CN109338258A - Solve the process of aluminium alloy bars material 2A12 electrochemical enamelizing film part piebald - Google Patents
Solve the process of aluminium alloy bars material 2A12 electrochemical enamelizing film part piebald Download PDFInfo
- Publication number
- CN109338258A CN109338258A CN201811017188.5A CN201811017188A CN109338258A CN 109338258 A CN109338258 A CN 109338258A CN 201811017188 A CN201811017188 A CN 201811017188A CN 109338258 A CN109338258 A CN 109338258A
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- Prior art keywords
- blanking
- enamelizing
- electrochemical
- outer diameter
- electrochemical enamelizing
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/057—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/16—Pretreatment, e.g. desmutting
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- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Insulating Bodies (AREA)
Abstract
The invention belongs to technical field of surface, are related to a kind of process for solving aluminium alloy bars material 2A12 electrochemical enamelizing film part piebald.The technical solution of the invention is as follows, (1) blanking: the outer diameter of pieces of bar stock is greater than 15-20mm of part outer diameter;(2) timeliness: 180-190 DEG C of aging temp after blanking, time 5-6 hour;Bar is uprightly placed and is separated;(3) machine adds: being machined by technique requirement;(4) electrochemical enamelizing: removing light except after light, carrying out cyanogen fluoric acid in nitric acid, when removing light between 5-10 seconds, then processed by normal technique requirement.Electrochemical enamelizing film of the present invention avoids the occurrence of part completely or speckle phenomena locally occur in many places, and film layer is bright, uniform, complete after part electrochemical enamelizing.It is suitble to the small part of rods and bars of aluminium alloy 2A12 processing to be also suitble to heavy parts, operating method is simply at low cost, can promote for military project, space flight, ship, civilian etc..
Description
Technical field
The invention belongs to technical field of surface, are related to a kind of solution aluminium alloy bars material 2A12 electrochemical enamelizing film office
The process of portion's piebald.
Background technique
Currently, carrying out electrochemical enamelizing after being processed into part through timeliness with rods and bars of aluminium alloy 2A12, technique part is wanted
By following process:
Blanking --- timeliness --- machine adds --- electrochemical enamelizing
(1) blanking: blanking outer diameter is Ф 30mm, blanking outer diameter when part outer diameter is Ф 45mm when part outer diameter is Ф 28mm
For Ф 48mm.
(2) timeliness: 180-190 DEG C of aging temp after blanking, time 3-4 hour.
(3) machine adds: carrying out by technique requirement.
(4) it electrochemical enamelizing: is carried out by technique requirement.Using the part of this process, in the porcelain sun of part outer wall
Locally there is speckle phenomena in polarized film part or many places.Speckle phenomena has and gently has weight, and general every batch of part has 3/4 to will appear speckle
Phenomenon.
Summary of the invention
The purpose of the present invention is: it solves after aluminium alloy bars material 2A12 is processed into part through timeliness, when electrochemical enamelizing
The technological problems of film layer part piebald.
The technical solution of the invention is as follows,
(1) blanking: the outer diameter of pieces of bar stock is greater than 15-20mm of part outer diameter;
(2) timeliness: 180-190 DEG C of aging temp after blanking, time 5-6 hour;Bar is uprightly placed and is separated;
(3) machine adds: being machined by technique requirement;
(4) electrochemical enamelizing: removing light except after light, carrying out cyanogen fluoric acid in nitric acid, when removing light between 5-10 second, then by normally
Technique requires to be processed.
Each bar separation gap is not less than 5mm when the timeliness.
The present invention has the advantage that and beneficial effect,
Since aluminium alloy bars material 2A12 is when drawing is become a useful person, the deep layer of external diameter surface 10-16mm is the unstable of material
Layer, therefore, the present invention, by the outer diameter overstriking of blank, enables aluminum alloy to the unstable of bar material 2A12 external diameter surface in blanking
Layer minimizes;In addition when material ages, invention increases aging time and aging temp, solve due to aging temp or
The non-uniform problem of material quality status brought by time deficiency, then aluminium alloy bars material 2A12 is uprightly placed and separated each
Part, to keep the material quality status homogeneity range of material bigger.Increase cyanogen fluoric acid after nitric acid is except light and remove light process, makes part
More evenly, by the part that above-mentioned technique is processed, electrochemical enamelizing film is not in that part or many places spot locally occur to surface state
Line phenomenon, part, after electrochemical enamelizing film layer it is bright, uniformly, it is complete.
Electrochemical enamelizing film of the present invention avoids the occurrence of part completely or speckle phenomena, part porcelain anode locally occur in many places
Film layer is bright, uniform, complete after change.It is suitble to the small part of rods and bars of aluminium alloy 2A12 processing to be also suitble to heavy parts, operating method
It is simple at low cost, it can promote for military project, space flight, ship, civilian etc..
Specific embodiment
Present invention process part will pass through following process:
Blanking --- timeliness --- machine adds --- electrochemical enamelizing
(1) blanking: the outer diameter of pieces of bar stock is greater than 15-20mm of part outer diameter;For example, part outer diameter is Ф
Blanking outer diameter is Ф 38-54mm when 28mm, and blanking outer diameter is Ф 54-60mm when part outer diameter is Ф 45mm.(guarantee that part uses
Outer diameter material settling out removes material external diameter surface instable layer)
(2) timeliness: 180-190 DEG C of aging temp after blanking, time 5-6 hour.(stabilizing material state, makes inside and outside material
Uniformly.)
(3) machine adds: being machined by technique requirement.
(4) electrochemical enamelizing: after nitric acid is except light, increasing cyanogen fluoric acid and remove light, other to carry out by normal process requirement.It is (complete
Full removal piece surface covers object)
By the part that above-mentioned new process is processed, electrochemical enamelizing film is not in that speckle locally occur existing for part or many places
As, part, bright, uniform, the complete of film layer after electrochemical enamelizing
Operation notice:
(1) part blanking outer diameter increases Ф 15-20mm on part outer diameter Ji Chu.
Aging temp cannot be below 180 DEG C after (2) blanking, and the time cannot be less than 5 hours, and when timeliness preferably founds material
It rises and places and separate.(to be separated between material)
The part of (3) electrochemical enamelizing aluminium bar material generally removes light without cyanogen fluoric acid, and only aluminum casting is just removed with cyanogen fluoric acid
Light, for 5-10 seconds between completely removing when piece surface covers when object increases cyanogen fluoric acid except light except light.
Embodiment
Example 1: electrochemical enamelizing after being processed into shell with aluminium alloy bars material 2A12, housing outer diameter Ф 28mm.
Part will pass through following process:
Blanking --- timeliness --- machine adds --- electrochemical enamelizing
(1) blanking: when part outer diameter is Ф 28mm, blanking outer diameter part outer diameter is Ф 45mm.
(2) timeliness: 180 DEG C of aging temp after blanking, the time 5 hours.Material is erected when timeliness and places and separates.
(to be separated between material)
(3) machine adds: carrying out by technique requirement.
(4) electrochemical enamelizing: 5 seconds between increasing when removing light when cyanogen fluoric acid removes light before electrochemical enamelizing, electrochemical enamelizing presses work
Skill requires to carry out,
By above method electrochemical enamelizing film, no speckle phenomena.
Example 2: electrochemical enamelizing after being processed into shell with aluminium alloy bars material 2A12, housing outer diameter Ф 45mm.
Part will pass through following process:
Blanking --- timeliness --- machine adds --- electrochemical enamelizing
(1) blanking: when part outer diameter is Ф 45mm, blanking outer diameter part outer diameter is Ф 60mm.
(2) timeliness: 180 DEG C of aging temp after blanking, the time 6 hours.Material is erected when timeliness and places and separates.
(to be separated between material)
(3) machine adds: carrying out by technique requirement.
(4) electrochemical enamelizing: 10 seconds between increasing when removing light when cyanogen fluoric acid removes light before electrochemical enamelizing, electrochemical enamelizing presses work
Skill requires to carry out,
By above method electrochemical enamelizing film, no speckle phenomena.
Example 3: electrochemical enamelizing after being processed into shell with aluminium alloy bars material 2A12, housing outer diameter Ф 120mm.
Part will pass through following process:
Blanking --- timeliness --- machine adds --- electrochemical enamelizing
(1) blanking: when part outer diameter is Ф 120mm, blanking outer diameter part outer diameter is Ф 140mm.
(2) timeliness: 190 DEG C of aging temp after blanking, the time 5 hours.Material is erected when timeliness and places and separates.
(to be separated between material)
(3) machine adds: carrying out by technique requirement.
(4) electrochemical enamelizing: 8 seconds between increasing when removing light when cyanogen fluoric acid removes light before electrochemical enamelizing, electrochemical enamelizing presses work
Skill requires to carry out,
By above method electrochemical enamelizing film, no speckle phenomena.
Claims (2)
1. a kind of process for solving aluminium alloy bars material 2A12 electrochemical enamelizing film part piebald, characterized in that
(1) blanking: the outer diameter of pieces of bar stock is greater than 15-20mm of part outer diameter;
(2) timeliness: 180-190 DEG C of aging temp after blanking, time 5-6 hour;Bar is uprightly placed and is separated;
(3) machine adds: being machined by technique requirement;
(4) electrochemical enamelizing: removing light except after light, carrying out cyanogen fluoric acid in nitric acid, when removing light between 5-10 second, then by normal technique
It is required that being processed.
2. a kind of technique side for solving aluminium alloy bars material 2A12 electrochemical enamelizing film part piebald according to claim 1
Method, characterized in that each bar separation gap is not less than 5mm when the timeliness.
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CN201811017188.5A CN109338258B (en) | 2018-08-31 | 2018-08-31 | Process method for solving local mottling of ceramic anodized film of aluminum alloy rod material 2A12 |
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CN201811017188.5A CN109338258B (en) | 2018-08-31 | 2018-08-31 | Process method for solving local mottling of ceramic anodized film of aluminum alloy rod material 2A12 |
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CN109338258B CN109338258B (en) | 2020-10-13 |
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Citations (6)
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CN101792919A (en) * | 2010-04-12 | 2010-08-04 | 北京航空航天大学 | Anodic oxidation treating fluid containing corrosion inhibition additive |
US20110119983A1 (en) * | 2009-11-25 | 2011-05-26 | James Richard Muller | Aluminum choke tube for a shotgun |
CN103540968A (en) * | 2013-09-24 | 2014-01-29 | 成都泛华航空仪表电器有限公司 | Process method for electroplating nickel on aluminum-copper composite material component |
CN103866369A (en) * | 2013-12-27 | 2014-06-18 | 陕西航天导航设备有限公司 | Insulation protection method for local hard anodizing of precision parts |
EP3056579A1 (en) * | 2015-02-16 | 2016-08-17 | The Boeing Company | Method for manufacturing anodized aluminum alloy parts without surface discoloration |
CN106637343A (en) * | 2016-12-07 | 2017-05-10 | 中国航空工业集团公司北京航空材料研究院 | Hard anodizing preprocessing method for 7A85-T7452 aluminum alloy aeronautical parts |
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2018
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US20110119983A1 (en) * | 2009-11-25 | 2011-05-26 | James Richard Muller | Aluminum choke tube for a shotgun |
CN101792919A (en) * | 2010-04-12 | 2010-08-04 | 北京航空航天大学 | Anodic oxidation treating fluid containing corrosion inhibition additive |
CN103540968A (en) * | 2013-09-24 | 2014-01-29 | 成都泛华航空仪表电器有限公司 | Process method for electroplating nickel on aluminum-copper composite material component |
CN103866369A (en) * | 2013-12-27 | 2014-06-18 | 陕西航天导航设备有限公司 | Insulation protection method for local hard anodizing of precision parts |
EP3056579A1 (en) * | 2015-02-16 | 2016-08-17 | The Boeing Company | Method for manufacturing anodized aluminum alloy parts without surface discoloration |
CN106637343A (en) * | 2016-12-07 | 2017-05-10 | 中国航空工业集团公司北京航空材料研究院 | Hard anodizing preprocessing method for 7A85-T7452 aluminum alloy aeronautical parts |
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