CN109294343A - A kind of ship anchor chains protective paint and preparation method thereof - Google Patents
A kind of ship anchor chains protective paint and preparation method thereof Download PDFInfo
- Publication number
- CN109294343A CN109294343A CN201811144292.0A CN201811144292A CN109294343A CN 109294343 A CN109294343 A CN 109294343A CN 201811144292 A CN201811144292 A CN 201811144292A CN 109294343 A CN109294343 A CN 109294343A
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- China
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- parts
- protective paint
- anchor chains
- ship anchor
- furan resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/04—Alginic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of ship anchor chains protective paint and preparation method thereof, which includes following component according to parts by weight: 15-25 parts of straw powder, 5-12 parts of hydroxy propyl methacrylate, 24-28 parts of modified furan resin, 10-18 parts of butyl stearate, 2-8 parts of foamed aluminium, 4-12 parts of barium sulfate, 2-8 parts of nano zine oxide, 25-38 parts of marine algae extract, 2-5 parts of hydroxymethyl cellulose sodium, 10-15 parts of polyester ester oligomer, 10-15 parts of polytetramethylene ether diol, 30-45 parts of deionized water.Hydroxy propyl methacrylate, modified furan resin, butyl stearate and polyester ester oligomer are mixed after melting, straw powder, foamed aluminium, barium sulfate, nano zine oxide, sodium cellulose glycolate and polytetramethylene ether diol is added, it is eventually adding marine algae extract, adjusts viscosity.The protective paint adhesive force is strong, resistance to scratch, has excellent corrosion resistance in briny environment.
Description
Technical field
The present invention relates to marine anchor chain fields, and in particular to a kind of ship anchor chains protective paint and preparation method thereof.
Background technique
Anchor chain refers to connection anchor and hull and the special chain for transmitting anchor holding power.Often by swivel piece, middle shot and end
Hold the composition such as chain link.The structure of chain link is pressed, stud link chain and two kinds of unstudded cable can be divided into, the former intensity is bigger than the latter；It presses
Manufacturing method anchor chain can be divided into cast steel anchor chain and electric welded anchor cable etc..The effect of anchor chain is mainly: connection anchor and ship are transmitted to hull
Anchor is grabbed in power；It, can be in water to the external force such as distinguished and admirable suffered by ship because the anchor chain dished out has certain weight in anchoring
Play certain buffer function；The anchor chain for lying down water-bed part keeps horizontal to the active force of anchor, and be conducive to anchor reliably grabs bottom.Together
When this part anchor chain because of the retardation by soil, moreover it is possible to a part of mooring forces are provided.
Since ship is run in marine environment for a long time, seawater is very serious to the corrosion of anchor chain, after a period of use,
There is rust staining, in order to protect anchor chain structure and prolong its service life, a coating is usually sprayed on anchor chain.But existing painting
The variety protection of material is more, and many components are more toxic, and enters in ocean after falling off and how to be eaten by fish, causes mortal injury.
Application number 201610285080.9 discloses a kind of ship anchor chains asphalt caulk and preparation method thereof, is related to marine paint
Technical field is made of the raw material of following parts by weight: 40-50 parts epoxide coal bituminous, 10-15 parts of fluorocarbon resin, volcanic ash 10-
15 parts, 8-11 parts of low density polyethylene (LDPE), 6-10 parts of disproportionated rosin, Macrogol 6000 double 6-10 parts of stearates, cetanol 5-8
Part, 4-6 parts of portland cement, 4-6 parts of adhesion promoter, 3-5 parts of carbomer, 3-5 parts of ethoxylated dodecyl alcohol, urea
2-3 parts, 1-2 parts of glass powder, 1-2 parts of nanometer aluminium powder, 1-2 parts of calgon, 12-17 parts of paraffin oil, 150-200 parts of water.This
Invention asphalt caulk, which is sprayed on ship anchor chains, can quickly form the paint film that adhesive force is extremely strong and hardness is big, which has excellent resistance to
Corrosive properly, weatherability and water resistance can mitigate the corrosion and loss of seawater and outdoor environment to anchor chain, and preparation cost
It is low, to reduce using investment.But chemical component is too many in the asphalt caulk, has certain danger to biology in ocean after falling off
Evil property.
A kind of application number 201410825980.9, entitled preparation method of corrosion resistant emulsion paint, belongs to coating technology
Field.Include the following steps: to take butyl acrylate, methyl methacrylate, hydroxy propyl methacrylate, maleic anhydride, emulsification
Agent and water, stir evenly, then heat up, and then under the protection of nitrogen, initiator is added dropwise, carries out polymerization reaction, after reaction,
It lets cool, obtains polymerizable aqueous lotion；Epoxy resin, styrene-acrylic emulsion, polyethylene glycol contracting are added in above-mentioned polymerizable aqueous lotion
Butyral resin, anti ultraviolet agent, bentonite, titanium dioxide, titanate coupling agent, surfactant, wetting dispersing agent, kills at chitosan
Microbial inoculum, water, after mixing evenly.The emulsion paint that the present invention is prepared has good weather resistance.Same problem,
The environmentally friendly rank of the component needs to be promoted.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of ship anchor chains protective paint and preparation method thereof, the protection
Paint adhesive force is strong, and hardness is big, wear-resistant scratch resistance, corrosion-resistant, ingredient environmental protection, and preparation method is simple, easily prepared.
A kind of ship anchor chains protective paint, including following component according to parts by weight: 15-25 parts of straw powder, methyl-prop
5-12 parts of olefin(e) acid hydroxypropyl acrylate, 24-28 parts of modified furan resin, 10-18 parts of butyl stearate, 2-8 parts of foamed aluminium, barium sulfate 4-12
Part, 2-8 parts of nano zine oxide, 25-38 parts of marine algae extract, 2-5 parts of hydroxymethyl cellulose sodium, polyester ester oligomer 10-
15 parts, 10-15 parts of polytetramethylene ether diol, 30-45 parts of deionized water.
It is above-mentioned ship anchor chains protective paint as improved, including following component according to parts by weight: straw powder 22
Part, 8 parts of barium sulfate, is received 8 parts of hydroxy propyl methacrylate, 25 parts of modified furan resin, 13 parts of butyl stearate, 5 parts of foamed aluminium
Rice 6 parts of zinc oxide, 30 parts of marine algae extract, 3 parts of hydroxymethyl cellulose sodium, 12 parts of polyester ester oligomer, polytetramethylene
13 parts of ether glycol, 40 parts of deionized water.
It is as improved, the modified furan resin is mixed by furane resins, maleic anhydride and graphene.
Specifically, furane resins, maleic anhydride and graphene are mixed in investment reaction kettle, after thawing, puts into extruder
Middle extrusion is to get modified furan resin.
Further improved to be, the molar ratio of the furane resins, maleic anhydride and graphene is 10-18:1:3-6.
It is that the straw powder is Spartina alterniflora's straw powder as improved.
The preparation method of above-mentioned ship anchor chains protective paint, comprising the following steps:
Step 1, hydroxy propyl methacrylate, modified furan resin, butyl stearate and polyester ester oligomer are mixed, is thrown
Enter in reaction kettle, after thawing, straw powder, foamed aluminium, barium sulfate, nano zine oxide, sodium cellulose glycolate and poly- four Asia is added
Ether glycol continues to stir to obtain mixture A；
Step 2, marine algae extract is added into mixture A, after stirring, adjusts viscosity with deionized water to get protective paint.
The utility model has the advantages that
Compared with prior art, the present invention is aided with hydroxy propyl methacrylate, stearic acid using modified furan resin as primary raw material
The components such as butyl ester and polyester ester oligomer prepare ship anchor chains protective paint, and the protective paint adhesive force is strong, resistance to scratch, in sea
There is excellent corrosion resistance in water environment, it is at low cost, and environmentally friendly degree is high.
Specific embodiment
The present invention is further described in detail below by specific embodiment.
Embodiment 1
A kind of ship anchor chains protective paint, including following component according to parts by weight: 15 parts of Spartina alterniflora's straw powder, methyl-prop
5 parts of olefin(e) acid hydroxypropyl acrylate, 24 parts of modified furan resin, 10 parts of butyl stearate, 2 parts of foamed aluminium, 4 parts of barium sulfate, nano zine oxide 2
Part, 25 parts of marine algae extract, 2 parts of hydroxymethyl cellulose sodium, 10 parts of polyester ester oligomer, polytetramethylene ether diol 10
Part, 30 parts of deionized water.
The modified furan resin is mixed by furane resins, maleic anhydride and graphene.
Specifically, furane resins, maleic anhydride and graphene are mixed in investment reaction kettle, after thawing, puts into extruder
Middle extrusion is to get modified furan resin.Wherein, the molar ratio of furane resins, maleic anhydride and graphene is 10:1:3.
The preparation method of above-mentioned ship anchor chains protective paint, comprising the following steps:
Step 1, hydroxy propyl methacrylate, modified furan resin, butyl stearate and polyester ester oligomer are mixed, is thrown
Enter in reaction kettle, after thawing, straw powder, foamed aluminium, barium sulfate, nano zine oxide, sodium cellulose glycolate and poly- four Asia is added
Ether glycol continues to stir to obtain mixture A；
Step 2, marine algae extract is added into mixture A, after stirring, adjusts viscosity with deionized water to get protective paint.
Embodiment 2
A kind of ship anchor chains protective paint, including following component according to parts by weight: 22 parts of Spartina alterniflora's straw powder, methyl-prop
8 parts of olefin(e) acid hydroxypropyl acrylate, 25 parts of modified furan resin, 13 parts of butyl stearate, 5 parts of foamed aluminium, 8 parts of barium sulfate, nano zine oxide 6
Part, 30 parts of marine algae extract, 3 parts of hydroxymethyl cellulose sodium, 12 parts of polyester ester oligomer, polytetramethylene ether diol 13
Part, 40 parts of deionized water.
The modified furan resin is mixed by furane resins, maleic anhydride and graphene.
Specifically, furane resins, maleic anhydride and graphene are mixed in investment reaction kettle, after thawing, puts into extruder
Middle extrusion is to get modified furan resin；The molar ratio of the furane resins, maleic anhydride and graphene is 15:1:5 parts.
The preparation method of above-mentioned ship anchor chains protective paint, comprising the following steps:
Step 1, hydroxy propyl methacrylate, modified furan resin, butyl stearate and polyester ester oligomer are mixed, is thrown
Enter in reaction kettle, after thawing, straw powder, foamed aluminium, barium sulfate, nano zine oxide, sodium cellulose glycolate and poly- four Asia is added
Ether glycol continues to stir to obtain mixture A；
Step 2, marine algae extract is added into mixture A, after stirring, adjusts viscosity with deionized water to get protective paint.
Embodiment 3
A kind of ship anchor chains protective paint, including following component according to parts by weight: 15-25 parts of Spartina alterniflora's straw powder, first
5-12 parts of base hydroxypropyl acrylate, 24-28 parts of modified furan resin, 10-18 parts of butyl stearate, 2-8 parts of foamed aluminium, barium sulfate
4-12 parts, 2-8 parts of nano zine oxide, 25-38 parts of marine algae extract, 2-5 parts of hydroxymethyl cellulose sodium, polyester ester oligomer
10-15 parts, 10-15 parts of polytetramethylene ether diol, 30-45 parts of deionized water.
The modified furan resin is mixed by furane resins, maleic anhydride and graphene.
Specifically, furane resins, maleic anhydride and graphene are mixed in investment reaction kettle, after thawing, puts into extruder
Middle extrusion is to get modified furan resin, wherein the molar ratio of furane resins, maleic anhydride and graphene is 18:1:6 parts.
The preparation method of above-mentioned ship anchor chains protective paint, comprising the following steps:
Step 1, hydroxy propyl methacrylate, modified furan resin, butyl stearate and polyester ester oligomer are mixed, is thrown
Enter in reaction kettle, after thawing, straw powder, foamed aluminium, barium sulfate, nano zine oxide, sodium cellulose glycolate and poly- four Asia is added
Ether glycol continues to stir to obtain mixture A；
Step 2, marine algae extract is added into mixture A, after stirring, adjusts viscosity with deionized water to get protective paint.
Comparative example 1
In addition to modified furan resin is changed to furane resins, remaining is the same as embodiment 2.
Protective paint in above-described embodiment is made a service test according to national standard, the results are shown in Table 1.
The present invention is aided with hydroxy propyl methacrylate, butyl stearate and polyester using modified furan resin as primary raw material
The components such as ester oligomer prepare ship anchor chains protective paint, and the protective paint adhesive force is strong, resistance to scratch, have in briny environment excellent
Different corrosion resistance, it is at low cost, and environmentally friendly degree is high.Comparing embodiment 2 and comparative example 1 are it is found that modified furan resin is bright
The aobvious resistance to scratch performance and weatherability for improving protective paint, has a good application prospect.
The foregoing is only a preferred embodiment of the present invention, the scope of protection of the present invention is not limited to this, it is any ripe
Know those skilled in the art within the technical scope of the present disclosure, the letter for the technical solution that can be become apparent to
Altered or equivalence replacement are fallen within the protection scope of the present invention.
Claims (6)
1. a kind of ship anchor chains protective paint, which is characterized in that including following component according to parts by weight: straw powder 15-25
Part, 5-12 parts of hydroxy propyl methacrylate, 24-28 parts of modified furan resin, 10-18 parts of butyl stearate, 2-8 parts of foamed aluminium,
4-12 parts of barium sulfate, 2-8 parts of nano zine oxide, 25-38 parts of marine algae extract, 2-5 parts of hydroxymethyl cellulose sodium, polyester acrylate
10-15 parts of oligomer, 10-15 parts of polytetramethylene ether diol, 30-45 parts of deionized water.
2. a kind of ship anchor chains protective paint according to claim 1, which is characterized in that including it is following according to parts by weight
Component: 22 parts of straw powder, 8 parts of hydroxy propyl methacrylate, 25 parts of modified furan resin, 13 parts of butyl stearate, foamed aluminium 5
Part, 8 parts of barium sulfate, 6 parts of nano zine oxide, 30 parts of marine algae extract, 3 parts of hydroxymethyl cellulose sodium, polyester ester oligomer
12 parts, 13 parts of polytetramethylene ether diol, 40 parts of deionized water.
3. a kind of ship anchor chains protective paint according to claim 1, which is characterized in that the modified furan resin is by furan
Furane resins, maleic anhydride and graphene mix.
4. a kind of ship anchor chains protective paint according to claim 3, which is characterized in that the furane resins, maleic acid
The molar ratio of acid anhydride and graphene is 10-18:1:3-6.
5. a kind of ship anchor chains protective paint according to claim 1, which is characterized in that the straw powder is Spartina alterniflora
Straw powder.
6. the preparation method based on a kind of ship anchor chains protective paint described in claim 5, which is characterized in that step 1, by first
Base hydroxypropyl acrylate, modified furan resin, butyl stearate and the mixing of polyester ester oligomer, put into reaction kettle, melt
After change, straw powder, foamed aluminium, barium sulfate, nano zine oxide, sodium cellulose glycolate and polytetramethylene ether diol is added, after
It is continuous to stir to obtain mixture A；Marine algae extract is added into mixture A, after stirring, adjusts viscosity with deionized water to get protection
Paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811144292.0A CN109294343A (en) | 2018-09-29 | 2018-09-29 | A kind of ship anchor chains protective paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811144292.0A CN109294343A (en) | 2018-09-29 | 2018-09-29 | A kind of ship anchor chains protective paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109294343A true CN109294343A (en) | 2019-02-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811144292.0A Pending CN109294343A (en) | 2018-09-29 | 2018-09-29 | A kind of ship anchor chains protective paint and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130662A (en) * | 2007-10-16 | 2008-02-27 | 刘善江 | Aquosity metallic protective paint and method for producing the same |
| CN103421419A (en) * | 2013-08-16 | 2013-12-04 | 石家庄世易糠醛糠醇有限公司 | Preparation method of high-performance furan marine anticorrosion coating |
| CN107858066A (en) * | 2017-11-23 | 2018-03-30 | 厦门中凯新材石墨烯科技有限公司 | A kind of graphene high-performance anticorrosion coating and preparation method thereof |
| CN108117802A (en) * | 2017-12-28 | 2018-06-05 | 安徽鑫铂铝业股份有限公司 | A kind of corrosion-resistant heronsbill aluminium alloy extrusions |
-
2018
- 2018-09-29 CN CN201811144292.0A patent/CN109294343A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130662A (en) * | 2007-10-16 | 2008-02-27 | 刘善江 | Aquosity metallic protective paint and method for producing the same |
| CN103421419A (en) * | 2013-08-16 | 2013-12-04 | 石家庄世易糠醛糠醇有限公司 | Preparation method of high-performance furan marine anticorrosion coating |
| CN107858066A (en) * | 2017-11-23 | 2018-03-30 | 厦门中凯新材石墨烯科技有限公司 | A kind of graphene high-performance anticorrosion coating and preparation method thereof |
| CN108117802A (en) * | 2017-12-28 | 2018-06-05 | 安徽鑫铂铝业股份有限公司 | A kind of corrosion-resistant heronsbill aluminium alloy extrusions |
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Application publication date: 20190201 |
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