CN109294196A - A kind of septic tank glass-reinforced plastic material - Google Patents
A kind of septic tank glass-reinforced plastic material Download PDFInfo
- Publication number
- CN109294196A CN109294196A CN201811268359.1A CN201811268359A CN109294196A CN 109294196 A CN109294196 A CN 109294196A CN 201811268359 A CN201811268359 A CN 201811268359A CN 109294196 A CN109294196 A CN 109294196A
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- Prior art keywords
- parts
- glass
- reinforced plastic
- plastic material
- septic tank
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of septic tank glass-reinforced plastic material, raw material includes: 50-70 parts of resin, 30-50 parts of glass fabric by weight, 10-20 parts of composite fibre, 15-25 parts of filler, 2-4 parts of dioctyl phthalate, 1-2 parts of cyclohexanone peroxide, 1-2 parts of ethylenediamine, 0.5-1.5 parts of cobalt naphthenate, 1-2 parts of Si69,1-2 parts of anti-aging agent, wherein, resin includes unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral.Intensity of the present invention is high, good toughness.
Description
Technical field
The present invention relates to glass fibre reinforced plastics technology field more particularly to a kind of septic tank glass-reinforced plastic materials.
Background technique
Glass reinforced plastic is also known as fiber-reinforced plastic, refers generally to glass fiber reinforcement unsaturated polyester, epoxy resin and phenolic aldehyde
Resin matrix.It is divided into glass fiber reinforced composite plastics, fibre reinforced composite plastic, boron fibre according to the fiber difference of use
Enhance composite plastic etc..It is using glass fibre and its product (glass cloth, band, felt, yarn etc.) as reinforcing material, to synthesize tree
Rouge makees a kind of composite material of basis material.Fibre reinforced composites are made of reinforcing fiber and matrix.Glass reinforced plastic has
High-strength light, the advantages that corrosion-resistant, hot property is good, craftsmanship is excellent, but glass steel brittleness is bad, needs to improve.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of septic tank glass-reinforced plastic material, the present invention
Intensity is high, good toughness.
A kind of septic tank glass-reinforced plastic material proposed by the present invention, raw material include: 50-70 parts of resin by weight, glass
30-50 parts of glass fiber cloth, 10-20 parts of composite fibre, 15-25 parts of filler, 2-4 parts of dioctyl phthalate, peroxidating hexamethylene
1-2 parts of ketone, 1-2 parts of ethylenediamine, 0.5-1.5 parts of cobalt naphthenate, 1-2 parts of Si69,1-2 parts of anti-aging agent, wherein resin includes not
Saturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral.
Preferably, glass fabric surface is coated with γ-methacryloxypropyl trimethoxy silane.
Preferably, filler is modified montmorillonoid, silane coupler modified magnesium hydroxide and modified carbon nano-tube.
Preferably, modified carbon nano-tube is γ-glycidyl ether oxygen propyl trimethoxy silicane graft modification carboxylated
Carbon nanotube.
Preferably, modified montmorillonoid is the montmorillonite of cetyl trimethylammonium bromide intercalation modifying.
Preferably, composite fibre is glass fibre, basalt fibre.
Preferably, unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral weight ratio be 10:6-
7:3-5:0.1-0.5.
Preferably, the weight ratio of modified montmorillonoid, silane coupler modified magnesium hydroxide and modified carbon nano-tube is 6-10:
6-10:1-2.
Preferably, glass fibre, basalt fibre weight ratio be 1-2:3-4.
Preferably, anti-aging agent is antioxidant 264, antioxidant 4010NA.
It is of the invention the preparation method comprises the following steps: by resin, composite fibre, filler, dioctyl phthalate, peroxidating hexamethylene
Ketone, ethylenediamine, cobalt naphthenate, Si69, anti-aging agent are uniformly mixed so as to obtain slurry；In the mold for being coated with release agent, one layer of slurry is first smeared
Material, then tile on slurry glass fabric, is laid with according to one layer of slurry layer of glass cloth interval to required thickness,
Then solidify, demoulding obtains septic tank glass-reinforced plastic material.
The present invention selects unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral to cooperate, can
To improve toughness of the invention, so that the present invention while having high-intensitive, has good toughness, improve of the invention crisp
Property；Unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral can be into one with proper ratio mutual cooperation
Step increases toughness of the invention；γ-methacryloxypropyl trimethoxy silane is coated on glass fabric surface, so that
Glass fibre can come into full contact with unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral, less seam
Gap to further increase intensity and toughness of the invention, and introduces carbon-carbon double bond in fiberglass surfacing, can be with insatiable hunger
It is condensed with the carbon-carbon double bond on polyester resin, so that resin is closely connect with glass fabric, greatly increases this hair
Bright toughness and intensity；In addition the montmorillonite of cetyl trimethylammonium bromide intercalation modifying, silane coupler modified magnesium hydroxide,
γ-glycidyl ether oxygen propyl trimethoxy silicane graft modification carboxylic carbon nano-tube, glass fibre, basalt fibre phase
Mutually cooperation, so that filler and fiber may be uniformly dispersed in resin, and resin energy intercalation is in montmorillonite, many kinds of substance phase
Mutually cooperation, and interact with glass fabric, to greatly increase toughness of the invention and be able to maintain intensity of the invention；And
Silane coupler modified magnesium hydroxide can increase anti-flammability of the invention；Dioctyl phthalate can further adjust this
The toughness and intensity of invention；Cyclohexanone peroxide, ethylenediamine, cobalt naphthenate are cooperated with proper ratio, so that resin is crosslinked
Solidification, further increases toughness of the invention；Si69 promotes each substance evenly dispersed；Anti-aging agent increases ageing resistance of the invention
Energy.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of septic tank glass-reinforced plastic material, raw material include: 60 parts of resin by weight, 40 parts of glass fabric, are mixed
15 parts of condensating fiber, 20 parts of filler, 3 parts of dioctyl phthalate, 1.5 parts of cyclohexanone peroxide, 1.5 parts of ethylenediamine, aphthenic acids
1 part of cobalt, 1.5 parts of Si69,1.5 parts of anti-aging agent, wherein resin includes unsaturated polyester resin, gel coating resin, epoxy resin, gathers
Vinyl butyral.
Embodiment 2
A kind of septic tank glass-reinforced plastic material, raw material include: 50 parts of resin by weight, 50 parts of glass fabric, are mixed
10 parts of condensating fiber, 25 parts of filler, 2 parts of dioctyl phthalate, 2 parts of cyclohexanone peroxide, 1 part of ethylenediamine, cobalt naphthenate 1.5
Part, 1 part of Si69,2 parts of anti-aging agent, wherein resin includes unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl alcohol
Butyral；
Glass fabric surface is coated with γ-methacryloxypropyl trimethoxy silane；
Filler is the montmorillonite of cetyl trimethylammonium bromide intercalation modifying, silane coupler modified magnesium hydroxide and γ-
The carboxylic carbon nano-tube of glycidyl ether oxygen propyl trimethoxy silicane graft modification；
Composite fibre is glass fibre, basalt fibre.
Embodiment 3
A kind of septic tank glass-reinforced plastic material, raw material include: 70 parts of resin by weight, 30 parts of glass fabric, are mixed
20 parts of condensating fiber, 15 parts of filler, 4 parts of dioctyl phthalate, 1 part of cyclohexanone peroxide, 2 parts of ethylenediamine, cobalt naphthenate 0.5
Part, 2 parts of Si69,1 part of anti-aging agent, wherein resin includes unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl alcohol
Butyral, wherein unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral weight ratio be 10:7:3:
0.5；
Glass fabric surface is coated with γ-methacryloxypropyl trimethoxy silane；
Filler is the montmorillonite of cetyl trimethylammonium bromide intercalation modifying, silane coupler modified magnesium hydroxide and γ-
The carboxylic carbon nano-tube of glycidyl ether oxygen propyl trimethoxy silicane graft modification, wherein cetyl trimethyl bromination
The montmorillonite of ammonium intercalation modifying, silane coupler modified magnesium hydroxide and γ-glycidyl ether oxygen propyl trimethoxy silicane grafting
The weight ratio of modified carboxylic carbon nano-tube is 6:10:1；
Composite fibre be glass fibre, basalt fibre, wherein glass fibre, basalt fibre weight ratio be 2:3；
Anti-aging agent is antioxidant 264, antioxidant 4010NA.
Embodiment 4
A kind of septic tank glass-reinforced plastic material, raw material include: 55 parts of resin by weight, 45 parts of glass fabric, are mixed
12 parts of condensating fiber, 23 parts of filler, 2.5 parts of dioctyl phthalate, 1.8 parts of cyclohexanone peroxide, 1.3 parts of ethylenediamine, cycloalkanes
1.2 parts of sour cobalt, 1.3 parts of Si69,1.7 parts of anti-aging agent, wherein resin includes unsaturated polyester resin, gel coating resin, asphalt mixtures modified by epoxy resin
Rouge, polyvinyl butyral, wherein the weight of unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral
Than for 10:6:5:0.1；
Glass fabric surface is coated with γ-methacryloxypropyl trimethoxy silane；
Filler is the montmorillonite of cetyl trimethylammonium bromide intercalation modifying, silane coupler modified magnesium hydroxide and γ-
The carboxylic carbon nano-tube of glycidyl ether oxygen propyl trimethoxy silicane graft modification, wherein cetyl trimethyl bromination
The montmorillonite of ammonium intercalation modifying, silane coupler modified magnesium hydroxide and γ-glycidyl ether oxygen propyl trimethoxy silicane grafting
The weight ratio of modified carboxylic carbon nano-tube is 10:6:2；
Composite fibre be glass fibre, basalt fibre, wherein glass fibre, basalt fibre weight ratio be 1:4；
Anti-aging agent is antioxidant 264, antioxidant 4010NA.
Embodiment 5
A kind of septic tank glass-reinforced plastic material, raw material include: 65 parts of resin by weight, 35 parts of glass fabric, are mixed
18 parts of condensating fiber, 17 parts of filler, 3.5 parts of dioctyl phthalate, 1.2 parts of cyclohexanone peroxide, 1.7 parts of ethylenediamine, cycloalkanes
0.8 part of sour cobalt, 1.7 parts of Si69,1.3 parts of anti-aging agent, wherein resin includes unsaturated polyester resin, gel coating resin, asphalt mixtures modified by epoxy resin
Rouge, polyvinyl butyral, wherein the weight of unsaturated polyester resin, gel coating resin, epoxy resin, polyvinyl butyral
Than for 10:6.5:4:0.3；
Glass fabric surface is coated with γ-methacryloxypropyl trimethoxy silane；
Filler is the montmorillonite of cetyl trimethylammonium bromide intercalation modifying, silane coupler modified magnesium hydroxide and γ-
The carboxylic carbon nano-tube of glycidyl ether oxygen propyl trimethoxy silicane graft modification, wherein cetyl trimethyl bromination
The montmorillonite of ammonium intercalation modifying, silane coupler modified magnesium hydroxide and γ-glycidyl ether oxygen propyl trimethoxy silicane grafting
The weight ratio of modified carboxylic carbon nano-tube is 8:8:1.5；
Composite fibre be glass fibre, basalt fibre, wherein glass fibre, basalt fibre weight ratio be 1.5:
3.5；
Anti-aging agent is antioxidant 264, antioxidant 4010NA.
The performance of embodiment 1-5 is detected, as a result as follows:
As can be seen from the above table, intensity of the present invention is high, good toughness.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of septic tank glass-reinforced plastic material, which is characterized in that its raw material includes: 50-70 parts of resin by weight, glass fibers
Cloth 30-50 parts of dimension, 10-20 parts of composite fibre, 15-25 parts of filler, 2-4 parts of dioctyl phthalate, cyclohexanone peroxide 1-2
Part, 1-2 parts of ethylenediamine, 0.5-1.5 parts of cobalt naphthenate, 1-2 parts of Si69,1-2 parts of anti-aging agent, wherein resin includes unsaturated poly-
Ester resin, gel coating resin, epoxy resin, polyvinyl butyral.
2. septic tank glass-reinforced plastic material according to claim 1, which is characterized in that glass fabric surface is coated with γ-
Methacryloxypropyl trimethoxy silane.
3. septic tank glass-reinforced plastic material according to claim 1 or claim 2, which is characterized in that filler is modified montmorillonoid, silane
Coupling agent modified magnesium hydroxide and modified carbon nano-tube.
4. septic tank glass-reinforced plastic material according to claim 3, which is characterized in that modified carbon nano-tube is that γ-shrink is sweet
The carboxylic carbon nano-tube of oily ether oxygen propyl trimethoxy silicane graft modification.
5. according to the septic tank glass-reinforced plastic material of claim 3 or 4, which is characterized in that modified montmorillonoid is cetyl
Trimethylammonium bromide intercalation modifying montmorillonite.
6. any one of -5 septic tank glass-reinforced plastic material according to claim 1, which is characterized in that composite fibre is glass fibers
Dimension, basalt fibre.
7. any one of -6 septic tank glass-reinforced plastic material according to claim 1, which is characterized in that unsaturated polyester resin,
Gel coating resin, epoxy resin, polyvinyl butyral weight ratio be 10:6-7:3-5:0.1-0.5.
8. according to any one of the claim 3-7 septic tank glass-reinforced plastic material, which is characterized in that modified montmorillonoid, silane
The weight ratio of coupling agent modified magnesium hydroxide and modified carbon nano-tube is 6-10:6-10:1-2.
9. according to any one of the claim 6-8 septic tank glass-reinforced plastic material, which is characterized in that glass fibre, basalt
The weight ratio of fiber is 1-2:3-4.
10. any one of -9 septic tank glass-reinforced plastic material according to claim 1, which is characterized in that anti-aging agent is anti-aging agent
264, antioxidant 4010NA.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811268359.1A CN109294196A (en) | 2018-10-29 | 2018-10-29 | A kind of septic tank glass-reinforced plastic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811268359.1A CN109294196A (en) | 2018-10-29 | 2018-10-29 | A kind of septic tank glass-reinforced plastic material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109294196A true CN109294196A (en) | 2019-02-01 |
Family
ID=65159093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811268359.1A Pending CN109294196A (en) | 2018-10-29 | 2018-10-29 | A kind of septic tank glass-reinforced plastic material |
Country Status (1)
| Country | Link |
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| CN (1) | CN109294196A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110408185A (en) * | 2019-07-11 | 2019-11-05 | 安徽金九鼎复合材料有限公司 | A kind of high-strength low-temperature-resistant glass reinforced plastic and preparation method thereof |
| CN110791092A (en) * | 2019-11-05 | 2020-02-14 | 苏州金螳螂文化发展股份有限公司 | Glass fiber reinforced plastic material for embossment molding and preparation method thereof |
| CN112794954A (en) * | 2019-11-14 | 2021-05-14 | 邵阳千两新型环保建材有限公司 | Heat-resistant glass fiber reinforced plastic material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110408185A (en) * | 2019-07-11 | 2019-11-05 | 安徽金九鼎复合材料有限公司 | A kind of high-strength low-temperature-resistant glass reinforced plastic and preparation method thereof |
| CN110791092A (en) * | 2019-11-05 | 2020-02-14 | 苏州金螳螂文化发展股份有限公司 | Glass fiber reinforced plastic material for embossment molding and preparation method thereof |
| CN112794954A (en) * | 2019-11-14 | 2021-05-14 | 邵阳千两新型环保建材有限公司 | Heat-resistant glass fiber reinforced plastic material |
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Application publication date: 20190201 |
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