CN109319993A - A kind of load vapour formula hc effluent evaporation and concentration processing unit - Google Patents
A kind of load vapour formula hc effluent evaporation and concentration processing unit Download PDFInfo
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- CN109319993A CN109319993A CN201811080579.1A CN201811080579A CN109319993A CN 109319993 A CN109319993 A CN 109319993A CN 201811080579 A CN201811080579 A CN 201811080579A CN 109319993 A CN109319993 A CN 109319993A
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- evaporation
- effluent
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- air
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
The present invention relates to a kind of load vapour formula hc effluents to be concentrated by evaporation processing unit, by evaporation tank, condensing heat exchanger, blower, solution heater and related ancillary equipment composition.The device is using dry air as the carrier of hc effluent evaporation steam after heating, and then low-temperature cooling water makes damp-heat air condensation produce water, removes the moisture in dehumidified air.Due to directly contacting evaporation profiles using air is upper on orifice plate, evaporation efficiency is high.Meanwhile orifice plate can use non-metallic material, avoid hc effluent to the corrosion and scaling problem of evaporator, improve service life of equipment and system run all right.On the other hand, system uses oxidizing gas generator, and under the action of orifice plate, Strong oxdiative gas can come into full contact with highly concentrated waste liquid, and chemical oxygen demand of waste water (COD), organic pollutant is effectively reduced, and effectively extend the use function of this equipment.This covering device, equipment is simple, and process flow is short, easy to control, and maintenance is easy, and realizes the clean and environmental protection processing of hc effluent.
Description
Technical field
The present invention relates to a kind of evaporation and concentration processing units of hc effluent, use air as more particularly, to one kind useless
The steam carrier that water evaporation comes out can make full use of the useless low-temperature heat source such as solar energy, low temperature exhaust heat waste heat to be used as heating thermal energy,
It is that a kind of air-hc effluent directly contacts evaporation mode concentration device again, belongs to difficult industrial wastewater (high-concentration waste
Water) environmental protection and energy saving minimizing processing technical field.
Background technique
The industries such as China's pharmacy, printing and dyeing, papermaking, chemical industry are in critical role in national economy, but this kind of enterprise is daily
The hc effluent water of generation is little, but COD is greater than 105, salt concentration is more than 10%, belongs to difficult, used water difficult to degradate.
Since current existing environmental protection treatment technology and equipment is difficult to reach environmental protection treatment requirement, many enterprises are disobeyed using stealthily in line
Local environment is seriously polluted in judicial act, so that problem of environmental pollution caused by these difficult industrial wastewaters becomes current China
One urgent problem.
Film concentration technology is used widely in municipal wastewater, industrial wastewater field in recent years, so that industrial wastewater,
Sanitary sewage concentration is able to continue to improve, and sewage total amount is greatly reduced.But the sewage after film is concentrated in practical projects
It is still difficult to reach the requirement of innoxious high temperature incineration.This is because sewage salt concentration is lower than 10%, after concentrated after film concentration
Sewage still contains compared with juicy, burns reprocessing there is still a need for consumption mass energy, leads to higher cost.Moreover, it burns and produces
Raw superheated vapor will cause irreversible lesion to equipment, it is therefore desirable to continue at minimizing to the hc effluent after film concentration
Reason.
The method for concentration of hc effluent thermal evaporation at present is most common technology, in order to reduce evaporation energy consumption, many skills
Art makes full use of the secondary steam latent heat re-evaporation hc effluent being evaporated, such as multiple-effect evaporation, steam recompression technology.
It finding by patent retrieval and market survey, hc effluent thermal concentration technology is used for difficult waste water at present, we
It was found that there is Railway Project to be still difficult to effectively be solved: 1) since higher salt content leads to stronger corrosion in hc effluent
Property, waste water has strong corrosivity to canister and heat exchange equipment;2) evaporation equipment mostly uses greatly in traditional evaporation technique
Metal material manufacture, hc effluent are easily precipitated in metal surface fouling or pipe, cause serious scale problems or pipeline stifled
Plug problem, concentration systems can not normal continuous operations;3) multiple-effect evaporation, mechanical compression re-evaporation complex process equipment, investment are inclined
Height is suitble to the processing of a large amount of waste water, and cost performance is low when handling a small amount of waste water;4) thermal evaporation techniques are steamed suitable for salt at present
Hair, once it is higher to have an opportunity, it is necessary to it is removed using pretreatment mode, integrated artistic is complicated.
On the whole, traditional thermal concentration technology existing at present is not suitable in a small amount of high load wastewater treatment, we are necessary
Find energy conservation and environmental protection processing technique and dress that a kind of suitable, adaptable concentration and evaporation technique realizes hc effluent minimizing
It sets.
Summary of the invention
The purpose of the present invention is to provide a kind of evaporation and concentration processing units of hc effluent, for existing hc effluent
Thermal concentration technique, it is with high salt caused by heat exchanger corrosion and fouling, the condensed water content of organic matter caused by high temperature evaporation, ammonia nitrogen are inclined
High problem solves traditional evaporation technology and is difficult to that the technical problem of indegradable industrial effluent is effectively treated.
In order to solve problem above, the evaporation of hc effluent organic matter is reduced, salinity is to equipment burn into solution hc effluent
Scale problems, the invention proposes a kind of evaporation and concentration processing units of hc effluent.The device uses air as steam load
Body, air can take away the principle of the moisture in solution after directly being contacted using air with waste water solution, realize hc effluent
It is concentrated by evaporation.Since air directly contacts evaporation with waste water solution, it is no longer necessary to which evaporation of metal heat exchanger is also just meaned without corruption
Erosion and scale problems.Meanwhile air only takes away the moisture in hc effluent, the extent of corrosion of condensing plant substantially drops in humid air
It is low, to improve service life of equipment.On this basis, advanced oxidation equipment is introduced, hc effluent organic matter is can reduce and contains
Amount, extends the present apparatus to the processing function of hc effluent.
A kind of load vapour formula hc effluent proposed by the present invention is concentrated by evaporation processing unit, by evaporation tank 1, porous plate 2, blower
3, condensing heat exchanger 4, solution pump 5, solution heater 6, air duct 7, cooling cycle water route 8, solution line 9, ancillary equipment 10, cold
Condensate discharge pipe 11 is constituted.In evaporation tank 1, lower horizontal location arrangements porous plate 2 wherein, porous plate 2 and cabinet 1 four
Week sealing installation, air are blown out from porous plate Hole 14.
According to gas flow direction, mouth is blown in by air duct 7 in 1 top of evaporation tank, is successively connected to heat exchanger 4, blower 3,
Then it is connect again with 1 lower part air port of evaporation tank.Oxidizing gas generator 10, the oxygen are arranged between condensing heat exchanger 4 and blower 3
Change the Strong oxdiative gas that gas generator 10 generates and air duct 7 is entered by fan action, evaporation tank is entered under the action of blower 3
1。
According to solution direction, waste water enters evaporation tank 1 from feed inlet 12.The outlet of 1 bottom solution of evaporation tank passes through solution conduit
Road 9 is successively connected to solution pump 5, heat exchanger 6, then returns again to evaporation tank 1, and solution inlet port position is higher than 2 position of porous plate.
Porous plate 2 is provided with leakage channel, 2 on porous plate on unevaporated hydrops can enter 1 bottom of evaporation tank by the channel
Continue cycling through heating.Waste water after concentration reaches setting index, is discharged from discharge port 13, then continues again into new waste water
It is concentrated by evaporation.
Condensing heat exchanger 4 is indirect type heat exchanger, is provided with and is condensed out the mouth of a river 11 and recirculated water interface 8.
The course of work of the invention is as follows:
Air circulation flow process is introduced first.It is high that the heat to be come by heater 6 has been gathered on the porous plate 2 on evaporation tank 1
Density wastewater, air are blown out from the bottom up from the hole 14 on porous plate 2, are directly contacted with thermal wastewater, are continued under fan action
It flows up.Since air is directly contacted with thermal wastewater, temperature is improved, and is increased containing wet ability, can be taken away in waste water
A small amount of moisture reduces moisture in waste water, realizes Waste water concentrating purpose.
Condensing heat exchanger 4 is flowed in air duct 7 containing the humid air compared with juicy, it is cold that condensing heat exchanger is provided with circulation
But water route 8 cool down to moisture after being passed through recirculated cooling water, and moisture temperature reduces, and steam is precipitated in condenser 4, then passes through
It is condensed out the discharge of the mouth of a river 11.Air continuation after dehumidifying is flowed in air hose, then evaporation tank more than 1 is returned under the action of blower 3
Under orifice plate 2, then continue to take away moisture with waste water by hole 14.
In order to extend present apparatus function, increase bypass between condensing heat exchanger 4 and blower 3, introduces ancillary equipment 10, it can
To introduce oxidizing gas, which enters evaporation tank 1 with the air after dehumidifying under the effect of blower 3, and useless on porous plate 2
Water contact.Advanced oxidation is carried out to waste water, removes organic matter.
Waste water is introduced again and circulates process, after the hc effluent on porous plate 2 takes away moisture by circulation air, due to water
Steam raising, waste water temperature reduce.By the channel on porous plate 2 enter 1 bottom of evaporation tank, and continues to enter from feed inlet 12
Circle hc effluent mixing, is delivered in heater 6 under the action of solution pump 5 and is heated, be then return to porous plate 2, continue
It is contacted with air, partial moisture is evaporated, and persistently forms evaporating concentration process.Once waste water is concentrated to certain journey in device
Degree, waste water are discharged from wastewater outlet 13.
From the point of view of total system, which, can also benefit by the way that high-temperature steam heat source both can be used
With using solar energy, fume afterheat, etc. low-temperature heat sources reduce operation energy consumption;Steam carrier is used air as, with low-temperature wastewater
It directly contacts, removes conventional metals evaporator, avoid core equipment corrosion and fouling, organic matter evaporation is reduced, thus effectively
Solve the technical problem of hc effluent concentration set forth above.
At a kind of evaporation and concentration processing unit of hc effluent proposed by the present invention, with existing widely used dense salt waste water
Science and engineering skill or equipment are compared, and feature and advantage are:
(1) hc effluent is concentrated by evaporation processing unit, uses air as evaporation steam carrier, and air is direct with hc effluent
Metal evaporator is cancelled in contact, solves equipment corrosion and scale problems.
(2) hc effluent is concentrated by evaporation processing unit, low to evaporating temperature requirement, can efficiently use low-temperature heat source,
Meet the requirement of energy-saving and environmental protection.
(3) the evaporation and concentration processing unit of the hc effluent, air contact evaporation, blower, waste water evaporation with hc effluent
Temperature is adjustable, is all suitable for the trade effluent of various concentration and various compositions, and the versatility of processing unit is very strong.
(4) the evaporation and concentration processing unit of the hc effluent can easily introduce advanced oxidation equipment, can effectively open up
Wastewater treatment range is opened up, the limitation that tradition evaporation is only a physically separate is broken through, extends the processing function of the enrichment facility.
(5) hc effluent is concentrated by evaporation processing unit, and portion is recycled air in the device always, no gas discharge,
It is environmentally friendly, thus the device its have broad application prospects.
Detailed description of the invention
Fig. 1 is the energy saving concentration device overall structure diagram of the dense salt waste water of the present invention.
Figure label: evaporation tank 1, porous plate 2, blower 3, condensing heat exchanger 4, solution pump 5, solution heater 6, air duct 7,
Cooling cycle water route 8, solution line 9, ancillary equipment 10, condensed water elimination pipeline 11, wastewater feed mouth 12, concentration waste water discharging
Mouth 13, hole 14.
Fig. 2 is the structural schematic diagram of porous plate 2 in Fig. 1 of the present invention
Figure label: porous plate 2, hole 14.
Specific embodiment
Below in conjunction with the specific example that attached drawing 1 and inventor are completed according to technical solution of the present invention, the present invention is made into one
The detailed description of step.
During air circulation flow, the temperature to be come by heater 6 has been gathered on the porous plate 2 on evaporation tank 1
High hc effluent, the air after dehumidifying blow out from the bottom up from the hole 14 on porous plate 2, directly contact with waste water, in wind
Flowing is continued up under machine effect.Since air is directly contacted with thermal wastewater, air themperature is improved, and is increased containing wet ability,
A small amount of moisture in waste water is taken away, so that moisture content is minimized in waste water, realizes Waste water concentrating purpose.
It is circulated in air duct 7 containing the humid air compared with juicy to condensing heat exchanger 4, by circulating cooling water route 8,
It is passed through recirculated cooling water in condensing heat exchanger 4, is cooled down to humid air.Moisture temperature reduces, and steam is just analysed in condenser 4
Out, condensed water is discharged by being condensed out the mouth of a river 11.Air continuation after dehumidifying is flowed in air duct 7, then under the action of blower 3
It returns in evaporation tank 1 under porous plate 2, then continues to take away Water Cycle flowing with waste water by hole 14.
In addition, increasing bypass between condensing heat exchanger 4 and blower 3, ancillary equipment 10 is introduced, such as oxidizing gas occurs
Device.The oxidizing gas enters evaporation tank 1 with the air after dehumidifying, on porous plate 2, sufficiently connects with waste water under the effect of blower 3
Touching, and then advanced oxidation is carried out to waste water, organic matter can be effectively removed, to extend present apparatus function.
During waste water circulates, after the hc effluent on porous plate 2 takes away moisture by circulation air, steam steams
Hair, waste water temperature reduce.Extra waste water can enter 1 bottom of evaporation tank by the channel on porous plate 2, with lasting from charging
The former hc effluents mixing that mouth 12 enters, is delivered in heater 6 under the action of solution pump 5 and is heated, be then return to more
Orifice plate 2, continuation contact evaporation with air, are formed and continue evaporating concentration process.Once the waste water in vaporising device is concentrated to one
Determine degree, the waste water after concentration is just discharged from wastewater outlet 13.
Claims (7)
1. a kind of load vapour formula hc effluent is concentrated by evaporation processing unit, it is characterised in that the device is by evaporation tank 1, porous plate 2, wind
Machine 3, condensing heat exchanger 4, solution pump 5, solution heater 6, air duct 7, cooling cycle water route 8, solution line 9, ancillary equipment 10,
Condensed water elimination pipeline 11 is constituted.
2. a kind of load vapour formula hc effluent according to claim 1 is concentrated by evaporation processing unit, which is characterized in that evaporation tank 1
Interior, lower horizontal location arrangements porous plate 2 wherein, porous plate 2 and the installation sealed around of evaporation tank 1, air is from porous plate 2
Hole 14 is blown out.
3. a kind of load vapour formula hc effluent according to claim 1 is concentrated by evaporation processing unit, which is characterized in that according to gas stream
Dynamic direction, 1 top air outlet of evaporation tank are successively connected to heat exchanger 4, blower 3 by air duct 7, then again with 1 lower part of evaporation tank
Air inlet connects, and is provided with the discharge port 13 after hc effluent stoste feed inlet 12 and Waste water concentrating on evaporation tank 1.
4. a kind of load vapour formula hc effluent according to claim 1 is concentrated by evaporation processing unit, which is characterized in that molten according to waste water
Liquid flow direction, the outlet of 1 bottom solution of evaporation tank are successively connected to solution pump 5, heat exchanger 6, then again by solution line 9
Evaporation tank is returned to, waste water solution entrance location is higher than 2 position of orifice plate.
5. a kind of load vapour formula hc effluent according to claim 1 is concentrated by evaporation processing unit, which is characterized in that condensing heat exchanger
4 be indirect type heat exchanger, is provided with and is condensed out the mouth of a river 11 and recirculated water interface 8.
6. a kind of load vapour formula hc effluent according to claim 1 is concentrated by evaporation processing unit, which is characterized in that in condensing heat-exchange
Arrange that oxidizing gas generator 10, the Strong oxdiative gas which generates pass through blower between device 4 and blower 3
3 effects enter evaporation tank 1.
7. according to claim 1, a kind of 2 load vapour formula hc effluent is concentrated by evaporation processing unit, which is characterized in that porous plate 2
It is provided with leakage channel, the hydrops on orifice plate 2 can enter 1 bottom of evaporation tank by channel.
Priority Applications (1)
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CN201811080579.1A CN109319993A (en) | 2018-09-17 | 2018-09-17 | A kind of load vapour formula hc effluent evaporation and concentration processing unit |
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CN201811080579.1A CN109319993A (en) | 2018-09-17 | 2018-09-17 | A kind of load vapour formula hc effluent evaporation and concentration processing unit |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110372055A (en) * | 2019-08-23 | 2019-10-25 | 庄卫敏 | A kind of weary vapor recompression low-temperature evaporation wastewater zero discharge system and technique |
CN112619186A (en) * | 2020-11-27 | 2021-04-09 | 攀枝花钢城集团瑞通制冷设备有限公司 | Liquid caustic soda concentration device and concentration method |
-
2018
- 2018-09-17 CN CN201811080579.1A patent/CN109319993A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110372055A (en) * | 2019-08-23 | 2019-10-25 | 庄卫敏 | A kind of weary vapor recompression low-temperature evaporation wastewater zero discharge system and technique |
CN112619186A (en) * | 2020-11-27 | 2021-04-09 | 攀枝花钢城集团瑞通制冷设备有限公司 | Liquid caustic soda concentration device and concentration method |
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Application publication date: 20190212 |