CN109301221A - A kind of compound micron bar electrode material of zinc oxide/nickel and preparation method thereof - Google Patents
A kind of compound micron bar electrode material of zinc oxide/nickel and preparation method thereof Download PDFInfo
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- CN109301221A CN109301221A CN201811188094.4A CN201811188094A CN109301221A CN 109301221 A CN109301221 A CN 109301221A CN 201811188094 A CN201811188094 A CN 201811188094A CN 109301221 A CN109301221 A CN 109301221A
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title claims abstract description 72
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000011787 zinc oxide Substances 0.000 title claims abstract description 36
- 239000007772 electrode material Substances 0.000 title claims abstract description 30
- 150000001875 compounds Chemical class 0.000 title claims abstract description 18
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 20
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000002441 reversible effect Effects 0.000 claims abstract description 9
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims abstract description 8
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims abstract description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 238000001556 precipitation Methods 0.000 claims abstract description 6
- 229910052786 argon Inorganic materials 0.000 claims abstract description 5
- 239000011259 mixed solution Substances 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 2
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 239000011159 matrix material Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 4
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 4
- 239000007773 negative electrode material Substances 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000012456 homogeneous solution Substances 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- IJRVLVIFMRWJRQ-UHFFFAOYSA-N nitric acid zinc Chemical compound [Zn].O[N+]([O-])=O IJRVLVIFMRWJRQ-UHFFFAOYSA-N 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 238000007086 side reaction Methods 0.000 claims description 3
- 239000007784 solid electrolyte Substances 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 150000002816 nickel compounds Chemical class 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000001351 cycling effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 239000011267 electrode slurry Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000007770 graphite material Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
The invention discloses compound micron bar electrode materials of a kind of zinc oxide/nickel and preparation method thereof, this method are as follows: use homogeneous precipitation method, presoma is prepared by raw material of the mixed solution of zinc nitrate, nickel nitrate and ethylenediamine, is then calcined in hydrogen argon mixing reducing atmosphere and the compound micron bar material of zinc oxide/nickel is made.When the material is used for lithium ion battery negative material, have many advantages, such as that initial coulomb efficiency is high, reversible capacity is high and good cycling stability.
Description
Technical field
The present invention relates to lithium ion battery electrode materials, and in particular to a kind of compound micron bar electrode material of zinc oxide/nickel
And preparation method thereof.
Background technique
Lithium ion battery because monomer battery voltage is high, energy and power density are big, have extended cycle life the advantages that, already take up
The leading position in secondary cell market, becomes most important electric energy storage device.The promotion of performance of lithium ion battery, mainly takes
Certainly in the development of electrode material technology.In existing commercialized lithium ion battery, negative electrode material is main or traditional
Graphite material, lower theoretical capacity (372 mAh/g) seriously limit the further promotion of lithium ion battery energy density.
Zinc oxide is as a kind of novel negative electrode of lithium ion battery alternative materials, and theoretical capacity is about 900 mAh/g, far
Higher than graphite material.Although high capacity advantage allows it to show very big application potential, commercial applications do not have always
It realizes.There are two serious problems: (1) head of zinc oxide when this is primarily due to zinc oxide directly as negative electrode material use
Secondary coulombic efficiency is low.The initial coulomb efficiency of regular oxidation zinc powder powder electrode material is generally below 50%, this is because zinc oxide
Discharging product for the first time (lithia and solid electrolyte membrane) cannot be decomposed completely during subsequent initial charge, charging is anti-
It should be not thorough.(2) cycle performance of zinc oxide is low.Regular oxidation zinc powder powder electrode material often holds at circulation initial stage
Amount makes particle this is because zinc oxide material there are serious volume expansion and is shunk in charge and discharge process with regard to sharp-decay
Rapid dusting and fail.
In order to improve the chemical property of zinc oxide negative electrode material, the common conventional means of researcher are nanostructures
Change.This means tend to the cyclical stability of reinforcing material, but to the raising of material initial coulomb efficiency without positive effect.It receives
Rice structural material generally has high specific surface area, often leads to the generation of more side reactions, is unfavorable for coulomb effect for the first time
The raising of rate.
Summary of the invention
It is a kind of for negative electrode of lithium ion battery the invention aims to provide, there is high initial coulomb efficiency, reversible appearance
The compound micron bar material of zinc oxide/nickel and preparation method thereof that amount and cyclical stability are all obviously improved.
A kind of preparation method of the compound micron bar electrode material of zinc oxide/nickel, its step are as follows:
(1) homogeneous precipitation method is used, precipitation from homogeneous solution reaction preparation is carried out to the mixed solution of zinc nitrate, nickel nitrate and ethylenediamine
Presoma, nitric acid zinc concentration is 0.20 ~ 0.25 mol/L in solution, and the concentration of nickel nitrate is 0.02 ~ 0.05 mol/L, second two
The concentration of amine is 0.03 ~ 0.07 mol/L, and reaction temperature is 60 ~ 70oC, reaction time are 1 ~ 2 h.
(2) step (1) resulting precursor powder is calcined in hydrogen argon mixing reducing atmosphere, calcination temperature be 300 ~
500 oC, calcination time are 0.5 ~ 3 h, obtain the compound micron bar electrode material of zinc oxide/nickel.
In the compound micron bar electrode material of zinc oxide/nickel, zinc oxide micron rods are matrix, and the length is 10 ~ 15 μ
M, diameter are 2 ~ 3 μm, and shared mass fraction is 90% ~ 95%；Nano nickel particles are dispersed in zinc oxide micron rods matrix, matter
Measuring score is 5% ~ 10%.
In the combination electrode material, the introducing of high activity metal nano nickel particles has the chemical property of material aobvious
The humidification of work, compared with regular oxidation zinc powder body material, the combination electrode material has the advantages that in following performance:
One, the metallic nickel nano granule in the composite material material is made by hydrogen reducing, has high electro-chemical activity,
During the charging process, it after can discharging for the first time with zinc oxide lithia generated occur to electrochemically convert reaction that (it is substantially
The storage lithium mechanism of nickel oxide material), the extent of reaction that lithia participates in charging reaction is significantly increased, charging capacity is improved；It is also
With high catalytic activity, during the charging process, can by discharge process for the first time because side reaction generate solid electrolyte
Film decomposes under its catalytic action, can also contribute a part of charging capacity.The raising of material initial charge capacity also results in it
The increase of initial coulomb efficiency, initial coulomb efficiency of the combination electrode material at 0.1 C is 70% ~ 80%, reversible for the first time
Capacity is 800 ~ 900 mAh/g.
Two, uniformly compound between zinc oxide micron rods matrix and score nano nickel particles in the combination electrode material, no
Material conductivity only can be enhanced, mitigate electrode polarization, the structural strength of micron bar particle can also be enhanced, inhibit material anti-
Because of dusting caused by volume constantly dilation during multiple lithiumation/go lithiumation, so as to improve material circulation stability.
Reversible capacity conservation rate after combination electrode material recycles 100 times at 0.1 C is 70% ~ 75%.
Three, in the combination electrode material, zinc oxide micron rods are along<001>direction preferential growth, a large amount of (001) interplanars
For gap in the exposure of micron bar side, its spacing is maximum, and lithium ion passes in and out resistance minimum, therefore combination electrode material enhances its high power
Rate charge-discharge performance.
Four, the combination electrode material because its particle size be micron order, the density of powder body material can be improved, effectively increase
The volume and capacity ratio of made electrode.The rodlike pattern of particle can shorten the diffusion path of lithium ion, efficiently solve large scale
The problem of particle increases electrode polarization because of ion diffusion path length.
Detailed description of the invention
It, below will be to attached drawing needed in the embodiment in order to illustrate more clearly of the technical solution that the present invention is implemented
It is briefly described.
Fig. 1 is the stereoscan photograph of the compound micron bar electrode material of zinc oxide/nickel in embodiment.
Specific embodiment
The present invention is made below by specific embodiment and further being illustrated, but the invention is not limited to following
Example.
Embodiment:
(1) homogeneous precipitation method is used, precipitation from homogeneous solution reaction preparation is carried out to the mixed solution of zinc nitrate, nickel nitrate and ethylenediamine
Presoma, nitric acid zinc concentration is 0.20 mol/L in solution, and the concentration of nickel nitrate is 0.03 mol/L, and the concentration of ethylenediamine is
0.05 mol/L, reaction temperature 65oC, reaction time are 1 h.
(2) step (1) resulting precursor powder is mixed in (hydrogen-containing gas fraction 5%) reducing atmosphere in hydrogen argon and is forged
It burns, calcination temperature 400oC, calcination time are 2 h, obtain the compound micron bar electrode material of zinc oxide/nickel.
In the compound micron bar electrode material of institute's Preparing of Zinc Oxide/nickel, zinc oxide micron rods are matrix, and the length is 10 ~ 15 μ
M, diameter are 2 ~ 3 μm, mass fraction 92%；Metallic nickel nano granule is dispersed in zinc oxide micron rods matrix, quality
Score is 8%.
Electrode material is prepared into slurry and working electrode is made.Electrode slurry is by the compound micron bar electrode of zinc oxide/nickel
Active material, acetylene black conductor, polyvinylidene fluoride (PVDF) binder are uniformly mixed by the mass ratio of 85:7.5:7.5, are added
Add N-Methyl pyrrolidone, stir and modulate into uniform sizing material, then electrode slurry is uniformly coated on copper foil, through vacuum drying,
Lithium ion battery working electrode is made in the processes such as roll-in, cutting.Chemical property is carried out to electrode using CR2025 button cell
Test, used is metal lithium sheet to electrode, and electrolyte is 1 mol/L LiPF6DEC+EC (volume ratio DEC:EC=1:
1) solution, diaphragm are 2400 polypropylene screen of Celgard.Battery assembling process water, oxygen concentration be below 1 ppm full of argon
It is completed in the glove box of gas.After battery installs and stands 12 h, using constant current charge-discharge method, in the voltage zone of 0.02 ~ 3.0 V
In, constant current charge-discharge circulation is carried out to it using the multiplying power of 0.1 C, tests its reversible capacity, initial coulomb efficiency and circulation
Performance.
Relative to regular oxidation zinc powder body material, which shows fabulous chemical property, it is 0.1
Initial coulomb efficiency under C is up to 78%, and reversible capacity is 880 mAh/g for the first time, and the reversible capacity after circulation 100 times is kept
Rate is 75%.
Claims (4)
1. a kind of compound micron bar electrode material of zinc oxide/nickel, which is characterized in that composite material granular is with zinc oxide micron rods
Matrix, the length is 10 ~ 15 μm, diameter is 2 ~ 3 μm, and mass fraction shared by zinc oxide is 90% ~ 95%；Nano nickel particles dispersion
In zinc oxide micron rods matrix, mass fraction is 5% ~ 10%.
2. the compound micron bar electrode material of zinc oxide/nickel according to claim 1, which is characterized in that be used for lithium-ion electric
When the negative electrode material of pond, during the charging process, high-activity nano metal nickel particle contained by composite material can significantly increase lithia this
One discharging product participates in the extent of reaction of charging reaction, while to the decomposition tool of this electric discharge side reaction product of solid electrolyte membrane
There is catalytic action, therefore material has high initial charge capacity and high initial coulomb efficiency；The combination electrode material is in 0.1 C
Under initial coulomb efficiency be 70% ~ 80%, for the first time reversible capacity be 800 ~ 900 mAh/g, circulation 100 times after reversible capacity
Conservation rate is 70% ~ 75%.
3. the compound micron bar electrode material of zinc oxide/nickel according to claim 1, which is characterized in that zinc oxide micron rods
Along<001>direction preferential growth, in the exposure of micron bar side, its spacing is maximum in a large amount of (001) crystal face gaps, lithium ion disengaging resistance
Power is minimum, therefore combination electrode material enhances its high-rate charge-discharge capability.
4. the preparation method of the compound micron bar electrode material of zinc oxide/nickel according to claim 1, it is characterised in that including
Following steps: (1) precipitation from homogeneous solution reaction is carried out to the mixed solution of zinc nitrate, nickel nitrate and ethylenediamine and prepares presoma, solution
Middle nitric acid zinc concentration is 0.20 ~ 0.25 mol/L, and the concentration of nickel nitrate is 0.02 ~ 0.05 mol/L, and the concentration of ethylenediamine is
0.03 ~ 0.07 mol/L, reaction temperature are 60 ~ 70oC, reaction time are 1 ~ 2 h；(2) by step (1) resulting presoma
It is calcined in hydrogen argon mixing reducing atmosphere, calcination temperature is 300 ~ 500oC, calcination time are 0.5 ~ 3 h, obtain zinc oxide/nickel
Compound micron bar electrode material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811188094.4A CN109301221B (en) | 2018-10-12 | 2018-10-12 | Zinc oxide/nickel composite micron rod electrode material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811188094.4A CN109301221B (en) | 2018-10-12 | 2018-10-12 | Zinc oxide/nickel composite micron rod electrode material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109301221B CN109301221B (en) | 2021-03-09 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110085816A (en) * | 2019-04-02 | 2019-08-02 | 深圳鸿鹏新能源科技有限公司 | Transition metal oxide negative electrode material and its preparation method and application |
| CN111360269A (en) * | 2020-04-03 | 2020-07-03 | 南京环达新材料有限公司 | Multi-stage nanostructure reinforced laminated nickel-based composite material and preparation method thereof |
| CN114016074A (en) * | 2021-10-27 | 2022-02-08 | 浙江大学 | Preparation method and application of high-load transition metal single-atom carbon-based catalyst |
| CN116692962A (en) * | 2023-07-27 | 2023-09-05 | 湖南埃索凯未来能源研究院有限公司 | Nano/micron composite structure nickel-manganese binary precursor containing nano particles and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110085816A (en) * | 2019-04-02 | 2019-08-02 | 深圳鸿鹏新能源科技有限公司 | Transition metal oxide negative electrode material and its preparation method and application |
| CN111360269A (en) * | 2020-04-03 | 2020-07-03 | 南京环达新材料有限公司 | Multi-stage nanostructure reinforced laminated nickel-based composite material and preparation method thereof |
| CN111360269B (en) * | 2020-04-03 | 2022-05-06 | 浙江蓝天知识产权运营管理有限公司 | Multi-stage nanostructure reinforced laminated nickel-based composite material and preparation method thereof |
| CN114016074A (en) * | 2021-10-27 | 2022-02-08 | 浙江大学 | Preparation method and application of high-load transition metal single-atom carbon-based catalyst |
| CN114016074B (en) * | 2021-10-27 | 2022-10-21 | 浙江大学 | Preparation method and application of high-load transition metal single-atom carbon-based catalyst |
| CN116692962A (en) * | 2023-07-27 | 2023-09-05 | 湖南埃索凯未来能源研究院有限公司 | Nano/micron composite structure nickel-manganese binary precursor containing nano particles and preparation method thereof |
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| CN109301221B (en) | 2021-03-09 |
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