CN109336433A - Utilize the method for industrial residue clinker production novel gelled material - Google Patents
Utilize the method for industrial residue clinker production novel gelled material Download PDFInfo
- Publication number
- CN109336433A CN109336433A CN201811200282.4A CN201811200282A CN109336433A CN 109336433 A CN109336433 A CN 109336433A CN 201811200282 A CN201811200282 A CN 201811200282A CN 109336433 A CN109336433 A CN 109336433A
- Authority
- CN
- China
- Prior art keywords
- gelled material
- novel gelled
- days
- novel
- finely ground
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000463 material Substances 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 17
- 239000002699 waste material Substances 0.000 claims abstract description 13
- 239000003245 coal Substances 0.000 claims abstract description 8
- 229920005551 calcium lignosulfonate Polymers 0.000 claims abstract description 7
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims abstract description 7
- 238000006467 substitution reaction Methods 0.000 claims abstract description 6
- 235000013312 flour Nutrition 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000010802 sludge Substances 0.000 claims abstract description 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 238000010248 power generation Methods 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims 1
- 235000019738 Limestone Nutrition 0.000 abstract description 3
- 239000004927 clay Substances 0.000 abstract description 3
- 239000006028 limestone Substances 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 description 5
- 238000003672 processing method Methods 0.000 description 4
- 239000004035 construction material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000202567 Fatsia japonica Species 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009440 infrastructure construction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
- C04B12/005—Geopolymer cements, e.g. reaction products of aluminosilicates with alkali metal hydroxides or silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
Abstract
The invention discloses a kind of methods using power plant industrial residue clinker production novel gelled material, percentage by weight is calculated as 100% as raw material, additional tailing rejectable waste 1-2% and paper mill sludge calcium lignosulfonate 0.5-1% is sent into flour mill through mixing and is finely ground into specific surface area 450-700m2The novel gelled material of/kg, direct 100% substitution cement products concrete batching build materials for industry and civilian equal architectural engineerings, and the quality index of cementitious material meets or exceeds 32.5,42.5,52.5 prescribed requirement of cement product quality index.Other requirements of properties of product are met, the utilization rate of waste residue reduces cement production enterprise production cost, protect ecological environment up to 100%, and the problem of improve attached value, saved natural resources lime stone, clay and coal, reduced the pollution to environment.
Description
Technical field
The invention belongs to energy conservation and environmental protection new material technology field, particularly relate to using one made of industrial residue clinker
Kind cementitious material.
Background technique
Currently, with the rapid development of our country's economy, Process of Urbanization Construction needs a large amount of building cementing material product, water
Cement concrete is 21st century most important construction material.China annual new building about 16-21m2, such as high speed public affairs
The infrastructure constructions such as road, high-speed railway, bridge, tunnel, subway are larger.Large-scale construction needs a large amount of cement mixed
Solidifying soil material, and manufacture of cement will consume a large amount of natural non-renewable resources and the energy, 1 ton of portland cement of every production are ripe
Material needs to consume 1.5 tons of fat lime stone, clay resource, consumes 0.15 ton of coal, co is discharged into atmosphere2And so2About 1.6 tons of gas
Equal pernicious gases, cause global warming problem by the common concern of whole world various countries.The cement industry of height consumption, high pollution
Aggravate the pressure of the energy resource and environment to society.And thermal power plants are after being generated electricity using a large amount of energy coal at present
A large amount of waste residue clinker is discharged, and pile up like a mountain, only makees general maintenance road etc. and uses, attached value is low, dosage is low, the benefit less than 20%
With rate.So the present invention produces a kind of cementitious material product using advanced technical matters, directly substitutes cement products and be used in
There is the processing method of concrete utilization rate to be up to 100%, and attached value is high, have a kind of energy-saving and environment-friendly utilization Industry Waste slag hearth
The method that slag produces novel gelled material is that the present invention to be solved the problems, such as to economize on resources and the energy and environmental pollution.
Summary of the invention
To the above problem of the prior art, Novel glue is produced using industrial residue clinker the object of the present invention is to provide a kind of
The processing method of gel material product has advanced technical matters, and low energy consumption, and attached value is high, using clinker 100%, without secondary dirt
The characteristics of dye, the protection for being conducive to economize on resources with the energy and environment.
The technical solution adopted by the present invention is that: the processing method of novel gelled material of the present invention, processing method
Include the following steps:
1, it stocks up: using the industrial residue clinker being discharged after the power generation of power plant's coal, adding auxiliary material tailing rejectable waste and make
Paper plant's waste residue calcium lignosulfonate；
2, ingredient: being 100% by industrial residue clinker count by weight percentage, and the tailing for being subject to total weight calculation outside, which is got a foothold, to give up
Expect 1-2% and waste residue calcium lignosulfonate 0.5-1%；
3, grinding: the mixture prepared feeding flour mill be finely ground into specific surface area up to 450-700m2The novel gelling of/kg
Material, abbreviation cementitious material；
4, cementitious material purposes and dosage and technical indicator；By the direct 100% substitution cement products of the novel gelled material being finely ground into
Industry and civilian equal architectural engineerings construction materials are widely used in for concrete batching.Technical indicator reaches following standard: comparing table
Area >=450-700m2/ kg, compatibility >=180mm, pre-hardening work >=45 minute, final set≤480 minute, sulfur trioxide≤4.0%,
Chloride ion≤0.06%, 32.5,42.5,52.5 grades of intensity values are distinguished flexural strength 3 days are as follows: 3.5mpa, 4.0mpa, 4.5mpa, 28
It are as follows: 6.0mpa, 6.5mpa, 7.0mpa;It is anti-to suppress intensity 3 days are as follows: 16.0mpa, 19.0mpa, 22.0mpa, to be within 28 days
32.5mpa、42.5mpa、52.5mpa。
The effect that the present invention obtains is:
1, novel gelled material product produced by the invention, can direct 100% substitution cement products to be used in concrete batching extensive
Materials are built for industry and civilian equal architectural engineerings, effect is better than the quality requirement of same cement products, improves concrete
The features such as service performance, compatibility is big, and water requirement is few, and intensity is high, economizes on electricity, the useless rate 100% of benefit, production cost is low；
2, product of the present invention is that the industrial residue clinker being discharged using power plant solves outlet, provides a new technology wound
New product protects environment not by secondary pollution, has saved natural resources lime stone, clay and coal for cement production enterprise 100%；
3, product of the present invention exploitation prospect is vast；
4, product of the present invention can be activated in 100% waste residue clinker using additional 1-2% tailing rejectable waste and 0.5-1% waste residue calcium lignosulfonate
Mineral composition, decomposition rate is fast, induction crystalline polymeric precipitability accelerate, and reduce dissolution in ion concentration increase than table
Grain rate of dispersion, so as to form the mineral composition ingredient of the cement cementitious material equal with cement products.Be conducive to Novel glue
The advanced hydration reaction of gel material.
Specific embodiment
In order to deepen to understand that the invention will be further described in conjunction with the embodiments, these realities to technical solution of the present invention
It applies example and is used to explain the present invention product, do not constitute and the scope of protection of the invention is limited.
Embodiment 1:
Novel gelled material product preparation method is raw material by weight using the industrial residue clinker being discharged after the power generation of power plant coal
Amount percentage is calculated as 100%, and additional tailing rejectable waste is calculated as 1% by total weight percent, additional paper mill sludge calcium lignosulfonate
It is calculated as 0.5% by total weight percent, is sent into flour mill through mixing and be finely ground into specific surface area greater than 450-700m2/kg
The direct 100% substitution cement products configuration concrete of novel gelled material build materials for industry and civilian equal architectural engineerings,
Through detecting cementitious material quality index are as follows: specific surface area 456m2/ kg, compatibility 312mm, initial set 126 minutes, final set 212 divides
Clock, sulfur trioxide 2.96%, chloride ion 0.02%, three days 5.1mpa of flexural strength, 28 days 8.5mpu, compression strength 3 days
23.6mpa, 28 days 51.6mpa
Embodiment 2
Novel gelled material product preparation method is raw material using the industrial residue clinker being discharged after the power generation of power plant coal,
It is count by weight percentage 100%, additional tailing rejectable waste is calculated as 2% by total weight percent, additional paper mill sludge
Calcium lignosulfonate is calculated as 1% by total weight percent, is sent into flour mill through mixing and carries out being finely ground into specific surface area >=450-700m2/kg
Novel gelled material, direct 100% substitution cement products configuration concrete uses for industry and civilian equal architectural engineerings construction
Material, through detecting cementitious material quality index are as follows: specific surface area 705m2/ kg, compatibility 315mm, initial set 125 minutes, final set 209
Minute, sulfur trioxide 2.92%, chloride ion 0.016%, 3 days 5.6mpa of flexural strength, 28 days 8.8mpa, compression strength 3 days
25.2mpa, 28 days 55.1mpa.
Embodiment described above only technical thought and feature to illustrate the invention, its object is to be familiar with personnel of the invention
It will appreciate that its content and pay in implementation, the protection scope of the technology of the present invention, all technologies according to the present invention etc. can not be limited with this
It imitates system or modification is all covered in the protection scope of the technology of the present invention.
Claims (4)
1. a kind of method using industrial residue clinker production novel gelled material, feature are included in, by weight percentage
It calculates using the industrial residue clinker being discharged after the station-service coal power generation that generates electricity as raw material, accounting 100% is additional to press total weight percent
Calculating is 1-2% using tailing leftover bits and pieces waste residue and paper mill sludge calcium lignosulfonate is 0.5-1% as added material, is sent into flour mill through mixing
Powder be finely ground into get novel gelled material.
2. production novel gelled material method according to claim 1, feature are included in, novel gelled material is compared into table
Area is finely ground into 450-700m2The cementitious material product of/kg.
3. production novel gelled material method according to claim 2, feature are included in, the novel gelling that will be finely ground into
The direct 100 substitution cement products of material build materials for industrial and civilian equal architectural engineerings using concrete batching.
4. production novel gelled material method according to claim 3, feature are included in, the novel gelling material being finely ground into
Expect quality and technical index are as follows: specific surface area, >=450-700m2/ kg, compatibility >=180mm, initial set >=45 minutes, final set≤480
Minute, sulfur trioxide≤4.0%, chloride ion≤0.06%, 32.5,42.5,52.5 grades of intensity value difference flexural strengths are 3 days
3.5mpa, 4.0mpa, 4.5mpa, 28 days 6.0mpa, 6.5mpa7.0mpu, compression strength be 3 days 16.0mpa, 19mpa,
22mpu, 28 days 32.5mpa, 42.5mpa, 52.5mpa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811200282.4A CN109336433B (en) | 2018-10-16 | 2018-10-16 | Method for producing cementing material by using industrial waste slag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811200282.4A CN109336433B (en) | 2018-10-16 | 2018-10-16 | Method for producing cementing material by using industrial waste slag |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109336433A true CN109336433A (en) | 2019-02-15 |
| CN109336433B CN109336433B (en) | 2021-12-31 |
Family
ID=65309403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811200282.4A Active CN109336433B (en) | 2018-10-16 | 2018-10-16 | Method for producing cementing material by using industrial waste slag |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109336433B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114890700A (en) * | 2022-04-06 | 2022-08-12 | 新疆交通投资(集团)有限责任公司 | Chloride-resistant geopolymer cementing material prepared from slag and carbide slag |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065851A (en) * | 1991-04-17 | 1992-11-04 | 王先进 | Adopt iron tailings and high calcium coal ash to produce the method for masonry cement |
| JP2006082989A (en) * | 2004-09-14 | 2006-03-30 | Kcmt Co Ltd | Pozzolan-based cement admixture using paper sludge |
| CN101481223A (en) * | 2009-02-04 | 2009-07-15 | 李三留 | Method for producing composite gel material from industrial residue and composite material thereof |
| CN102765889A (en) * | 2012-07-11 | 2012-11-07 | 北京科技大学 | Preparation method for tailing barren rock-made high-strength concrete containing coal ash |
| WO2013039311A2 (en) * | 2011-09-14 | 2013-03-21 | (유)그린원 | Method for preparing mineral pulp using waste coal resources |
| CN103951294A (en) * | 2014-04-15 | 2014-07-30 | 滨州键合胶凝新材料研究所 | Inorganic chemical bonding cementing material and preparation method thereof |
-
2018
- 2018-10-16 CN CN201811200282.4A patent/CN109336433B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065851A (en) * | 1991-04-17 | 1992-11-04 | 王先进 | Adopt iron tailings and high calcium coal ash to produce the method for masonry cement |
| JP2006082989A (en) * | 2004-09-14 | 2006-03-30 | Kcmt Co Ltd | Pozzolan-based cement admixture using paper sludge |
| CN101481223A (en) * | 2009-02-04 | 2009-07-15 | 李三留 | Method for producing composite gel material from industrial residue and composite material thereof |
| WO2013039311A2 (en) * | 2011-09-14 | 2013-03-21 | (유)그린원 | Method for preparing mineral pulp using waste coal resources |
| CN102765889A (en) * | 2012-07-11 | 2012-11-07 | 北京科技大学 | Preparation method for tailing barren rock-made high-strength concrete containing coal ash |
| CN103951294A (en) * | 2014-04-15 | 2014-07-30 | 滨州键合胶凝新材料研究所 | Inorganic chemical bonding cementing material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘仁庆，: "《造纸入门》", 31 October 1981, 轻工业出版社 * |
| 韩怀强等: "《粉煤灰利用技术》", 31 January 2001, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114890700A (en) * | 2022-04-06 | 2022-08-12 | 新疆交通投资(集团)有限责任公司 | Chloride-resistant geopolymer cementing material prepared from slag and carbide slag |
| CN114890700B (en) * | 2022-04-06 | 2024-02-06 | 新疆交通投资(集团)有限责任公司 | Chlorine salt-resistant geopolymer cementing material prepared from slag and carbide slag |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109336433B (en) | 2021-12-31 |
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Legal Events
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| SE01 | Entry into force of request for substantive examination | ||
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| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220325 Address after: 223211 Shi Tang Zhen Jian Huai Cun, Huai'an District, Huai'an City, Jiangsu Province Patentee after: Tan Jilin Address before: 223211 Jianhuai Village, Jianhuai Township, Huai'an District, Huai'an City, Jiangsu Province Patentee before: Huaian Cement Factory Co.,Ltd. Patentee before: Tan Jilin |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231116 Address after: 211600 No. 188, Shanhe Avenue, Jinbei building materials Industrial Park, Jinhu County, Huai'an City, Jiangsu Province Patentee after: Jiangsu Shanhe Cement Co.,Ltd. Address before: 223211 Shi Tang Zhen Jian Huai Cun, Huai'an District, Huai'an City, Jiangsu Province Patentee before: Tan Jilin |