CN109294648A - A kind of novel process that feces of livestock and poultry utilizes - Google Patents
A kind of novel process that feces of livestock and poultry utilizes Download PDFInfo
- Publication number
- CN109294648A CN109294648A CN201811128684.8A CN201811128684A CN109294648A CN 109294648 A CN109294648 A CN 109294648A CN 201811128684 A CN201811128684 A CN 201811128684A CN 109294648 A CN109294648 A CN 109294648A
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- livestock
- feces
- methane
- biogas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/103—Sulfur containing contaminants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
- C02F11/04—Anaerobic treatment; Production of methane by such processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Treatment Of Sludge (AREA)
Abstract
The present invention provides a kind of novel process that feces of livestock and poultry utilizes, comprising the following steps: feces of livestock and poultry first passes through anaerobic fermentation first, and generated biogas passes through pretreatment, the solid particle in raw material and the H2S removing in the drop and biogas that condense out；Enter decarburization psa unit after biogas pressurization after desulfurization；Methane gas after purification enters Methane Steam Reforming equipment, and gas enters the pressure-swing absorption apparatus of special hydrogen purification, hydrogen purity is finally purified to 99.999%, then can be directly used for hydrogen energy automobile aerating by pressurization in hydrogenation stations.The present invention is by methane steam reforming technique to hydrogen, it again passes by pressure swing adsorption and hydrogen mixed gas is purified into the High Purity Hydrogen that hydrogen purity is 99.999%, then hydrogenated station supply hydrogen energy automobile is with being used as power, product after burning is vapor, the secondary pollution that carbon dioxide is generated when avoiding methyl hydride combustion is that a real environmental protection utilizes technique.
Description
Technical field
The present invention relates to waste utilization method and technology field, specially a kind of novel process that feces of livestock and poultry utilizes.
Background technique
Contain a large amount of organic matter in feces of livestock and poultry, these organic principles can produce based on methane by anaerobic fermentation
Fuel gas, methane is generally 60% in composition, while going back carbonated and a small amount of vapor, hydrogen sulfide, organic volatile
Object etc..It is using purification technique currently with most modes, such as pressure-variable adsorption, WATER-WASHING METHOD, amine washes method and embrane method Deng, according to state
Family's standard GB17820 natural gas and GB18047 compressed natural gas used as vehicle fuel standard purification are to pipe natural gas or natural gas used for automobile.
Summary of the invention
Technical problem solved by the invention is to provide a kind of novel process that feces of livestock and poultry utilizes, to solve above-mentioned back
The problems in scape technology.
Technical problem solved by the invention is realized using following technical scheme: a kind of novel work that feces of livestock and poultry utilizes
Skill, comprising the following steps:
Step (1): feces of livestock and poultry first passes through anaerobic fermentation, solid of the generated biogas by pre-processing, in raw material first
H in grain and the drop and biogas that condense out2S removing；
Step (2): enter decarburization psa unit after the biogas pressurization after desulfurization；Methane gas after purification enters steam methane
Reformation hydrogen production equipment,
Step (3): the discharge gas of Methane Steam Reforming equipment enters the pressure-swing absorption apparatus of special hydrogen purification,
Hydrogen purity is finally purified to 99.999%, then can be directly used for hydrogen energy automobile aerating by pressurization in hydrogenation stations.
The gas that shown Methane Steam Reforming equipment generates is 78% containing hydrogen volume score based on hydrogen,
Residual air body mainly based on carbon dioxide, contains a small amount of methane impurities simultaneously.
Be compared to open technology, there are following advantages by the present invention: the present invention by methane steam reforming technique to hydrogen,
It again passes by pressure swing adsorption and hydrogen mixed gas is purified into the High Purity Hydrogen that hydrogen purity is 99.999%, then hydrogenated station
For supply hydrogen energy automobile with being used as power, the product after burning is vapor, generates the secondary of carbon dioxide when avoiding methyl hydride combustion
Pollution is that a real environmental protection utilizes technique.
Detailed description of the invention
Fig. 1 is process flow diagram of the invention.
Specific embodiment
In order to make, technological means of the invention, creation characteristic, workflow, application method reach purpose and effect is easy to bright
White understanding, below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " company ", " connection "
It shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected to be mechanical connection,
It is also possible to be electrically connected;It can be directly connected, can also indirectly connected through an intermediary, it can company inside two elements
It is logical, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts
Example, shall fall within the protection scope of the present invention.
As shown in Figure 1, a kind of novel process that feces of livestock and poultry utilizes, comprising the following steps:
Step (1): feces of livestock and poultry first passes through anaerobic fermentation, solid of the generated biogas by pre-processing, in raw material first
H in grain and the drop and biogas that condense out2S removing；
Step (2): enter decarburization psa unit after the biogas pressurization after desulfurization；Methane gas after purification enters steam methane
Reformation hydrogen production equipment,
Step (3): the discharge gas of Methane Steam Reforming equipment enters the pressure-swing absorption apparatus of special hydrogen purification,
Hydrogen purity is finally purified to 99.999%, then can be directly used for hydrogen energy automobile aerating by pressurization in hydrogenation stations.
The gas that shown Methane Steam Reforming equipment generates is 78% containing hydrogen volume score based on hydrogen,
Residual air body mainly based on carbon dioxide, contains a small amount of methane impurities simultaneously.
The present invention first passes through pressure swing adsorption to pipe network natural gas requirement, then livestock manure fermented is gone out methane purification
By methane steam reforming technique to hydrogen, again passes by pressure swing adsorption hydrogen mixed gas is purified into hydrogen purity and be
99.999% High Purity Hydrogen, then hydrogenated station supply hydrogen energy automobile is with being used as power.
The above shows and describes the basic principle, main features and advantages of the invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.Claimed range of the invention by appended claims and
Its equivalent thereof.
Claims (2)
1. a kind of novel process that feces of livestock and poultry utilizes, it is characterised in that: the following steps are included:
Step (1): feces of livestock and poultry first passes through anaerobic fermentation, solid of the generated biogas by pre-processing, in raw material first
H in grain and the drop and biogas that condense out2S removing；
Step (2): enter decarburization psa unit after the biogas pressurization after desulfurization；Methane gas after purification enters steam methane
Reformation hydrogen production equipment,
Step (3): the discharge gas of Methane Steam Reforming equipment enters the pressure-swing absorption apparatus of special hydrogen purification,
Hydrogen purity is finally purified to 99.999%, then can be directly used for hydrogen energy automobile aerating by pressurization in hydrogenation stations.
2. the novel process that a kind of feces of livestock and poultry according to claim 1 utilizes, it is characterised in that: shown steam methane weight
The gas that whole hydrogen producer generates is 78% containing hydrogen volume score based on hydrogen, and remaining gas is mainly with carbon dioxide
It is main, contain a small amount of methane impurities simultaneously.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811128684.8A CN109294648A (en) | 2018-09-27 | 2018-09-27 | A kind of novel process that feces of livestock and poultry utilizes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811128684.8A CN109294648A (en) | 2018-09-27 | 2018-09-27 | A kind of novel process that feces of livestock and poultry utilizes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109294648A true CN109294648A (en) | 2019-02-01 |
Family
ID=65164730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811128684.8A Pending CN109294648A (en) | 2018-09-27 | 2018-09-27 | A kind of novel process that feces of livestock and poultry utilizes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109294648A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110282843A (en) * | 2019-07-01 | 2019-09-27 | 杨帆 | A kind of excrement extraction methane supply dynamic combustion mode |
| CN113636524A (en) * | 2021-09-10 | 2021-11-12 | 山东恒昌聚材化工科技股份有限公司 | Gas conversion and purification device and method for producing high-purity hydrogen by using methane |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591083A (en) * | 2015-01-28 | 2015-05-06 | 张进勇 | Hydrogen preparation method |
-
2018
- 2018-09-27 CN CN201811128684.8A patent/CN109294648A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591083A (en) * | 2015-01-28 | 2015-05-06 | 张进勇 | Hydrogen preparation method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110282843A (en) * | 2019-07-01 | 2019-09-27 | 杨帆 | A kind of excrement extraction methane supply dynamic combustion mode |
| CN113636524A (en) * | 2021-09-10 | 2021-11-12 | 山东恒昌聚材化工科技股份有限公司 | Gas conversion and purification device and method for producing high-purity hydrogen by using methane |
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Application publication date: 20190201 |