CN109320985A - Colorful wood plastic composite board modelled after an antique and preparation method thereof - Google Patents
Colorful wood plastic composite board modelled after an antique and preparation method thereof Download PDFInfo
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- CN109320985A CN109320985A CN201810971078.6A CN201810971078A CN109320985A CN 109320985 A CN109320985 A CN 109320985A CN 201810971078 A CN201810971078 A CN 201810971078A CN 109320985 A CN109320985 A CN 109320985A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic System
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
- D06M13/5135—Unsaturated compounds containing silicon atoms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/002—Panels; Plates; Sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
Abstract
The present invention relates to colorful wood plastic composite board modelled after an antique and preparation method thereof, it is suitable for making various modeling log art wares, or the reparation for the seat of heritage buildings door and window and its auxiliary, bed etc..Colorful wood plastic composite board modelled after an antique is combined by polyethylene, pigment, wood powder, silane coupler modified wood-fibred, hollow silica alumina ball, terpene resin, butyl stearate and oxidic polyethylene.It is convenient to manufacture, and continuous production is strong, high-efficient；It is compared with common wood plastic composite board, color is more stable, color variation range is broader, the designability of color is stronger, and performance modelled after an antique is more excellent, closer to some old woodworks in form.Colorful wood plastic composite board waterproof modelled after an antique, anti-corrosion, termite-proof erosion, light-weight, intensity is high, long service life；Secondary operation is convenient；The leftover pieces generated in production and use process can be with recycling and reusing, and environmental protection is pollution-free.
Description
Technical field
The present invention relates to a kind of Wood plastic composites, more particularly to colorful wood plastic composite board modelled after an antique and its preparation
Method.Suitable for making various modeling log art wares, or the reparation for the seat of heritage buildings door and window and its auxiliary, bed etc..
Background technique
As the improvement of people's living standards, spiritual pursuit is stronger, craftwork has come into huge numbers of families.Tradition
On, these craftworks are generally wooden, pottery, metallic, the nature of glass, unsaturated-resin material are made, using this
All there is certain limitations for a little traditional material craft articles, such as: the craftwork waterproof and anticorrosion of wood materials production
Can be poor, it is easily corroded by termite, paint layer from surface is easy to fall off, and production process need to fall trees, and is unfavorable for water and soil conservation and environment is protected
Shield etc.；Pottery craftwork is heavy, and sense of touch is poor, frangible, and price is more expensive etc.；Metallic craftwork is heavy, and manufacturing process is more difficult, can
Modified is poor etc.；Nature of glass craftwork is frangible, and it is more difficult to colour, and production efficiency is low etc.；Unsaturated-resin matter craftwork can be repaired
Decorations property is poor, and at high cost, production process easily causes environmental pollution etc..
In addition, many ancient buildings have been included into (historical relic) protection scope, these ancient buildings, the discipline including some modern ages now
Shop is read, after the exposing to the weather by many years drenches with rain, part has been damaged door and window, it would be highly desirable to be repaired；These ancient buildings, souvenir
Seat, bed of shop inner satellite etc. equally have conservation value, but equally exist partial destruction phenomenon to be repaired.Repairing this
When a little door and window, tables and chairs, beds, if selecting timber, " doing old " this procedure, complex procedures, waste of manpower, wealth are just had to pass through
Power, and it is easy to produce color difference, final effect is influenced, can also there is a possibility that rotting after repairing using timber.
In recent years, with the enhancing of people's environmental protection consciousness, raw material sources are extensive, environmental-friendly, renewable, recyclable
The Wood plastic composite used is increasingly valued by people.It is that Raw material processing makes that it, which is with waste plastic, wood powder etc.,
A kind of widely used composite material, process principle is: by waste plastic and the wood fibre (sawdust, bamboo that have no value for use
Powder, rice husk, straw obstruct etc.) it is mixed in a certain ratio, and special auxiliary agent is added, it is made through techniques such as high-temperature fusion, mixing, moldings
The profile of certain shapes.It has the processing performance similar with timber, can saw, can follow closely, can dig, excellent resistance to ethyl alcohol, corrosion resistant
Performance, not bacterial growth is not easy to be damaged by insects, by the way that different auxiliary agents is added the density etc. of plastic-wood material can be changed in not long fungi
Characteristic may also reach up the particular/special requirements such as anti-aging, antistatic, fire-retardant.Meanwhile Wood plastic composite have timber appearance,
The hardness higher than plastic products, material homogeneous, size are stable compared with timber, are not likely to produce crackle and without spies such as timber knot, twills
Point；It has processability of thermoplastic, small to equipment attrition in production process；It is not required to using at toxic chemical substance
Reason is free of formaldehyde；Reusable and recycling and reusing after discarded, many advantages, such as being good for the environment.
So the colorful wood plastic composite board modelled after an antique of invention, substitutes traditional material, for making some craftworks, or
It is very necessary for the reparation of the seat of heritage buildings door and window and its auxiliary, bed etc..
Summary of the invention
The purpose of the present invention is provide colorful wood plastic composite board modelled after an antique and its preparation side in view of the above shortcomings
Method, the plate is in addition to having the characteristics that the repeatable processing use of general wood plastic composite board, easily molded processing, with more more
The features such as color, modelled after an antique.
Colorful wood plastic composite board modelled after an antique is by including that the raw material of following parts by weight is prepared:
The polyethylene color master batch is coffee-like polyethylene color master batch, dark brown polyethylene color master batch, brown polyethylene color
One of master batch.
The pigment is that iron oxide yellow, iron is green, one of iron oxide red.
The wood powder, partial size are 40-120 mesh.
The silane coupler modified wood-fibred, average length 2-6mm.
The silane coupling agent is vinyltriethoxysilane, vinyl three ('beta '-methoxy ethyoxyl) silane, 3-
One of (methacryloxypropyl) propyl-triethoxysilicane.
The hollow silica alumina ball, partial size are 5-10 μm.
The preparation method of colorful wood plastic composite board modelled after an antique of the invention comprising following steps:
(1) in mass ratio 100: 3-9 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 4-6 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 60-80 DEG C, be ultrasonically treated 30- under the pressure of 0.3-0.7MPa
60min；
(6) pressurizeing ultrasonically treated terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane idol
Join the modified wood-fibred of agent；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and stir 6-
10min, then extruding pelletization, 170-180 DEG C of extruder barrel temperature, obtain the modified modeling of Masterbatch by 170-180 DEG C of die head temperature
The wooden particle；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
6-10min is stirred in mechanical stirring kettle, then extruding pelletization, 175-185 DEG C of extruder barrel temperature, die head temperature 174-184
DEG C, it obtains pigment modification and moulds the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 170-180 DEG C of extruder barrel temperature, obtains colour by 172-182 DEG C of die head temperature
Plastic wood sheet；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
It is convenient that the colorful wood plastic composite board modelled after an antique of the present invention is manufactured, and traditional plastic wood sheet production line can be used to
It is produced, and continuous production is strong, high production efficiency；It is compared with common wood plastic composite board, colorful wood-plastic composite modelled after an antique
Flitch material carries out color combined processing using organic plastic masterbatch and inorganic pigment simultaneously, and color is more stable, color becomes
Change range is broader, color designability is stronger, and performance modelled after an antique is more excellent, while being filled out using wood powder and modified wood-fibred
It fills, the addition of longer wood-fibred is so that the present invention apparently directly truly shows wood grain, along with embossing processing generation
Artificial wood pattern's lines, so that the invention is morphologically closer to some old woodworks.Colorful Wood plastic composite modelled after an antique
Plate waterproof, anti-corrosion, termite-proof erosion, light-weight, intensity is high, long service life；Secondary operation is convenient；Production and use process
The leftover pieces of middle generation can be with recycling and reusing, and environmental protection is pollution-free.
Specific embodiment
Colorful wood plastic composite board modelled after an antique and preparation method thereof of the invention is illustrated using embodiment below.
Embodiment 1:
(1) in mass ratio 100: 6 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [three (beta-methoxy of vinyl
Base oxethyl) silane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 5 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 70 DEG C, be ultrasonically treated 45min under the pressure of 0.5MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B: by terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
8min, then extruding pelletization, 175 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 175 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
8min is stirred in mechanical stirring kettle, then extruding pelletization, 179 DEG C of die head temperature, obtains pigment by 180 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 175 DEG C of extruder barrel temperature, 177 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 2:
(1) in mass ratio 100: 3 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [vinyl triethoxyl silicon
Alkane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 4 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 60 DEG C, be ultrasonically treated 30min under the pressure of 0.3MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
6min, then extruding pelletization, 170 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 170 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
6min is stirred in mechanical stirring kettle, then extruding pelletization, 174 DEG C of die head temperature, obtains pigment by 175 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 170 DEG C of extruder barrel temperature, 172 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 3:
(1) in mass ratio 100: 9 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [3- (methacryloxypropyl)
Propyl-triethoxysilicane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 6 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 80 DEG C, be ultrasonically treated 60min under the pressure of 0.7MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
10min, then extruding pelletization, 180 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 180 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
10min is stirred in mechanical stirring kettle, then extruding pelletization, 184 DEG C of die head temperature, obtains pigment by 185 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 180 DEG C of extruder barrel temperature, 182 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 4:
(1) in mass ratio 100: 6 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [3- (methacryloxypropyl)
Propyl-triethoxysilicane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 4 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 60 DEG C, be ultrasonically treated 60min under the pressure of 0.5MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
6min, then extruding pelletization, 180 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 175 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
6min is stirred in mechanical stirring kettle, then extruding pelletization, 184 DEG C of die head temperature, obtains pigment by 180 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 170 DEG C of extruder barrel temperature, 177 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 5:
(1) in mass ratio 100: 9 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [vinyl triethoxyl silicon
Alkane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 5 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 70 DEG C, be ultrasonically treated 30min under the pressure of 0.7MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
8min, then extruding pelletization, 170 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 180 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
8min is stirred in mechanical stirring kettle, then extruding pelletization, 174 DEG C of die head temperature, obtains pigment by 185 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 175 DEG C of extruder barrel temperature, 182 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 6:
(1) in mass ratio 100: 3 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [three (beta-methoxy of vinyl
Base oxethyl) silane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 6 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 80 DEG C, be ultrasonically treated 45min under the pressure of 0.3MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
10min, then extruding pelletization, 175 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 170 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
10min is stirred in mechanical stirring kettle, then extruding pelletization, 179 DEG C of die head temperature, obtains pigment by 175 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 180 DEG C of extruder barrel temperature, 172 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 7:
(1) in mass ratio 100): 9 weigh formula ratio respectively weighs wood-fibred and silane coupling agent [vinyl triethoxyl
Silane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 4 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 70 DEG C, be ultrasonically treated 45min under the pressure of 0.5MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio:
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
6min, then extruding pelletization, 180 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 175 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
8min is stirred in mechanical stirring kettle, then extruding pelletization, 174 DEG C of die head temperature, obtains pigment by 185 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 180 DEG C of extruder barrel temperature, 172 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 8:
(1) in mass ratio 100: 3 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [3- (methacryloxypropyl)
Propyl-triethoxysilicane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 6 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 60 DEG C, be ultrasonically treated 60min under the pressure of 0.3MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
10min, then extruding pelletization, 170 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 175 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
10min is stirred in mechanical stirring kettle, then extruding pelletization, 174 DEG C of die head temperature, obtains pigment by 175 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 180 DEG C of extruder barrel temperature, 182 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Embodiment 9:
(1) in mass ratio 100: 7 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent [three (beta-methoxy of vinyl
Base oxethyl) silane]；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupled
Agent-ferrous chloride aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 4.6 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 68 DEG C, be ultrasonically treated 50min under the pressure of 0.4MPa；
(6) ultrasonic treatment terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；By terpenes tree
Rouge in mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；By 5: 3: 2 points in mass ratio of butyl stearate
At three parts, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is marked respectively
It is denoted as OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and are stirred
7min, then extruding pelletization, 178 DEG C of die head temperature, obtains the wooden particle of the modified modeling of Masterbatch by 178 DEG C of extruder barrel temperature；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in
9min is stirred in mechanical stirring kettle, then extruding pelletization, 179 DEG C of die head temperature, obtains pigment by 179 DEG C of extruder barrel temperature
It is modified to mould the wooden particle；
(11) it after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, adopts
Melt blending is carried out with extruder and is squeezed out, and 177 DEG C of extruder barrel temperature, 176 DEG C of die head temperature, it is compound to obtain color plastic wood
Material plate；
(12) by colored plastic wood sheet under draw by knurling rolls, embossing roller surface has prefabricated rough
Lines, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate table
Color is not quite identical at face lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
Illustrate the effect of embodiment 1 below by inspection:
Test result shows: the performance parameter of embodiment 1 is superior to standard specified value, has more preferably mechanical property and ruler
Very little stability.
Claims (8)
1. colorful wood plastic composite board modelled after an antique, it is characterised in that be prepared by the raw material for including following parts by weight:
2. colorful wood plastic composite board modelled after an antique according to claim 1, it is characterised in that the polyethylene color masterbatch
Grain is one of coffee-like polyethylene color master batch, dark brown polyethylene color master batch, brown polyethylene color master batch.
3. colorful wood plastic composite board modelled after an antique according to claim 1, it is characterised in that the pigment be iron oxide yellow,
Iron is green, one of iron oxide red.
4. colorful wood plastic composite board modelled after an antique according to claim 1, it is characterised in that the wood powder, partial size
For 40-120 mesh.
5. colorful wood plastic composite board modelled after an antique according to claim 1, it is characterised in that the silane coupling agent
Modified wood-fibred, average length 2-6mm.
6. according to claim 1, colorful wood plastic composite board modelled after an antique described in claim 5, it is characterised in that described
Silane coupling agent is vinyltriethoxysilane, vinyl three ('beta '-methoxy ethyoxyl) silane, 3- (methacryloxypropyl)
One of propyl-triethoxysilicane.
7. colorful wood plastic composite board modelled after an antique according to claim 1, it is characterised in that the hollow silica alumina ball,
Its partial size is 5-10 μm.
8. the preparation method of colorful wood plastic composite board modelled after an antique according to claim 1, it is characterised in that it is prepared
Process the following steps are included:
(1) in mass ratio 100: 3-9 formula ratio is weighed respectively weigh wood-fibred and silane coupling agent；
(2) in mass ratio 1: 100: 0.03: 0.05 silane coupling agent, distilled water, hydrogen peroxide and frerrous chloride are weighed respectively；
(3) silane coupling agent, distilled water and frerrous chloride are added in pressure vessel, are stirred into silane coupling agent-chlorine
Change ferrous aqueous solution；
(4) silane coupling agent-ferrous chloride aqueous solution pH value to 4-6 is adjusted, hydrogen peroxide is then added, stirs evenly；
(5) wood-fibred is added thereto, is warming up to 60-80 DEG C, be ultrasonically treated 30-60min under the pressure of 0.3-0.7MPa；
(6) pressurizeing ultrasonically treated terminates, taking-up wood-fibred, and after distilled water flushing to neutrality, vacuum drying obtains silane coupling agent
Modified wood-fibred；
(7) each raw material is weighed by formula ratio；
(8) vinyon particle in mass ratio 7: 3 is divided into two parts, is respectively labeled as PE-A and PE-B；Terpene resin is pressed
Mass ratio 4: 3: 3 is divided into three parts, is respectively labeled as TX-A, TX-B and TX-C；Butyl stearate in mass ratio 5: 3: 2 is divided into three
Part, it is respectively labeled as HST-A, HST-B and HST-C；Oxidic polyethylene in mass ratio 4: 4: 2 is divided into three parts, is respectively labeled as
OPE-A, OPE-B and OPE-C；
(9) PE-A, polyethylene color master batch, wood powder, TX-A, HST-A and OPE-A are placed in mechanical stirring kettle and stir 6-10min,
Then extruding pelletization, 170-180 DEG C of extruder barrel temperature, obtain the wooden grain of the modified modeling of Masterbatch by 170-180 DEG C of die head temperature
Son；
(10) PE-B, pigment, silane coupler modified wood-fibred, hollow silica alumina ball, TX-B, HST-B and OPE-B are placed in machinery
6-10min is stirred in stirred tank, then extruding pelletization, 175-185 DEG C of extruder barrel temperature, obtain by 174-184 DEG C of die head temperature
The wooden particle is moulded to pigment modification；
(11) after mixing the wooden particle of the modified modeling of Masterbatch, the wooden particle of pigment modification modeling, TX-C, HST-C and OPE-C, using crowded
Machine carries out melt blending and squeezes out, 170-180 DEG C of extruder barrel temperature, 172-182 DEG C of die head temperature out, obtains color plastic wood
Plate；
(12) colored plastic wood sheet is passed through to knurling rolls under draw, embossing roller surface has prefabricated rough line
Road, for colored plastic wood sheet after pressure roller squeezes, surface is just accordingly squeezed out the lines of similar wood grain, and plate surface
Color is not quite identical at lines different location, different depth, obtains colorful wood plastic composite board modelled after an antique.
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