CN109306086A - A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material - Google Patents
A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material Download PDFInfo
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- CN109306086A CN109306086A CN201710629789.0A CN201710629789A CN109306086A CN 109306086 A CN109306086 A CN 109306086A CN 201710629789 A CN201710629789 A CN 201710629789A CN 109306086 A CN109306086 A CN 109306086A
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- parts
- oil
- protective cover
- cover material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material, belongs to field of cable technology.Each component including following parts by weight is prepared: 15-25 parts of isoprene rubber, 3-5 parts of haloflex, 14-24 parts of microfine acrylic ester rubber powder, 10-17 parts of vulcanizing agent, 10-26 parts of white carbon black, 5-8 parts of talcum powder, 8-12 parts of nano silica, 13-17 parts of auxiliary curing agent, 1.3-1.6 parts of zinc oxide, 2-4 parts of zinc stearate, 1-7 parts of sulphur, N, N ' -5-8 parts of penylene bismaleimide, 6-8 parts of calcium stearate, 1-4 parts of promotor, 1-5 parts of anti-aging agent.Resistance to ultraviolet radiation of the present invention can be excellent, and flexibility is good, and has excellent physical mechanical property and flame retardant property, durable, has established raw material basis for the exploitation of Ultraviolet radiation resistant power cord sheath, and meet UL and European Union ROHS requirement, environmental protection is completely.
Description
Technical field
The present invention relates to a kind of cable material, especially a kind of oil-resistant high-temperature cables for submersible oil pump protective cover material belongs to electricity
Cable technical field.
Background technique
With wire and cable industrial expansion, people propose higher tightened up performance requirement to cable products.Cable
Sheath is the indispensable intermediate structure part of electric wire, plays a part of protection power source line, guarantees the energization safety of power supply line, allows
The isolation of the media such as copper wire and water, air, avoids the occurrence of leaky.However existing power supply line sheath is for a long time in strong day illumination
It penetrates down, it may occur that embrittlement phenomena, or even rupture, to influence the service performance of power supply line.
Material such as coating, building plastic, rubber product etc., the test applied to outdoor through climate, such as illumination, cold
Comprehensive caused by heat, wind and rain, bacterium etc. to destroy, tolerance is weatherability.The drastic change of temperature is the baptism to material,
At a high temperature of certain, such or such variation can occur for the service performance of cable material, some can even lose using valence
Value, so, using rubber as insulation or the material of sheath, if not having certain heat resistance, even if other performance is good again,
It is not available.
Summary of the invention
The purpose of the present invention is in view of the above shortcomings of the prior art, provide a kind of oil-resistant high-temperature cables for submersible oil pump shield
Jacking, the material have heat-resisting, oil resistant, resistance to chemical corrosion, can extend the service life of cable, a large amount of to save conductor material
And insulating materials, make the light softness of cable.
The purpose of the present invention is what is be achieved through the following technical solutions: a kind of oil-resistant high-temperature cables for submersible oil pump sheath
Material, characterized in that each component including following parts by weight is prepared: 15-25 parts of isoprene rubber, haloflex 3-5
Part, 14-24 parts of microfine acrylic ester rubber powder, 10-17 parts of vulcanizing agent, 10-26 parts of white carbon black, 5-8 parts of talcum powder, nano-silica
8-12 parts of SiClx, 13-17 parts of auxiliary curing agent, 1.3-1.6 parts of zinc oxide, 2-4 parts of zinc stearate, 1-7 parts of sulphur, N, N '-isophthalic
Support bismaleimide 5-8 parts, 6-8 parts of calcium stearate, 1-4 parts of promotor, 1-5 parts of anti-aging agent.
The vulcanizing agent be cumyl peroxide, 1,1- dual-tert-butyl peroxy -3,3,5- trimethyl-cyclohexane or
Dual-tert-butyl peroxy isopropyl base benzene.
Chlorinity is 35%~45% in the haloflex.
The auxiliary curing agent is triallylcyanurate or cyanuric acid tripropylene.
The anti-aging agent model Kg-405.
A kind of high-performance rubber for tire production of isoprene rubber, English Polyisoprene rubber.With its stabilization
Chemical property be widely used among Tire production industry.It has elasticity, cold resistance (- 68 DEG C of vitrification point) well
And very high tensile strength.Resistance to tongue tear is higher than natural rubber under resistance to oxidation and multiple deformation condition, but processing performance is such as
Mixing, calendering etc. are more slightly worse than natural rubber.Chemical equation is CH3-C (CH3)=CH-CH3, Chinese name: polyisoprene rubber
Glue, cis 1,4 polyisoprene rubber, isoprene rubber, IR.Isoprene is widely used in the various polyisoprene of production
Elastomer (isoprene rubber, SIS etc.), it is also used as the comonomer of inlay and break copolymer, produces adhesive and tackifier.
The demand of nineteen ninety-five whole world isoprene is more than 27.8 ten thousand tons (not including the former Soviet Union), wherein production isoprene rubber dosage accounts for
Half is up to 37.0 ten thousand tons in 2005.It, will be bigger to the demand of isoprene with isoprene rubber industrial expansion.
Acrylic rubber (hereinafter referred to as ACM) is elastomer obtained by being copolymerized using acrylate as main monomer, master
Chain is saturated carbon chains, and side group is polar ester groups.Since special construction assigns its many excellent feature, such as: heat-resisting, ageing-resistant,
Oil resistant, resistance to ozone, uvioresistant etc., mechanical property and processing performance be better than fluorubber and silicon rubber, heat-resisting, resistance to ag(e)ing and
Oil resistivity is better than nitrile rubber.ACM is widely used in various high temperature, in resistance to oil environment, becomes auto industry in recent years and focuses on
A kind of sealing material promoted is developed, high temperature resistant oil sealing, crankshaft, valve rod, cylinder liner, the hydraulic oil pipeline of automobile are especially used for
Deng the import of domestic demand almost all dependence at present.
White carbon black is the general name of white powder X-ray amorphous silicic acid and silicate product, is primarily referred to as precipitating dioxy
SiClx, fumed silica and superfine silicon dioxide gel also include powdered synthetic aluminium silicate and calcium silicates etc..White carbon black is
Porous material, composition can indicate that wherein nH2O is existed in the form of surface hydroxyl with SiO2nH2O.Causticity can be dissolved in
Alkali and hydrofluoric acid, not soluble in water, solvent and acid (except hydrofluoric acid).High temperature resistant, it is non-ignitable, tasteless, odorless, have well electricity absolutely
Edge.
Material resistance to ultraviolet radiation of the present invention can be excellent, and flexibility is good, and has excellent physical mechanical property and resistance
Performance is fired, it is durable, raw material basis is established for the exploitation of Ultraviolet radiation resistant power cord sheath, and meet UL and European Union ROHS
It is required that environmental protection is completely, solves ultraviolet light resistant performance, physical mechanical property, environmental-protecting performance etc. and be difficult to reach requirement comprehensively
Technical problem has huge Social benefit and economic benefit.
Specific embodiment
Embodiment 1
A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material, characterized in that each component including following parts by weight is prepared:
15-25 parts of isoprene rubber, 3-5 parts of haloflex, 14-24 parts of microfine acrylic ester rubber powder, 10-17 parts of vulcanizing agent,
10-26 parts of white carbon black, 5-8 parts of talcum powder, 8-12 parts of nano silica, 13-17 parts of auxiliary curing agent, 1.3-1.6 parts of zinc oxide,
2-4 parts of zinc stearate, 1-7 parts of sulphur, N, N ' -5-8 parts of penylene bismaleimide, 6-8 parts of calcium stearate, promotor 1-4
Part, 1-5 parts of anti-aging agent.
The vulcanizing agent be cumyl peroxide, 1,1- dual-tert-butyl peroxy -3,3,5- trimethyl-cyclohexane or
Dual-tert-butyl peroxy isopropyl base benzene.
Chlorinity is 35%~45% in the haloflex.
The auxiliary curing agent is triallylcyanurate or cyanuric acid tripropylene.
The anti-aging agent model Kg-405.
Embodiment 2
A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material, characterized in that each component including following parts by weight is prepared:
15 parts of isoprene rubber, 3 parts of haloflex, 14 parts of microfine acrylic ester rubber powder, 10 parts of vulcanizing agent, 10 parts of white carbon black,
5 parts of talcum powder, 8 parts of nano silica, 13 parts of auxiliary curing agent, 1.3 parts of zinc oxide, 2 parts of zinc stearate, 7 parts of sulphur, N, N '-
Between 5 parts of penylene bismaleimide, 8 parts of calcium stearate, 4 parts of promotor, 5 parts of anti-aging agent.
The vulcanizing agent be cumyl peroxide, 1,1- dual-tert-butyl peroxy -3,3,5- trimethyl-cyclohexane or
Dual-tert-butyl peroxy isopropyl base benzene.
Chlorinity is 35% in the haloflex.
The auxiliary curing agent is triallylcyanurate or cyanuric acid tripropylene.
The anti-aging agent model Kg-405.
Claims (5)
1. a kind of oil-resistant high-temperature cables for submersible oil pump protective cover material, characterized in that the preparation of each component including following parts by weight and
At: 15-25 parts of isoprene rubber, 3-5 parts of haloflex, 14-24 parts of microfine acrylic ester rubber powder, vulcanizing agent 10-17
Part, 10-26 parts of white carbon black, 5-8 parts of talcum powder, 8-12 parts of nano silica, 13-17 parts of auxiliary curing agent, zinc oxide 1.3-1.6
Part, 2-4 parts of zinc stearate, 1-7 parts of sulphur, N, N ' -5-8 parts of penylene bismaleimide, 6-8 parts of calcium stearate, promotor
1-4 parts, 1-5 parts of anti-aging agent.
2. a kind of oil-resistant high-temperature cables for submersible oil pump protective cover material according to claim 1, characterized in that the vulcanization
Agent is cumyl peroxide, 1,1- dual-tert-butyl peroxy -3,3,5- trimethyl-cyclohexane or dual-tert-butyl peroxy isopropyl
Base benzene.
3. a kind of oil-resistant high-temperature cables for submersible oil pump protective cover material according to claim 1, characterized in that the chlorination
Chlorinity is 35%~45% in polyethylene.
4. a kind of oil-resistant high-temperature cables for submersible oil pump protective cover material according to claim 1, characterized in that described to help vulcanization
Agent is triallylcyanurate or cyanuric acid tripropylene.
5. a kind of oil-resistant high-temperature cables for submersible oil pump protective cover material according to claim 1, characterized in that the anti-aging agent
Model Kg-405.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710629789.0A CN109306086A (en) | 2017-07-28 | 2017-07-28 | A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710629789.0A CN109306086A (en) | 2017-07-28 | 2017-07-28 | A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109306086A true CN109306086A (en) | 2019-02-05 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710629789.0A Pending CN109306086A (en) | 2017-07-28 | 2017-07-28 | A kind of oil-resistant high-temperature cables for submersible oil pump protective cover material |
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|---|---|
| CN (1) | CN109306086A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114960241A (en) * | 2022-04-29 | 2022-08-30 | 江苏赛福天钢索股份有限公司 | High-temperature-resistant anti-aging steel wire rope and preparation method thereof |
-
2017
- 2017-07-28 CN CN201710629789.0A patent/CN109306086A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114960241A (en) * | 2022-04-29 | 2022-08-30 | 江苏赛福天钢索股份有限公司 | High-temperature-resistant anti-aging steel wire rope and preparation method thereof |
| CN114960241B (en) * | 2022-04-29 | 2023-10-13 | 江苏赛福天集团股份有限公司 | High-temperature-resistant anti-aging steel wire rope |
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Application publication date: 20190205 |