CN109334161A - A kind of high-performance self-lubricating composite material and preparation method - Google Patents

A kind of high-performance self-lubricating composite material and preparation method Download PDF

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Publication number
CN109334161A
CN109334161A CN201811293102.1A CN201811293102A CN109334161A CN 109334161 A CN109334161 A CN 109334161A CN 201811293102 A CN201811293102 A CN 201811293102A CN 109334161 A CN109334161 A CN 109334161A
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CN
China
Prior art keywords
fiber
composite material
lubricating
self
metal plate
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811293102.1A
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Chinese (zh)
Inventor
王明祥
姬祖春
赵虎
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Ming Yang Technology (suzhou) Ltd By Share Ltd
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Ming Yang Technology (suzhou) Ltd By Share Ltd
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Priority to CN201811293102.1A priority Critical patent/CN109334161A/en
Publication of CN109334161A publication Critical patent/CN109334161A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/043Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/14Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/06Coating on the layer surface on metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • B32B2262/0269Aromatic polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres

Abstract

The present invention provides a kind of high-performance self-lubricating composite materials to overcome original material and pass through the defect that rolling is prepared, and the good, long service life using the bearing rub resistance of material production, meet the higher requirement of client without rolling.It includes metal plate and high molecular material liner, the metal plate and high molecular material liner is compound is integrally formed, high molecular material liner are specially the composite material liner that self-lubricating high molecular material fiber, organic or inorganic material fiber are knitted to form.

Description

A kind of high-performance self-lubricating composite material and preparation method
Technical field
The present invention relates to the technical field of self-lubricating material, specially a kind of high-performance self-lubricating composite material, the present invention Additionally provide the preparation method of the self-lubricating composite.
Background technique
Patent No. ZL201520870794.7, denomination of invention are as follows: " a kind of bearing for automobile glass lifter " is special Benefit discloses a kind of bearing for automobile glass lifter, it includes one kind using quality carbon structural steel as matrix, described Matrix a side be provided with vertical rib, the substrates sintering has spherical bronze bisque, in the spherical shape bronze powder It is also applied on layer and rolls and be sintered one layer by the plastic working layer based on polytetrafluoroethylene (PTFE) and form a kind of 3-layer composite material.
Existing self-lubricating bearing material is using metal, copper powder and polytetrafluoroethylene (PTFE) tradition 3-layer composite material by rolling System is prepared, and the self-lubricating bearing prepared by this kind of material, frictional behavior is relatively poor and service life is short, Wu Faman The sufficient higher requirement of client.
Summary of the invention
In view of the above-mentioned problems, without rolling, overcoming original the present invention provides a kind of high-performance self-lubricating composite material There is material to pass through the defect that rolling is prepared, and the good, long service life using the bearing rub resistance of material production, meets Client higher requirement.
A kind of high-performance self-lubricating composite material, it is characterised in that: it includes metal plate and high molecular material liner, institute It states metal plate and high molecular material liner is compound is integrally formed, high molecular material liner is specially self-lubricating high score The composite material liner that sub- material fiber, organic or inorganic material fiber are knitted to form.
It is further characterized by:
The metal plate is single-layer metal or double-level-metal;
The metal plate include but is not limited to be common carbon containing rolled plate, it is the carbon containing steel plate of surface anticorrosion processing, stainless Steel plate, copper alloy plate or aluminium alloy plate;
The self-lubricating high molecular material fiber includes but is not limited to fluoroplastics fiber or ultra high density polyethylene fiber;
The organic or inorganic material fiber include but is not limited to be glass fibre or aramid fiber;
The metal plate and high molecular material liner are by being bonded compound be integrally formed.
A kind of preparation method of high-performance self-lubricating composite material, it is characterised in that: previously prepared metal plate, macromolecule Material liners, the high molecular material liner are specially self-lubricating high molecular material fiber, the braiding of organic or inorganic material fiber The composite material of formation pads, after metal plate is carried out surface activation process later, cleaning oil removing, by metal plate and high score Sub- material liners bonding is compound, later by bond it is compound after integral structure be heating and curing, then cool to room temperature.
It is further characterized by:
It needs after the self-lubricating high molecular material fiber, the braiding of organic or inorganic material fiber are compound through row pre-preg, Ensure that self-lubricating high molecular material fiber, organic or inorganic material fiber bond together, and keep certain shapes;
The liquid that the pre-preg is submerged is specially high molecule plastic liquid, the high molecule plastic liquid include but It is not limited to epoxies, nylon-type, phenolic or fluoroplastics;
The metal plate and high molecular material liner bonding compound tense use high-temperature agglomerant, the high-temperature agglomerant Heatproof need to reach 220 DEG C or more;
The surface activation process of the metal plate specifically includes surface texturing, plating and applies primary coat;
Material sub-sectional cooling after being heating and curing is to room temperature.
After applying the present invention, metal plate and the high molecular material pad compound be integrally formed as high-performance self-lubricating Composite material carries out blanking according to designed scantling and is subsequently used for bearing molding, change and pass when preparing bearing System self-lubricating bearing is passed through the composite material that rolling is prepared by metal, copper powder and polytetrafluoroethylene (PTFE) tradition 3-layer composite material It is prepared, the double layer material frictional behavior of use is more excellent, and wearability is more preferable, can guarantee requirement of the user to the bearing long-life; And in double-layer composite material preparation process, using high temperature adhesive, the requirement of bearing at high temperature ensure that;To sum up, It overcomes original material and passes through the defect that rolling is prepared without rolling, and using the bearing rub resistance of material production The good, long service life of property, meets the higher requirement of client.
Specific embodiment
A kind of high-performance self-lubricating composite material: it includes that metal plate and high molecular material pad, metal plate and height Molecular material liner is compound to be integrally formed, and high molecular material liner is specially self-lubricating high molecular material fiber, organic or inorganic The composite material liner that material fiber is knitted to form.
Metal plate is single-layer metal or double-level-metal;
Metal plate include but is not limited to be common carbon containing rolled plate, the carbon containing steel plate of surface anticorrosion processing, stainless steel plate, Copper alloy plate or aluminium alloy plate;
Self-lubricating high molecular material fiber includes but is not limited to fluoroplastics fiber or ultra high density polyethylene fiber;
Organic or inorganic material fiber include but is not limited to be glass fibre or aramid fiber;
Metal plate and high molecular material liner are by being bonded compound be integrally formed.
A kind of preparation method of high-performance self-lubricating composite material: previously prepared metal plate, high molecular material liner are high The composite material lining that molecular material liner specially self-lubricating high molecular material fiber, organic or inorganic material fiber are knitted to form Pad, it is after metal plate is carried out surface activation process later, cleaning oil removing, metal plate and high molecular material liner bonding is multiple Close, later by bond it is compound after integral structure be heating and curing, then cool to room temperature.
It needs after self-lubricating high molecular material fiber, the braiding of organic or inorganic material fiber are compound through row pre-preg, it is ensured that Self-lubricating high molecular material fiber, organic or inorganic material fiber bond together, and keep certain shapes;
The liquid that pre-preg is submerged is specially high molecule plastic liquid, and high molecule plastic liquid includes but is not limited to be Epoxies, nylon-type, phenolic or fluoroplastics;
Metal plate and high molecular material liner bonding compound tense use high-temperature agglomerant, and the heatproof of high-temperature agglomerant need to reach To 220 DEG C or more;
The surface activation process of metal plate specifically includes surface texturing, plating and applies primary coat;
Material sub-sectional cooling after being heating and curing is to room temperature.
The high-performance self-lubricating composite material that preparation is completed is slab construction, and blanking when for making bearing needs reality Existing continuity, and guarantee that the efficiency, quality, laying of blanking not will receive destruction;Its production efficiency for preparing bearing is not less than Existing 3-layer composite material prepares the processing efficiency of bearing.
Its self-lubricating bearing produced is to pad the two-layer compound being combined by metal plate and high molecular material Material overcomes existing metal, copper powder and polytetrafluoroethylene (PTFE) 3-layer composite material and passes through the defect that rolling is prepared, friction Characteristic is more excellent, and wearability is more preferable, can guarantee requirement of the user to the bearing long-life;And it can guarantee that existing production efficiency is constant; And in double-layer composite material preparation process, using high temperature adhesive, the requirement of bearing at high temperature ensure that.
Specific embodiments of the present invention are described in detail above, but content is only the preferable implementation of the invention Example, should not be considered as limiting the invention the practical range of creation.It is all to become according to equalization made by the invention application range Change and improve etc., it shall still fall within the scope of this patent.

Claims (10)

1. a kind of high-performance self-lubricating composite material, it is characterised in that: it includes that metal plate and high molecular material pad, described Metal plate and high molecular material liner is compound is integrally formed, high molecular material liner is specially self-lubricating macromolecule The composite material liner that material fiber, organic or inorganic material fiber are knitted to form.
2. a kind of high-performance self-lubricating composite material as described in claim 1, it is characterised in that: the metal plate is single layer Metal or double-level-metal.
3. a kind of high-performance self-lubricating composite material as described in claim 1, it is characterised in that: the metal plate include but It is not limited to common carbon containing rolled plate, the carbon containing steel plate of surface anticorrosion processing, stainless steel plate, copper alloy plate or aluminium alloy plate.
4. a kind of high-performance self-lubricating composite material as described in claim 1, it is characterised in that: the self-lubricating macromolecule material Material fiber includes but is not limited to fluoroplastics fiber or ultra high density polyethylene fiber.
5. a kind of high-performance self-lubricating composite material as described in claim 1, it is characterised in that: the organic or inorganic material Fiber includes but is not limited to glass fibre or aramid fiber.
6. a kind of high-performance self-lubricating composite material as described in claim 1, it is characterised in that: the metal plate and described High molecular material liner is by being bonded compound be integrally formed.
7. a kind of preparation method of high-performance self-lubricating composite material, it is characterised in that: previously prepared metal plate, macromolecule material Material liner, the high molecular material liner are specially self-lubricating high molecular material fiber, organic or inorganic material fiber braiding shape At composite material liner, later by metal plate carry out surface activation process after, cleaning oil removing, by metal plate and macromolecule Material liners bonding it is compound, later by bond it is compound after integral structure be heating and curing, then cool to room temperature.
8. a kind of preparation method of high-performance self-lubricating composite material as claimed in claim 7, it is characterised in that: described from profit It needs after sliding high molecular material fiber, the braiding of organic or inorganic material fiber are compound through row pre-preg, it is ensured that self-lubricating macromolecule Material fiber, organic or inorganic material fiber bond together, and keep certain shapes;The liquid that the pre-preg is submerged Specially high molecule plastic liquid, the high molecule plastic liquid include but is not limited to be epoxies, nylon-type, phenolic or fluorine Plastics.
9. a kind of preparation method of high-performance self-lubricating composite material as claimed in claim 7, it is characterised in that: the metal Plate and high molecular material liner bonding compound tense use high-temperature agglomerant, and the heatproof of the high-temperature agglomerant need to reach 220 DEG C More than.
10. a kind of preparation method of high-performance self-lubricating composite material as claimed in claim 7, it is characterised in that: heating is solid Material sub-sectional cooling after change is to room temperature.
CN201811293102.1A 2018-11-01 2018-11-01 A kind of high-performance self-lubricating composite material and preparation method Pending CN109334161A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111394156A (en) * 2020-04-28 2020-07-10 北京稳力科技有限公司 Alloy-fluororesin double-layer self-lubricating wear-resistant composite material, preparation method thereof and friction pair
WO2020237784A1 (en) * 2019-05-29 2020-12-03 明阳科技(苏州)股份有限公司 Thin-wall bonded self-lubricating plate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1259599A (en) * 1999-12-24 2000-07-12 中国科学院兰州化学物理研究所 Self lubricating fabric thin layer composite material and its prepn. method
CN101126417A (en) * 2007-09-11 2008-02-20 嘉兴中达自润轴承工业有限公司 Self-lubricating sliding bearing material and its preparation method
CN101126418A (en) * 2007-09-11 2008-02-20 嘉兴中达自润轴承工业有限公司 Polymer self-lubricating thin layer composite axle sleeve and its preparation method
CN103410863A (en) * 2013-07-30 2013-11-27 广东工业大学 Half-bearing, material, device and method for steel backing/carbon fiber knitted fabric self-lubricating lining
CN106079771A (en) * 2016-06-02 2016-11-09 江苏大学 A kind of vibration damping wear-resistant self-lubricating axle sleeve and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1259599A (en) * 1999-12-24 2000-07-12 中国科学院兰州化学物理研究所 Self lubricating fabric thin layer composite material and its prepn. method
CN101126417A (en) * 2007-09-11 2008-02-20 嘉兴中达自润轴承工业有限公司 Self-lubricating sliding bearing material and its preparation method
CN101126418A (en) * 2007-09-11 2008-02-20 嘉兴中达自润轴承工业有限公司 Polymer self-lubricating thin layer composite axle sleeve and its preparation method
CN103410863A (en) * 2013-07-30 2013-11-27 广东工业大学 Half-bearing, material, device and method for steel backing/carbon fiber knitted fabric self-lubricating lining
CN106079771A (en) * 2016-06-02 2016-11-09 江苏大学 A kind of vibration damping wear-resistant self-lubricating axle sleeve and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020237784A1 (en) * 2019-05-29 2020-12-03 明阳科技(苏州)股份有限公司 Thin-wall bonded self-lubricating plate
US11401480B2 (en) 2019-05-29 2022-08-02 Mingyang Technology (Suzhou) Co., Ltd. Thin-wall bonded self-lubricating plate
CN111394156A (en) * 2020-04-28 2020-07-10 北京稳力科技有限公司 Alloy-fluororesin double-layer self-lubricating wear-resistant composite material, preparation method thereof and friction pair

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Application publication date: 20190215