CN109306106A - A kind of Ultralight high abrasion rubber tread and preparation process - Google Patents
A kind of Ultralight high abrasion rubber tread and preparation process Download PDFInfo
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- CN109306106A CN109306106A CN201811002969.7A CN201811002969A CN109306106A CN 109306106 A CN109306106 A CN 109306106A CN 201811002969 A CN201811002969 A CN 201811002969A CN 109306106 A CN109306106 A CN 109306106A
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- rubber
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- preparation process
- ultralight
- plastics
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
Abstract
A kind of Ultralight high abrasion rubber tread and preparation process, be grouped as by mass percentage by 70 ~ 80% rubber-plastic composition and two big groups of rubber and plastics auxiliaries of 22 ~ 28%, rubber-plastic composition component by 65 ~ 70% ethylene-vinyl acetate copolymer (EVA), 15 ~ 18% isoprene rubber (IR), 15 ~ 18% olefin block copolymers (BOC) form；Rubber and plastics auxiliaries component is made of 48 ~ 52% anti-wear agents, 22 ~ 28% fillers, 1.2 ~ 1.8% vulcanization accelerators, 2.2 ~ 2.8% vulcanizing activator, 3 ~ 4% activating agent, 2.0 ~ 2.5% crosslinking agent, 7.5 ~ 9.0% foaming agent and 7 ~ 8% color developing agent；The preparation process of micelle is first by the rubber-plastic composition component of formula ratio and except the rubber and plastics auxiliaries component of foaming agent and crosslinking agent puts into mixing in mixer, foaming agent and crosslinking agent are added afterwards, then at Ultralight wear-resisting rubber-plastics micelle after mill, slice, extruding pelletization；The moulding process of sole includes according to mold injection moulding and sulfidization molding.
Description
Technical field
The present invention relates to a kind of sole, in particular to a kind of Ultralight high abrasion rubber tread and preparation process belong to high score
Sub- field of material technology.
Background technique
Shoes are a kind of articles that can be through on foot to prevent foot from coming to harm based on sole, be with skin, cloth, wood,
Grass, plastics etc. are that material makes and is through on foot to the article to land and the essential daily necessity of the mankind, this is pair
The general paraphrase of shoes.But in today of modern civilization, many Functional Units are added again in traditional sense for shoes
Element, such as playshoes, sneakers, climbing boot, running shoe, pump add all on the basis of " to the article to land "
Specific functional attributes.Modern shoes have the functional element of a multitude of names additional, how to do these additional functional elements
It is more preferable, this researches and develops, for producers sole, and being forever can not concluding, full of challenges project.
Summary of the invention
To solve modern sole the technical issues of meeting market and consumer demand on functional element as far as possible, the present invention
A kind of Ultralight high abrasion rubber tread and preparation process are disclosed.
The technical scheme adopted by the invention is that: a kind of Ultralight high abrasion rubber tread and preparation process, by quality hundred
Be divided to and be grouped as than counting by 70 ~ 80% rubber-plastic composition and two big groups of rubber and plastics auxiliaries of 22 ~ 28%, rubber-plastic composition component by 65 ~
70% ethylene-vinyl acetate copolymer (EVA), 15 ~ 18% isoprene rubber (IR), 15 ~ 18% olefin block copolymers
(BOC) it forms；Rubber and plastics auxiliaries component is by 48 ~ 52% anti-wear agents, 22 ~ 28% fillers, 1.2 ~ 1.8% vulcanization accelerators, 2.2 ~ 2.8%
Vulcanizing activator, 3 ~ 4% activating agent, 2.0 ~ 2.5% crosslinking agent, 7.5 ~ 9.0% foaming agent and 7 ~ 8% color developing agent group
At；Preparation process includes the preparation process of micelle and the moulding process of sole；The preparation process of micelle is first by the rubber of formula ratio
Molding composition component and the anti-wear agent in rubber and plastics auxiliaries component, filler, vulcanization accelerator, vulcanizing activator, activating agent, colour developing
Mixing in mixer is put into agent, rear that foaming agent and crosslinking agent is added, then after mill, slice, extruding pelletization it is resistance at Ultralight
Rubber and plastic micelle is ground, wherein the time of mill is 12 minutes, and slice is that sheet and thin slice are respectively secondary out, and pelletizer die temperature is
85 °C, granulator heating plate temperature is 80 °C, and the stirring cooling time after pelletizing in cooling bucket is 15 minutes；The molding work of sole
Skill includes according to mold injection moulding and sulfidization molding.
Filler is using the 2000 mesh talcum powder of BHS-818, and activating agent is using zinc oxide, and vulcanizing activator is using hard
Resin acid zinc, vulcanization accelerator use stearic acid, and color developing agent uses R103 titanium dioxide.
Crosslinking agent includes cumyl peroxide (DCP), di-isopropylbenzene hydroperoxide, benzoyl peroxide, di-t-butyl
Peroxide, 2,5- dimethyl -2,5 di-t-butyl hexane peroxide, dual-tert-butyl dicumyl peroxide, the present invention adopt
With dual-tert-butyl dicumyl peroxide (BIPB).
Foaming agent includes the one of which of blowing agent H or blowing agent AC or foaming agent OBSH.
Injection molding method is: being heated with any erect-position formula injection (mo(u)lding) machine to the Ultralight wear-resisting rubber-plastics micelle
Pressurization, makes it at turbulent sizing material, which is injected into mold cavity, and vulcanize the turbulent in the mold cavity
Sizing material, after cooling, demoulding, deburring Ultralight high elasticity abrasion-proof sole.
The method of sulfidization molding is: by the mould of the Ultralight wear-resisting rubber-plastics micelle investment curing forming mold of set weight
Have intracavitary, mold enter vulcanization bed heating pressurization make it at turbulent sizing material, vulcanize the turbulent sizing material in the mold cavity, through cold
But, demoulding, after deburring Ultralight high elasticity abrasion-proof sole.
The beneficial effects of the present invention are: the present invention is used with EVA as main structural resin, cooperate the alkene of novel elastomer embedding
Section copolymer (BOC) and isoprene rubber and ethylene-methacrylic acid copolymer, by lower cost, good elasticity, broader
Temperature limit, Ultralight, high abrasion, Resisting fractre, resistance to tongue tear characteristic be fused to one, be to pursue lightweight, high-elastic
The optimum structure of property and high abrasion open air footwear.
Specific embodiment
A kind of Ultralight high abrasion rubber tread and preparation process, by mass percentage by 70 ~ 80% rubber-plastic composition
Be grouped as with two big groups of rubber and plastics auxiliaries of 22 ~ 28%, rubber-plastic composition component by 65 ~ 70% ethylene-vinyl acetate copolymer
(EVA), 15 ~ 18% isoprene rubber (IR), 15 ~ 18% olefin block copolymers (BOC) composition；Rubber and plastics auxiliaries component by 48 ~
52% anti-wear agent, 22 ~ 28% fillers, 1.2 ~ 1.8% vulcanization accelerators, 2.2 ~ 2.8% vulcanizing activator, 3 ~ 4% activating agent,
2.0 ~ 2.5% crosslinking agent, 7.5 ~ 9.0% foaming agent and 7 ~ 8% color developing agent composition；Preparation process includes the preparation work of micelle
The moulding process of skill and sole；The preparation process of micelle is first will be in the rubber-plastic composition component and rubber and plastics auxiliaries component of formula ratio
Anti-wear agent, filler, vulcanization accelerator, vulcanizing activator, activating agent, color developing agent put into mixing in mixer, it is rear to be added
Foaming agent and crosslinking agent, then at Ultralight wear-resisting rubber-plastics micelle after mill, slice, extruding pelletization, wherein the time of mill is
12 minutes, slice was that sheet and thin slice are respectively secondary out, and pelletizer die temperature is 85 °C, and granulator heating plate temperature is 80 °C,
Stirring cooling time after pelletizing in cooling bucket is 15 minutes；The moulding process of sole includes being injection moulded and being sulfided into according to mold
Type.
Filler is using the 2000 mesh talcum powder of BHS-818, and activating agent is using zinc oxide, and vulcanizing activator is using hard
Resin acid zinc, vulcanization accelerator use stearic acid, and color developing agent uses R103 titanium dioxide.
Crosslinking agent includes cumyl peroxide (DCP), di-isopropylbenzene hydroperoxide, benzoyl peroxide, di-t-butyl
Peroxide, 2,5- dimethyl -2,5 di-t-butyl hexane peroxide, dual-tert-butyl dicumyl peroxide, the present invention adopt
With dual-tert-butyl dicumyl peroxide (BIPB).
Injection molding method is: being added with any erect-position formula injection (mo(u)lding) machine to the Ultralight wear-resisting rubber-plastics micelle
Heat pressurization, makes it at turbulent sizing material, which is injected into mold cavity, and vulcanize the turbulent flow in the mold cavity
State sizing material, after cooling, demoulding, deburring Ultralight high elasticity abrasion-proof sole.
The method of sulfidization molding is: by the mould of the Ultralight wear-resisting rubber-plastics micelle investment curing forming mold of set weight
Have intracavitary, mold enter vulcanization bed heating pressurization make it at turbulent sizing material, vulcanize the turbulent sizing material in the mold cavity, through cold
But, demoulding, after deburring Ultralight high elasticity abrasion-proof sole.
Embodiment:
Ethylene-vinyl acetate copolymer (EVA) 49.91%
Isoprene rubber (IR) 12.48%
Olefin block copolymers (BOC) 12.47%
Talcum powder 6.23%
Anti-wear agent 12.47%
Stearic acid 0.37%
Zinc stearate 0.62%
Zinc oxide 0.87%
Dual-tert-butyl dicumyl peroxide 0.56%
R103 titanium dioxide 1.90%
AC foaming agent 2.12%
This formula is the product requirement for adapting to lightweight, high resiliency and high abrasion open air footwear.Preparation step is: first by formula ratio
Rubber-plastic composition, anti-wear agent, filler, vulcanization accelerator, vulcanizing activator, activating agent, color developing agent are put into close in mixer
Refining is added foaming agent and crosslinking agent after mixing 8 minutes, remixes 4 minutes, 105 DEG C of mixer temperature, then makes through mill, extrusion
At Ultralight wear-resisting rubber-plastics micelle after grain.
Ultralight wear-resisting rubber-plastics micelle is put into the hopper of erect-position formula injection (mo(u)lding) machine, opens injection (mo(u)lding) machine to super
Light wear-resistant rubber and plastic micelle temperature-pressure makes it at turbulent sizing material, and the temperature of this process is controlled at 100 DEG C, and pressure exists
105MPa.When Ultralight wear-resisting rubber-plastics micelle becomes the turbulent sizing material that can be injected, which is injected into mould
In the mold cavity of tool, vulcanize the turbulent sizing material in the mold cavity, curing temperature is 170 DEG C, and vulcanization time is 3 minutes, sizing material
Foaming while vulcanization.Demoulding is finished product Ultralight high elasticity abrasion-proof sole after reaching the vulcanization time of setting.
The Ultralight wear-resisting rubber-plastics micelle of set weight is put into the mold cavity of curing forming mold, closes mold simultaneously
It is sent to the vulcanization bed of fluid pressure type vulcanizer, temperature-pressure is carried out to curing forming mold, keeps the Ultralight in mold cavity resistance to
While rubber and plastic micelle is ground into turbulent sizing material, vulcanize the turbulent sizing material in the mold cavity, the pressure of this process in 125MPa,
Temperature is 160 DEG C, and vulcanization time is 5 minutes, foaming while sizing material is vulcanized.Reaching demoulding after the vulcanization time of setting is
The Ultralight wear-resisting rubber-plastics micelle sole of finished product.
Claims (6)
1. a kind of Ultralight high abrasion rubber tread and preparation process, it is characterized in that: by mass percentage by 70 ~ 80% rubber
Molding composition and two big groups of rubber and plastics auxiliaries of 22 ~ 28% are grouped as, rubber-plastic composition component by 65 ~ 70% ethene-vinyl acetate
Copolymer (EVA), 15 ~ 18% isoprene rubber (IR), 15 ~ 18% olefin block copolymers (BOC) composition；Rubber and plastics auxiliaries component
By 48 ~ 52% anti-wear agents, 22 ~ 28% fillers, 1.2 ~ 1.8% vulcanization accelerators, 2.2 ~ 2.8% vulcanizing activator, 3 ~ 4% work
Property agent, 2.0 ~ 2.5% crosslinking agent, 7.5 ~ 9.0% foaming agent and 7 ~ 8% color developing agent composition；Preparation process includes the system of micelle
The moulding process of standby technique and sole；The preparation process of micelle is first by the rubber-plastic composition component of formula ratio and rubber and plastics auxiliaries group
Anti-wear agent, filler, vulcanization accelerator, vulcanizing activator, activating agent, color developing agent in point put into mixing in mixer, after
Foaming agent and crosslinking agent is added, then at Ultralight wear-resisting rubber-plastics micelle after mill, slice, extruding pelletization, wherein mill when
Between be 12 minutes, slice is that sheet and thin slice are respectively secondary out, and pelletizer die temperature is 85 °C, and granulator heating plate temperature is
80 °C, the stirring cooling time after pelletizing in cooling bucket is 15 minutes；The moulding process of sole include according to mold injection moulding and
Sulfidization molding.
2. a kind of Ultralight high abrasion rubber tread according to claim 1 and preparation process, it is characterized in that: described fills out
Agent is filled using the 2000 mesh talcum powder of BHS-818, and activating agent uses zinc oxide, and vulcanizing activator uses zinc stearate, sulphur
Change promotor and use stearic acid, color developing agent uses R103 titanium dioxide.
3. a kind of Ultralight high abrasion rubber tread according to claim 1 and preparation process, it is characterized in that: the friendship
Join agent and include cumyl peroxide (DCP), di-isopropylbenzene hydroperoxide, benzoyl peroxide, di-tert-butyl peroxide, 2,
5- dimethyl -2,5 di-t-butyl hexane peroxide, dual-tert-butyl dicumyl peroxide, the present invention use dual-tert-butyl mistake
It aoxidizes diisopropyl benzene (BIPB).
4. a kind of Ultralight high abrasion rubber tread according to claim 1 and preparation process, it is characterized in that: the hair
Infusion includes the one of which of blowing agent H or blowing agent AC or foaming agent OBSH.
5. a kind of Ultralight high abrasion rubber tread according to claim 1 and preparation process, it is characterized in that: the note
Penetrating molding method is: being heated and is pressurizeed to the Ultralight wear-resisting rubber-plastics micelle with any erect-position formula injection (mo(u)lding) machine, makes it
At turbulent sizing material, which is injected into mold cavity, and vulcanizes the turbulent sizing material in the mold cavity, through cold
But, demoulding, after deburring Ultralight high elasticity abrasion-proof sole.
6. a kind of Ultralight high abrasion rubber tread according to claim 1 and preparation process, it is characterized in that: the sulphur
Changing molding method is: the Ultralight wear-resisting rubber-plastics micelle of set weight being put into the mold cavity of curing forming mold, mould
Tool enter vulcanization bed heating pressurization make it at turbulent sizing material, vulcanize the turbulent sizing material in the mold cavity, through cooling, demoulding,
After deburring Ultralight high elasticity abrasion-proof sole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811002969.7A CN109306106A (en) | 2018-08-30 | 2018-08-30 | A kind of Ultralight high abrasion rubber tread and preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811002969.7A CN109306106A (en) | 2018-08-30 | 2018-08-30 | A kind of Ultralight high abrasion rubber tread and preparation process |
Publications (1)
| Publication Number | Publication Date |
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| CN109306106A true CN109306106A (en) | 2019-02-05 |
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Family Applications (1)
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| CN201811002969.7A Pending CN109306106A (en) | 2018-08-30 | 2018-08-30 | A kind of Ultralight high abrasion rubber tread and preparation process |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110105640A (en) * | 2019-05-25 | 2019-08-09 | 佛山市南海创意鞋材有限公司 | Lightweight rubber soles and its preparation process |
| CN111253673A (en) * | 2020-03-31 | 2020-06-09 | 界首市通达塑业有限公司 | High-elastic wear-resistant rubber sole material |
| CN112679902A (en) * | 2020-12-07 | 2021-04-20 | 天津天星科生皮革制品有限公司 | Preparation process of wear-resistant sole |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277316A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Antiskid EVA sole and preparation method thereof |
| CN105001505A (en) * | 2015-07-09 | 2015-10-28 | 福建豪威节能科技发展有限公司 | Formula and preparation technology for ternary rubber synthetic cross-linked polymer |
| CN107936321A (en) * | 2017-11-03 | 2018-04-20 | 中国科学院宁波材料技术与工程研究所 | A kind of shooting foaming elastomeric material and preparation method thereof |
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2018
- 2018-08-30 CN CN201811002969.7A patent/CN109306106A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277316A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Antiskid EVA sole and preparation method thereof |
| CN105001505A (en) * | 2015-07-09 | 2015-10-28 | 福建豪威节能科技发展有限公司 | Formula and preparation technology for ternary rubber synthetic cross-linked polymer |
| CN107936321A (en) * | 2017-11-03 | 2018-04-20 | 中国科学院宁波材料技术与工程研究所 | A kind of shooting foaming elastomeric material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110105640A (en) * | 2019-05-25 | 2019-08-09 | 佛山市南海创意鞋材有限公司 | Lightweight rubber soles and its preparation process |
| CN111253673A (en) * | 2020-03-31 | 2020-06-09 | 界首市通达塑业有限公司 | High-elastic wear-resistant rubber sole material |
| CN112679902A (en) * | 2020-12-07 | 2021-04-20 | 天津天星科生皮革制品有限公司 | Preparation process of wear-resistant sole |
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