CN109354054A - A method of copper is recycled from printing in useless version Kun for cupric oxide powder - Google Patents
A method of copper is recycled from printing in useless version Kun for cupric oxide powder Download PDFInfo
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- CN109354054A CN109354054A CN201811484554.8A CN201811484554A CN109354054A CN 109354054 A CN109354054 A CN 109354054A CN 201811484554 A CN201811484554 A CN 201811484554A CN 109354054 A CN109354054 A CN 109354054A
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- kun
- copper
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- useless
- oxide powder
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 58
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 52
- 239000010949 copper Substances 0.000 title claims abstract description 52
- 229960004643 cupric oxide Drugs 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000000843 powder Substances 0.000 title claims abstract description 25
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 21
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 claims abstract description 21
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 19
- 239000011651 chromium Substances 0.000 claims abstract description 19
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 238000004064 recycling Methods 0.000 claims abstract description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 6
- OVFCVRIJCCDFNQ-UHFFFAOYSA-N carbonic acid;copper Chemical compound [Cu].OC(O)=O OVFCVRIJCCDFNQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 238000010521 absorption reaction Methods 0.000 claims abstract description 3
- 239000007787 solid Substances 0.000 claims abstract description 3
- 238000001354 calcination Methods 0.000 claims description 9
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 8
- 239000000908 ammonium hydroxide Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 5
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 5
- 239000001099 ammonium carbonate Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 238000007599 discharging Methods 0.000 abstract description 3
- 239000006227 byproduct Substances 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 239000005751 Copper oxide Substances 0.000 description 6
- 229910000431 copper oxide Inorganic materials 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229920002955 Art silk Polymers 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 1
- WXYNCCWBUXKSBG-UHFFFAOYSA-N copper;nitric acid Chemical compound [Cu].O[N+]([O-])=O WXYNCCWBUXKSBG-UHFFFAOYSA-N 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Catalysts (AREA)
Abstract
The invention discloses a kind of from printing with recycling copper in useless version Kun for the method for cupric oxide powder, uses useless version Kun acid processing by that will print, dissolves the chromium on surface, the obtained useless version Kun for removing surface chromium；The useless version Kun for removing surface chromium is placed in ammonia solution, and is passed through air and dissolves the useless surface version Kun copper, obtains ammonia formula carbonic acid copper solution；Ammonia formula carbonic acid copper solution is transferred in heating kettle, 100 DEG C are to slowly warm up in 1~2h, keeps the temperature 1h, Kocide SD is made after discharging ammonia completely, the ammonia of release is absorbed through absorption plant to be recycled；Kocide SD mixed liquor is transferred in settling tank through settling separated from the water, the Kocide SD that solid is dried powdered；Kocide SD is calcined at high temperature, cupric oxide powder is made.The method of the present invention is simple, easy to operate, and byproduct of reaction is less, and the yield of cupric oxide powder is up to 95%, purity up to 98% or more.
Description
Technical field
The invention belongs to copper scrap resource reutilization technical fields, more particularly to one kind to recycle copper in useless version Kun from printing
The method of standby cupric oxide powder.
Background technique
Useless version Kun is the waste as caused by large-sized print factory, annual to generate about few hundred thousand tonnes of, version Kun main component of giving up
For iron, contain 0.3%~1.0% chromium and 2.5%~5% copper.The internal layer of useless version Kun is iron, iron surface successively copper facing, chromium.
Cupric oxide powder is mainly used for colorant, the You Jihe of fireworks, ceramics and glass as important Inorganic Chemicals
At catalyst, the desulfurizing agent of oils, magnetic material, circuit version plating of electronic industry, manufacture artificial silk and gas analysis etc.
Industry.The production method of cupric oxide powder mainly has the oxidizing process of molten state copper, the molten copper-of alkali precipitation-calcination method, ammonium hydroxide containing mantoquita
Calcination method.Patent CN201310571018.2 disclose it is a kind of by waste and old red copper wire or red copper bar, by red copper wire or red copper bar
It is cut into fritter, is put into embedded with being heated in copper lining board or high temperature resistant stainless steel copper lining board rotary furnace, and red copper is added in rotary furnace
Ball is passed through oxygen reaction generation copper oxide after being heated to certain temperature as abrading-ball.Patent CN201410550840.5 is disclosed
Using copper sheet as raw material, ammonia leaching process preparation copper ammonia complexation solution evaporates to obtain alkali formula carbon using tiny structure one kind by secondary filter
Sour copper obtains active oxidation copper powder product through low temperature calcination, and the leaching copper raw material in the technique mainly is ammonium hydroxide, accurate overanxious institute
Membrane aperture is 2~5 microns and is difficult to carry out.CN201410240133.6 is reported to be dissolved in industrial acetic copper or copper nitrate
In pure water, powdery cocoanut active charcoal is added, with ammonium hydroxide or carbonic acid hydrogen ammonium tune pH value, and is precipitated under ultrasound condition, from anti-
Collection target product high pure and ultra-fine cupric oxide powder in product is answered, ultrafine copper oxide powder purity is up to 99%.Patent
CN102320644A is reported using copper sulphate as raw material, and using ammonium hydroxide as buffer, sodium hydroxide is precipitating reagent, reaction preparation oxidation
Copper powder.However, the above-mentioned method raw materials for preparing copper oxide are high-purity red copper wire, red copper bar, copper sheet, copper acetate, nitric acid
Copper or copper sulphate etc..
Summary of the invention
The purpose of the present invention is to provide a kind of from printing with recycling copper in useless version Kun for the method for cupric oxide powder, it is intended to
Solving the existing method raw materials for preparing copper oxide is high-purity red copper wire, red copper bar, copper sheet, copper acetate, copper nitrate or sulphur
The problem of sour copper etc..
The invention is realized in this way a method of copper is recycled from printing in useless version Kun for cupric oxide powder, the party
Method the following steps are included:
(1) by printing useless version Kun acid processing, the chromium on surface is dissolved, the useless version Kun for removing surface chromium is made；
(2) the useless version Kun for removing surface chromium is placed in ammonia solution, and is passed through air and dissolves the useless surface version Kun copper, obtain ammonia
Formula carbonic acid copper solution；Ammonia formula carbonic acid copper solution is transferred in heating kettle, 100 DEG C are to slowly warm up in 1~2h, 1h is kept the temperature, makes
Kocide SD is made in ammonia after discharging completely, the ammonia of release is absorbed through absorption plant to be recycled；Kocide SD mixed liquor is turned
Enter in settling tank through settling separated from the water, the Kocide SD that solid is dried powdered；
(3) Kocide SD is calcined at high temperature and cupric oxide powder is made.
Preferably, in step (1), the acid be mass concentration be 2~37% hydrochloric acid, 2~50% sulfuric acid and/or
2~30% nitric acid.
Preferably, in step (1), the mass ratio of the material of chromium and acid ion is 1:(2~6 in the useless version Kun).
Preferably, in step (1), the reaction temperature of the acid processing is 10~40 DEG C, the reaction time is 0.5~12h.
Preferably, in step (2), the ammonia solution be mass concentration be 2~17.8% ammonium hydrogencarbonate, 2~50%
Carbonic acid ammonia and/or 2~25% ammonium hydroxide.
Preferably, in step (2), copper in the useless version Kun, oxygen in air, ammonium ion the mass ratio of the material be 1:(1
~10): (4~20).
Preferably, in step (2), it is 10~45 DEG C that ammonia, which dissolves copper reaction temperature, and the reaction time is 4~48h.
Preferably, in step (3), calcined under the high temperature specifically: 300~800 DEG C of temperature lower calcinations 0.5~
10h。
The present invention overcomes the deficiencies of the prior art and provide a kind of use in useless version Kun from printing and recycles copper for cupric oxide powder
Method, comprising steps of dissolving the chromium on surface, chromous salts being made printing useless version Kun acid processing；The useless of surface chromium will be removed
Version Kun, which is placed in ammonia solution and is passed through air, dissolves the useless surface version Kun copper, obtains ammonia formula carbonic acid copper solution；Then in heating condition
Under release ammonia be made Kocide SD；Kocide SD obtained is calcined at high temperature is made cupric oxide powder.
Compared with the prior art the shortcomings that and deficiency, the invention has the following advantages:
(1) from the yield of useless version Kun recycling copper and obtained cupric oxide powder up to 95%, the purity of copper oxide reaches the method for the present invention
98% or more；
(2) the method for the present invention is simple, easy to operate, and byproduct of reaction is less, and correlated response product can be with repetitive cycling
It uses, energy-efficient, cost is lower；
(3) remove surface chromium, copper useless version Kun main component iron content be 98% or more, can be used as excellent iron material
Material.
Detailed description of the invention
Fig. 1 is the process flow chart that the useless version Kun of the present invention prepares cupric oxide powder.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right
The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and
It is not used in the restriction present invention.
Embodiment
(1) it weighs the useless version Kun of 10.0kg to be placed in 5 liters of groove type reactors of glass, prepared acid solution is added, one
It is reacted under fixed temperature and time, useless version Kun is rotated in reaction process.Concrete outcome is as shown in table 1 below:
The chromium experiment condition on the useless surface version Kun is dissolved in 1 acid processing of table
By the experimental result of embodiment 1~17 in table 1 provided it is found that well the surface useless version Kun in embodiment
Chromium all dissolves, and the surface version Kun of giving up is in the copper color of glassy yellow.
(2) ammonium bicarbonate solution is added in 100L slot type stainless steel reactor, the useless version Kun of 10.0kg removal chromium is added,
It is heated to the temperature of setting, air is periodically passed through, is reacted under setting time, end of reaction, removes useless version Kun, solution, which is transferred to, to be added
It in hot kettle, is to slowly warm up to 100 DEG C (1~2h), keeps the temperature 1h, Kocide SD is made after discharging ammonia completely.Ammonia is through absorbing
Device, which absorbs, to be recycled.Kocide SD is separated from the water through settling, and obtains powdered Kocide SD through drying.
Specific embodiment parameter and its reaction result such as following table 2-1, shown in table 2-2, table 2-3 and table 2-4:
The copper experiment condition on the useless surface version Kun is dissolved in the processing of table 2-1 ammonium hydrogencarbonate
The copper experiment condition on the useless surface version Kun is dissolved in table 2-2 carbonic acid ammonia treatment
Table 2-3 AMMONIA TREATMENT dissolves the copper experiment condition on the useless surface version Kun
The AMMONIA TREATMENT that table 2-4 recycles dissolves the copper experiment condition on the useless surface version Kun
Difference it can be seen from the quality of the reaction condition and Kocide SD that are provided by embodiment 18~68 in table 2-1~2-4
Give up under the concentration of ammonium hydrogencarbonate, differential responses temperature and differential responses time conditions the surface version Kun copper dissolved well under
It is converted to four ammino copper, adds hydrogen to decompose and generate Kocide SD.
(3) Kocide SD made from is calcined in high-temperature calcination stove, sampling amount, calcination temperature, calcination time parameter and oxygen
Change copper yield such as table 3.
3 different temperatures of table and Kocide SD is calcined under the time
It can be seen from embodiment 69~85 when 300~800 DEG C of calcination temperature, calcination time produces in 0.5~12h
The yield of product copper oxide is 95.0% or more, and the purity of copper oxide is 98.0% or more.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (8)
1. a kind of recycle copper in useless version Kun from printing for the method for cupric oxide powder, which is characterized in that this method includes following
Step:
(1) by printing useless version Kun acid processing, the chromium on surface is dissolved, the useless version Kun for removing surface chromium is made；
(2) the useless version Kun for removing surface chromium is placed in ammonia solution, and is passed through air and dissolves the useless surface version Kun copper, obtain ammonia formula carbon
Sour copper solution；Ammonia formula carbonic acid copper solution is transferred in heating kettle, 100 DEG C are to slowly warm up in 1~2h, 1h is kept the temperature, makes ammonia
Kocide SD is made after release completely, the ammonia of release is absorbed through absorption plant to be recycled；It is heavy that Kocide SD mixed liquor is transferred to
It drops in pond through settling separated from the water, the Kocide SD that solid is dried powdered；
(3) Kocide SD is calcined at high temperature and cupric oxide powder is made.
2. recycling copper from printing in useless version Kun as described in claim 1 for the method for cupric oxide powder, which is characterized in that
In step (1), the acid is hydrochloric acid, 2~50% sulfuric acid and/or 2~30% nitric acid that mass concentration is 2~37%.
3. recycling copper from printing in useless version Kun as claimed in claim 2 for the method for cupric oxide powder, which is characterized in that
In step (1), the mass ratio of the material of chromium and acid ion is 1:(2~6 in the useless version Kun).
4. recycling copper from printing in useless version Kun as claimed in claim 3 for the method for cupric oxide powder, which is characterized in that
In step (1), the reaction temperature of the acid processing is 10~40 DEG C, the reaction time is 0.5~12h.
5. recycling copper from printing in useless version Kun as described in claim 1 for the method for cupric oxide powder, which is characterized in that
In step (2), the ammonia solution be mass concentration be 2~17.8% ammonium hydrogencarbonate, 2~50% carbonic acid ammonia and/or 2~
25% ammonium hydroxide.
6. recycling copper from printing in useless version Kun as described in claim 1 for the method for cupric oxide powder, which is characterized in that
In step (2), copper in the useless version Kun, oxygen in air, ammonium ion the mass ratio of the material be 1:(1~10): (4~20).
7. recycling copper from printing in useless version Kun as described in claim 1 for the method for cupric oxide powder, which is characterized in that
In step (2), it is 10~45 DEG C that ammonia, which dissolves copper reaction temperature, and the reaction time is 4~48h.
8. recycling copper from printing in useless version Kun as described in claim 1 for the method for cupric oxide powder, which is characterized in that
It in step (3), is calcined under the high temperature specifically: in 300~800 DEG C of 0.5~10h of temperature lower calcination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811484554.8A CN109354054A (en) | 2018-12-06 | 2018-12-06 | A method of copper is recycled from printing in useless version Kun for cupric oxide powder |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811484554.8A CN109354054A (en) | 2018-12-06 | 2018-12-06 | A method of copper is recycled from printing in useless version Kun for cupric oxide powder |
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| CN109354054A true CN109354054A (en) | 2019-02-19 |
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| CN201811484554.8A Pending CN109354054A (en) | 2018-12-06 | 2018-12-06 | A method of copper is recycled from printing in useless version Kun for cupric oxide powder |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110315243A (en) * | 2019-07-03 | 2019-10-11 | 郑州机械研究所有限公司 | The processing method of slag in a kind of copper-phosphorus brazing alloy |
| CN114804186A (en) * | 2022-05-16 | 2022-07-29 | 吴江市威士达铜业科技有限公司 | Production method and production device of copper oxide |
| CN115304093A (en) * | 2022-08-10 | 2022-11-08 | 李晓清 | Continuous production process of high-purity copper oxide based on ammonia circulation system |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1172074A (en) * | 1997-08-15 | 1998-02-04 | 张礼英 | Preparation method of cupric oxide or cupric sulfate using copper sheathed steel by ammonia immersion |
-
2018
- 2018-12-06 CN CN201811484554.8A patent/CN109354054A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1172074A (en) * | 1997-08-15 | 1998-02-04 | 张礼英 | Preparation method of cupric oxide or cupric sulfate using copper sheathed steel by ammonia immersion |
Non-Patent Citations (2)
| Title |
|---|
| 孙传尧: "《选矿工程师手册（第3册）》", 31 March 2015, 冶金工业出版社 * |
| 藏广州: "《凹版印刷技术分册（上卷）》", 30 November 2003, 安徽音像出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110315243A (en) * | 2019-07-03 | 2019-10-11 | 郑州机械研究所有限公司 | The processing method of slag in a kind of copper-phosphorus brazing alloy |
| CN110315243B (en) * | 2019-07-03 | 2021-08-03 | 郑州机械研究所有限公司 | Method for treating slag in copper-phosphorus brazing filler metal |
| CN114804186A (en) * | 2022-05-16 | 2022-07-29 | 吴江市威士达铜业科技有限公司 | Production method and production device of copper oxide |
| CN115304093A (en) * | 2022-08-10 | 2022-11-08 | 李晓清 | Continuous production process of high-purity copper oxide based on ammonia circulation system |
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