CN109336205A - A kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler - Google Patents

A kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler Download PDF

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Publication number
CN109336205A
CN109336205A CN201811513496.7A CN201811513496A CN109336205A CN 109336205 A CN109336205 A CN 109336205A CN 201811513496 A CN201811513496 A CN 201811513496A CN 109336205 A CN109336205 A CN 109336205A
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CN
China
Prior art keywords
fluidized bed
circulating fluidized
waste water
bed boiler
processing device
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811513496.7A
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Chinese (zh)
Inventor
蒋敏华
钟犁
肖平
郭涛
李强
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Huaneng Clean Energy Research Institute
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Huaneng Clean Energy Research Institute
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Priority to CN201811513496.7A priority Critical patent/CN109336205A/en
Publication of CN109336205A publication Critical patent/CN109336205A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/043Details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/12Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
    • B01D45/16Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream, the centrifugal forces being generated solely or partly by mechanical means, e.g. fixed swirl vanes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/16Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/10Energy recovery

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The invention discloses a kind of desulfurizing waste water processing devices suitable for circulating fluidized bed boiler, including desulfurizing tower, desulfurization wastewater pipe and slag cooler, atomizer is provided in slag cooler, the desulfurization wastewater outlet of desulfurizing tower is connected through desulfurization wastewater pipe with the atomizer in slag cooler, the side of slag cooler is provided with slag outlet, which can be suitable for circulating fluidized bed boiler.

Description

A kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler
Technical field
The invention belongs to thermal power generation unit and environment protection fields, and it is useless to be related to a kind of desulfurization suitable for circulating fluidized bed boiler Water treatment facilities.
Background technique
A large amount of flue dust, sulfur dioxide are contained in the flue gas of coal burning generation based on coal fired power generation in power plant of China (SO2), nitrogen oxides (NOX) etc. pollutants, be the primary discharge source of above-mentioned pollutant.It is effective in order to be carried out to above-mentioned pollutant Control, State Ministry of Environmental Protection is also in the continuous limit value reduced to coal-burning power plant's pollutant emission.
Wherein, in order to meet SO2Discharge standard, it is de- that most of coal-burning power plant is all configured with Gypsum Wet flue gas Sulphur system (WFGD), accounting reaches 90% or more.But a certain amount of desulfurization wastewater can be generated when system operation, the waste water Complicated component, and there is strong corrosive, being effectively treated becomes the key for restricting coal-burning power plant's wastewater zero discharge.
Currently, the main processing technique of desulfurization wastewater includes: concentration Decrement Technique, evaporative crystallization technique, flue evaporation skill Art.Wherein, the investment operating cost that Decrement Technique and evaporative crystallization technique is concentrated is high, and flue evaporation technique has influence boiler It the problems such as efficiency, flue blockage fouling, is still left to be desired.
Recirculating fluidized bed (CFB) boiler technology, be only second to pulverized-coal fired boiler technology China's Coal-fired Power Plants technology it One.In early days, work as SO2When discharge standard is not yet so stringent, CFB boiler generallys use desulfuration in furnace technology and realizes SO2Row up to standard It puts.But under minimum discharge requirement, quite a few CFB boiler also selects to use WFGD Wet Flue Gas Desulfurization Technique, therefore also face Face the processing problem of desulfurization wastewater.
Summary of the invention
It is an object of the invention to overcome the above-mentioned prior art, provide a kind of suitable for circulating fluidized bed boiler Desulfurizing waste water processing device, which can be suitable for circulating fluidized bed boiler.
In order to achieve the above objectives, the desulfurizing waste water processing device of the present invention suitable for circulating fluidized bed boiler includes Desulfurizing tower, desulfurization wastewater pipe and slag cooler, atomizer is provided in slag cooler, and the desulfurization wastewater outlet of desulfurizing tower is useless through desulfurization Water pipe is connected with the atomizer in slag cooler, and the side of slag cooler is provided with slag outlet.
Further include boiler, cyclone separator, back-end ductwork and deduster, wherein boiler, cyclone separator, back-end ductwork, Deduster and desulfurizing tower are sequentially connected logical, and the slag notch of cyclone separator is connected with the clinker entrance of slag cooler by scum pipe It is logical, residual cake valve is provided on the scum pipe.
Steam (vapor) outlet at the top of slag cooler is communicated with steam outlet pipe.
It further include steam blower, steam outlet pipe is connected through steam blower with back-end ductwork.
Steam outlet pipe is connected with dust-extraction unit and heat-exchanger rig in turn.
The ash hole of cyclone separator is connected through circulating ash delivery pipe with slag cooler, is provided with and follows in circulating ash delivery pipe Ring ash valve.
Boiler is circulating fluidized bed boiler, and slag cooler is roller slag cooler or air-water combined slag cooler.
It is socketed with sleeve on the outer wall of slag cooler, cooling medium entrance and cooling medium outlet are provided on sleeve.
Temperature sensor is provided in slag cooler and in steam outlet pipe.
The invention has the following advantages:
Desulfurizing waste water processing device of the present invention suitable for circulating fluidized bed boiler is when specific operation, desulfurizing tower Desulfurization wastewater outlet be connected through desulfurization wastewater pipe with the atomizer in slag cooler, by by the desulfurization wastewater in desulfurizing tower It is passed through in slag cooler, by boiler slag or the sensible heat of circulating ash, realizes the vaporization process of desulfurization wastewater, wherein desulfurization wastewater The solid particle of middle remnants is largely discharged with clinker, it should be noted simultaneously that, desulfurization wastewater boiler slag and is followed in acidity Ring ash is in alkalinity, by acid-base neutralization, to realize the innoxious of desulfurization wastewater, in addition, the steam of slag cooler discharge can carry out Recycling and reusing, to realize the zero-emission of desulfurization wastewater, structure is simple, easy to operate, and practicability is stronger, for realizing coal-fired electricity Factory waste water zero discharge has very important significance.In addition, clinker sensible heat tends not to recycle, or be converted to low-grade Heat recovery, the initiative heat source as processing desulfurization wastewater of the present invention imitate unit compared to flue evaporation technique The influence of rate significantly reduces, and compared to technologies such as existing concentration decrement and evaporative crystallizations, the present invention invests operating cost It is lower, it is with good economic efficiency.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of embodiment one in the present invention;
Fig. 2 is the structural schematic diagram of embodiment two in the present invention;
Fig. 3 is the structural schematic diagram of embodiment three in the present invention.
Wherein, 1 it is boiler, 2 be scum pipe, 3 be residual cake valve, 4 be atomizer, 5 be clinker entrance, 6 is slag cooler, 7 It is steam outlet pipe for steam blower, 8,9 be sleeve, 10 be cooling medium outlet, 11 be cooling medium entrance, 12 is that clinker goes out Mouthful, 13 be back-end ductwork, 14 be deduster, 15 be desulfurizing tower, 16 be desulfurization wastewater pipe, 17 be dust-extraction unit, 18 be heat exchange fill It sets, 19 be cyclone separator, 20 be circulating ash delivery pipe, 21 be circulating ash valve.
Specific embodiment
The invention will be described in further detail with reference to the accompanying drawing:
With reference to Fig. 1, the desulfurizing waste water processing device of the present invention suitable for circulating fluidized bed boiler includes desulfurizing tower 15, desulfurization wastewater pipe 16 and slag cooler 6 are provided with atomizer 4 in slag cooler 6, and the desulfurization wastewater outlet of desulfurizing tower 15 is through de- Sulphur waste pipe 16 is connected with the atomizer 4 in slag cooler 6, and the side of slag cooler 6 is provided with slag outlet 12.
The invention also includes boiler 1, cyclone separator 19, back-end ductwork 13 and dedusters 14, wherein boiler 1, whirlwind point It is sequentially connected from device 19, back-end ductwork 13, deduster 14 and desulfurizing tower 15 logical, the clinker of the slag notch and slag cooler 6 of boiler 1 enters Mouth 5 is connected by scum pipe 2, is provided with residual cake valve 3 on the scum pipe 2;The steam (vapor) outlet at 6 top of slag device is communicated with steam Outlet 8.
Boiler 1 is circulating fluidized bed boiler, and slag cooler 6 is roller slag cooler or air-water combined slag cooler;Outside slag cooler 6 It is socketed with sleeve 9 on wall, cooling medium entrance 11 and cooling medium outlet 10 are provided on sleeve 9;In slag cooler 6 and steam goes out Temperature sensor is provided in mouth pipe 8.
Embodiment one
With reference to Fig. 1, handled using the desulfurization wastewater that the high temperature furnace slag that boiler 1 generates generates desulfurizing tower 15, cold slag Device 6 is roller slag cooler, and desulfurization wastewater is injected in slag cooler 6 through desulfurization wastewater pipe 16 and atomizer 4, utilizes slag cooler 6 In clinker sensible heat, realize the vaporization of desulfurization wastewater, while realizing the cooling of clinker, remaining solid after desulfurization wastewater vaporization Grain is discharged with clinker through slag outlet 12.The steam formed after desulfurization wastewater vaporization goes out entrainment of fine particle through steam Mouth pipe 8 and steam blower 7 are discharged into back-end ductwork 13, wherein fine particle is trapped through deduster 14 and removed, and steam then enters de- Moisturizing is realized in sulphur tower 15, is equipped with temperature sensor, the penetrating of feedback regulation desulfurization wastewater in slag cooler 6 and steam outlet pipe 8 Amount, to guarantee vapor (steam) temperature more than condensing temperature, steam is condensed during preventing.Slag cooler 6 is socketed with sleeve 9, realizes table The cooling in face, and the supplement as desulfurization wastewater sprinkling cooled slag, cooling medium is cooling wind, and cooling wind enters from cooling medium Mouth 11 enters in sleeve 9, leaves after heating through cooling medium outlet 10;Cooling wind used is derived from the high-pressure spray of fluidized-bed combustion boiler 1 Change wind, the cooling medium after heating sends hp fluid air main pipe back to, so that returning to burner hearth realizes heat recovery;When there is no desulfurization useless When water needs to spray into, cooling medium can be switched to cooling circulating water, guarantee the cooling effect of original clinker using cooling circulating water.
The present embodiment makes full use of existing roller slag cooler, passes through the realization pair of a large amount of high temperature furnace slags caused by boiler 1 The processing of desulfurization wastewater, while playing the role of cooled slag, realize making full use of for waste heat, the cooling medium outside slag cooler 6 It can be selected as needed in cooling wind and recirculated cooling water, flexibility is good, contamination-free secondary emission.
Embodiment two
As shown in Fig. 2, on the basis of example 1, the steam that desulfurization wastewater evaporation generates in the present embodiment is not discharged into In back-end ductwork 13, but after steam outlet pipe 8 and steam blower 7, independent dust-extraction unit 17 and heat-exchanger rig 18 are set, To remove the fine particle in devaporation, while steam is condensed into water using low-temperature heater water supply, the low-temperature heat after heating Device water supply returns to low-temperature heating system, realizes heat recovery and utilization, recycles after condensed water is purified.
Embodiment three
As shown in figure 3, on the basis of example 1, the part that the present embodiment separates cyclone separator 19 recycles Ash is sent into slag cooler 6 by circulating ash delivery pipe 20, and circulating ash quantity is regulated and controled by circulating ash valve 21, circulating ash and clinker Processing is vaporized to desulfurization wastewater together, the cooling medium in sleeve 9 is recirculated cooling water, to increase to clinker and/or follow The absorption of ring ash physical sensible heat to have bigger desulfurization wastewater processing capacity, and is suitable for that circulating ash quantity is big needs volume The power plant of outer discharge.

Claims (9)

1. a kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler, which is characterized in that including desulfurizing tower (15), take off Sulphur waste pipe (16) and slag cooler (6), slag cooler (6) is interior to be provided with atomizer (4), the desulfurization wastewater outlet of desulfurizing tower (15) It is connected through desulfurization wastewater pipe (16) with the atomizer (4) in slag cooler (6), the side of slag cooler (6) is provided with clinker and goes out Mouth (12).
2. the desulfurizing waste water processing device according to claim 1 suitable for circulating fluidized bed boiler, which is characterized in that also Including boiler (1), cyclone separator (19), back-end ductwork (13) and deduster (14), wherein boiler (1), cyclone separator (19), back-end ductwork (13), deduster (14) and desulfurizing tower (15) are sequentially connected logical, the slag notch of boiler (1) and slag cooler (6) Clinker entrance (5) be connected by scum pipe (2), be provided with residual cake valve (3) on the scum pipe (2).
3. the desulfurizing waste water processing device according to claim 1 suitable for circulating fluidized bed boiler, which is characterized in that cold Steam (vapor) outlet at the top of slag device (6) is communicated with steam outlet pipe (8).
4. the desulfurizing waste water processing device according to claim 3 suitable for circulating fluidized bed boiler, which is characterized in that also Including steam blower (7), steam outlet pipe (8) is connected through steam blower (7) with back-end ductwork (13).
5. the desulfurizing waste water processing device according to claim 3 suitable for circulating fluidized bed boiler, which is characterized in that steam Vapor outlet pipe (8) is connected with dust-extraction unit (17) and heat-exchanger rig (18) in turn.
6. the desulfurizing waste water processing device according to claim 1 suitable for circulating fluidized bed boiler, which is characterized in that rotation The ash hole of wind separator (19) is connected through circulating ash delivery pipe (20) with slag cooler (6), and circulating ash delivery pipe is set on (20) It is equipped with circulating ash valve (21).
7. the desulfurizing waste water processing device according to claim 1 suitable for circulating fluidized bed boiler, which is characterized in that pot Furnace (1) is circulating fluidized bed boiler, and slag cooler (6) is roller slag cooler or air-water combined slag cooler.
8. the desulfurizing waste water processing device according to claim 1 suitable for circulating fluidized bed boiler, which is characterized in that cold It is socketed on the outer wall of slag device (6) sleeve (9), cooling medium entrance (11) and cooling medium outlet is provided on sleeve (9) (10)。
9. the desulfurizing waste water processing device according to claim 1 suitable for circulating fluidized bed boiler, which is characterized in that cold Temperature sensor is provided in slag device (6) and in steam outlet pipe (8).
CN201811513496.7A 2018-12-11 2018-12-11 A kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler Pending CN109336205A (en)

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CN201811513496.7A CN109336205A (en) 2018-12-11 2018-12-11 A kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4874428A (en) * 1988-09-12 1989-10-17 Armco Inc. Fluidizing a lime-silica slag
CN103090375A (en) * 2013-02-16 2013-05-08 滕州亿达华闻煤电化有限公司 Process for performing desulphurization by using slag of circulating fluidized bed boiler
CN108033516A (en) * 2017-11-13 2018-05-15 北京国电富通科技发展有限责任公司 Power plant desulfurization wastewater treatment system
CN108558110A (en) * 2018-06-22 2018-09-21 西安交通大学 A kind of ultra supercritical CFB boiler desulfurization wastewater zero-discharge treatment system and method
CN209276189U (en) * 2018-12-11 2019-08-20 中国华能集团清洁能源技术研究院有限公司 A kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4874428A (en) * 1988-09-12 1989-10-17 Armco Inc. Fluidizing a lime-silica slag
CN103090375A (en) * 2013-02-16 2013-05-08 滕州亿达华闻煤电化有限公司 Process for performing desulphurization by using slag of circulating fluidized bed boiler
CN108033516A (en) * 2017-11-13 2018-05-15 北京国电富通科技发展有限责任公司 Power plant desulfurization wastewater treatment system
CN108558110A (en) * 2018-06-22 2018-09-21 西安交通大学 A kind of ultra supercritical CFB boiler desulfurization wastewater zero-discharge treatment system and method
CN209276189U (en) * 2018-12-11 2019-08-20 中国华能集团清洁能源技术研究院有限公司 A kind of desulfurizing waste water processing device suitable for circulating fluidized bed boiler

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