CN109337197A - A kind of durable chopping block plastics and preparation method thereof - Google Patents

A kind of durable chopping block plastics and preparation method thereof Download PDF

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Publication number
CN109337197A
CN109337197A CN201811058033.6A CN201811058033A CN109337197A CN 109337197 A CN109337197 A CN 109337197A CN 201811058033 A CN201811058033 A CN 201811058033A CN 109337197 A CN109337197 A CN 109337197A
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CN
China
Prior art keywords
parts
nano
chopping block
durable
antibacterial agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811058033.6A
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Chinese (zh)
Inventor
黄桂云
许焱
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Anhui Tianle Plastic Co Ltd
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Anhui Tianle Plastic Co Ltd
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Publication date
Application filed by Anhui Tianle Plastic Co Ltd filed Critical Anhui Tianle Plastic Co Ltd
Priority to CN201811058033.6A priority Critical patent/CN109337197A/en
Publication of CN109337197A publication Critical patent/CN109337197A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2286Oxides; Hydroxides of metals of silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of durable chopping block plastics, the raw material including following parts by weight: 90-110 parts of polypropylene, 4-6 parts of low density polyethylene (LDPE), 3-5 parts of glycerol, 4-7 parts of sorbierite, 2-4 parts of vinyltriethoxysilane, 2-4 parts of basic zirconium phosphate, 3-6 parts of ceramic fibre, 3-6 parts of nanometer calcium carbonate, 2-5 parts of asbestos, 3-6 parts of bentonite, 10-16 parts of antibacterial agent, 1-3 parts of fire retardant, 1-3 parts of potassium sorbate.The plastics select polypropylene plastics to be made, and light weight, intensity are high, do not absorb water, excellent in mechanical performance.By the way that magnesium hydroxide is added as fire retardant, plastics inflammable disadvantage in use is prevented;By the way that the antibacterial agent of nano phase ag_2 o, nano zeolite, nano-titanium dioxide composition is added, play the role of inhibition or kills bacterium, the pollution for breeding bacterium to food is avoided, therefore, which is highly suitable for production chopping block, and durable.

Description

A kind of durable chopping block plastics and preparation method thereof
Technical field
The present invention relates to plastics and preparation method thereof, and in particular to a kind of durable chopping block plastics and preparation method thereof.
Background technique
Chopping block is a kind of indispensable daily necessity of the occasions such as family, hotel, restaurant.The chopping block used now is largely Made of timber, their density are high, toughness is strong, use securely, and still, there are many chopping block type as made of timber, Be not easy to select, and some wood chopping blocks (such as poplar) due to wooden than more loose, hardness is inadequate, easy to crack, and surface is easy Tool marks are generated, if cleaning is not thorough, it is easy to shelter evil people and countenance evil practices, breed bacterium, contaminated food.Moreover, because wood chopping block its Surface can not print any pattern, and wood chopping block appearance is very dull and unchanged, thus can not attract consumer's sight Attention.Most of all, being widely used for wood chopping block must just cut down a large amount of trees, certain break is caused to ecological environment It is bad.
Currently, with plastic products development it is increasingly mature, light weight, intensity are high, durable, environmentally friendly, easy to carry Plastic chopping block start the sight for gradually attracting consumer.Therefore it provides a kind of plastics of superior performance are used to prepare chopping block change It obtains particularly significant.
Summary of the invention
It is an object of the invention to: a kind of durable chopping block plastics and preparation method thereof are provided.
To achieve the goals above, the invention provides the following technical scheme:
A kind of durable chopping block plastics, the raw material including following parts by weight:
90-110 parts of polypropylene, 4-6 parts of low density polyethylene (LDPE), 3-5 parts of glycerol, 4-7 parts of sorbierite, vinyl triethoxyl 2-4 parts of silane, 3-6 parts of ceramic fibre, 3-6 parts of nanometer calcium carbonate, 2-5 parts of asbestos, 3-6 parts of bentonite, resists 2-4 parts of basic zirconium phosphate 10-16 parts of microbial inoculum, 1-3 parts of fire retardant, 1-3 parts of potassium sorbate.
Preferably, a kind of durable chopping block plastics, the raw material including following parts by weight:
102 parts of polypropylene, 5 parts of low density polyethylene (LDPE), 4 parts of glycerol, 5 parts of sorbierite, 3 parts of vinyltriethoxysilane, 3 parts of basic zirconium phosphate, 4 parts of ceramic fibre, 5 parts of nanometer calcium carbonate, 3 parts of asbestos, 5 parts of bentonite, 12 parts of antibacterial agent, 2 parts of fire retardant, mountain 2 parts of potassium sorbate.
Preferably, the antibacterial agent is the mixture of nano phase ag_2 o, nano zeolite, nano-titanium dioxide.
Preferably, nano phase ag_2 o in the antibacterial agent, nano zeolite, nano-titanium dioxide mass ratio be 1:(3- 5):(2-4)。
Preferably, nano phase ag_2 o in the antibacterial agent, nano zeolite, nano-titanium dioxide mass ratio be 1:4:3.
Preferably, the fire retardant is magnesium hydroxide.
A kind of preparation method of durable chopping block plastics, weighs each raw material according to the ratio, mixing, and melting mixing, extrusion are made Grain.
The beneficial effects of the present invention are:
Plastics of the present invention select polypropylene plastics to be made, and light weight, intensity are high, do not absorb water, excellent in mechanical performance.By adding Enter magnesium hydroxide as fire retardant, prevents plastics inflammable disadvantage in use, improve the safety of plastics.By adding The antibacterial agent for entering nano phase ag_2 o, nano zeolite, nano-titanium dioxide composition plays the role of inhibition or kills bacterium, avoids Pollution of the bacterium to food is bred, therefore, which is highly suitable for production chopping block, and durable.
Specific embodiment
Embodiment 1
A kind of durable chopping block plastics, the raw material including following parts by weight:
90 parts of polypropylene, 4 parts of low density polyethylene (LDPE), 3 parts of glycerol, 4 parts of sorbierite, 2 parts of vinyltriethoxysilane, phosphorus 2 parts of sour zirconium, 3 parts of ceramic fibre, 3 parts of nanometer calcium carbonate, 2 parts of asbestos, 3 parts of bentonite, 10 parts of antibacterial agent, 1 part of magnesium hydroxide, mountain 1 part of potassium sorbate.
Antibacterial agent is made of nano phase ag_2 o, nano zeolite, the nano-titanium dioxide that mass ratio is 1:3:4.
The preparation method of above-mentioned durable chopping block plastics is to weigh each raw material according to the ratio, is mixed, and melting mixing, extrusion are made Grain.
Embodiment 2
A kind of durable chopping block plastics, the raw material including following parts by weight:
102 parts of polypropylene, 5 parts of low density polyethylene (LDPE), 4 parts of glycerol, 5 parts of sorbierite, 3 parts of vinyltriethoxysilane, 3 parts of basic zirconium phosphate, 4 parts of ceramic fibre, 5 parts of nanometer calcium carbonate, 3 parts of asbestos, 5 parts of bentonite, 12 parts of antibacterial agent, 2 parts of magnesium hydroxide, 2 parts of potassium sorbate.
Antibacterial agent is made of nano phase ag_2 o, nano zeolite, the nano-titanium dioxide that mass ratio is 1:4:3.
The preparation method of above-mentioned durable chopping block plastics is to weigh each raw material according to the ratio, is mixed, and melting mixing, extrusion are made Grain.
Embodiment 3
A kind of durable chopping block plastics, the raw material including following parts by weight:
110 parts of polypropylene, 6 parts of low density polyethylene (LDPE), 5 parts of glycerol, 7 parts of sorbierite, 4 parts of vinyltriethoxysilane, 4 parts of basic zirconium phosphate, 6 parts of ceramic fibre, 6 parts of nanometer calcium carbonate, 5 parts of asbestos, 6 parts of bentonite, 16 parts of antibacterial agent, 3 parts of magnesium hydroxide, 3 parts of potassium sorbate.
Antibacterial agent is made of nano phase ag_2 o, nano zeolite, the nano-titanium dioxide that mass ratio is 1:5:2.
The preparation method of above-mentioned durable chopping block plastics is to weigh each raw material according to the ratio, is mixed, and melting mixing, extrusion are made Grain.
Antibacterial test is carried out to plastics obtained by embodiment 1-3, anti-microbial property presses " QB/T2591-2003 antibiotic plastic antibacterial Method for testing performance and antibacterial effect " test method as defined in standard tested, and bacteriologic test strain is Staphylococcus aureus Bacterium, Escherichia coli, as a result as shown in the table:
Staphylococcus aureus Escherichia coli
Embodiment 1 98.9% 98.5%
Embodiment 2 99.2% 99.3%
Embodiment 3 98.4% 98.6%
As can be seen from the table: the plastics of the embodiment of the present invention have good anti-microbial property, meet long acting antibiotic Requirement.

Claims (7)

1. a kind of durable chopping block plastics, it is characterised in that: the raw material including following parts by weight:
90-110 parts of polypropylene, 4-6 parts of low density polyethylene (LDPE), 3-5 parts of glycerol, 4-7 parts of sorbierite, vinyltriethoxysilane 2-4 parts, 2-4 parts of basic zirconium phosphate, 3-6 parts of ceramic fibre, 3-6 parts of nanometer calcium carbonate, 2-5 parts of asbestos, 3-6 parts of bentonite, antibacterial agent 10-16 parts, 1-3 parts of fire retardant, 1-3 parts of potassium sorbate.
2. a kind of durable chopping block plastics according to claim 1, it is characterised in that: the original including following parts by weight Material:
102 parts of polypropylene, 5 parts of low density polyethylene (LDPE), 4 parts of glycerol, 5 parts of sorbierite, 3 parts of vinyltriethoxysilane, phosphoric acid 3 parts of zirconium, 4 parts of ceramic fibre, 5 parts of nanometer calcium carbonate, 3 parts of asbestos, 5 parts of bentonite, 12 parts of antibacterial agent, 2 parts of fire retardant, sorbic acid 2 parts of potassium.
3. a kind of durable chopping block plastics according to claim 1, it is characterised in that: the antibacterial agent is nano oxygen Change the mixture of silver, nano zeolite, nano-titanium dioxide.
4. a kind of durable chopping block plastics according to claim 3, it is characterised in that: nano oxygen in the antibacterial agent Change silver, nano zeolite, nano-titanium dioxide mass ratio be 1:(3-5): (2-4).
5. a kind of durable chopping block plastics according to claim 4, it is characterised in that: nano oxygen in the antibacterial agent Change silver, nano zeolite, nano-titanium dioxide mass ratio be 1:4:3.
6. a kind of durable chopping block plastics according to claim 1, it is characterised in that: the fire retardant is hydroxide Magnesium.
7. a kind of preparation method of durable chopping block plastics described in -6 any one according to claim 1, it is characterised in that: Each raw material is weighed according to the ratio, is mixed, melting mixing, extruding pelletization.
CN201811058033.6A 2018-09-11 2018-09-11 A kind of durable chopping block plastics and preparation method thereof Withdrawn CN109337197A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811058033.6A CN109337197A (en) 2018-09-11 2018-09-11 A kind of durable chopping block plastics and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811058033.6A CN109337197A (en) 2018-09-11 2018-09-11 A kind of durable chopping block plastics and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109337197A true CN109337197A (en) 2019-02-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811058033.6A Withdrawn CN109337197A (en) 2018-09-11 2018-09-11 A kind of durable chopping block plastics and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109337197A (en)

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Application publication date: 20190215