CN109298476A - A kind of back board module reflective joint strip and preparation method thereof - Google Patents

A kind of back board module reflective joint strip and preparation method thereof Download PDF

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Publication number
CN109298476A
CN109298476A CN201811512385.4A CN201811512385A CN109298476A CN 109298476 A CN109298476 A CN 109298476A CN 201811512385 A CN201811512385 A CN 201811512385A CN 109298476 A CN109298476 A CN 109298476A
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CN
China
Prior art keywords
reflective
joint strip
board module
back board
prism structures
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CN201811512385.4A
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Chinese (zh)
Inventor
唐海江
夏寅
周鼎
高斌基
汪诚
刘建凯
李刚
张彦
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Ningbo Exciton Technology Co Ltd
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Ningbo Exciton Technology Co Ltd
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Application filed by Ningbo Exciton Technology Co Ltd filed Critical Ningbo Exciton Technology Co Ltd
Publication of CN109298476A publication Critical patent/CN109298476A/en
Priority to PCT/CN2019/079422 priority Critical patent/WO2020118962A1/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/08Mirrors
    • G02B5/10Mirrors with curved faces
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • G02B5/122Reflex reflectors cube corner, trihedral or triple reflector type
    • G02B5/124Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/04Prisms
    • G02B5/045Prism arrays
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/08Mirrors
    • G02B5/09Multifaceted or polygonal mirrors, e.g. polygonal scanning mirrors; Fresnel mirrors

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Elements Other Than Lenses (AREA)

Abstract

The present invention relates to a kind of reflective joint strip of back board module more particularly to a kind of back board module reflective joint strips and preparation method thereof.In order to solve the problems, such as that the reflective joint strip of existing back board module cannot change reflected in parallel optical path, the present invention provides a kind of back board module reflective joint strip and preparation method thereof that can change reflected in parallel optical path.The reflective joint strip of the back board module includes trigone lens array, the trigone lens array includes structure sheaf and substrate layer, the structure is placed on substrate layer, the structure sheaf includes several prism structures, the cross section of the prism structures is triangle, at least one side of the triangle is the arc to triangle indent, at least one side of the prism is cancave cambered surface, and the cancave cambered surface is reflective surface.The back board module uses cancave cambered surface prism structures with reflective joint strip, can change reflected in parallel optical path, so that reflected light path is generated deflection angle, linear light source is modified to non-parallel optical path, modifies for parallel light path.

Description

A kind of back board module reflective joint strip and preparation method thereof
Technical field
The present invention relates to a kind of reflective joint strips of back board module, more particularly to one kind to have the micro- knot of cancave cambered surface trigone lens array Structure, it is suitable for back board module reflective joint strip and preparation method thereof of different sun angles.
Background technique
Its section of traditional prism is generally the triangular structure of standard, even special equilateral triangle or isosceles three It is angular etc..Prism generally has the following two kinds purposes as optical texture:
Corresponding three face in (1) three side is transparent surface, as a kind of optical transmission structure.Usually utilize two sides Refractive light paths are used as spectroscope, or using reflection, total reflection, refractive light paths as reflective mirror, two side foldings can also be used Optical path on directive even combines special 90 ° of apex angles as reflector as condenser using two sides.
The corresponding face in (2) at least one or more side is reflecting surface, as a kind of optical reflection structure.Usually using more A prism combination, multiple reflections optical path is constituted using its reflecting surface, and as guide-lighting mirror, typical such as underwater dive hopes, is outdoor The applications such as light acquisition conduction.
For reflective prism structures, Chinese patent application 200420034925.X (on January 14th, 2004) is open A kind of simulation window natural light acquisition and conduction device, Chinese patent application 201420617918.6 (on October 24th, 2014) A kind of single camera panorama recording device is disclosed, Chinese patent application 200910079162.8 (on March 3rd, 2009) discloses A kind of mirror-image stereo camera apparatus and method.
However, no matter which kind of above-mentioned patent, reflective prism structures are traditional prism structures, three side of section All sides of shape are straight line, and in other words, any side is a kind of standard flat, this kind of structure also can be only done simply Optical path reflection is that can not break the depth of parallelism of emergent light, needless to say make it full after modifying it when source of parallel light incidence The specific optical path reflexive property of foot (such as average reflection direction is raised or reduces, it completes convenient for other associated members to reflected light Collection, again secondary reflection, again transmission etc. require or pure light is upset or ray convergence), so as to cause traditional trigone The application limitation of mirror structure.
Existing back board module uses common prism structures with reflective joint strip, cannot change reflected in parallel optical path.
Therefore, in view of the above-mentioned problems, it is necessary to propose further solution.
Summary of the invention
In order to solve the problems, such as that the reflective joint strip of existing back board module cannot change reflected in parallel optical path, the present invention provides one Kind can change back board module reflective joint strip and preparation method thereof of reflected in parallel optical path.The back board module is adopted with reflective joint strip With cancave cambered surface prism structures, reflected in parallel optical path can be changed, so that reflected light path is generated deflection angle, linear light source is modified to Non-parallel optical path is modified for parallel light path.This invention also solves the reflective prism structures of tradition, in the parallel of linear light source When optical path is incident on its reflecting surface, the problem of its reflected in parallel optical path can not be changed.The present invention also provides one kind to be used for directional light Prism structures of road modification and preparation method thereof and a kind of trigone lens array.The reflective surface of the prism structures is cancave cambered surface, Linear light source can be modified to non-parallel optical path, reflected light path is made to generate deflection angle.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical solutions:
The present invention provides a kind of back board module reflective joint strip, and the reflective joint strip of the back board module includes prism battle array Column, the trigone lens array includes structure sheaf and substrate layer, and the structure is placed on substrate layer, and the structure sheaf includes several Prism structures (abbreviation prism), the cross section of the prism structures are triangle, at least one side of the triangle Side is the arc to triangle indent, at least one side of the prism structures is cancave cambered surface, and the cancave cambered surface is reflective Face.
Further, the reflective joint strip of the back board module includes hot melt laminating layer and trigone lens array, the hot melt patch Conjunction is placed under the substrate layer of trigone lens array.
The present invention also provides a kind of reflective joint strip of back board module, the reflective joint strip of the back board module includes hot melt fitting Layer and trigone lens array (also referred to as prism structures array), the trigone lens array includes structure sheaf and substrate layer, the knot Structure is placed on substrate layer, and the structure sheaf includes several prism structures, and the cross section of the prism structures is triangle, Two sides of the triangle are the arc to triangle indent, and two sides of the prism structures are cancave cambered surface, institute Stating cancave cambered surface is reflective surface;The hot melt fitting is placed under the substrate layer of prism array.
Further, the prism structures cover the surface of substrate layer.
Further, in the back board module in reflective joint strip, two sides of the prism structures include left side Reflecting surface and right side reflecting surface, the left side reflecting surface and right side reflecting surface are cancave cambered surface.
The left side reflecting surface of the structure sheaf cross section (triangle) is concave arc, the direction angle alpha of place string2, corresponding circle Heart angle is θa, right side reflecting surface is concave arc, the deflection β of place string2, corresponding central angle is θb
Further, the longitudinal extension of the prism structures and ground edge extending direction form 45 degree of folder Angle.
Further, the material of the substrate layer is selected from the high molecular material that can be formed a film;The material of the structure sheaf is selected From can be with molding high molecular material or material identical with substrate layer.
Further, the substrate layer is selected with a thickness of 0.012~0.3mm, foundation.
Further, the hot melt laminating layer is comprising one layer of hot melt adhesive film, such as EVA or PVC etc., and heating shows to glue Property, it can be used for thermal-adhering.
Further, the hot melt laminating layer (hot melt adhesive film) is with a thickness of 0.01~0.1mm, preferably 0.02~ 0.05mm。
The present invention also provides the preparation method of the reflective joint strip described in one kind, the method includes following step:
(1) in the mold of particular complementary structure fill ultraviolet light solidification or thermally curable polymer material, using photocuring, Heat curing process molding, forms specific trigone lens array after demoulding, the semi-finished product A containing substrate layer and structure sheaf is made;
(2) structure sheaf of semi-finished product A is subjected to reflective processing, be made the reflective membrane half of the reflective trigone lens array containing cambered surface at Product B;
(3) the substrate layer back side of semi-finished product B is subjected to hot melt laminating layer processing (gum processing), hot melt adhesive showering can be used Mode, generate semi-finished product C.
(4) semi-finished product C is subjected to slitting, winding ultimately forms reflective joint strip.
The reflective joint strip can be used on photovoltaic module, is heated by the residual temperature of welding and is affixed on welding (such as Figure 12 It is shown), the region unserviceable sunlight of script can be recycled by the redirection of light, improve the function of component Rate.Since structure and slitting direction have 45 degree of angle (as shown in figure 13), thus it is suitable for the group of horizontal dress or perpendicular dress simultaneously Part.
During being raised up to from morning and to fall at dusk due to the sun, lighting angle be do not stopping transformation, thus with it is existing There is technology to compare, the reflective joint strip of the arc side structure can preferably adapt to the reflection of the sunlight of different angle, and its is heavy It orients and is recycled by slide total reflection.
The present invention also provides a kind of prism structures, the cross section of the prism structures is triangle, the triangle Two sides be arc to triangle indent, two sides of the prism are cancave cambered surface, and the cancave cambered surface is reflective Face.
The cancave cambered surface of above-mentioned prism structures is reflective surface, the also referred to as reflective prism structures of cancave cambered surface.
The reflective prism structures of cancave cambered surface can modify to gradual change optical path, alternatively referred to as a kind of optical path can gradual change modification it is recessed The reflective prism structures of cambered surface.
Further, in the prism structures, the left side arc side of the triangle, central angle where circular arc is θa, The deflection of place string is α2;The right side arc side of the triangle, central angle where circular arc are θb, the deflection of place string is β2, A height of H of the triangle;α2With β2It is acute angle.
Pass through H, α2And θaIt can determine triangle left side shape;Pass through H, β2And θbIt can determine triangle right side Shape.
H is the height of prism structures, and the range of H is 10-2~102Mm is selected according to practical application, is not made preferably. The height H of prism structures can choose 10-2~1mm, 1~102Mm, 0.1mm or 10mm.
The prism structures only define shape, do not define size, and size variation meets principle of similarity.
Further, in the prism structures, the left side arc side and right side arc side of the triangle are symmetrical, α22, and θab
Further, in the prism structures, the left side arc side and right side arc side of the triangle are asymmetric, α2≠ β2Or θa≠θb
Further, in the prism structures, α2With β2Range be respectively 15 °~75 °.
Further, α2With β2Range be respectively preferably 30 °~60 °.Further, α2With β2It is respectively preferably 45 °.θa With θbIt is acute angle, range is 0.5 °~45 °, preferably 5 °~20 °, further, it is preferable to be 10 °.
Further, the side of the prism structures has carried out reflective processing and has formed reflective surface.
The reflective processing of the prism surfaces is to generate the side of reflective surface on surface using any chemistry, physical process Method, including the coating of the enterprising row metal plated film of structure sheaf, high-molecular coating, can also structure sheaf material itself direct sanding and polishing or pressure Prolong molding.
Further, reflecting layer is provided on the cancave cambered surface of the prism structures.
Reflecting layer is also referred to as reflecting surface.Reflecting surface, that is, reflective surface.
Further, the material in the reflecting layer is selected from the coat of metal or polymeric coating layer or material identical with structure sheaf Matter.
The shape in the reflecting layer is cancave cambered surface.The reflecting layer is reflective surface.
Further, the prism structures further include substrate layer, and the substrate layer is tightly attached to the bottom surface of prism.
Further, in trigone lens array, the thickness T=0.1~10H, T of the substrate layer are preferably 1H.
Further, the material of the structure sheaf is selected from one of high molecular material, metal material or nonmetallic materials Or at least two combination;The material of the substrate layer is selected from high molecular material or material identical with structure sheaf.
After parallel rays is incident in the reflective cambered surface of above-mentioned prism structures, original depth of parallelism can be broken, caused anti- It penetrates and generates deflection angle between light.
The parallel light path of linear light source can be modified to non-parallel optical path by reflection by prism structures provided by the invention, Modification effect (such as is raised or is reduced average reflection direction to meet specific optical path reflexive property, be convenient for other associated members Complete to the collection of reflected light, again secondary reflection, transmission etc. requires again or pure light is upset or ray convergence), thus The application limitation of traditional reflective prism structures is broken.
Compared with prior art, prism structures and trigone lens array provided by the present invention, has the characteristics that following: can incite somebody to action Linear light source is modified to non-parallel optical path by curved reflecting surface, and reflected light path is made to generate deflection angle.It can be used for needing to upset straight Linear light road controls the occasion that its emergent light angle meets specific deflection angle.
Compared with existing back board module is with reflective joint strip, back board module provided by the invention uses cancave cambered surface with reflective joint strip Prism structures can change reflected in parallel optical path, so that reflected light path is generated deflection angle, linear light source is modified to non-parallel light Road is modified for parallel light path.The reflective joint strip of the arc side structure can preferably adapt to the reflection of the sunlight of different angle, And it is redirected and is recycled by slide total reflection.
Detailed description of the invention
Fig. 1 is the optical path direction angle analysis chart on infinitesimal reflecting interface;
Fig. 2 is the index path of left side incidence on the cross section of the reflective prism structures of tradition;
Fig. 3 is the index path of left side incidence on the cross section of the reflective prism structures of cancave cambered surface;
Fig. 4 is the complete reflective prism structures of tradition;
Fig. 5 is the reflective prism structures array of tradition containing ground;
Fig. 6 is prism structures provided by the invention;
Fig. 7 is trigone lens array provided by the invention;
Fig. 8 is the trigone lens array of two layers of same material of ground and structure sheaf;
Fig. 9 is the trigone lens array of ground and three layers of structure sheaf, reflecting surface same material;
The radius of Figure 10 circular arc is symmetrically emitted optical focus, focus to chordal distance, the numerical relation of chord length;
The reflective joint strip structural schematic diagram of Figure 11;
The fitting schematic diagram of the reflective joint strip of Figure 12;
Application schematic diagram of the reflective joint strip of Figure 13 on photovoltaic module.
Wherein:
01: horizontal direction
02: infinitesimal reflecting interface (imfinitesimal method decomposition can be used in any curve)
The normal of 020:02
Incident light on 021:02
The correspondence reflected light of 022:021
The extending direction ray of 023:021
03: the cross section of the reflective prism structures of tradition
04: the cross section of the reflective prism structures of cancave cambered surface
The left side reflecting interface of 05:03 or 04
The right side reflecting interface of 06:03 or 04
07: parallel input light source
The return radiation of 08:07
09: the reflective prism structures (array) of tradition
The structure sheaf of 091:09
The left side reflective surface of 092:09
The right side reflective surface of 093:09
The substrate layer of 094:09
10: the reflective prism structures of cancave cambered surface (one or array)
The structure sheaf of 101:10
The left side reflective surface of 102:10
The right side of 103:10
The substrate layer of 104:10
13: the radius of curvature R of side circular arc
14: the focus about the symmetrical emitting light path of circular arc
15: the distance D of focus to circular arc string
16: circular arc chord length L
The tangent line of any position 50:05
The normal of 500:50
The incident light of 501:50 and 500 point of intersection
The correspondence reflected light of 502:501
The lower tangent line of 51:05
The normal of 510:51
The incident light of 511:51 and 510 point of intersection
The correspondence reflected light of 512:511
The upper tangent line of 53:05
The normal of 530:53
The incident light of 531:53 and 530 point of intersection
The correspondence reflected light of 532:531
17: reflective joint strip
18: hot melt laminating layer
181: hot melt adhesive
19: the reflective joint strip after fitting
20: welding
21: silicon wafer (before patch reflective strip)
22: silicon wafer (after patch reflective strip)
23: hot melt fitting process
24: joint strip partial enlargement
25: the longitudinal extension of reflective joint strip structure sheaf prism structures
26: reflective joint strip ground edge extending direction (with slitting direction)
Specific embodiment
It, hereafter will be of the invention preferable for the functional character and advantage that is more readily understood structure of the invention and can reach Embodiment, and schema is cooperated to be described below in detail.
When light is incident on irregular reflection face, the tangent line of the incoming position point and the method vertical with the tangent line Line, it is symmetrical about normal on the plane of reflection based on incident light and reflected light, that is, it can determine complete reflected light path.
Fig. 1 show the optical path direction angle analysis chart on infinitesimal reflecting interface, and by taking left side as an example, infinitesimal reflecting interface 02 is regarded For straight line, deflection α0, then the deflection of normal 09 is necessarily 90 ° of+α0If the direction in general parallel input light source 07 Angle isThe deflection (deflection of straight line where being equal to) of so its return radiation is its 180 ° of rotation counterclockwise, ForThen the deflection angle (the former-the latter) of normal and incident light return radiation isAccording to Symmetry principle, incident light return radiation and emergent light are full symmetric about normal, then the deflection angle of emergent light and normal is (preceding Person-the latter) be alsoTherefore
In order to which subsequent schematic diagram is more clear, by taking left part as an example, the return radiation of source of parallel light will be only marked DeflectionAnd the direction angle alpha of the tangent line of different incoming positionsn(n=0,1,2,3 ...), remaining incident light, normal, reflection The deflection of light byWith αnIt determines, there is no need to mark: for source of parallel light, even if position is different, owning The angle of incident light is all the same, is allSecondly, according to the angle [alpha] of different location tangent linen, can directly calculate corresponding method The angle of line must be 90 ° of+αn;Finally, by symmetry principle, the angle that can directly calculate reflected light must be
Fig. 2 show the index path of left side incidence on the cross section of the reflective prism structures of tradition, parallel input light source 07 deflection isThe deflection of its return radiation 08 isThe deflection of left side reflecting interface 05 is α0, then on 05 The deflection of the tangent line 50 of any position is also α0(50 are overlapped with 05, therefore mark is omitted in figure), normal 500 is in polar coordinates In deflection be 90 ° of+α0, when incident light 501 is mapped to any position of reflecting interface 05,501 correspondence reflected light 503 Deflection isIt can be found that all emergent rays are parallel always, γaWithAnd α0It is unrelated.Particularly, when using vertical When incident light source,The deflection of reflected light is 180 ° -90 °+2 α0=90 ° of+2 α0, all emergent rays still put down always Row, maximum deflection angle γa=(90 ° of+2 α0)-(90°+2α0)=0, still withAnd α0It is unrelated.
Fig. 3 show the index path of left side incidence on the cross section of the reflective prism structures of cancave cambered surface, parallel input light The deflection in source 07 isThe deflection of its return radiation 08 isDefine the tangent line where the endpoint up and down of concave arc Referred to as tangent line, the deflection of the lower tangent line 51 where left side reflecting interface 05 are α up and down1, the deflection of normal 510 is 90 ° of+α1, The deflection of upper tangent line 53 is α3, the deflection of normal 530 is 90 ° of+α3, and the side of tangent line 50 where any position of intermediate region It is α to angle0, the deflection of normal 500 is 90 ° of+α0.It is right when incident light 511 at lower extreme point is incident on circular arc incision inferius The deflection for answering reflected light 513 isIt is right when incident light 531 at upper extreme point is incident on circular arc incision superius The deflection for answering reflected light 533 isAnd when intermediate region vertical incidence light 501 is incident on circular arc intermediate region When, the deflection for corresponding to reflected light 503 isObviouslyBetweenWithBetween.Be easy discovery, the reflected light of different location incidence cannot keep it is parallel to each other, That is γaOnly with θaIt is related, withAnd αnIt is unrelated.Particularly, when using vertical incidence light source,The minimum of reflected light Deflection is 90 ° of+2 α1, maximum deflection is 90 ° of+2 α3, maximum deflection angle γa=(90 ° of+2 α3)-(90°+2α1(the α of)=23- α1The θ of)=2a, i.e. γaStill only with θaIt is related, withAnd αnIt is unrelated.
In prism structures, as shown in Figure 4 and Figure 5, the left side of the cross section of prism and horizontal angle are α2, α2The referred to as deflection of left side.The right edge of the cross section of prism and horizontal angle are β2, β2The referred to as side of right edge To angle.H is the height of the triangle in the cross section of prism structures.H is also the height of structure sheaf.
It is recessed on the left of prism in cross section in the reflective prism structures of cancave cambered surface as shown in Fig. 6, Fig. 7, Fig. 8 and Fig. 9 String and horizontal angle are α where circular arc2, it is θ that left side concave arc, which corresponds to central angle,a, α2The referred to as deflection of left side string.Three String and horizontal angle are β where the concave arc of the cross section of prism2, β2The referred to as deflection of right side string.H is prism knot The height of triangle in the cross section of structure.H is also the height of structure sheaf.
In the reflective prism structures of cancave cambered surface of the present invention, wherein the optional height H of structure sheaf (prism) is 10-2~ 102Mm can be selected, H 10 according to practical optical device size and use occasion-2~1mm is relatively suitably applied in Microstructure Optics Device, H are 1~102Mm is relatively suitably applied in ordinary optical device.
The optional material of structure sheaf is high molecular material, metal material, inorganic non-metallic material etc.: high molecular material is optional General-purpose plastics, engineering plastics, general plastics, rubber, high-molecular coating etc., generally do structural member be preferably engineering plastics, it is general Plastics and high-molecular coating (after solidification), it is contemplated that cost, Yi Zhixing, surface tractability, the preferred macromolecule of parts with microstructure apply Material, especially facilitate photocuring transfer micro-structured form acrylic resin (PMMA), general structure part then preferably poly- carbonic acid Ester (PC) and organic glass (PMMA);The optional ferrous metal of metal material, non-ferrous metal, specialty metal and alloy etc. are done general Structural member is preferably lower-cost stainless steel, aluminium alloy, does parts with microstructure and then uses the preferable aluminium foil of ductility, copper foil, tin The calendering such as foil;The optional category of glass of inorganic non-metallic material, ceramic-like, no matter general structure part or the preferred glass of microstructure part Glass (SiO2Based on ingredient), and be both needed to be processed by accurate cutting.
The material of substrate layer is chosen as the material of same structure sheaf, cooperation using one-shot forming technique (injection molding, casting, calendering, Accurate cutting etc.);Also it can choose the material different from structure sheaf, cooperation is using secondary forming process (compound, transfer etc.).Its In be different from structure sheaf the preferred high molecular material of material, such as polyethylene terephthalate (PET), poly terephthalic acid fourth Diol ester (PBT), polycarbonate (PC), polymethyl methacrylate (PMMA), polystyrene (PS), polypropylene (PP), poly- second One of alkene (PE), preferred generic is high, cost is relatively low, thermal stability is good and the PET for the surface treatment that is easy to do.
The material in reflecting layer (also referred to as reflecting surface) is chosen as the coat of metal, macromolecule material coating, no matter general structure Part or microstructure part can choose the coat of metal, the optional silver of coating material, aluminium etc., for cost, unless to reflectivity High request can select it is silver-plated, otherwise selection aluminize;General structure part is also an option that macromolecule material coating, coating color It is preferred that TiO2(common used material for doing white reflection);The flatness of polymeric coating layer does not have coat of metal precision high, can generate certain Ratio diffusing reflection, therefore the structure devices of high reflection required precision especially micromechanical devices preferentially select the coat of metal.
The material of hot melt adhesive is chosen as thermoplastics type's macromolecule glue system, such as polyethylene, polypropylene, polyvinyl chloride (PVC), second Alkene-vinyl acetate co-polymer (EVA), polystyrene systems, polyamide system, polycarbonate system, polyformaldehyde, thermoplastic poly Ester, polyphenylene oxide, polyphenylene sulfide, polysulfones, polyketone class or polybenzoate etc., it is generally preferable to be more general EVA or PVC etc..
In following all embodiment and comparative examples: when depth of structural layer H is 1~102Preferably without substrate layer, knot when mm Structure layer material is preferably SiO2, PMMA, PC, stainless steel, aluminium alloy, reflecting layer material is preferably Al, Ag, TiO2;When structure sheaf height H is spent 10-2Preferably there is substrate layer when~1mm, material is preferably PET, and structure sheaf material is preferably PMMA, and reflecting layer material is excellent It is selected as Al, Ag, the thickness T of substrate layer is chosen as 0.1~10H, preferably 1H.
Comparative example 1
As shown in figure 4, the complete reflective prism structures 09 of tradition for comparison, include structure sheaf 091, reflecting surface 092, structure sheaf cross section 03, left side reflecting interface 05 is straight line, direction angle alpha2It is 30 °, right side reflecting interface 06, deflection β2 It is 30 °, wherein depth of structural layer H is 10mm, and structure sheaf material is SiO2, reflecting surface material is Al.
Comparative example 2
As shown in figure 5, the reflective prism structures array 09 of tradition containing ground for comparison, includes structure sheaf 091, Reflecting surface 092, substrate layer 093, structure sheaf cross section 03, left side reflecting interface 05 are straight line, direction angle alpha2It is 30 °, right side is anti- Firing area face 06 is straight line, deflection β2It is 30 °, wherein depth of structural layer H is 0.1mm, and structure sheaf material is PMMA, ground thickness 1 times, i.e. 0.1mm, material PET that T is depth of structural layer H is spent, reflecting surface material is Al.
Embodiment 1
As shown in fig. 6, the reflective prism structures 10 of entire cancave cambered surface provided by the invention, include structure sheaf 101, left side is anti- Face 102 is penetrated, right side reflecting surface 103, structure sheaf cross section 04, left side reflecting interface 05 is concave arc, the direction angle alpha of place string2 It is 15 °, corresponding central angle is θaIt is 10 °, right side reflecting interface 06 is concave arc, the deflection β of place string2It is 15 °, corresponding circle Heart angle is θbIt is 10 °, wherein depth of structural layer H is 10mm, and structure sheaf material is SiO2, left side reflecting surface material is Al, and right side is anti- Penetrating plane materiel matter is Al.
Embodiment 2
Such as the reflective prism structures of entire cancave cambered surface that embodiment 1 provides, in the left side reflecting interface 05, the direction of string Angle α2It is 30 °, in right side reflecting interface 06, the deflection β of string2It is 30 °.
Embodiment 3-22
Such as the reflective prism structures of entire cancave cambered surface that embodiment 2 provides, in the left side reflecting interface 05, the direction of string Angle α2, corresponding central angle be θa, in right side reflecting interface 06, the deflection β of string2, corresponding central angle be θb, depth of structural layer H, Structure sheaf material, left or right lateral reflection plane materiel matter are referring to table 3.
Embodiment 23
As shown in fig. 7, the reflective prism structures array 10 of cancave cambered surface provided by the invention, includes structure sheaf 101, left side is anti- Face 102 is penetrated, right side reflecting surface 103, substrate layer 104, structure sheaf cross section 04, left side reflecting interface 05 is concave arc, place string Direction angle alpha2It is 15 °, corresponding central angle is θaIt is 10 °, right side reflecting interface 06 is concave arc, the deflection β of place string2For 15 °, corresponding central angle is θbIt is 10 °, wherein depth of structural layer H is 0.1mm, substrate layer thickness T=1H, and structure sheaf material is PMMA, left side reflecting surface material are Al, and right side reflecting surface material is Al, and substrate layer material is PET.
Embodiment 24
Such as the reflective prism structures array of cancave cambered surface that embodiment 23 provides, in the left side reflecting interface 05, the side of string To angle α2It is 30 °, in right side reflecting interface 06, the deflection β of string2It is 30 °.
Embodiment 25-37,44-45
Such as the reflective prism structures array of cancave cambered surface that embodiment 23 provides, in the left side reflecting interface 05, the side of string To angle α2, corresponding central angle be θa, in right side reflecting interface 06, the deflection β of string2, corresponding central angle be θb, depth of structural layer H, substrate layer thickness T, structure sheaf material, left or right lateral reflection plane materiel matter, substrate layer material are referring to table 4.
Embodiment 38
As shown in figure 8, the reflective prism structures array 10 of cancave cambered surface provided by the invention, includes structure sheaf 101, left side is anti- Face 102 is penetrated, right side reflecting surface 103, substrate layer 104, structure sheaf cross section 04, left side reflecting interface 05 is concave arc, place string Direction angle alpha2It is 45 °, corresponding central angle is θaIt is 10 °, right side reflecting interface 06 is concave arc, the deflection β of place string2For 45 °, corresponding central angle is θbIt is 10 °, wherein depth of structural layer H is 0.1mm, substrate layer thickness T=1H, and structure sheaf material is PMMA, left side reflecting surface material are Al, and right side reflecting surface material is Al, and substrate layer material is PMMA.
Embodiment 39
Such as the reflective prism structures array of cancave cambered surface that embodiment 38 provides, the structure sheaf material is PC, substrate layer material Matter is PC.
Embodiment 40
Such as the reflective prism structures array of cancave cambered surface that embodiment 38 provides, the structure sheaf material is SiO2, substrate layer Material is SiO2
Embodiment 41
As shown in figure 8, the reflective prism structures array 10 of cancave cambered surface provided by the invention, includes structure sheaf 101, left side is anti- Face 102 is penetrated, right side reflecting surface 103, substrate layer 104, structure sheaf cross section 04, left side reflecting interface 05 is concave arc, place string Direction angle alpha2It is 45 °, corresponding central angle is θaIt is 10 °, right side reflecting interface 06 is concave arc, the deflection β of place string2For 45 °, corresponding central angle is θbIt is 10 °, wherein depth of structural layer H is 0.1mm, substrate layer thickness T=1H, structure sheaf material, a left side Side or reflecting surface material and substrate layer material are Al.
Embodiment 42
As embodiment 38 provide the reflective prism structures array of cancave cambered surface, the structure sheaf material, reflecting surface material with And substrate layer material is Sn.As shown in Figure 9.
Embodiment 43
As embodiment 38 provide the reflective prism structures array of cancave cambered surface, the structure sheaf material, reflecting surface material with And substrate layer material is Cu.As shown in Figure 9.
Embodiment 46
As shown in figure 11, reflective joint strip 17 provided by the invention, including hot melt laminating layer 18 and trigone lens array, prism Array includes structure sheaf 101 and substrate layer 104;Structure sheaf 101 includes several prism structures, and the prism structures include a left side Lateral reflection face 102 and right side reflecting surface 103, wherein structure sheaf is the reflective prism structures array of cancave cambered surface, heats laminating layer 18 Including hot melt adhesive 181.Structure sheaf cross section 04, left side reflecting interface 05 are concave arc, the direction angle alpha of place string2It is 15 °, it is right Answering central angle is θa, θaIt is 10 °, right side reflecting interface 06 is concave arc, the deflection β of place string2It is 15 °, corresponding central angle is θb, θbIt is 10 °, wherein depth of structural layer H is 0.1mm, and substrate layer thickness T is 0.1mm, heat laminating layer 18 with a thickness of 0.05mm, Structure sheaf material is PMMA, and left side reflecting surface material is Al, and right side reflecting surface material is Al, and substrate layer material is PET, hot melt adhesive Material is EVA.
Embodiment 47
Such as the reflective joint strip that embodiment 46 provides, the substrate layer is with a thickness of 0.012mm.As shown in figure 11.
Embodiment 48
Such as the reflective joint strip that embodiment 46 provides, the substrate layer is with a thickness of 0.3mm.As shown in figure 11.
Embodiment 49
Such as the reflective joint strip that embodiment 46 provides, the substrate layer is with a thickness of 0.012mm.As shown in figure 11.
Embodiment 50
Such as the reflective joint strip that embodiment 46 provides, the hot melt adhesive (hot melt laminating layer) is with a thickness of 0.01mm.Such as Figure 11 institute Show.
Embodiment 51
Such as the reflective joint strip that embodiment 46 provides, the hot melt adhesive is with a thickness of 0.1mm.As shown in figure 11.
Embodiment 52
Such as the reflective joint strip that embodiment 46 provides, the substrate layer material is polycarbonate.As shown in figure 11.
Embodiment 53
Such as the reflective joint strip that embodiment 46 provides, the hot melt adhesive material is PVC.As shown in figure 11.
Such as the fit type reflective membrane that embodiment 46 provides, the Different structural parameters protection scope of the structure sheaf, with reference to reality A 23-45 is applied, details are not described herein.
Evaluate in the following manner optical path provided by the invention can gradual change modification prism structures or trigone lens array Main performance.
(A) optical path modification effect
Using the maximum deflection angle γ of source of parallel light its reflected light after incidentabSize assess optical path modification effect, Bigger modification effect is more significant.The corresponding central angle θ of circular arc can also be usedabSize assess, as shown in table 1.In table 1 θabRadius of curvature 13, symmetrical about circular arc at=5 °, 10 °, 20 °, 30 °, 45 °, 60 ° (0.5 ° of summary), about side circular arc Outgoing optical focus 14, the distance 15 of focus to string, (radius of curvature R is with 100 as shown in Figure 10 for chord length 16 and its numerical relation Unit indicates).
Using γabOpinion rating: extremely weak (0 °, 1 °) < weak [1 °, 10 °) < it is weaker [10 °, 20 °) < it is moderate [20 °, 40 °) < relatively strong [40 °, 60 °) < strong [60 °, 90 °] < extremely strong (90 °, 120 °).
Accordingly use θabOpinion rating: extremely weak (0 °, 0.5 °) < weak [0.5 °, 5 °) < it is weaker [5 °, 10 °) < it is moderate [10 °, 20 °) < relatively strong [20 °, 30 °) < strong [30 °, 45 °] < extremely strong (45 °, 60 °).
Note: indicating when value range that round parentheses " (" or ") " indicate not include end value, square brackets " [" or "] " indicate include End value
It is worth noting that, θabIt is not the bigger the better, its applicability will be greatly reduced when bigger: being with left side parameter Example, due to α32+0.5θa, α1=α2-0.5θa, therefore work as α2(such as 60~75 °) or α when bigger2When smaller (such as 15~ 30 °), if θaLarger (30~60 °), are more easy to cause α1< 0 ° or α3> 90 °, non-acute angle leads to not to form prism structures.
Therefore suggest θ hereinabRange is eventually held between weak~strong in modification effect and selects, i.e., 0.5~45 °, excellent Select range weaker~suitable, i.e., 5~20 °, because inclined lower range universality is relatively more preferable, and limit more on the lower side is excellent in midrange Selecting 10 ° is optimum value.
The opinion rating and relevant parameter of 1 optical path modification effect of table correspond to table
Note: being infinity at 0 °, i.e., do not cross, and 0~0.5 ° i.e. " close to infinity "." in structure " indicates focal length mistake Closely, within 0.5 times of chord length.L=2R × cos (90- θa/ 2) D=0.5L × Sin (90- θ a)
(B) balance between the sensitivity and precision of optical treatment
Sensitivity and essence are evaluated using the deflection (same to mean direction angle) of prism structures bumps or side circular arc string Degree, is considered as balance when sensitivity is identical with accuracy class, and 1~2 grade of rank difference when is considered as imbalance, and 3~4 grades of rank difference whens regard To be extremely uneven, as shown in table 2.
When deflection becomes smaller, reflected light and incident light offset angular are smaller, i.e. deflection more hour sensitivity is lower, instead It is also anti-, i.e., sensitivity is higher when deflection is higher.Therefore as shown in table 2, sensitivity evaluation grade is from low to high are as follows:
1 (0 °~20 °) < 2 (20 °~40 °) < 3 (40 °~50 °) < 4 (50 °~70 °) < 5 (70 °~90 °).
When deflection becomes smaller, unit projection area becomes larger, from it is incident (from distant place incidence can near normal it is incident) and instead The amount of light penetrated is more, i.e., precision is higher when deflection is lower, vice versa, i.e., precision is lower when deflection is higher.Therefore As shown in table 2, precision evaluation grade is from high to low are as follows:
5 (0 °~20 °) > 4 (20 °~40 °) > 3 (40 °~50 °) > 2 (50 °~70 °) > 1 (70 °~90 °).
The equilibrium relation evaluation table of 2 sensitivity of table and precision
(C) difficulty of processing
Carry out comprehensive assessment difficulty of processing from the acuity of structure sheaf, side sinking degree size and structure sheaf size.
Direction angle alpha of the acuity of structure sheaf by string2Or β2It influences, α2Or β2It is smaller more flat, α2Or β2It is more big more Sharply.Flat structure is easily worked, it is not easy to be damaged;And sharp structure is exactly the opposite, hardly possible processing, is also easily damaged.
The side camber degree of structure sheaf is by θaOr θbIt influences, θaOr θbSmaller cambered surface is more straight, and bigger cambered surface is more curved.More Straight cambered surface is more easily worked, macrostructure part more easy mold release, cutting, polishing, polishing, microstructure part be easier to filling, demoulding, Calendering.And more curved cambered surface is then more difficult to process, macrostructure part is more difficult demoulding, cutting, polishing, polishing, and microstructure part is more difficult Filling, demoulding, calendering.
The size of structure sheaf is influenced by height H, and H is bigger, and structure sheaf is bigger, vice versa.And size All difficulty of processing can be simultaneously amplified or reduce, after being determined due to the processing method of macrostructure part and microstructure part, Machining accuracy also determines that, under identical machining accuracy, size is bigger, and difficulty is lower, and the smaller difficulty of size is bigger.In general, working as H Belong to 10-2When~1mm, belong to microcosmic processing scope, when H is closer to 10-2When mm, processing is more difficult to, and when H is closer to 1mm, is added Work is simpler;In general, belonging to 1~10 in H2When mm, belong to macroscopic view processing scope, when H is closer to 1mm, processing is more difficult to, when H is closer to 102When mm, process simpler;
The performance comparison of the embodiment 1-22 of 3 prism structures of table, comparative example 1
Note: "/" represents the meaning of "or" in table.
As shown in table 3, the embodiment of the present invention all plays certain effect to the emitting light path modification of source of parallel light, dashes forward The function limitation of traditional reflective prism is broken: (a), by the comparison of embodiment 1-22 it can be found that when side circular arc string Direction angle alpha2Or β2When taking 15 ° or 75 ° of end value at 15~75 ° of preferred scope, the sensitivity of optical treatment and precision are extremely uneven, And structure sheaf is too sharp at 75 °, difficulty of processing is high, when taking 30 ° or 60 ° of end value for 30~60 ° of further preferred range, at optics The sensitivity of reason and precision are still uneven, and structure sheaf is still relatively sharp at 60 °, and difficulty of processing is still higher, be not still it is best, finally The embodiment 3 that further preferred value is 45 ° is best, and optical treatment balances and difficulty of processing is moderate;(b), pass through 3 He of embodiment The comparison of embodiment 6-9 is it can be found that when side circular arc corresponds to central angle θaOr θb0.5 ° of end value is taken at 0.5~45 ° of preferred scope Or at 45 ° or 0.5 ° of optics modification effect is weak or 45 ° of sides are too curved causes difficulty of processing high, further preferred range 5 ~20 ° when taking 5 ° or 20 ° of end value or 5 ° of optics modification effects are still weaker or 20 ° of sides too it is curved cause difficulty of processing still compared with Height, be not still it is best, the embodiment 3 that final further preferred value is 10 ° is best, and optics modification effect is moderate and difficulty of processing Also moderate;(c), by the comparison of embodiment 3 and 10,11 it can be found that when structure height H is in the preferred scope 1 of macro-scale ~102When mm, end value 10 is taken0Mm, median (index median) 101Mm, end value 102When mm, draw as H increases size The difficulty of processing risen is lower, and needs according to the mating selection suitable dimension of entire requirement on devices, the structural member Chang You of the general scale 10mm is selected, difficulty of processing is also moderate;(d), by embodiment 3,12-19 comparison it can be found that structure sheaf and reflecting surface material Matter does not have an impact optical property and difficulty of processing, can according to actual needs, using different structure size, collocation selection SiO2, PMMA, PC, stainless steel, the materials such as aluminium alloy structure sheaf and Al, Ag, TiO2Reflecting surface;It should be appreciated that more The embodiment of material collocation does not influence protection scope of the present invention though being not listed herein.(e), it is also listed in table 3 Three asymmetric members are respectively adopted in embodiment 20,21,22, the entire cancave cambered surface reflective structure or left-right asymmetry Element is triangle shape (α2≠β2), asymmetry side circular arc curvature (θa≠θb) and differentiation reflecting surface material (the left right side Al Ag it) realizes.It should be appreciated that left-right asymmetry embodiment can also be taken mutually using two or three of asymmetric element simultaneously Match, the relevant parameter of single asymmetry element is there are also more selections, and left and right reflecting surface also still there are more materials to arrange in pairs or groups, herein It is not listed in though, does not influence protection scope of the present invention.
The performance comparison of the embodiment 23-45 of the reflective prism structures array of table 4, comparative example 2
Note: because tablespace is limited, ground thickness T can not indicate that other embodiments are 1H, only embodiment in the table 34,35 is different, respectively 10H and 0.1H.Wherein 34 ground of embodiment is thicker, and extra cost is too high, and 35 ground of embodiment is too thin, It is too big to form difficulty.
As shown in table 4, the embodiment of the present invention all plays certain effect to the emitting light path modification of source of parallel light, dashes forward The function limitation of traditional reflective trigone lens array is broken: (a), by the comparison of embodiment 23~27 it can be found that when side circle The direction angle alpha of arc string2Or β2When taking 15 ° or 75 ° of end value at 15~75 ° of preferred scope, the sensitivity of optical treatment and precision pole are not Balance, and structure sheaf is too sharp at 75 °, difficulty of processing is high, when taking 30 ° or 60 ° of end value for 30~60 ° of further preferred range, The sensitivity of optical treatment and precision are still uneven, and structure sheaf is still relatively sharp at 60 °, and difficulty of processing is still higher, is not still most Good, the embodiment 25 that final further preferred value is 45 ° is best, and optical treatment balances and difficulty of processing is moderate, therefore, α2With β2Optional range be 15 °~75 °, preferably 30 °~60 °, further, it is preferable to be 45 °;(b), pass through embodiment 25 and 28- 31 comparison is it can be found that when side circular arc corresponds to central angle θaOr θb0.5 ° or 45 ° of end value is taken at 0.5~45 ° of preferred scope When or 0.5 ° of optics modification effect is weak or 45 ° of sides are too curved causes difficulty of processing high, 5~20 ° of further preferred range When taking 5 ° or 20 ° of end value or 5 ° of optics modification effects are still weaker or 20 ° of sides are too curved causes difficulty of processing still higher, still It is not that most preferably, the embodiment 25 that final further preferred value is 10 ° is best, and optics modification effect is moderate and difficulty of processing is also fitted In, therefore, θaWith θbOptional range be 0.5 °~45 °, preferably 5 °~20 °, further, it is preferable to be 10 °.;(c), pass through reality The comparison of example 25 and 32,33 is applied it can be found that when structure height H is in the preferred scope 10 of micro-scale-2When~1mm, end value is taken 10-2Mm, median (index median) 10-1Mm, end value 100When mm, become as H increases difficulty of processing caused by size It is low, it needs according to the mating selection suitable dimension of entire requirement on devices, the structural member Chang Youxuan 0.1mm of the general scale, difficult processing It spends also moderate;(d), by the comparison of embodiment 25 and 34,35 it can be found that the optional range of ground thickness T be 10~0.1H, When taking end value 10H, median 1H, end value 0.1H, with the increase of T, extra cost increases, and with the reduction of T, forms difficulty and increases Add, it is generally preferable to which T=1H is proper;(e), by embodiment 25,36-43 comparison it can be found that structure sheaf, reflecting surface and The material of ground does not have an impact optical property and difficulty of processing, can be selected according to actual needs using different process various Collocation, as different grounds may be selected when embodiment 25,36,37 is using compound or UV transfer printing process, if embodiment 38,39 is using heat Substrate layer and structure sheaf same material may be selected when pressing combination process, it can when using metal foil calendering technology such as embodiment 41-43 Substrate layer, structure sheaf, reflecting surface same material are selected, if embodiment 30 is using SiO optional when microscopic carvings technique2Material undercuts knot Naturally substrate layer can be reserved while structure layer.It should be appreciated that the embodiment of more material collocation, though it is not listed herein, But do not influence protection scope of the present invention;(f), 2 embodiments 44,45 have been also listed in table 4, the cancave cambered surface reflective structure is left It is right asymmetric, two kinds asymmetry element i.e. triangle shape (α are respectively adopted2≠β2), asymmetry side circular arc curvature (θa ≠θb), it should be understood that left-right asymmetry embodiment can also be arranged in pairs or groups mutually using two kinds of asymmetric elements simultaneously, it is single not The relevant parameter of symmetry elements, though being not listed herein, does not influence protection scope of the present invention there are also more selections.
It should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to limit protection of the invention Range.The equivalent changes and modifications that all contents according to the present invention are done, are encompassed by the scope of the patents of the invention.

Claims (10)

1. a kind of reflective joint strip of back board module, which is characterized in that the reflective joint strip of the back board module includes trigone lens array, The trigone lens array includes structure sheaf and substrate layer, and the structure is placed on substrate layer, and the structure sheaf includes several three Prism structure, the cross section of the prism structures are triangle, at least one side of the triangle is into triangle Recessed arc, at least one side of the prism structures are cancave cambered surface, and the cancave cambered surface is reflective surface.
2. according to the reflective joint strip of back board module described in claims 1, which is characterized in that the reflective joint strip of the back board module Including hot melt laminating layer and trigone lens array, the hot melt fitting is placed under the substrate layer of prism array.
3. according to the reflective joint strip of back board module described in claims 1, which is characterized in that the reflective joint strip of the back board module It include structure sheaf and substrate layer including hot melt laminating layer and trigone lens array, the trigone lens array, the structure is placed on bottom On material layer, the structure sheaf includes several prism structures, and the cross section of the prism structures is triangle, the triangle Two sides be arc to triangle indent, two sides of the prism structures are cancave cambered surface, and the cancave cambered surface is Reflective surface;The hot melt fitting is placed under the substrate layer of prism array.
4. according to the reflective joint strip of back board module described in claims 1, which is characterized in that the prism structures cover bottom The surface of material layer.
5. according to the reflective joint strip of back board module described in claims 3, which is characterized in that two sides of the prism structures Face includes left side reflecting surface and right side reflecting surface, and the left side reflecting surface and right side reflecting surface are cancave cambered surface.
6. according to the reflective joint strip of back board module described in claims 5, which is characterized in that the longitudinal direction of the prism structures Extending direction and ground edge extending direction form 45 degree of angle.
7. according to the reflective joint strip of back board module described in claims 1, which is characterized in that the left side arc side of the triangle, Central angle where circular arc is θa, the deflection of place string is α2;The right side arc side of the triangle, central angle where circular arc are θb, The deflection of place string is β2, a height of H of the triangle;α2With β2It is acute angle.
8. according to the reflective joint strip of back board module described in claims 7, which is characterized in that α2With β2Range be respectively 15 °~ 75°。
9. according to the reflective joint strip of back board module described in claims 1, which is characterized in that the cancave cambered surface of the prism structures On be provided with reflecting layer.
10. a kind of preparation method of the reflective joint strip of back board module according to claim 1 to 9, feature exist In the method includes following step:
(1) ultraviolet light solidification or thermally curable polymer material are filled in the mold of particular complementary structure, utilize photocuring, thermosetting Change technological forming, form specific trigone lens array after demoulding, the semi-finished product A containing substrate layer and structure sheaf is made;
(2) structure sheaf of semi-finished product A is subjected to reflective processing, the reflective membrane semi-finished product B of the reflective trigone lens array containing cambered surface is made;
(3) the substrate layer back side of semi-finished product B is subjected to hot melt laminating layer processing, by the way of hot melt adhesive showering, generate half at Product C.
(4) semi-finished product C is subjected to slitting, winding ultimately forms reflective joint strip.
CN201811512385.4A 2017-12-12 2018-12-11 A kind of back board module reflective joint strip and preparation method thereof Pending CN109298476A (en)

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CN201822074622.5U Active CN209327601U (en) 2017-12-12 2018-12-11 A kind of reflective joint strip of double hot-melt adhesive layer
CN201822073335.2U Active CN209514111U (en) 2017-12-12 2018-12-11 A kind of reflective joint strip of back board module
CN201811512332.2A Pending CN109490999A (en) 2017-12-12 2018-12-11 Fit type reflective membrane and preparation method thereof built in a kind of
CN201811510859.1A Pending CN109283606A (en) 2017-12-12 2018-12-11 A kind of moisture-resistant oxygen reflective membrane and preparation method thereof
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