CN109338399A - A kind of built-in gas water cyclic electrolysis formula ozone generating-device - Google Patents

A kind of built-in gas water cyclic electrolysis formula ozone generating-device Download PDF

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Publication number
CN109338399A
CN109338399A CN201811373740.4A CN201811373740A CN109338399A CN 109338399 A CN109338399 A CN 109338399A CN 201811373740 A CN201811373740 A CN 201811373740A CN 109338399 A CN109338399 A CN 109338399A
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CN
China
Prior art keywords
cathode
anode
water
water tank
chamber
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Pending
Application number
CN201811373740.4A
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Chinese (zh)
Inventor
周元全
涂晓波
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Wuhan Weimeng Environmental Protection Technology Co ltd
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Wuhan Weimeng Environmental Protection Technology Co ltd
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Priority to CN201811373740.4A priority Critical patent/CN109338399A/en
Publication of CN109338399A publication Critical patent/CN109338399A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/13Ozone
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00Diaphragms; Spacing elements
    • C25B13/02Diaphragms; Spacing elements characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded

Abstract

The invention belongs to electrochemical technology fields, are related to a kind of built-in gas water cyclic electrolysis formula ozone generating-device.Cathode water tank and cathode chamber, anode water tank and anode chamber are used integrated design by the present invention, and recycle duct using built-in raw water between water tank and reaction chamber, are allowed to constitute a W-response component.When water electrolysis works, the raw water in the built-in duct of cathode reaction component and anode reaction component carries out automatic cycle, and realizes gas-liquid separation and heat dissipation dual function.

Description

A kind of built-in gas water cyclic electrolysis formula ozone generating-device
Technical field
The invention belongs to electrochemical technology fields, are related to a kind of built-in gas water cyclic electrolysis formula ozone generating-device.
Background technique
Proton exchange model water electrolysis type ozone generating-device is all using pure water as raw material, in the effect of low-voltage DC Under, high concentration, high-purity ozone are generated in anode region, generates High Purity Hydrogen in cathodic region, and is not generated harmful to human body and environment Nitrogen oxides (NOx), application field is very wide.
Existing electrolytic ozone generator such as Chinese patent ZL201420547893.7 and Chinese patent Electrolytic ozone generator disclosed in ZL201611046873.1 etc., all in advance by cathode water tank, anode water tank and with film The generator of electrode assembly composition is fabricated to independent three components respectively, is then constituted using external water circulating pipe bipolar outer Circulation waterway.Large-scale production, and water pipe pipeline joint are difficult to according to the electrolytic ozone generator that above three component is assembled More, the assembly process is complicated, and there are leakage hidden troubles when bipolar outer circulation waterpipe works, it is difficult to guarantee product quality.
Summary of the invention
In order to overcome the shortcomings of above-mentioned prior art, technical problem to be solved by the invention is to provide a kind of built-in Gas water cyclic electrolysis formula ozone generating-device.
Cathode water tank and cathode chamber, anode water tank and anode chamber are used integrated design by the present invention, and in cathode water tank Duct is recycled using built-in raw water between cathode chamber, is allowed to constitute a whole cathode reaction component.Equally, anode water Duct is recycled using built-in raw water between case and anode chamber, is allowed to constitute a whole anode reaction component.Water electrolysis work When making, the raw water in the built-in duct of cathode reaction component and anode reaction component carries out automatic cycle, and realizes gas-liquid point From with heat dissipation dual function.Keep hot and cold water automatic by inner circulating tube by the power that water temperature difference inside and outside reaction chamber and gas rise Circulation, while generating heat exchange.
The present invention is achieved by the following technical solutions:
A kind of built-in gas water cyclic electrolysis formula ozone generating-device, including the cathode assembly and anode assemblies to fit together, institute It states cathode assembly to be made of the cathode water tank of top and the cathode chamber component of lower section, has through sky in the cathode chamber component Chamber, cavity bottom are connected to by the cathode inlet opening of cathode chamber component inside with cathode water tank, and top passes through in cathode chamber component Cathode water outlet/the stomata in portion is connected to cathode water tank;The anode assemblies are by the anode water tank of top and anode chamber's structure of lower section Part composition, anode chamber's member center have through cavity, and cavity bottom is intake by the anode of anode chamber's component inside Hole is connected to anode water tank, and top is connected to by anode water outlet/stomata of anode chamber's component inside with anode water tank;
The cavity of the cathode chamber component and anode chamber's member center is for installing electrolysis cells, including intermediate membrane electrode assembly Part, the cathode diversion plate of membrane electrode assembly two sides, anode flow field are close with sealing ring between membrane electrode assembly periphery and cavity Envelope, the gas mixing for preventing cathode and anode from generating have pillar in the cathode diversion plate and anode flow field, for make water, Gas is uniform, has cathode conducting end plates and anode conducting end plate to cover cavity respectively on the outside of cathode diversion plate and anode flow field, makes The bolt hole fastening on cathode conducting end plates, cathode chamber component, anode chamber's component and anode conducting end plate is passed through with bolt.
Cathode water tank and anode water tank pass through holding of external communicating pipe water level balance.
There are also cathode water supplement port and hydrogen outlet on cathode water tank, there are anode water supplement port and ozone outlet on anode water tank.
The cathode water tank and cathode chamber component constitute the cathode assembly of an entirety.It is provided in cathode chamber component built-in Water circulating pipe, be made of cathode inlet opening and cathode water outlet/stomata, formed in solid cathode chamber component inside.Yin Pole water outlet/stomata internal diameter is greater than cathode inlet opening internal diameter, is beneficial to hydrogen discharge.
The anode water tank and anode chamber's component constitute the anode assemblies of an entirety.Water is provided in anode chamber's component to follow Endless tube road is made of anode inlet opening and anode water outlet/stomata.Anode water outlet/stomata internal diameter is greater than anode inlet opening internal diameter, It is beneficial to ozone discharge.
The cathode water tank and anode water tank bottom is provided with external communicating pipe, it is ensured that passes through ion by anode reaction area Anode water tank is returned in time to the water that cathodic reaction zone migrates inside exchange membrane, and keeps two cistern water levels in equal height.
There is being one section of water resistance solenoid in the external communicating pipe close to anode water tank location, and the water resistance bore is remote External less than other positions is connected to bore.Resistance tube can prevent ozone from migrating to cathode water tank, but the water of cathode water tank can It is migrated to anode water tank, it is ensured that Yin/Yang pole cistern water level balance.
Symmetrical bolt hole is provided on the cathode chamber component and anode chamber's component.
The anode water tank, anode chamber's component use polytetrafluoroethylene material, vinylidene plastics, the cathode water Case, cathode chamber component select plastics, such as ABS plastic.
The bolt of fastening uses metal material, such as 304 or more stainless steel material.
The seal washer is made of silicon rubber or fluorubber material, it is ensured that the gas and raw water of the indoor generation of yin-yang two Sealing.
The cathode conducting end plates, anode conducting end plate use metal material, preferably cemented carbide aluminum, stainless steel At.
Pillar on the cathode diversion plate, anode flow field can be round, rectangular or diamond shape.
The cathode conducting end plates, anode conducting end plate are respectively arranged with symmetrical bolt hole, with cathode chamber structure Bolt hole in part, anode chamber's component is corresponding.
The structure of the membrane electrode assembly has prior art report, by cathode porous current-collector, cathode catalysis film, from Proton exchange, anode-catalyzed film, anodic porous current-collector are constituted.
The amberplex is perfluorinated sulfonic acid cation-exchange membrane commonly used in the prior art.
The cathode porous current-collector, anodic porous current-collector are made using the titanium plate of sintered type through processing.
Construction package of the invention uses cathode assembly and anode assemblies, and cathode assembly makes cathode water tank and cathode chamber component Realize integration, anode assemblies make anode water tank and anode chamber's component realize integration, and structure is simple, external connection is reduced, It is easily able to standardize and minimize, can be used for the field of household appliances such as refrigerator, air-conditioning, washing machine, be also easy to large-scale production.
The present invention built-in gas water circulating line in cathode assembly and anode assemblies respectively, the separation of enhancing gas water and raw material Water-cooled.Built-in gas water cyclic electrolysis formula ozone generating-device of the invention is compact-sized, simple, stable, ozone concentration It is high.
Detailed description of the invention
A kind of Fig. 1: built-in gas water cyclic electrolysis formula ozone generating-device structural schematic diagram.
1- membrane electrode assembly in Fig. 1,2- seal washer, 3- cathode chamber, 4- cathode diversion plate, 5- cathode conducting end plates, 6- Bolt, 7- cathode water tank, 8- cathode water supplement port, 9- hydrogen outlet, 10- ozone outlet, 11- anode water supplement port, 12- anode water Case, 13- water resistance solenoid, 14- anode conducting end plate, the anode chamber 15-, 16- anode flow field, 17- outside communicating pipe.
Fig. 2: Yin/Yang pole component construction profile.
18- cathode chamber component in Fig. 2,19- bolt hole, 20- cathode inlet opening, 21- cathode cavity, 22- cathode go out water/gas Hole, 23- anode water outlet/stomata, 24- anode cavity, 25- anode inlet opening, the anode chamber 26- component.
Fig. 3: membrane electrode assembly schematic diagram.
27- amberplex in Fig. 3,28- cathode catalysis film, 29- cathode porous current-collector, 30- anodic porous current collection Device, the anode-catalyzed film of 31-.
Specific embodiment
Embodiment 1
As shown in Fig. 1, a kind of built-in gas water cyclic electrolysis formula ozone generating-device, including the cathode assembly to fit together And anode assemblies.
As shown in Fig. 2, the cathode assembly is made of the cathode water tank of top and the cathode chamber component of lower section, the yin Pole room member center has through cavity, and cavity bottom is connected by the cathode inlet opening of cathode chamber component inside and cathode water tank Logical, top is connected to by cathode water outlet/stomata of cathode chamber component inside with cathode water tank;The anode assemblies by top sun Pole water tank and anode chamber's component of lower section composition, anode chamber's member center have through cavity, and cavity bottom passes through sun The anode inlet opening of pole room component inside is connected to anode water tank, and top passes through anode water outlet/stomata of anode chamber's component inside It is connected to anode water tank.
As shown in Figure 1, the cavity of the cathode chamber component and anode chamber's member center is for installing electrolysis cells, including in Between membrane electrode assembly, the cathode diversion plate of membrane electrode assembly two sides, anode flow field, between membrane electrode assembly periphery and cavity It is sealed with sealing ring, the gas mixing for preventing cathode and anode from generating, has pillar in the cathode diversion plate and anode flow field, For keeping water, gas uniform, there are cathode conducting end plates and anode conducting end plate lid respectively on the outside of cathode diversion plate and anode flow field Firmly cavity passes through the bolt hole on cathode conducting end plates, cathode chamber component, anode chamber's component and anode conducting end plate using bolt Fastening.
Cathode water tank and anode water tank pass through holding of external communicating pipe water level balance.
The seal washer is made of silicon rubber or fluorubber material, it is ensured that the gas and raw water of the indoor generation of yin-yang two Sealing.
The cathode conducting end plates, anode conducting end plate are made of metal.
The cathode and anode deflector its be provided with equally distributed pillar on one side.Pillar can be round, rectangular or diamond shape.
The cathode conducting end plates, anode conducting end plate are respectively arranged with symmetrical fastening bolt holes, with cathode Fastening bolt holes in room component, anode chamber's component are corresponding.
The membrane electrode assembly is by amberplex, cathode catalysis film, cathode porous current-collector, anodic porous current collection Device, anode-catalyzed film are constituted, as shown in Figure 3.
The amberplex is perfluorinated sulfonic acid cation-exchange membrane commonly used in the prior art.
The cathode porous current-collector, anodic porous current-collector are made using the titanium plate of sintered type through processing.
When processing, molding is pre-machined in above-mentioned cathode and anode component respectively.
Production is pre-machined in above-mentioned membrane electrode assembly respectively.
Each component of the membrane electrode assembly processed is placed in the cavity of cathode chamber component, anode chamber's component.
Cathode assembly, cathode diversion plate, membrane electrode assembly, anode flow field and the anode assemblies of forming will be pre-machined It is tightened together by cathode conducting end plates and cathode conducting end plates with fastening bolt, it is smelly to constitute built-in gas water cyclic electrolysis formula Oxygengenerating plant.
Order after above-mentioned each component assembling of built-in gas water cyclic electrolysis formula ozone generating-device be cathode conducting end plates, Cathode assembly, cathode diversion plate, cathode porous current-collector, cathode catalysis film, amberplex, anode-catalyzed film, anodic porous Current-collector, anode flow field, anode assemblies, anode conducting end plate.
Built-in gas water cyclic electrolysis formula ozone generating-device of the invention reaction component difference in Yin/Yang pole as shown in Fig. 2 Molding is pre-machined;Production is also pre-machined in each component of membrane electrode assembly as shown in Fig. 3 respectively;It will be pre-machined and make again Cathode assembly, cathode diversion plate, each component of membrane electrode assembly, anode flow field, anode reaction component pass through cathode conducting end Plate and cathode conducting end plates are tightened together with fastening bolt, are connected to cathode water finally by communicating pipe outside the water tank of Yin/Yang pole Case and anode water tank constitute built-in gas water cyclic electrolysis formula ozone generating-device.Its is compact-sized, simple, stable, smelly Oxygen concentration is high.
Embodiment 2
The built-in gas water cyclic electrolysis formula ozone generating-device assembled according to embodiment 1 is smelly under DC constant flowing power effect Oxygengenerating plant list tank voltage is 3.6v, and the ozone concentration for the ozone gas that anode chamber generates is 28.5%(wt%).Ozone fills Set can the operation of continuous or slotted mode, it is stable.

Claims (10)

1. a kind of built-in gas water cyclic electrolysis formula ozone generating-device, which is characterized in that including the cathode assembly to fit together And anode assemblies, the cathode assembly are made of the cathode water tank of top and the cathode chamber component of lower section, the cathode chamber structure There is through cavity at part center, and cavity bottom is connected to by the cathode inlet opening of cathode chamber component inside with cathode water tank, top It is connected to by cathode water outlet/stomata of cathode chamber component inside with cathode water tank;The anode assemblies by top anode water tank It is formed with anode chamber's component of lower section, anode chamber's member center has through cavity, and cavity bottom passes through anode chamber's structure Anode inlet opening inside part is connected to anode water tank, and top passes through the anode water outlet/stomata and anode of anode chamber's component inside Water tank connection;
The cavity of the cathode chamber component and anode chamber's member center is for installing electrolysis cells, including intermediate membrane electrode assembly Part, the cathode diversion plate of membrane electrode assembly two sides, anode flow field are close with sealing ring between membrane electrode assembly periphery and cavity Envelope, the gas mixing for preventing cathode and anode from generating have pillar in the cathode diversion plate and anode flow field, for make water, Gas is uniform, has cathode conducting end plates and anode conducting end plate to cover cavity respectively on the outside of cathode diversion plate and anode flow field, makes The bolt hole fastening on cathode conducting end plates, cathode chamber component, anode chamber's component and anode conducting end plate is passed through with bolt.
2. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that cathode water tank Water level balance is kept by external communicating pipe with anode water tank.
3. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that cathode water tank Also cathode water supplement port and hydrogen outlet are gone up, has anode water supplement port and ozone outlet on anode water tank.
4. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that the cathode Water outlet/stomata internal diameter is greater than cathode inlet opening internal diameter.
5. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that the anode Water outlet/stomata internal diameter is greater than anode inlet opening internal diameter.
6. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that described is outer There is being one section of water resistance solenoid in portion's communicating pipe close to anode water tank location, and the water resistance bore is outer much smaller than other positions Portion is connected to bore.
7. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that the yin Symmetrical bolt hole is provided on pole room component and anode chamber's component.
8. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that the sun Pole water tank, anode chamber's component use polytetrafluoroethylene material or vinylidene plastics, the cathode water tank, the choosing of cathode chamber component Use plastic material.
9. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that the cathode Pillar on deflector, anode flow field is round, rectangular or diamond shape.
10. built-in gas water cyclic electrolysis formula ozone generating-device according to claim 1, which is characterized in that the yin Pole conducting end plates, anode conducting end plate are respectively arranged with symmetrical bolt hole, in cathode chamber component, anode chamber's component Bolt hole is corresponding.
CN201811373740.4A 2018-11-19 2018-11-19 A kind of built-in gas water cyclic electrolysis formula ozone generating-device Pending CN109338399A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114182274A (en) * 2021-12-30 2022-03-15 深圳康诚博信科技有限公司 Ozone generation and transmission device designed without water pipe
CN114470289A (en) * 2021-12-30 2022-05-13 深圳康诚博信科技有限公司 Ozone disinfection machine
CN114755282A (en) * 2022-04-12 2022-07-15 山东赛克赛斯氢能源有限公司 Novel membrane electrode testing device for pure water electrolysis catalyst

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1195643A (en) * 1997-03-07 1998-10-14 武汉大学 Electrolytic ozone generator
CN2431290Y (en) * 2000-07-04 2001-05-23 胡柏 Generator for producing ozone by electrolyzing process
CN2571771Y (en) * 2002-10-16 2003-09-10 武汉大学 Ozone water preparation machine
US20080179185A1 (en) * 2006-08-08 2008-07-31 Chlorine Engineers Corp., Ltd. Ozone producing system
CN209307492U (en) * 2018-11-19 2019-08-27 武汉威蒙环保科技有限公司 A kind of built-in gas water cyclic electrolysis formula ozone generating-device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1195643A (en) * 1997-03-07 1998-10-14 武汉大学 Electrolytic ozone generator
CN2431290Y (en) * 2000-07-04 2001-05-23 胡柏 Generator for producing ozone by electrolyzing process
CN2571771Y (en) * 2002-10-16 2003-09-10 武汉大学 Ozone water preparation machine
US20080179185A1 (en) * 2006-08-08 2008-07-31 Chlorine Engineers Corp., Ltd. Ozone producing system
CN209307492U (en) * 2018-11-19 2019-08-27 武汉威蒙环保科技有限公司 A kind of built-in gas water cyclic electrolysis formula ozone generating-device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114182274A (en) * 2021-12-30 2022-03-15 深圳康诚博信科技有限公司 Ozone generation and transmission device designed without water pipe
CN114470289A (en) * 2021-12-30 2022-05-13 深圳康诚博信科技有限公司 Ozone disinfection machine
CN114470289B (en) * 2021-12-30 2023-09-26 深圳康诚博信科技有限公司 Ozone sterilizer
CN114182274B (en) * 2021-12-30 2023-12-12 深圳康诚博信科技有限公司 Ozone generation and transmission device with design of anhydrous pipe
CN114755282A (en) * 2022-04-12 2022-07-15 山东赛克赛斯氢能源有限公司 Novel membrane electrode testing device for pure water electrolysis catalyst
CN114755282B (en) * 2022-04-12 2024-01-30 山东赛克赛斯氢能源有限公司 Novel membrane electrode test device of pure water electrolysis catalyst

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