CN109354417B - NaTbF is separated out4Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof - Google Patents
NaTbF is separated out4Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof Download PDFInfo
- Publication number
- CN109354417B CN109354417B CN201811563087.8A CN201811563087A CN109354417B CN 109354417 B CN109354417 B CN 109354417B CN 201811563087 A CN201811563087 A CN 201811563087A CN 109354417 B CN109354417 B CN 109354417B
- Authority
- CN
- China
- Prior art keywords
- glass
- natbf
- germanosilicate
- melting
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011521 glass Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 239000002241 glass-ceramic Substances 0.000 claims abstract description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- 238000002844 melting Methods 0.000 claims abstract description 13
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910004299 TbF3 Inorganic materials 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 9
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 9
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 9
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 9
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 9
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000002425 crystallisation Methods 0.000 claims abstract description 4
- 230000008025 crystallization Effects 0.000 claims abstract description 4
- 238000000137 annealing Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 239000000156 glass melt Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 2
- LKNRQYTYDPPUOX-UHFFFAOYSA-K trifluoroterbium Chemical compound F[Tb](F)F LKNRQYTYDPPUOX-UHFFFAOYSA-K 0.000 claims description 2
- 239000006121 base glass Substances 0.000 abstract description 11
- 238000010791 quenching Methods 0.000 abstract description 2
- 230000000171 quenching effect Effects 0.000 abstract description 2
- 238000004455 differential thermal analysis Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 14
- 239000013078 crystal Substances 0.000 description 9
- -1 rare earth ions Chemical class 0.000 description 9
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 4
- 239000013081 microcrystal Substances 0.000 description 4
- 229910052863 mullite Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000002910 rare earth metals Chemical class 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- LBCIOIBZLPJTGC-UHFFFAOYSA-N [Ge].[O].[F] Chemical compound [Ge].[O].[F] LBCIOIBZLPJTGC-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002189 fluorescence spectrum Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000075 oxide glass Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/16—Halogen containing crystalline phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Dispersion Chemistry (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a method for separating out NaTbF4Nanocrystalline germanosilicate glass ceramics and a preparation method thereof. The microcrystalline glass comprises the following components in percentage by mole: GeO2:20~50%、SiO2:15~35%、Al2O3:5~10%、Na2CO3:10~15%、TbF33-10% and 15-20% of NaF. The preparation method of the microcrystalline glass comprises the following steps: weighing a certain mass of raw materials according to the mol percentage, fully grinding and uniformly mixing, and preparing the base glass by adopting a melting quenching method. Obtaining the thermal property of the base glass by adopting a differential thermal analysis test, and thermally treating the base glass for a plurality of hours in a crystallization temperature range to obtain the glass containing NaTbF4Nanocrystalline germanosilicate glass-ceramics. The microcrystalline glass prepared by the invention has simple preparation method, and single beta-phase NaTbF is precipitated4Crystalline phase and has high transparency.
Description
Technical Field
The invention relates to the technical field of rare earth luminescent materials, in particular to a method for separating out NaTbF4Nanocrystalline germanosilicate glass ceramics and a preparation method thereof.
Background
Microcrystalline glass, a new material with complementary advantages of combining microcrystal grains and a glass matrix, has led researchers in the field of functional glass and ceramics to make extensive research. In recent years, oxyfluoride microcrystalline glass is favored as a novel microcrystalline glass, in which rare earth-doped oxyfluoride glass is embedded in an oxide glass matrix to form fluoride nano-crystallites under a certain heat treatment condition, and rare earth ions are preferentially concentrated in the fluoride crystallites. The glass with the structure not only keeps the excellent physical and chemical properties of the oxide, but also provides a lower phonon energy environment for rare earth ions by the generation of the fluoride nano-microcrystal, thereby enhancing the luminous efficiency. The crystallite size of the microcrystallized glass is smaller, generally dozens of nanometers, and the scattering phenomenon of energy loss is effectively reduced due to the fact that the matched refractive index exists between the microcrystals and the glass matrix, so that the microcrystalline glass still keeps higher transmittance.
Terbium ion (Tb)3+) The transition mode belongs to a typical 4f-4f energy level transition mode, and compared with other rare earth elements, the rare earth element has high quenching concentration and strong light emission. Due to Tb3+The 4f electron layer is protected by the outer layer orbit, so that the influence of the external environment is small, and meanwhile, the energy level difference between the 4f electron layer is small, so Tb is3+The energy transfer efficiency of (2) is high, and the fluorescence spectrum shows a sharp line shape. Tb3+The fluorescence has longer decay time, generally in the millisecond level, so the fluorescence can be applied to the detection of slow events, in addition, the fluorescence has stronger capability of bearing high-energy rays and shows stronger green light emission, and can be used for high-energy ray conversion and the like.
The research of the rare earth doped microcrystalline glass is relatively extensive. Generally, after rare earth doped glass is prepared, rare earth ions are preferentially enriched into a fluoride crystal phase through heat treatment, and the rare earth ions serving as a luminescence center are not part of the crystal phase generally. Since the radius of the luminescent ion is usually different from the lattice constant or ionic radius of the crystal phase, it is easy to control whether the luminescent ion is totally incorporated into the crystal phase or the crystal lattice is distorted. Therefore, the luminescent rare earth ions can be controlled to be part of the crystal lattice, and the problem that whether the rare earth ions enter the crystal phase or not does not need to be considered, but the crystal phase exists, namely the rare earth ions are in the crystal phase, so that the optical quality (transparency and the like) of the glass ceramics can be greatly improved. The lattice sites occupied by the rare earth ions in the beta-phase rare earth tetrafluoride are stable, and the luminous efficiency is higher. Therefore, the beta-phase NaTbF can be precipitated in the glass4Obtained to have Tb3+The microcrystalline glass has higher luminous efficiency.
Disclosure of Invention
The invention aims to solve the technical problem of providing a NaTbF-containing material4A novel fluorine oxygen germanium silicate microcrystalline glass of nano crystal and a preparation method thereof. Preparation process of microcrystalline glassSimple and separate out single beta-phase NaTbF4Crystalline phase and the microcrystalline glass has high transparency. The specific technical scheme is as follows:
NaTbF is separated out4The nanocrystalline germanosilicate microcrystalline glass is prepared from the following raw materials in percentage by mol: GeO2: 20~50%，SiO2: 15~35%，Al2O3: 5~10%，Na2O: 10~15%，TbF3: 3~10%，NaF: 15~20%。
Another object of the present invention is to provide a method for precipitating NaTbF4The preparation method of the novel oxyfluoride germanosilicate microcrystal of the nanocrystalline specifically comprises the following steps:
1) preparing materials: with GeO2，SiO2，Al2O3，Na2CO3，TbF3NaF is a glass composition raw material, and the raw materials with corresponding mass are weighed according to the selected mole percentage of the glass composition and are ground and mixed uniformly in a mortar;
2) melting: pouring the glass raw materials which are ground and mixed uniformly into a crucible, and putting the crucible into a silicon carbide rod electric furnace for melting, wherein the melting temperature is 1450-1550 ℃, and the melting time is 30-60 minutes;
3) molding: pouring the glass melt into a mold preheated to 450-550 ℃;
4) annealing: putting the formed glass into a muffle furnace for annealing at the temperature of 450-550 DEG CoAnd C, annealing for 2-4 hours. Then, a power supply of the muffle furnace is closed and cooled to room temperature along with the furnace;
5) and (3) heat treatment: putting the annealed initial glass into a muffle furnace, and carrying out crystallization at a crystallization temperature range (590-700℃)oC) Heat treatment for several hours;
6) polishing: and cutting, grinding and polishing the heat-treated glass to prepare the microcrystalline glass with the thickness of 10mm by 1.5 mm.
Drawings
Fig. 1 is an XRD pattern of the glass ceramics prepared in example 1 provided by the present invention.
Detailed Description
The invention will be further explained with reference to the drawings.
Example 1:
according to the composition: 30GeO2-25SiO2-8Al2O312Na2CO3-6TbF3-19NaF (mol%) the desired GeO is weighed out in a total mass of 20 g2、SiO2、Al2O3、Na2CO3、TbF3And the NaF powder raw material is put into an agate mortar to be fully ground and uniformly mixed. Pouring the uniformly mixed glass raw materials into a crucible, covering with a mullite cover, and placing at 1450oMelting for 40 minutes in a C silicon carbide rod electric furnace, and then quickly pouring the glass melt into a preheating furnace of 450 DEG CoC in the mold, after the glass is formed, the glass is turned into 550oAnd C, annealing for 2 hours in a muffle furnace, and naturally cooling to room temperature to obtain the base glass. The base glass obtained is placed in a muffle furnace at 10oThe temperature rise rate of C/min is increased to 610oC, preserving the heat for 2 hours to obtain the product containing NaTbF4Nanocrystalline germanosilicate glass-ceramics. And cutting, grinding and polishing the obtained glass ceramics to prepare the glass ceramics with the thickness of 10mm by 1.5 mm.
In this example, a composition containing NaTbF4XRD of nanocrystalline germanosilicate microcrystalline glass is shown in fig. 1.
Example 2:
according to the composition: 40GeO2-20SiO2-5Al2O3-15Na2CO3-4TbF315NaF (mol%) the desired GeO was weighed out in a total mass of 20 g2、SiO2、Al2O3、Na2CO3、TbF3And the NaF powder raw material is put into an agate mortar to be fully ground and uniformly mixed. Pouring the uniformly mixed glass raw materials into a crucible, covering a mullite cover, and placing at 1460oMelting for 45 minutes in a C silicon carbide rod electric furnace, and then quickly pouring the glass melt into a preheating 480oC in the mold, after the glass is formed, the glass is turned into 550oAnd C, annealing for 2 hours in a muffle furnace, and naturally cooling to room temperature to obtain the base glass. The base glass obtained is placed in a muffle furnace at 10oThe temperature rise rate of C/min is increased to 630oC, keeping the temperature for 2 hours to obtainTo contain NaTbF4Nanocrystalline germanosilicate glass-ceramics. The obtained glass ceramics are cut, ground and polished to be made into 10mm 1.5 mm.
Example 3:
according to the composition: 50GeO2-20SiO2-7Al2O3-13Na2CO3-5TbF315NaF (mol%) the desired GeO was weighed out in a total mass of 20 g2、SiO2、Al2O3、Na2CO3、TbF3And the NaF powder raw material is put into an agate mortar to be fully ground and uniformly mixed. Pouring the uniformly mixed glass raw materials into a crucible, covering a mullite cover, and placing the crucible at 1500 DEG CoMelting for 60 minutes in a C silicon carbide rod electric furnace, and then rapidly pouring the glass melt into a preheating furnace 500oC, in the mold, the glass is turned into 520 after being formedoAnd C, annealing for 3 hours in a muffle furnace, and naturally cooling to room temperature to obtain the base glass. The base glass obtained is placed in a muffle furnace at 10oThe temperature rise rate of C/min is increased to 650oC, preserving the heat for 1.5h to obtain the NaTbF-containing material4Nanocrystalline germanosilicate glass-ceramics. And cutting, grinding and polishing the obtained glass ceramics to prepare the glass ceramics with the thickness of 10mm by 1.5 mm.
Example 4:
according to the composition: 30GeO2-30SiO2-5Al2O3-10Na2CO3-5TbF3-20NaF (mol%) the desired GeO is weighed out in a total mass of 20 g2、SiO2、Al2O3、Na2CO3、TbF3And the NaF powder raw material is put into an agate mortar to be fully ground and uniformly mixed. Pouring the uniformly mixed glass raw materials into a crucible, covering the crucible with a mullite cover, and placing the crucible at 1550 DEGoMelting for 35 minutes in a C silicon carbide rod electric furnace, and then quickly pouring glass melt into a preheating chamber 510oC in the mold, after the glass is formed, the glass is transferred into a mold 540oAnd C, annealing for 3 hours in a muffle furnace, and naturally cooling to room temperature to obtain the base glass. The base glass obtained is placed in a muffle furnace at 10oThe temperature rise rate of C/min is increased to 670oC, preserving the heat for 1.5h to obtain the NaTbF-containing material4Nanocrystalline germanosilicate glass-ceramics. And cutting, grinding and polishing the obtained glass ceramics to prepare the glass ceramics with the thickness of 10mm by 1.5 mm.
The above-described embodiments are intended to illustrate rather than to limit the invention, and any modifications and variations of the present invention are within the spirit of the invention and the scope of the appended claims.
Claims (1)
1. NaTbF is separated out4The preparation method of the nanocrystalline germanosilicate glass ceramics comprises the following raw materials in percentage by mol:
the component mol%
GeO2 20~50%
SiO2 15~35%
Al2O3 5~10%
Na2CO3 10~15%
TbF3 3~10%
NaF 15~20%；
The method is characterized by comprising the following steps:
1) preparing materials: with GeO2，SiO2，Al2O3，Na2CO3，TbF3The NaF is a glass composition raw material, and the raw materials with corresponding mass are weighed according to the selected mole percentage composition of the glass raw material and are ground and mixed uniformly in a mortar;
2) melting: pouring the glass raw material which is ground and mixed uniformly into a crucible, and putting the crucible into a silicon carbide rod electric furnace for melting, wherein the melting temperature is 1450-1550 DEG CoC, melting time is 30-60 minutes;
3) molding: pouring the glass melt into a preheating furnace with the temperature of 450-550 DEG CoC in the mold;
4) annealing: glass to be shapedPutting the mixture into a muffle furnace for annealing at the temperature of 450-550 DEG CoC, annealing for 2-4 hours, and then closing a power supply of the muffle furnace to cool to room temperature along with the furnace;
5) and (3) heat treatment: at a crystallization temperature of 590-700 deg.Co590-700 of C rangeoC, carrying out heat treatment for several hours;
6) polishing: and cutting, grinding and polishing the heat-treated glass to prepare the microcrystalline glass with the thickness of 10mm by 1.5 mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811563087.8A CN109354417B (en) | 2018-12-20 | 2018-12-20 | NaTbF is separated out4Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811563087.8A CN109354417B (en) | 2018-12-20 | 2018-12-20 | NaTbF is separated out4Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109354417A CN109354417A (en) | 2019-02-19 |
| CN109354417B true CN109354417B (en) | 2021-06-29 |
Family
ID=65329978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811563087.8A Active CN109354417B (en) | 2018-12-20 | 2018-12-20 | NaTbF is separated out4Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109354417B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112010564B (en) * | 2020-08-25 | 2022-04-22 | 暨南大学 | Rare earth ion in-situ crystallization-based fluorine-oxygen microcrystalline glass and preparation method and application thereof |
| CN116891343B (en) * | 2023-06-25 | 2024-05-10 | 华南理工大学 | Niobium silicate microcrystalline glass for precipitating biphase nonlinear crystal, and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1239936A (en) * | 1997-01-02 | 1999-12-29 | 康宁股份有限公司 | Transparent oxyfluoride glass-ceramic composition and process for making the same |
| CN101234852A (en) * | 2008-01-16 | 2008-08-06 | 中南大学 | 0.3-5mum wave range infrared permeation high temperature resistant glass ceramic material and preparing method thereof |
| CN102603194A (en) * | 2011-12-22 | 2012-07-25 | 中国计量学院 | Rare earth doped microcrystalline glass of precipitated beta-NaGdF4 nanocrystalline and preparation method thereof |
| CN102992630A (en) * | 2012-12-12 | 2013-03-27 | 中国科学院福建物质结构研究所 | Nano-structure glass ceramic with up / down conversion luminescent property and preparation method thereof |
| CN104961343A (en) * | 2015-06-26 | 2015-10-07 | 中国计量学院 | Rare-earth-doped microcrystalline glass separating out NaYF4 nanocrystalline and manufacturing method thereof |
-
2018
- 2018-12-20 CN CN201811563087.8A patent/CN109354417B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1239936A (en) * | 1997-01-02 | 1999-12-29 | 康宁股份有限公司 | Transparent oxyfluoride glass-ceramic composition and process for making the same |
| CN101234852A (en) * | 2008-01-16 | 2008-08-06 | 中南大学 | 0.3-5mum wave range infrared permeation high temperature resistant glass ceramic material and preparing method thereof |
| CN102603194A (en) * | 2011-12-22 | 2012-07-25 | 中国计量学院 | Rare earth doped microcrystalline glass of precipitated beta-NaGdF4 nanocrystalline and preparation method thereof |
| CN102992630A (en) * | 2012-12-12 | 2013-03-27 | 中国科学院福建物质结构研究所 | Nano-structure glass ceramic with up / down conversion luminescent property and preparation method thereof |
| CN104961343A (en) * | 2015-06-26 | 2015-10-07 | 中国计量学院 | Rare-earth-doped microcrystalline glass separating out NaYF4 nanocrystalline and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| Eu3+-Doped glass ceramics containing NaTbF4 nanocrystals: controllable glass crystallization, Tb3+-bridged energy transfer and tunable luminescence;Li Xinyue et al.;《JOURNAL OF MATERIALS CHEMISTRY C》;ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND;20171231;4,20 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109354417A (en) | 2019-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1325412C (en) | Nano-multicrystal phase glass ceramics and its production method | |
| Kukkonen et al. | Nucleation and crystallisation of transparent, erbium III-doped, oxyfluoride glass-ceramics | |
| CN109354417B (en) | NaTbF is separated out4Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof | |
| CN108423984A (en) | A kind of full-inorganic perovskite Quantum Dot Glass of divalent additive Mn and its preparation method and application | |
| Zheng et al. | Crystallization behavior and IR structure of yttrium aluminosilicate glasses | |
| CN102765883B (en) | Preparation method of YAG microcrystalline glass | |
| CN102603194A (en) | Rare earth doped microcrystalline glass of precipitated beta-NaGdF4 nanocrystalline and preparation method thereof | |
| Guo et al. | Gd3+ doping induced enhanced upconversion luminescence in Er3+/Yb3+ co-doped transparent oxyfluoride glass ceramics containing NaYF4 nanocrystals | |
| CN107540227B (en) | Europium-doped feldspar phase-containing microcrystalline glass and preparation method thereof | |
| CN109369024B (en) | Precipitated BaEuF5Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof | |
| CN112811821B (en) | Rare earth doped YAG high-crystallinity transparent glass ceramics and preparation method thereof | |
| CN110204209B (en) | Up-conversion glass ceramic composite material of selective rare earth doped scandium-based fluorinated nanocrystalline | |
| CN109369023B (en) | Precipitated Ba2LaF7Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof | |
| RU2616648C1 (en) | Method for production of glass-ceramic material with rare earth elements niobates nanoscale crystals | |
| CN108395103A (en) | A kind of body crystallization α cordierite glass-ceramic standby using Bayan Obo tailing and coal ash for manufacturing and preparation method thereof | |
| CN114455842B (en) | Precipitation of Bi 2 GeO 5 Nanocrystalline high-density bismuth germanate microcrystalline glass and preparation method thereof | |
| CN109437572B (en) | Precipitated BaTbF5Nanocrystalline germanosilicate microcrystalline glass and preparation method thereof | |
| CN105330161B (en) | TiO2Saturating infrared aluminate glass ceramics of doping and preparation method thereof | |
| CN105776871A (en) | Method for regulating emission cross section of Nd3+/ Na2Ca2Si3O9 laser glass ceramic | |
| CN110818267B (en) | Terbium-doped transparent glass ceramic containing sodium yttrium molybdate crystal phase | |
| Kolobkova et al. | Optical glass-ceramics based on fluorine-containing silicate glasses doped with rare-earth ions | |
| RU2787608C1 (en) | Luminescent material and method for its production | |
| WO2024208147A1 (en) | Spinel microcrystalline glass, and preparation method therefor and use thereof | |
| CN1966439A (en) | Nd-doped glass ceramic and preparing process thereof | |
| Hou et al. | Transparent oxyfluoride glass-ceramics containing CaF2 nano-crystalline phase |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231008 Address after: Room 407-10, floor 4, building 2, Haichuang science and technology center, Cangqian street, Yuhang District, Hangzhou City, Zhejiang Province, 311100 Patentee after: Zhejiang Zhiduo Network Technology Co.,Ltd. Address before: 310018, No. 258, source street, Xiasha Higher Education Park, Hangzhou, Zhejiang Patentee before: China Jiliang University |