 (b) is the structural schematic diagram of another preferred embodiment of complex layered materials shown in the present invention.
Fig. 3 (c) is the binding structure schematic diagram of complex layered materials shown in the present invention.
Fig. 4 (a) is a coat of colo(u)r partition-type structures schematic diagram of complex layered materials shown in the present invention.
Fig. 4 (b) is another coat of colo(u)r partition-type structures schematic diagram of complex layered materials shown in the present invention.
Appended drawing reference: 21- outer layer；22- frangible frangible material layer；23- coat of colo(u)r；24- internal layer；31- top layer；32- friable material Layer；33- coat of colo(u)r；34- bottom；4- partition；5- bound edge.
Specific embodiment
Specific embodiments of the present invention will be further explained with reference to the accompanying drawing.It should be noted that for The explanation of these embodiments is used to help understand the present invention, but does not constitute the restriction to invention.In addition, disclosed below Technical characteristic involved in each embodiment of the invention can be combined with each other as long as they do not conflict with each other.
Embodiment one
As shown in Figure 1, a kind of complex layered materials proposed by the present invention, successively include outer layer 21, frangible frangible material layer from outside to inside 22 and coat of colo(u)r 23.Outer layer 21 is transparent or semitransparent toughness material, so that the lines that frangible frangible material layer 22 ruptures passes through face Color preferably shows, and has aesthetic feeling.Outer layer 21 is that transparent material is conducive to clearly indicate intermediate frangible frangible material layer 22 Ruptured type and color change.
In the present embodiment, coat of colo(u)r 23 is covered with the solution of solvent and pigment powder composition.Coat of colo(u)r 23 with a thickness of frangible material / 10th of the bed of material 22 so that its with 22 fiting effect of frangible frangible material layer more preferably.
In the present embodiment, outer layer 21 is the transparent PET that impact strength is 5.7KJ/m2 and elongation (elongation percentage) is 8% (polyethylene terephthalate), frangible frangible material layer 22 are that impact strength is 1.4KJ/m2 and elongation (elongation percentage) is 1.8% Ground glass, the present embodiment is suitable for doing the skin-material of product, such as articles for daily use, electronic product shell, toy；It is also suitable In the packaging material for doing product, such as skin care item outer packing, cosmetics outer packing, packing box.
Embodiment two
The difference of itself and embodiment one is: in the present embodiment, outer layer 21 is the translucent nephrite that impact strength is 1.5KJ/m2, Frangible frangible material layer 22 is the emerald that impact strength is 0.9KJ/m2 and elongation (elongation percentage) is 2.9%, and the present embodiment is suitable for Do ornament material, such as bangle, necklace, ring, pendant, brooch, the art work and ornament.Producing the complex layered materials When, the producer just can rupture frangible frangible material layer 22 in production, so that the lines of rupture is more evenly good-looking, then by coat of colo(u)r 23 directly fill between the rupture, so that coat of colo(u)r 23 combines together with the frangible frangible material layer.Due to the treasure of jewel Your property, and it is hit due to toughness and little, such as sharppointed article, still has the possibility of rupture, therefore the producer is in production Just frangible frangible material layer 22 is ruptured, better effect, to allow user preferably to save it.
Embodiment three
The difference of itself and embodiment one is: in the present embodiment, outer layer 21 is that the transparent PMMA(that impact strength is 11KJ/m2 is poly- Methyl methacrylate), frangible frangible material layer 22 is the ceramics that impact strength is 0.4KJ/m2 and elongation (elongation percentage) is 1.8%, The present embodiment is suitable for doing the surfacing of dinnerware article class, such as bowl tool, plate, chopsticks.
Example IV
The difference of itself and embodiment one is: in the present embodiment, outer layer 21 is the transparent mica that impact strength is 3KJ/m2, frangible Material layer 22 is the moonstone that impact strength is 0.2KJ/m2 and elongation (elongation percentage) is 1.1%, which is suitable for filling The surfacing of decorations property product, such as decorative dial plate, bracelet, pendant, craftwork.
Embodiment five
The difference of itself and embodiment one is: in the present embodiment, outer layer 21 is the translucent NBR that impact strength is 7.1KJ/m2 (nitrile rubber), frangible frangible material layer 22 are the gypsum that impact strength is 0.8KJ/m2 and elongation (elongation percentage) is 1.6%, this reality The protection surfacing that example is suitable for doing product is applied, such as electronic product valve jacket, the product external surfaces etc. of articles for daily use.
Embodiment six
The difference of itself and embodiment one is: in the present embodiment, as shown in Fig. 2, complex layered materials further include internal layer 24, internal layer 24 are set to the inside of coat of colo(u)r 23.Internal layer 24 is used to support coat of colo(u)r 23, so that it is guaranteed that 23 stable structure of coat of colo(u)r.
Embodiment seven
The difference of itself and any of the above-described embodiment is: coat of colo(u)r 23 is equipped with several partitions 4, is respectively arranged in each partition 4 The coloring matter with mobility of identical or different color.In the present embodiment, the material for separating 3 is transparent TPR(thermoplasticity Rubber).In the present embodiment, separate 4 for hexagonal mesh (referring to fig. 4 (a)) or quadrilateral mesh (referring to fig. 4 (b)), uniformly And rule, it can preferably make the structure for protecting upper and lower level, and it can make that different colours coloring matter is arranged in each partition, from And keep the color of coat of colo(u)r richer, more various, unique also more attractive.
Embodiment eight
Another complex layered materials that the present invention also proposes include top layer 31, bottom 34, wherein top layer 31 and bottom from top to bottom Frangible frangible material layer 32 and coat of colo(u)r 33 are additionally provided between layer 34.The sequence of frangible frangible material layer 32 and coat of colo(u)r 33 is to can be interchanged , referring to Fig. 3 (a) and Fig. 3 (b).As shown in Fig. 3 (a), from top to bottom according to this are as follows: top layer 31, frangible frangible material layer 32, coat of colo(u)r 33, bottom 34.As shown in Figure 3 (b), from top to bottom according to this are as follows: top layer 31, coat of colo(u)r 33, frangible frangible material layer 32, bottom 34.This Embodiment is suitable for doing the skin-material of product, such as desk, chair, floor, metope, window face and furniture, to increase product Uniqueness, aesthetics and interest.
In the present embodiment, top layer 31 is the transparent graphene that impact strength is 14.3KJ/m2, and frangible frangible material layer 32 is impact The marble that intensity is 1.4KJ/m2 and elongation (elongation percentage) is 4.9%, the embodiment are suitable for making decorative screen etc..
In the present embodiment, coat of colo(u)r 33 is covered with the solution of solvent and pigment powder composition.Coat of colo(u)r 33 with a thickness of frangible material / 8th of the bed of material 32 so that its with 32 fiting effect of frangible frangible material layer more preferably.
Embodiment nine
The difference of itself and embodiment eight is: in the present embodiment, as shown in Figure 3 (c), the side of complex layered materials is additionally provided with packet Side 5 is for sealing coat of colo(u)r 33.In the present embodiment, the material of bound edge 5 is PVC(polyvinyl chloride), it can be preferably closely sealed compound The side of stratified material.The material selection of bound edge 5 can be consistent with top layer 31, and the material different from top layer 32 also may be selected Material.
Embodiment ten
The difference of itself and embodiment eight or embodiment nine is: coat of colo(u)r 33 is equipped with several partitions 4, sets respectively in each partition 4 It is equipped with the coloring matter with mobility of identical or different color.In the present embodiment, it is poly- for transparent PC(to separate 3 material Carbonic ester).In the present embodiment, referring to fig. 4 (a), partition 4 is hexagonal mesh.Referring to fig. 4 (b), partition 4 is quadrilateral mesh. It is uniformly and regular, can preferably make the structure for protecting upper and lower level, and it can make setting different colours in each partition coloured Substance, to keep the color of coat of colo(u)r richer, more various, unique also more attractive.
In the present embodiment, separate 4 height it is identical as 23 height of coat of colo(u)r.Surroundings are closed when there is partition 4 and separate 4 When, since it can be very good protection coat of colo(u)r, there is no need to bound edge 5 is arranged again.
This hair can be understood and applied the above description of the embodiments is intended to facilitate those skilled in the art It is bright.Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein General Principle is applied in other embodiments without having to go through creative labor.Therefore, the present invention is not limited to implementations here Example, those skilled in the art's announcement according to the present invention, improvement and modification made without departing from the scope of the present invention all should be Within protection scope of the present invention.

Claims (10)

1. a kind of complex layered materials, it is characterised in that: from outside to inside successively include outer layer, frangible frangible material layer and coat of colo(u)r, institute The outer layer stated is transparent or semitransparent toughness material；
Preferably, the complex layered materials further include internal layer, and the internal layer is set to the inside of coat of colo(u)r, and described is interior Layer is used to support coat of colo(u)r, so that it is guaranteed that coat of colo(u)r stable structure；
Preferably, the coat of colo(u)r is covered with coloring matter or the coat of colo(u)r of the single layer with mobility equipped with several Separate, the coloring matter with mobility of identical or different color is respectively arranged in each partition；
It is further preferred that the coloring matter is selected from pigment, dyestuff or dissolved with the solution of pigments or dyes or lotion etc.；
It is further preferred that the height of the partition is identical as pigment layer height；
It is further preferred that the partition is uniform polygonal mesh；It is highly preferred that the partition is hexagonal mesh Or quadrilateral mesh.
2. a kind of complex layered materials according to claim 1, it is characterised in that: the outer layer, internal layer or partition Material is selected from transparent or semitransparent toughness material；
Preferably, the impact strength of the toughness material >=1.5KJ/m2；
It is further preferred that the impact strength of the toughness material >=3KJ/m2；
It is highly preferred that selected from elongation (elongation percentage) >=6.4% plastics, jewel, glass, rubber, mineral or nano material；
It is further preferred that the plastics are selected from AES resin (acrylonitrile-EPDM rubber-styrol copolymer), AS resin (acrylonitritrile-styrene resin), ABS plastic (acrylonitrile-butadiene-styrene copolymer), HDPE(high density polyethylene (HDPE)), LDPE(low density polyethylene (LDPE)), MDPE(medium density polyethylene), LLDPE(linear low density polyethylene), ULDPE(extremely-low density Polyethylene), 3 third polypropylene of PPR(), HIPS(high impact polystyrene), SMMA(styrene methyl methacrylate copolymerization Object), PVC(polyvinyl chloride), PET(polyethylene terephthalate), PETG(polyethylene terephthalate -1,4- ring Hexane diformazan alcohol ester), PBT(polybutylene terephthalate (PBT)), POM(acetal resin), PSU(polysulfones), the poly- carbonic acid of PC( Ester), PPO(polyphenylene oxide), PP(polypropylene), PES(polyethersulfone resin), PI(polyimides), PEI(polyetherimide), PEEK (polyether-ether-ketone), PTFE(polytetrafluoroethylene (PTFE)), PMMA(polymethyl methacrylate), PFA(Meltability polytetrafluorethyletubular), PPO (polyphenylene oxide or polyphenylene ether), PBT(polybutylene terephthalate (PBT)), PCT(poly terephthalic acid 1,4- hexamethylene Alkane diformazan alcohol ester), PCTG(armorphous copolyester), PPSU(polyphenylene sulphone resin), POE plastics (polyolefin elastomer), altogether Polyester, FRP(fiber-reinforced polymer), CPVC(chliorinated polyvinyl chloride), COC(cyclenes hydrocarbon type copolymer), UHMWPE(superelevation Molecular weight polyethylene), UPE(ultra high molecular polyethylene), -1 true qualities of TPX(poly 4-methylpene-1 monomer 4- methylpentene it is poly- 4- methylpentene -1), sarin resin, PVDF(Kynoar), EVA(ethylene-vinyl acetate copolymer), MS(styrene-first Base methyl acrylate copolymer)；
The jewel is selected from nephrite, Khotan jade, amphibole jade, Huanglong's jade, green lardite；
The glass is selected from tempered glass；
The rubber be selected from EPR(EP rubbers), NR(natural rubber), BR(butadiene rubber), SBR(butadiene-styrene rubber), IIR (butyl rubber), NBR(nitrile rubber), fluorubber, silica gel, TPR(thermoplastic elastomer), TPV(thermoplastic vulcanizates), TPO (thermoplastic polyolefin), TPE(1,1,2,2- tetraphenyl ethylene), TPEE(thermoplastic polyester elastomer), TPU(thermoplastic polyurethane Elastomer rubber)；
The mineral are selected from mica；
The nano material is selected from graphene.
3. a kind of complex layered materials according to claim 1, it is characterised in that: the frangible frangible material layer is brittleness material Material, the impact strength < 1.5KJ/m2 and elongation (elongation percentage) < 5% of the fragile material；
Preferably, impact strength < 1KJ/m2 of the fragile material and elongation (elongation percentage) < 3%；
It is further preferred that the fragile material is selected from brick, stone material, ceramics, glass, concrete, cast iron, gypsum, calcite, day Right marble, talcum, lime stone, ceramics, fluorite, coloured glaze, white stone, emerald, emerald, moonstone, sunstone, Topaz, Opal, coral, spinelle, smooth Sang Shi, demantoid, chrome diopside, tsavolite, cordierite, rosy quartz, apatite, amber Amber, diamond, emerald, tourmaline, sapphire, ruby, sea blue treasured, resin, crystal, quartz, garnet, agate, olivine, opal Stone, opal, Nanyang jade, ice coloured silk calcedony, Lantian jade, malachite, chrysocolla, turquoise, Dongling stone, lapis lazuli；More preferably Ground, the fragile material are glass；It is further preferred that the fragile material is ground glass.
4. a kind of complex layered materials according to claim 1, it is characterised in that: the outer layer, frangible frangible material layer, pigment Layer is engaged by modes such as splicing, heating or pressurizations or the outer layer, frangible frangible material layer, coat of colo(u)r, internal layer are by being glued or adding The modes such as heat or pressurization engage.
5. a kind of complex layered materials include from top to bottom top layer, bottom, frangible material are wherein additionally provided between top layer and bottom The bed of material and coat of colo(u)r；
Preferably, the coat of colo(u)r is covered with coloring matter or the coat of colo(u)r of the single layer with mobility equipped with several Separate, the coloring matter with mobility of identical or different color is respectively arranged in each partition；
It is further preferred that the coloring matter is selected from pigment, dyestuff or dissolved with the solution of pigments or dyes or lotion etc.；
It is further preferred that the height of the partition is identical as pigment layer height；
It is further preferred that the partition is uniform polygonal mesh；It is highly preferred that the partition is hexagonal mesh Or quadrilateral mesh；
Preferably, the side of the complex layered materials is additionally provided with bound edge, and the bound edge is for sealing coat of colo(u)r；
It is further preferred that the bound edge is toughness material.
6. a kind of complex layered materials according to claim 5, it is characterised in that: top layer, bottom, partition or the packet The material on side is transparent or semitransparent toughness material；
Preferably, the impact strength of the toughness material >=1.5KJ/m2；
It is further preferred that the impact strength of the toughness material >=3KJ/m2；
It is highly preferred that selected from elongation (elongation percentage) >=6.4% plastics, jewel, glass, rubber, mineral or nano material；
It is further preferred that the plastics are selected from AES resin (acrylonitrile-EPDM rubber-styrol copolymer), AS resin (acrylonitritrile-styrene resin), ABS plastic (acrylonitrile-butadiene-styrene copolymer), HDPE(high density polyethylene (HDPE)), LDPE(low density polyethylene (LDPE)), MDPE(medium density polyethylene), LLDPE(linear low density polyethylene), ULDPE(extremely-low density Polyethylene), 3 third polypropylene of PPR(), HIPS(high impact polystyrene), SMMA(styrene methyl methacrylate copolymerization Object), PVC(polyvinyl chloride), PET(polyethylene terephthalate), PETG(polyethylene terephthalate -1,4- ring Hexane diformazan alcohol ester), PBT(polybutylene terephthalate (PBT)), POM(acetal resin), PSU(polysulfones), the poly- carbonic acid of PC( Ester), PPO(polyphenylene oxide), PP(polypropylene), PES(polyethersulfone resin), PI(polyimides), PEI(polyetherimide), PEEK (polyether-ether-ketone), PTFE(polytetrafluoroethylene (PTFE)), PMMA(polymethyl methacrylate), PFA(Meltability polytetrafluorethyletubular), PPO (polyphenylene oxide or polyphenylene ether), PBT(polybutylene terephthalate (PBT)), PCT(poly terephthalic acid 1,4- hexamethylene Alkane diformazan alcohol ester), PCTG(armorphous copolyester), PPSU(polyphenylene sulphone resin), POE plastics (polyolefin elastomer), altogether Polyester, FRP(fiber-reinforced polymer), CPVC(chliorinated polyvinyl chloride), COC(cyclenes hydrocarbon type copolymer), UHMWPE(superelevation Molecular weight polyethylene), UPE(ultra high molecular polyethylene), -1 true qualities of TPX(poly 4-methylpene-1 monomer 4- methylpentene it is poly- 4- methylpentene -1), sarin resin, PVDF(Kynoar), EVA(ethylene-vinyl acetate copolymer), MS(styrene-first Base methyl acrylate copolymer)；
The jewel is selected from nephrite, Khotan jade, amphibole jade, Huanglong's jade, green lardite；
The glass is selected from tempered glass；
The rubber be selected from EPR(EP rubbers), NR(natural rubber), BR(butadiene rubber), SBR(butadiene-styrene rubber), IIR (butyl rubber), NBR(nitrile rubber), fluorubber, silica gel, TPR(thermoplastic elastomer), TPV(thermoplastic vulcanizates), TPO (thermoplastic polyolefin), TPE(1,1,2,2- tetraphenyl ethylene), TPEE(thermoplastic polyester elastomer), TPU(thermoplastic polyurethane Elastomer rubber)；
The mineral are selected from mica；
The nano material is selected from graphene.
7. a kind of complex layered materials according to claim 5, it is characterised in that: the frangible frangible material layer is brittleness material Material, the impact strength < 1.5KJ/m2 and elongation (elongation percentage) < 5% of the fragile material；
Preferably, impact strength < 1KJ/m2 of the fragile material and elongation (elongation percentage) < 3%；
It is further preferred that the fragile material is selected from brick, stone material, ceramics, glass, concrete, cast iron, gypsum, calcite, day Right marble, talcum, lime stone, ceramics, fluorite, coloured glaze, white stone, emerald, emerald, moonstone, sunstone, Topaz, Opal, coral, spinelle, smooth Sang Shi, demantoid, chrome diopside, tsavolite, cordierite, rosy quartz, apatite, amber Amber, diamond, emerald, tourmaline, sapphire, ruby, sea blue treasured, resin, crystal, quartz, garnet, agate, olivine, opal Stone, opal, Nanyang jade, ice coloured silk calcedony, Lantian jade, malachite, chrysocolla, turquoise, Dongling stone, lapis lazuli；More preferably Ground, the fragile material are glass；It is further preferred that the fragile material is ground glass.
8. a kind of complex layered materials according to claim 5, it is characterised in that: the top layer of the complex layered materials, Frangible frangible material layer, coat of colo(u)r, bottom and bound edge are engaged by modes such as splicing, pressurization or heating.
9. a kind of preparation method of above-mentioned complex layered materials includes the following steps: to be laid with bottom and top layer, in top layer and bottom Between place frangible frangible material layer and coat of colo(u)r；The position that is connected between each layer is equipped with binder；
Preferably, complex layered materials are subjected to bound edge；
Preferably, the complex layered materials heated under vacuum conditions, pressurizeed；
It is further preferred that heating temperature is 90 DEG C~130 DEG C；Pressure is 1Mpa~1Mpa, heats and pressing time is 1h~1.5h.
10. the present invention also provides a kind of complex layered materials to be used as product subsurface material, product packaging material, ornament material The purposes of material；Preferably, the product surface material is selected from electronic equipment casing material, furniture alien invasion, cosmetics containers Surfacing or ornament.
CN201811549799.4A 2018-12-18 2018-12-18 A kind of complex layered materials and its preparation method and application Pending CN109367161A (en)

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CN112280273A (en) * 2020-10-16 2021-01-29 金发科技股份有限公司 PMMA/ionomer/PC ternary alloy and preparation method thereof
CN117285813A (en) * 2023-09-14 2023-12-26 广州敬信高聚物科技有限公司 Wire and cable material for new energy automobile charging pile

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CN201669942U (en) * 2010-05-17 2010-12-15 马义贵 Glass composite board
CN104553207A (en) * 2014-12-12 2015-04-29 中国航空工业集团公司北京航空材料研究院 Safety glass capable of preventing splashing during breaking

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CN1740828A (en) * 2004-08-24 2006-03-01 大日本网目版制造株式会社 Method of forming colored layers of color image display unit
CN201669942U (en) * 2010-05-17 2010-12-15 马义贵 Glass composite board
CN104553207A (en) * 2014-12-12 2015-04-29 中国航空工业集团公司北京航空材料研究院 Safety glass capable of preventing splashing during breaking

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CN110100598A (en) * 2019-03-04 2019-08-09 上海亮籽智能科技有限公司 A kind of implant bed
CN112280273A (en) * 2020-10-16 2021-01-29 金发科技股份有限公司 PMMA/ionomer/PC ternary alloy and preparation method thereof
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CN117285813A (en) * 2023-09-14 2023-12-26 广州敬信高聚物科技有限公司 Wire and cable material for new energy automobile charging pile
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