CN109294507A - One kind is built a wall with polyurethane adhesive and application - Google Patents

One kind is built a wall with polyurethane adhesive and application Download PDF

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Publication number
CN109294507A
CN109294507A CN201810978993.8A CN201810978993A CN109294507A CN 109294507 A CN109294507 A CN 109294507A CN 201810978993 A CN201810978993 A CN 201810978993A CN 109294507 A CN109294507 A CN 109294507A
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CN
China
Prior art keywords
wall
polyether polyol
polyurethane adhesive
silicone oil
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810978993.8A
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Chinese (zh)
Inventor
步帅
步贺
张旺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shijiazhuang Dongxiang Chemical Co Ltd
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Shijiazhuang Dongxiang Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201810978993.8A priority Critical patent/CN109294507A/en
Publication of CN109294507A publication Critical patent/CN109294507A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J191/00Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
    • C09J191/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses one kind to build a wall with polyurethane adhesive and application, and the polyurethane adhesive specifically includes the component of following parts by weight: white material, black material, dimethyl ether, the third butane;It wherein, include polyether polyol 310, polyether polyol 210, polyether polyol 5631, even bubble silicone oil, brokenly bubble silicone oil, dual-morpholinyl diethyl ether and chlorinated paraffin in white material;Black material is polymethylene multi-phenenyl isocyanate.The dedicated wall bonding agent that the present invention is used as non-bearing wall body inside building constructure, have the advantages that take i.e. use, light-weight, construction is simple, operation to be easy, cement is replaced to carry out the construction of construction wall using the present invention, the construction time is not only reduced, but also also reduces construction cost and the labor intensity of construction worker.

Description

One kind is built a wall with polyurethane adhesive and application
Technical field
The present invention relates to building material technical fields, especially a kind of for for replacing cement to build a wall as construction material When the polyurethane adhesive that uses.
Background technique
Cranny filler of polyurethane foam is commonly called as foaming agent, PU gap filler, is a kind of one pack system, moisture-curable, multiduty poly- The foam filled elaxtic seal of urethane is that the components such as Ju urethane Yu Ju Ti ﹑ Fa Pao Ji ﹑ catalyst are loaded on pressure-resistant inhalator jar In special polyurethane products.Mist colloid is sprayed to portion to be onstructed by mating applicator gun or manual jet pipe when construction Position, the polyurethane materials of foam shape, which are expanded rapidly and are cured with the moisture in air or the matrix touched, reacts formation bubble Foam completes molding, foaming, bonding and seal process short-term, and solidification foam elastomer has bonding, waterproof, resistance to heat expansion cold Excellent performances, the filling being widely used at building doors and windows side seam, member expansion joint and hole such as contracting, heat-insulated, sound insulation, fire-retardant are close Envelope, energy conservation and environmental protection are easy to use;However, most of cranny filler of polyurethane foam are also only used as gap filler at present.
In building field, construction worker during building a wall, be all be sufficiently stirred using a certain proportion of water and sand it is mixed The wall of building is formed after closing uniformly for being bonded brick.And in the process, since cement self weight and volume are larger, Whipping process is not only time-consuming and laborious, and construction worker's large labor intensity, brings larger inconvenience to construction and use.In addition, water Requirement of the mud as current construction walling, production also bring along biggish pollution, cause larger pressure to environmental protection.
Although cranny filler of polyurethane foam has binding function, mainly use joint filling, thus its coefficient of foaming compared with The foam of height, generation is more, and the coefficient of expansion is very big, carries out operation of building a wall if be directly used in instead of cement, when construction It is unable to control the uniformity of building masonry wall, wall crack also reduces greatly adhesive strength because of foam volume, and can not also protect Demonstrate,prove the stability of building.
Chinese formerly application for a patent for invention 2016103658322 discloses a kind of polyurethane adhesive glue and replaces cementitious sand The application of the bonding and thermal insulation material on exterior walls of buildings is starched, although proposing instead of cementitious mortar, the viscoelastic polyurethane It connects glue and is also only applicable to the bonding and thermal insulation layer on exterior wall, equally exist the generally existing foaming times of conventional polyurethane foams gap filler The problem that number is high, the coefficient of expansion is big, is not used to the use of building a wall of construction.
Summary of the invention
The technical problem to be solved by the invention is to provide a kind of for substituting poly- ammonia of the cement as proprietary material of building a wall Ester gum and its application can reduce the construction time on the basis of guaranteeing to build physical performance, reduce labor intensity and be constructed into This.
In order to solve the above technical problems, the technical solution used in the present invention is as follows.
One kind is built a wall with polyurethane adhesive, and the component of following parts by weight is specifically included:
White 300 ~ 320g of material, black 300 ~ 310g of material, dimethyl ether 55 ~ 62g, third 48 ~ 55g of butane;
It wherein, include the component of following weight percentage: 30 ~ 32% polyether polyol 310,30 ~ 35% polyether polyols in white material Alcohol 210, the even bubble silicone oil of 5 ~ 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 23 ~ 26% Chlorinated paraffin;
Black material is polymethylene multi-phenenyl isocyanate.
Above-mentioned one kind is built a wall with polyurethane adhesive, and the component of following parts by weight is specifically included:
White 300 ~ 310g of material, black 300 ~ 305g of material, dimethyl ether 58 ~ 60g, third 50 ~ 52g of butane;
It wherein, include the component of following weight percentage: 30 ~ 31% polyether polyol 310,30 ~ 32% polyether polyols in white material Alcohol 210, the even bubble silicone oil of 8 ~ 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 25 ~ 26% Chlorinated paraffin;
Black material is polymethylene multi-phenenyl isocyanate.
Above-mentioned one kind is built a wall with polyurethane adhesive, and the component of following parts by weight is specifically included:
White material 306g, black material 304g, dimethyl ether 60g, the third butane 50g;
Wherein, in white material include following weight percentage component: 30% polyether polyol 310,30% polyether polyol 210, The even bubble silicone oil of 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 25.2% chlorinated paraffin;
Black material is polymethylene multi-phenenyl isocyanate.
Above-mentioned one kind is built a wall with polyurethane adhesive, and the viscosity of the chlorinated paraffin is 600(50 DEG C) mpa.s.
A kind of application built a wall with polyurethane adhesive, the polyurethane adhesive are applied to building for frame construction inner partition wall Cheng Zhong, it is first that the brick body upper surface for needing to be bonded is clean, and a small amount of water is sprayed, keep bonding plane wet;Secondly it takes out Polyurethane glue bottle level is installed in dedicated glue rifle after shaking up;Then wet brick body upper surface is glued;Then immediately will Another brick body is placed in the lower layer's brick body for applied glue and compresses.
Due to using above technical scheme, the invention technological progress is as follows.
The dedicated wall bonding agent that the present invention is used as non-bearing wall body inside building constructure, have take use, The easy advantage of light-weight, construction is simple, operation replaces cement to carry out the construction of construction wall using the present invention, and one bottle 900 Gram polyurethane adhesive can bond area about 5m2Wall, or so construction time about half an hour not only reduces the construction time, drops Low construction cost and construction worker's labor intensity;Simultaneously because cement can be substituted completely, therefore it is raw also to avoid cement There are the appearance of problem of environmental pollution for production.
Main component of the invention uses conventional polyether polyalcohol and polymethylene multi-phenenyl isocyanate, but to by gathering The white material that ethoxylated polyhydric alcohol is constituted has carried out the stringent proportion of component, and is added to even bubble silicone oil and brokenly bubble silicone oil, and by new Increase the restriction of weight percentages of components, so that polyurethane adhesive, when being sprayed on wet construction surface, moment completes by hair The process of bubble and brokenly bubble, the effect of binding component medium-high viscosity chlorinated paraffin had both limited its coefficient of foaming, while being also provided with High viscosity and high-strength characteristic, so that the building masonry wall finished building both maintains intensity, it may have preferable uniformity, reliably It ensure that the stability of building.
Specific embodiment
The present invention provides one kind and builds a wall with polyurethane adhesive, realizes interior of building non-bearing for replacing existing cement The construction of wall has the advantages that take i.e. use, light-weight, construction is simple, operation to be easy.
Polyurethane adhesive of the present invention specifically includes the component of following parts by weight: white 300 ~ 320g of material, and black material 300 ~ 310g, dimethyl ether 55 ~ 62g, third 48 ~ 55g of butane;Wherein, include the component of following weight percentage in white material: 30 ~ 32% is poly- Ethoxylated polyhydric alcohol 310,30 ~ 35% polyether polyol 210, the even bubble silicone oil of 5 ~ 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 23 ~ 26% chlorinated paraffins;Black material is polymethylene multi-phenenyl isocyanate.Chlorine in the present invention Fossil waxes use viscosity for 600(50 DEG C) the self-control chlorinated paraffin of mpa.s or so.
During polyurethane adhesive of the invention is used to that cement to be replaced to build for interior of building non-bearing wall body, first The brick body upper surface for needing to be bonded is clean, and a small amount of water is sprayed, keep bonding plane wet;Secondly polyurethane glue bottle is taken out Level is installed in dedicated glue rifle after shaking up;Then wet brick body upper surface is glued;Then another brick body is put immediately It sets and is compressed in the lower layer's brick body for applied glue.
Below in conjunction with specific embodiment, the present invention will be described in further detail.
Embodiment 1
One kind is built a wall with polyurethane adhesive, specifically includes the component of following parts by weight: white material 306g, black material 304g, dimethyl ether 60g, the third butane 50g;It wherein, include the component of following weight percentage: 30% polyether polyol 310,30% polyethers in white material Polyalcohol 210, the even bubble silicone oil of 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 25.2% chlorinated paraffin;Black material is polymethylene multi-phenenyl isocyanate.
Embodiment 2
One kind is built a wall with polyurethane adhesive, specifically includes the component of following parts by weight: white material 300g, black material 308g, dimethyl ether 62g, the third butane 53g;It wherein, include the component of following weight percentage: 31% polyether polyol 310,33% polyethers in white material Polyalcohol 210, the even bubble silicone oil of 7% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 24.2% Chlorinated paraffin;Black material is polymethylene multi-phenenyl isocyanate.
Embodiment 3
One kind is built a wall with polyurethane adhesive, specifically includes the component of following parts by weight: white material 320g, black material 300g, dimethyl ether 55g, the third butane 55g;It wherein, include the component of following weight percentage: 32% polyether polyol 310,33% polyethers in white material Polyalcohol 210, the even bubble silicone oil of 6% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 24.2% Chlorinated paraffin;Black material is polymethylene multi-phenenyl isocyanate.
Embodiment 4
One kind is built a wall with polyurethane adhesive, specifically includes the component of following parts by weight: white material 310g, black material 310g, dimethyl ether 58g, the third butane 48g;It wherein, include the component of following weight percentage: 30% polyether polyol 310,34% polyethers in white material Polyalcohol 210, the even bubble silicone oil of 8% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 23.2% Chlorinated paraffin;Black material is polymethylene multi-phenenyl isocyanate.
Embodiment 5
One kind is built a wall with polyurethane adhesive, specifically includes the component of following parts by weight: white material 312g, black material 305g, dimethyl ether 60g, the third butane 50g;It wherein, include the component of following weight percentage: 32% polyether polyol 310,31% polyethers in white material Polyalcohol 210, the even bubble silicone oil of 9% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 23.2% Chlorinated paraffin;Black material is polymethylene multi-phenenyl isocyanate.
It is respectively used to cement is replaced to carry out operation of building a wall using polyurethane adhesive prepared by the various embodiments described above, and to puzzling Wall carries out the measurement of verticality and the test of seismic behavior, can satisfy the requirement of national standard.And use this hair Bright to carry out operation of building a wall, relative to cementitious construction method is used, speed of application improves more than half, is constructed into this section About half or so, while greatly reducing the labor intensity of construction worker.

Claims (5)

1. one kind is built a wall with polyurethane adhesive, which is characterized in that specifically include the component of following parts by weight:
White 300 ~ 320g of material, black 300 ~ 310g of material, dimethyl ether 55 ~ 62g, third 48 ~ 55g of butane;
It wherein, include the component of following weight percentage: 30 ~ 32% polyether polyol 310,30 ~ 35% polyether polyols in white material Alcohol 210, the even bubble silicone oil of 5 ~ 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 23 ~ 26% Chlorinated paraffin;
Black material is polymethylene multi-phenenyl isocyanate.
2. one kind according to claim 1 is built a wall with polyurethane adhesive, which is characterized in that specifically include following parts by weight Component:
White 300 ~ 310g of material, black 300 ~ 305g of material, dimethyl ether 58 ~ 60g, third 50 ~ 52g of butane;
It wherein, include the component of following weight percentage: 30 ~ 31% polyether polyol 310,30 ~ 32% polyether polyols in white material Alcohol 210, the even bubble silicone oil of 8 ~ 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 25 ~ 26% Chlorinated paraffin;
Black material is polymethylene multi-phenenyl isocyanate.
3. one kind according to claim 1 is built a wall with polyurethane adhesive, which is characterized in that specifically include following parts by weight Component:
White material 306g, black material 304g, dimethyl ether 60g, the third butane 50g;
Wherein, in white material include following weight percentage component: 30% polyether polyol 310,30% polyether polyol 210, The even bubble silicone oil of 10% polyether polyol 5631,2.5%, 1% brokenly bubble silicone oil, 1.3% dual-morpholinyl diethyl ether, 25.2% chlorinated paraffin;
Black material is polymethylene multi-phenenyl isocyanate.
4. one kind according to any one of claims 1 to 3 is built a wall with polyurethane adhesive, which is characterized in that the chlorinated paraffin Viscosity be 600(50 DEG C) mpa.s.
5. a kind of application of polyurethane adhesive described in Claims 1-4, which is characterized in that the polyurethane adhesive is applied to frame It is first that the brick body upper surface for needing to be bonded is clean in the construction process of formula building interior partition wall, and a small amount of water is sprayed, it protects It is wet to hold bonding plane;Secondly it takes out after polyurethane glue bottle level shakes up and is installed in dedicated glue rifle;Then to table in wet brick body Face is glued;Then another brick body is placed on immediately in the lower layer's brick body for applied glue and is compressed.
CN201810978993.8A 2018-08-27 2018-08-27 One kind is built a wall with polyurethane adhesive and application Pending CN109294507A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114656915A (en) * 2022-02-22 2022-06-24 礼泉多力克环保科技有限公司 Polyurethane foaming bonding material suitable for dry masonry method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101883805A (en) * 2007-12-03 2010-11-10 巴斯夫欧洲公司 Single-component polyurethane adhesive
CN104987850A (en) * 2015-07-15 2015-10-21 锋泾(中国)建材集团有限公司 Green environment-friendly universal polyurethane foam sealing agent and preparing method of universal polyurethane foam sealing agent
CN105906774A (en) * 2016-06-09 2016-08-31 营口天元化工研究所股份有限公司 Recoverable one-component polyurethane foam joint mixture contained in pressure steel cylinder
CN107227017A (en) * 2017-07-14 2017-10-03 苏州市建筑科学研究院集团股份有限公司 A kind of normal temperature synthesis type environment-friendly polyurethane grouting leak-stopping agent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101883805A (en) * 2007-12-03 2010-11-10 巴斯夫欧洲公司 Single-component polyurethane adhesive
CN104987850A (en) * 2015-07-15 2015-10-21 锋泾(中国)建材集团有限公司 Green environment-friendly universal polyurethane foam sealing agent and preparing method of universal polyurethane foam sealing agent
CN105906774A (en) * 2016-06-09 2016-08-31 营口天元化工研究所股份有限公司 Recoverable one-component polyurethane foam joint mixture contained in pressure steel cylinder
CN107227017A (en) * 2017-07-14 2017-10-03 苏州市建筑科学研究院集团股份有限公司 A kind of normal temperature synthesis type environment-friendly polyurethane grouting leak-stopping agent and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114656915A (en) * 2022-02-22 2022-06-24 礼泉多力克环保科技有限公司 Polyurethane foaming bonding material suitable for dry masonry method

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Application publication date: 20190201