CN109337561A - The solvent-free UV coating of artificial leather - Google Patents

The solvent-free UV coating of artificial leather Download PDF

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Publication number
CN109337561A
CN109337561A CN201811195496.7A CN201811195496A CN109337561A CN 109337561 A CN109337561 A CN 109337561A CN 201811195496 A CN201811195496 A CN 201811195496A CN 109337561 A CN109337561 A CN 109337561A
Authority
CN
China
Prior art keywords
coating
additive
agent
solvent
free
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811195496.7A
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Chinese (zh)
Inventor
李鑫
林海江
刘立华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tangshan Fengrun Mile Photosensitive New Materials Co Ltd
Original Assignee
Tangshan Fengrun Mile Photosensitive New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tangshan Fengrun Mile Photosensitive New Materials Co Ltd filed Critical Tangshan Fengrun Mile Photosensitive New Materials Co Ltd
Priority to CN201811195496.7A priority Critical patent/CN109337561A/en
Publication of CN109337561A publication Critical patent/CN109337561A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/47Levelling agents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The present invention relates to a kind of UV technical field of coatings more particularly to a kind of solvent-free UV coating of artificial leather.The coating composition and mass percent are as follows: photosensitive resin 40%~50%;Crosslinking agent 20%~30%;Photoinitiator 5%~10%;Additive 8%~25%;Additive includes levelling agent and dispersing agent.Compared with prior art, the application is a kind of solventless coatings, and non-hazardous property gaseous volatilization does not pollute environment, be content with very little environmental requirement;By adding additive, the quality of the coating is made to be highly improved with performance;The coating has the characteristics that curing rate is fast, can shorten the construction time, improves working efficiency;The coating can replace PU coating commonly used in the market completely.

Description

The solvent-free UV coating of artificial leather
Technical field
The present invention relates to a kind of UV technical field of coatings more particularly to a kind of solvent-free UV coating of artificial leather.
Background technique
PU coating is a kind of emerging high-molecular organic material, is known as " the fifth-largest plastics ", due to the performance of its brilliance It is widely used in national economy various fields.PU coating application field be related to light industry, chemical industry, electronics, weaving, medical treatment, building, Building materials, automobile, national defence, space flight, aviation etc..And generally using currently on the market is PU coating, entity curing time is longer, raw Produce inefficiency;In addition, generated exhaust gas, waste water can have certain pollution, Er Qiesheng to environment when producing these PU coating Production process is affected by environment larger, and capability and performance can not ensure.Therefore, it is badly in need of researching and developing a kind of new coating, instead of general in the market All over the PU coating of application.
Summary of the invention
The purpose of the present invention is to provide a kind of solvent-free UV coating of artificial leather.
The present invention adopts the following technical scheme:
A kind of solvent-free UV coating of artificial leather, component and mass percent are as follows: photosensitive resin 40%~50%;Crosslinking agent 20% ~30%;Photoinitiator 5%~10%;Additive 8%~25%;Wherein, additive includes levelling agent and dispersing agent.
By adopting the above technical scheme compared with the prior art, the invention has the following advantages: the present invention is a kind of without molten Agent coating, non-hazardous property gaseous volatilization, does not pollute environment, be content with very little environmental requirement;By adding additive, make this The quality of coating is highly improved with performance;The coating has the characteristics that curing rate is fast, can shorten the construction time, Improve working efficiency;The coating can replace PU coating commonly used in the market completely.
Preferred embodiment of the invention is:
The preparation method of photosensitive resin is to be mixed and stirred for performed polymer and diluent uniformly, to add photosensitizer and additive, High-speed stirred is made.
Additive component and mass percent are as follows: levelling agent 10%~35%, dispersing agent 60%~90%.
Specific embodiment
Embodiment 1
A kind of solvent-free UV coating of artificial leather, component and mass percent are as follows: 40 parts of photosensitive resin;30 parts of crosslinking agent;Light 8 parts of initiator;22 parts of additive.
Additive is made of levelling agent and dispersing agent;Additive component and mass percent are as follows: levelling agent 11%, dispersion Agent 89%.Dispersing agent is organosilicon-modified acrylate;Levelling agent is polyether silicone acrylate.
Photosensitive resin the preparation method comprises the following steps: performed polymer and diluent 3:1 in mass ratio are mixed and stirred for uniformly, adding Photosensitizer and additive high-speed stirred are made.Performed polymer uses three wood products of Jiangsu: performed polymer 6105-80;Diluent uses river The field Su Li product: diluent NPGDA.
Embodiment 2
A kind of solvent-free UV coating of artificial leather, component and mass percent are as follows: 48 parts of photosensitive resin;28 parts of crosslinking agent;Light 10 parts of initiator;14 parts of additive.
Additive is made of levelling agent and dispersing agent;Additive component and mass percent are as follows: levelling agent 20%, dispersion Agent 80%.Dispersing agent is organosilicon-modified acrylate;Levelling agent is polyether silicone acrylate.
Photosensitive resin the preparation method comprises the following steps: performed polymer and diluent 3:1 in mass ratio are mixed and stirred for uniformly, adding Photosensitizer and additive high-speed stirred are made.Performed polymer uses three wood products of Jiangsu: performed polymer 6105-80;Diluent uses river The field Su Li product: diluent NPGDA.
Embodiment 3
A kind of solvent-free UV coating of artificial leather, component and mass percent are as follows: 41 parts of photosensitive resin;23 parts of crosslinking agent;Light 11 parts of initiator;25 parts of additive.
Additive is made of levelling agent and dispersing agent;Additive component and mass percent are as follows: levelling agent 30%, dispersion Agent 70%.Dispersing agent is organosilicon-modified acrylate;Levelling agent is polyether silicone acrylate.
Photosensitive resin the preparation method comprises the following steps: performed polymer and diluent 3:1 in mass ratio are mixed and stirred for uniformly, adding Photosensitizer and additive high-speed stirred are made.Performed polymer uses three wood products of Jiangsu: performed polymer 6105-80;Diluent uses river The field Su Li product: diluent NPGDA.
Embodiment 4
A kind of solvent-free UV coating of artificial leather, component and mass percent are as follows: 50 parts of photosensitive resin;20 parts of crosslinking agent;Light 9 parts of initiator;21 parts of additive.
Additive is made of levelling agent and dispersing agent;Additive component and mass percent are as follows: levelling agent 35%, dispersion Agent 65%.Dispersing agent is organosilicon-modified acrylate;Levelling agent is polyether silicone acrylate.
Photosensitive resin the preparation method comprises the following steps: performed polymer and diluent 3:1 in mass ratio are mixed and stirred for uniformly, adding Photosensitizer and additive high-speed stirred are made.Performed polymer uses three wood products of Jiangsu: performed polymer 6105-80;Diluent uses river The field Su Li product: diluent NPGDA.

Claims (3)

1. a kind of solvent-free UV coating of artificial leather, it is characterised in that: its component and mass percent are as follows: photosensitive resin 40%~ 50%;Crosslinking agent 20%~30%;Photoinitiator 5%~10%;Additive 8%~25%;Additive is made of levelling agent and dispersing agent.
2. the solvent-free UV coating of artificial leather according to claim 1, it is characterised in that: the preparation method of photosensitive resin is will Performed polymer and diluent are mixed and stirred for uniformly, adding photosensitizer and additive, and high-speed stirred is made.
3. the solvent-free UV coating of artificial leather according to claim 1, it is characterised in that: additive component and mass percent It is as follows: levelling agent 10%~35%, dispersing agent 60%~90%.
CN201811195496.7A 2018-10-15 2018-10-15 The solvent-free UV coating of artificial leather Pending CN109337561A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811195496.7A CN109337561A (en) 2018-10-15 2018-10-15 The solvent-free UV coating of artificial leather

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811195496.7A CN109337561A (en) 2018-10-15 2018-10-15 The solvent-free UV coating of artificial leather

Publications (1)

Publication Number Publication Date
CN109337561A true CN109337561A (en) 2019-02-15

Family

ID=65310075

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811195496.7A Pending CN109337561A (en) 2018-10-15 2018-10-15 The solvent-free UV coating of artificial leather

Country Status (1)

Country Link
CN (1) CN109337561A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103012722A (en) * 2012-12-26 2013-04-03 河北智生环保科技有限公司 Photocuring polyurethane resin for leather or synthetic leather coating decoration and preparation method for photocuring polyurethane resin
CN107892863A (en) * 2017-12-14 2018-04-10 湖南阳光新材料有限公司 A kind of PVC floor plastic-rubber antibacterial type UV coating
CN108299886A (en) * 2016-08-10 2018-07-20 上海长悦涂料有限公司 A kind of solvent-free UV spray paints coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103012722A (en) * 2012-12-26 2013-04-03 河北智生环保科技有限公司 Photocuring polyurethane resin for leather or synthetic leather coating decoration and preparation method for photocuring polyurethane resin
CN108299886A (en) * 2016-08-10 2018-07-20 上海长悦涂料有限公司 A kind of solvent-free UV spray paints coating and preparation method thereof
CN107892863A (en) * 2017-12-14 2018-04-10 湖南阳光新材料有限公司 A kind of PVC floor plastic-rubber antibacterial type UV coating

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Application publication date: 20190215