CN109305773A - A kind of hilllock stone jade and preparation method thereof - Google Patents
A kind of hilllock stone jade and preparation method thereof Download PDFInfo
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- CN109305773A CN109305773A CN201811255120.0A CN201811255120A CN109305773A CN 109305773 A CN109305773 A CN 109305773A CN 201811255120 A CN201811255120 A CN 201811255120A CN 109305773 A CN109305773 A CN 109305773A
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- hilllock stone
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a kind of hilllock stone jades and preparation method thereof.The present invention is combined optimization to various raw materials according to the distinctive gradation principle of hilllock stone.Hilllock stone jade raw materials for production of the present invention are made of primary raw materials such as 400 mesh aluminium hydrate powders, 90 mesh sand of calcium carbonate, unsaturated polyester resins, the auxiliary materials such as curing agent, promotor and pigment are added again, these raw materials are put into blender according to rational proportion respectively and are mixed, it is stirred to and compares the wet feed transition of bulk and be then shut off blender door and vacuumize again, suppress rear to product of the invention.Compared to the material that pure cerium hydroxide aluminum material is worked it out, present invention adds hilllock stone jade plates made from calcium carbonate to be not easy to deform, the effect of light transmission but indifference.
Description
Technical field
The invention belongs to the field of building materials, and in particular to a kind of hilllock stone jade and preparation method thereof.
Background technique
Hilllock stone jade refers to a kind of artificial stone with jade effect, due to jade texture and translucency with
And gorgeous changeable texture, so also very popular on the market.
Existing hilllock stone jade product, since filler material aluminium hydroxide dosage is bigger, amount of resin is also with hydroxide
The dosage of aluminium and and then direct proportion change.But amount of resin excessively then makes hilllock that stone jade product is easily deformed, influence using
Effect；And the ratio in the cost stone jade totle drilling cost on duty of resin accounts for very high, so the increase of amount of resin so that
The overall cost of hilllock stone jade also improves.Therefore, under the premise of guaranteeing hilllock stone jade quality, it is necessary to reduce aluminium hydroxide
Dosage, or find part substitution aluminium hydroxide material to reduce cost.
Summary of the invention
To solve the shortcomings and deficiencies of the prior art, the primary purpose of the present invention is that providing a kind of hilllock stone jade
Preparation method.
Another object of the present invention is to provide a kind of hilllock stone jades obtained by above-mentioned preparation method.
The object of the invention is achieved through the following technical solutions:
A kind of preparation method of hilllock stone jade, comprising the following steps:
(1) gross mass is based on 100%, weighs 400 mesh aluminium hydrate powder 50-57%, 90 mesh sand 26-34% of calcium carbonate, no
Saturated polyester resin 15-17%, hybrid pigment 0.01-0.03%, curing agent 0.2-0.4% and promotor 0.02-0.05%；
(2) first by promotor and unsaturated polyester resin mixing for standby use；By in above-mentioned raw materials 400 mesh aluminium hydrate powders and
90 mesh sand of calcium carbonate is charged first in blender, then hybrid pigment is poured into blender and stirred, after stirring that unsaturation is poly-
The mixture and curing agent of ester resin and promotor are added to blender stirring, close while stirring blender door take out it is true
Sky, vacuum degree reach 0.096Mpa or more, and after the completion of stirring then cloth is suppressed to mold, vacuum is put after the completion of compacting
Mold is released with trolley, spontaneous curing, blank and sanding and polishing are up to the hilllock stone jade.
Preferably, in step (1), gross mass weighs raw material: 400 mesh aluminium hydrate powders based on 100%, according to following proportion
56.69%, 90 mesh sand 26.4% of calcium carbonate, unsaturated polyester resin 16.55%, hybrid pigment 0.01%, curing agent 0.3%,
Promotor 0.05%.
Preferably, in step (1), gross mass weighs raw material: 400 mesh aluminium hydrate powders based on 100%, according to following proportion
53.35%, 90 mesh sand 30.05% of calcium carbonate, unsaturated polyester resin 16.25%, hybrid pigment 0.01%, curing agent
0.29%, promotor 0.05%.
Preferably, in step (1), gross mass weighs raw material: 400 mesh aluminium hydrate powders based on 100%, according to following proportion
50.45%, 90 mesh sand 33.86% of calcium carbonate, unsaturated polyester resin 15.35%, hybrid pigment 0.01%, curing agent
0.28%, promotor 0.05%.
Preferably, the frequency of the blender stirring is 65Hz, stirring after all raw materials addition blenders in preparation process
Mixing the time is 20-25 minutes.
Preferably, the time of the compacting is 8-10 minutes；The time of the spontaneous curing is 10-15 days.
The present invention also provides one kind hilllock stone jade as made from above-mentioned preparation method.
The present invention is combined optimization to various raw materials according to the distinctive gradation principle of hilllock stone.Hilllock stone of the present invention is beautiful
Stone raw materials for production are made of primary raw materials such as 400 mesh aluminium hydrate powders, 90 mesh sand of calcium carbonate, unsaturated polyester resins, then are added
These raw materials are put into mixing in blender according to rational proportion respectively and stirred by the auxiliary materials such as curing agent, promotor and pigment
It mixes, is stirred to and compares the wet feed transition of bulk and be then shut off blender door and vacuumize again, suppress rear to product of the invention,
To realize the purpose of the present invention.
In the prior art, conventional hilllock stone jade main raw material(s) is by 400 mesh aluminium hydrate powders and 100 mesh hydroxide aloxites
Resin is added to be made, aluminium hydroxide dosage is more.Good 90 mesh sand material substitution of calcium carbonate, the 100 mesh hydrogen-oxygen in part is used in the present invention
Change aluminum material, due to calcium carbonate material more, the reduction of amount of resin fewer than the absorption amount of resin of aluminum hydroxide material, therefore hilllock
The entire cost of stone jade just reduces, and compared to the material that pure cerium hydroxide aluminum material is worked it out, present invention adds calcium carbonate systems
Hilllock stone jade plate be not easy to deform, the effect of light transmission but indifference.
Compared with prior art, the present invention has the following advantages and beneficial effects:
(1) key point of the invention is to change the raw material proportioning of traditional hilllock stone jade, with the high quality carbon of more preferably more cost-saving
Sour calcium material is instead of current existing partial aluminum hydroxide material, in the case where guaranteeing to reach same effect, energy of the present invention
Substantially reduce amount of resin.
(2) present invention is by the preferred of raw material and technological parameter, stone jade in hilllock obtained have jade texture and
Translucency, and ensure that quality.
Detailed description of the invention
Fig. 1 is the photo of hilllock stone jade prepared by embodiment 1.
Specific embodiment
Below with reference to embodiment and attached drawing, the present invention is described in further detail, but embodiments of the present invention are unlimited
In this.
Unsaturated polyester resin of the present invention is that the unsaturation of the p-phenyl of Putian Yu Cheng Chemical Co., Ltd. production is poly-
Ester resin (model YC-818), 90 mesh sand of calcium carbonate are the 90 mesh sand of white spar produced with Lianzhou City Yun Tong Chemical Co., Ltd..
Aluminium hydrate powder is purchased from Shandong Aluminum Co., Ltd..Hybrid pigment is by the various iron pigments of the happy company's production of Bayer and the dioxy of Du Pont's production
Change titanium (model 706) composition.Curing agent (methyl ethyl ketone peroxide) and promotor (cobalt water) are purchased from the beautiful prosperous curing agent science and technology in Guangzhou
Co., Ltd.
Embodiment 1
A kind of preparation method of hilllock stone jade, comprising the following steps:
(1) gross mass weighs 400 mesh aluminium hydrate powders 56.69%, 90 mesh sand 26.4% of calcium carbonate, insatiable hunger based on 100%
With polyester resin 16.55%, hybrid pigment 0.01%, curing agent 0.3%, promotor 0.05%；
(2) hilllock stone jade product of this experiment is made of that (hybrid pigment is 3 kinds of colors, and mass ratio is three colors
2:1:1, total amount account for the 0.01% of prescription quality), thus need three blenders could complete, a master mixer and two it is attached
Blender, master mixer and attached 1, attached 2 two attached blenders materials mass ratio are 2:1:1；
(3) by three respective promotors of blender, (master mixer: attached 1 blender: attached 2 are stirred with unsaturated polyester resin
Mix machine=2:1:1) mix it is spare；By in above-mentioned raw materials aluminium hydrate powder and 90 mesh sand of calcium carbonate according to weight 2:1:1's
Ratio is charged first in respective blender, then a kind of hybrid pigment (each blender uses color) of each blender is poured into
It in respective blender and stirs, stirring added the mixture and curing agent of promotor and unsaturated polyester resin after 5 minutes
Enter to respective blender and be mixed, stirring reached pockets of state after 20 minutes, and the material of latter two right attached blender is simultaneously
Blanking is simultaneously transmitted in master mixer by belt, and 2 circle of mixing turns off blender door and vacuumizes in master mixer,
Vacuum degree reach 0.096Mpa or more than be stirred for 4 circles (about 108 seconds) afterwards then cloth suppressed to mold, compacting 10
It minute then puts vacuum and releases mold with trolley, spontaneous curing 10 days, blank and sanding and polishing is up to the hilllock stone jade；On
The frequency for stating stirring is 65Hz.
Fig. 1 is hilllock stone jade photo prepared by embodiment 1, and the entitled highest-ranking imperial concubine's carbuncle of product has both the penetrating of natural jade
Sense and artificial stone exquisiteness sense.
Embodiment 2
(1) gross mass is based on 100%, weighs 400 mesh aluminium hydrate powders 53.35%, 90 mesh sand 30.05% of calcium carbonate, no
Saturated polyester resin 16.25%, hybrid pigment 0.01%, curing agent 0.29%, promotor 0.05%；
(2) hilllock stone jade product of this experiment is made of that (hybrid pigment is 3 kinds of colors, and mass ratio is three colors
2:1:1, total amount account for the 0.01% of prescription quality), thus need three blenders could complete, a master mixer and two it is attached
Blender, master mixer and attached 1, attached 2 two attached blenders materials mass ratio are 2:1:1；
(3) by three respective promotors of blender, (master mixer: attached 1 blender: attached 2 are stirred with unsaturated polyester resin
Mix machine=2:1:1) mix it is spare；By in above-mentioned raw materials aluminium hydrate powder and 90 mesh sand of calcium carbonate according to weight 2:1:1's
Ratio is charged first in respective blender, then a kind of hybrid pigment (each blender uses color) of each blender is poured into
It in respective blender and stirs, stirring added the mixture and curing agent of promotor and unsaturated polyester resin after 5 minutes
Enter to respective blender and be mixed, stirring reached pockets of state after 20 minutes, and the material of latter two right attached blender is simultaneously
Blanking is simultaneously transmitted in master mixer by belt, and 2 circle of mixing turns off blender door and vacuumizes in master mixer,
Vacuum degree reach 0.096Mpa or more than be stirred for 4 circles (about 108 seconds) afterwards then cloth suppressed to mold, compacting 10
It minute then puts vacuum and releases mold with trolley, spontaneous curing 10 days, blank and sanding and polishing is up to the hilllock stone jade；On
The frequency for stating stirring is 65Hz.
Embodiment 3
(1) gross mass is based on 100%, weighs 400 mesh aluminium hydrate powders 50.45%, 90 mesh sand 33.86% of calcium carbonate, no
Saturated polyester resin 15.35%, hybrid pigment 0.01%, curing agent 0.28%, promotor 0.05%；
(2) hilllock stone jade product of this experiment is made of that (hybrid pigment is 3 kinds of colors, and mass ratio is three colors
2:1:1, total amount account for the 0.01% of prescription quality), thus need three blenders could complete, a master mixer and two it is attached
Blender, master mixer and attached 1, attached 2 two attached blenders materials mass ratio are 2:1:1；
(3) by three respective promotors of blender, (master mixer: attached 1 blender: attached 2 are stirred with unsaturated polyester resin
Mix machine=2:1:1) mix it is spare；By in above-mentioned raw materials aluminium hydrate powder and 90 mesh sand of calcium carbonate according to weight 2:1:1's
Ratio is charged first in respective blender, then a kind of hybrid pigment (each blender uses color) of each blender is poured into
It in respective blender and stirs, stirring added the mixture and curing agent of promotor and unsaturated polyester resin after 5 minutes
Enter to respective blender and be mixed, stirring reached pockets of state after 20 minutes, and the material of latter two right attached blender is simultaneously
Blanking is simultaneously transmitted in master mixer by belt, and 2 circle of mixing turns off blender door and vacuumizes in master mixer,
Vacuum degree reach 0.096Mpa or more than be stirred for 4 circles (about 108 seconds) afterwards then cloth suppressed to mold, compacting 10
It minute then puts vacuum and releases mold with trolley, spontaneous curing 10 days, blank and sanding and polishing is up to the hilllock stone jade；On
The frequency for stating stirring is 65Hz.
Properties of product detection prepared in the above embodiments is as follows:
Bending strength therein is tested by electronic universal tester.
Variation of the above three embodiments to some data of main raw material(s), final obtained product also some difference are main
(permeability comparison mainly judges transparent performance by the irradiation comparison of same light source) is embodied in above permeability.It will be above-mentioned
The product of embodiment preparation is polished into same thickness, then compares under light, it is seen that and the permeability of 1 product of embodiment is best,
Embodiment 2 is secondly, embodiment 3 is worst, and mainly or the influence of how many pairs of aluminium powder dosage its permeabilities is bigger.However hilllock
Stone jade seeks to reduce cost on the basis of the reservation most feature of jade, if excessively reducing the dosage of aluminium powder,
The texture of jade will be lost, does not also just achieve the purpose that we do hilllock stone jade.
Above-mentioned pure aluminium powder template refers to according to processing step described in embodiment 1, and 90 mesh sand of calcium carbonate is replaced with 100 mesh
Aluminium hydrate powder, product template obtained.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (7)
1. a kind of preparation method of hilllock stone jade, which comprises the following steps:
(1) gross mass weighs 400 mesh aluminium hydrate powder 50-57%, 90 mesh sand 26-34% of calcium carbonate, unsaturation based on 100%
Polyester resin 15-17%, hybrid pigment 0.01-0.03%, curing agent 0.2-0.4% and promotor 0.02-0.05%；
(2) first by promotor and unsaturated polyester resin mixing for standby use；By the 400 mesh aluminium hydrate powders and carbonic acid in above-mentioned raw materials
90 mesh sand of calcium is charged first in blender, then hybrid pigment is poured into blender and stirred, by unsaturated polyester (UP) tree after stirring
The mixture and curing agent of rouge and promotor are added to blender stirring, and blender door is closed while stirring and is vacuumized,
Vacuum degree reaches 0.096Mpa or more, and after the completion of stirring then cloth is suppressed to mold, puts vacuum for mould after the completion of compacting
Tool is released with trolley, spontaneous curing, and blank and sanding and polishing are up to the hilllock stone jade.
2. a kind of preparation method of hilllock stone jade according to claim 1, which is characterized in that in step (1), gross mass is pressed
100% meter weighs raw material: 400 mesh aluminium hydrate powders 56.69%, 90 mesh sand 26.4% of calcium carbonate, unsaturation according to following proportion
Polyester resin 16.55%, hybrid pigment 0.01%, curing agent 0.3%, promotor 0.05%.
3. a kind of preparation method of hilllock stone jade according to claim 1, which is characterized in that in step (1), gross mass is pressed
100% meter weighs raw material: 400 mesh aluminium hydrate powders 53.35%, 90 mesh sand 30.05% of calcium carbonate, insatiable hunger according to following proportion
With polyester resin 16.25%, hybrid pigment 0.01%, curing agent 0.29%, promotor 0.05%.
4. a kind of preparation method of hilllock stone jade according to claim 1, which is characterized in that in step (1), gross mass is pressed
100% meter weighs raw material: 400 mesh aluminium hydrate powders 50.45%, 90 mesh sand 33.86% of calcium carbonate, insatiable hunger according to following proportion
With polyester resin 15.35%, hybrid pigment 0.01%, curing agent 0.28%, promotor 0.05%.
5. a kind of preparation method of hilllock stone jade according to any one of claims 1 to 4, which is characterized in that the stirring
The frequency of machine stirring is 65Hz, and the mixing time in preparation process after all raw materials addition blenders is 20-25 minutes.
6. a kind of preparation method of hilllock stone jade according to any one of claims 1 to 4, which is characterized in that the compacting
Time be 8-10 minutes；The time of the spontaneous curing is 10-15 days.
7. the hilllock stone jade as made from a kind of preparation method of hilllock stone jade described in any one of claims 1-6.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811255120.0A CN109305773A (en) | 2018-10-26 | 2018-10-26 | A kind of hilllock stone jade and preparation method thereof |
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| CN201811255120.0A CN109305773A (en) | 2018-10-26 | 2018-10-26 | A kind of hilllock stone jade and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113443855A (en) * | 2021-07-30 | 2021-09-28 | 广西利升石业有限公司 | Functional granite capable of releasing negative ions and preparation method thereof |
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|---|---|---|---|---|
| CN113443855A (en) * | 2021-07-30 | 2021-09-28 | 广西利升石业有限公司 | Functional granite capable of releasing negative ions and preparation method thereof |
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Application publication date: 20190205 |